Physical Sciences and Mathematics Commons^™

Evaluation Of Fluorapatite As A Waste-Form Material, Dennis W. Lindle, Oliver Hemmers, Dale L. Perry

Separations Campaign (TRP)

Argonne National Laboratory has proposed a new extraction procedure to handle TRISO-coated fuels, the Fluoride Extraction Process, or FLEX. The FLEX process is designed to separate the uranium in the fuel from the actinides and most fission products by taking advantage of the unique properties of uranium hexafluoride (UF₆). In the FLEX process, the used TRISO fuel is reacted with zirconium fluoride salt, forming UF₆ and the fluoride salts of the actinides and fission products. At process temperatures, the UF₆ volatizes into a gas, and is released from the molten salt mixture. This leaves behind the …

Development Of Integrated Process Simulation System Model For Spent Fuel Treatment Facility (Sftf) Design, Yitung Chen, Sean Hsieh

Separations Campaign (TRP)

The overall goal of this project is the creation of a framework that combines all the strengths of AMUSE’s complicated calculations, well-established commercial system process packages, and TRPSEMPro’s flexible parameter optimization modules. Development of the process simulation code can be done using the solvent extraction process at Argonne National Laboratory in collaboration with the UNLV Nevada Center for Advanced Computational Methods.

The major objectives are the following:

• Develop a framework for simulating the Spent Fuel Treatment Facility (SFTF) process using AMUSE code, commercial process package, such as ASPEN-PLUS, and system engineering model.
• Develop a middleware package that can communicate between …

Electrochemical Separation Of Curium And Americium, David W. Hatchett, Kenneth Czerwinski

Separations Campaign (TRP)

The objective of this project is to use electrochemical techniques to develop a thermodynamic understanding of actinide and lanthanide species in aqueous solution and use this data to effectively separate species with very similar chemical properties. In consultation with a national laboratory collaborators, electrochemical methods and materials will be evaluated and used to exploit the thermodynamic differences between similar chemical species enhancing the ability to selectively target and sequester individual species from mixtures. This project is in its third year and has successfully completed Phases 1 and 2.

The following were specific goals for this year:

• To develop a fundamental …

Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System, Kenneth Czerwinski, Byron Bennett

Separations Campaign (TRP)

The research objectives of this project are as follows:

• To determine the influence of nitrate on the speciation of U and Pu in the TBP-dodecane-nitric acid system. The aqueous and organic speciation of U and Pu are examined as a function of the nitric acid concentration, nitrate concentration (by the addition of NaNO₃), actinide ion concentration, temperature, and time.
• To determine the speciation of U and Pu with AHA in the presence and absence of TBP-dodecane organic phase. The aqueous and organic speciation of U and Pu are evaluated as a function of AHA concentration, metal ion concentration, …

Bomb-Pulse Chlorine-36 At The Proposed Yucca Mountain Repository Horizon: An Investigation Of Previous Conflicting Results And Collection Of New Data, James Cizdziel, Amy J. Smiecinski

Publications (YM)

Previous studies by scientists at Los Alamos National Laboratory (LANL) found elevated ratios of chlorine-36 to total chloride (36C1/C1) in samples of rock collected from the Exploratory Studies Facility (ESF) and the Enhanced Characterization of the Repository Block (ECRB) at Yucca Mountain as the tunnels were excavated. The data were interpreted as an indication that fluids containing "bomb-pulse" 36C1 reached the repository horizon in the -50 years since the peak period of above-ground nuclear testing. Moreover, the data support the concept that so-called fast pathways for infiltration not only exist but are active, possibly through a combination of porous media, …

Isothermal Titration Calorimetry And Transmission Electron Microscopy Of Main-Chain Viologen Polymer Containing Bromide As Counerions, Pradip K. Bhowmik, Marcos A. Cheney, Haesook Han, Longzhou Ma

Transmission Electron Microscope

Polyelectrolytes are an important class of macromolecules that contain dissociable ionic groups. When introduced into polar solvent, usually the universal solvent water, dissociation takes place so that electrically charged macromolecule is suspended in solution. The electrostatic interaction is operative between ionized groups inside the macromolecule, between the macromolecules, between the counterions, and between the macromolecule and counterion. Since this interaction is characterized by its long-range nature, the solution exhibits various interesting properties including the polyelectrolyte behavior very different from solutions of neutral polymers.

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 1st Quarterly Report, 2006, Clemens Heske

Fuels Campaign (TRP)

This project is devoted to an in-depth study of the chemical and electronic impact of metal fission products on the coating layers in TRISO nuclear fuel. In particular, there is a focus on the investigation of Pd, Cs, and Ag and their interface formation with SiC and carbon-based substrates. A variety of surface and near-surface bulk sensitive probes that investigate the occupied and unoccupied electronic states of the substrate and the metal overlayer have been utilized. By a controlled and stepwise deposition of the metal overlayer, it is possible to gain substantial insight into the formation of interfaces and their …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

In this project the chemical bonding and interface formation of metal fission products with the coating materials used in TRISO fuel particles is investigated. The interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon is studied in detail. Using the SiC single crystals and TRISO coating materials as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied with a photoelectron spectroscopy, Auger electron spectroscopy, Inverse Photoemission, X-ray emission spectroscopy, and X-ray absorption spectroscopy. Recent additions to the experimental approach include microscopic techniques (Transmission Electron Microscopy, Scanning Tunneling Microscopy, Atomic Force Microscopy) …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

The safe and effective manufacturing of actinide-bearing fuels for any transmutation strategy requires that the entire manufacturing process be contained within a shielded hot cell environment. To ensure that the fabrication process is feasible, the entire process must be designed for remote operation. The equipment must be reliable enough to perform over several decades, and also easy to maintain or repair remotely. The facility must also be designed to facilitate its own decontamination and decommissioning. In addition to these design factors, the potential viability of any fuel fabrication process will also be impacted by a number of variables, such as …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project examines inert fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations are used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of ²³⁹Pu. Ceramics are synthesized and characterized based on the reactor physics results. The solubility of the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, are investigated in a manner to provide thermodynamic data necessary for …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Thomas Hartmann

Fuels Campaign (TRP)

Advanced Fuel Cycle Initiative research on transmutation fuels includes mono-nitride ceramic fuel forms, and consists of closely coordinated “hot” actinide and “cold” inert and surrogate fuels work. Matrix and surrogate materials work involves three major components: (1) fuel matrix synthesis and fabrication, (2) fuel performance, and (3) fuel materials modeling. The synthesis and fabrication component supports basic material studies, as well as actinide fuel fabrication work through fuel fabrication process development. Fuel performance studies are examining the tolerance of nitride-type fuel to heavy irradiation damage. The fuel materials simulation work involves both atomistic and continuum scale modeling employing first principles, …

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Thomas Hartmann

Fuels Campaign (TRP)

A wide variety of fuel concepts are considered for advanced reactor technology including metals, metal oxides or metal nitrides as solid solutions or composite materials. Nitride fuels have appropriate properties for advanced fuels including high thermal conductivity, thermal stability, solid-state solubility of actinides, fissile metal density, and suitable neutronic properties. A drawback of nitride fuels involves their synthesis. A key parameter for preparing oxide fuels is the precipitation step in the sol-gel process. For nitride fuels, the current synthetic route is carbothermic reduction from the oxide to the nitride. This process step is based on solid phase reactions and for …

A Study Of Environmental Justice In Relation To Air Pollution And Income, Christian A. Malveaux

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this paper is come to a conclusion on whether or not air pollution and income levels are connected. There is an ongoing pollution problem in Las Vegas. The question that will be attempted to answer in this is paper is: Is there a difference in the amount of air pollution in affluent parts of the Las Vegas Valley and the less affluent parts of the valley? Information and data regarding air pollution is gathered from the Clark County website and other literature. Information on income levels is gathered from journals and literature pertinent to the subject and …

A Chloride Selective Calix[4]Arene Optical Sensor Combining Urea Functionality With Pyrene Excimer Transduction, Benjamin Schazmann, Dermot Diamond

Articles

A neutral 2-site chloride selective compound has been developed (3), based on a 1,3- alternate tetrasubstituted calix[4]arene providing a preorganised supramolecular scaffold. The resultant supramolecular cavity is amongst the first to combine urea functional groups bridged with single methylene spacers to pyrene moieties. It combines a naturally and synthetically proven H-bonding system with the elegant ratiometric fluorescent signalling properties of an intramolecular pyrene excimer system, triggered by conformational changes upon anion coordination. The excimer emission of 3 is quenched, with a simultaneous rise in the monomer emission solely by the chloride anion amongst a wide variety of anions tested. 3 …

Existence Of Optimal Controls For Singular Control Problems With State Constraints, Amarjit Budhiraja, Kevin Ross

Statistics

We establish the existence of an optimal control for a general class of singular control problems with state constraints. The proof uses weak convergence arguments and a time rescaling technique. The existence of optimal controls for Brownian control problems, associated with a broad family of stochastic networks, follows as a consequence.

Prediction In The Panel Data Model With Spatial Correlation: The Case Of Liquor, Badi H. Baltagi, Dong Li

Center for Policy Research

This paper considers the problem of prediction in a panel data regression model with spatial autocorrelation in the context of a simple demand equation for liquor. This is based on a panel of 43 states over the period 1965-1994. The spatial autocorrelation due to neighboring states and the individual heterogeneity across states is taken explicitly into account. We compare the performance of several predictors of the states demand for liquor for one year and five years ahead. The estimators whose predictions are compared include OLS, fixed effects ignoring spatial correlation, fixed effects with spatial correlation, random effects GLS estimator ignoring …

On The Existence Of Infinitely Many Closed Geodesics On Orbifolds Of Revolution, Joseph Borzellino, Christopher R. Jordan-Squire, Gregory C. Petrics, D. Mark Sullivan

Mathematics

Using the theory of geodesics on surfaces of revolution, we introduce the period function. We use this as our main tool in showing that any two-dimensional orbifold of revolution homeomorphic to S2 must contain an infinite number of geometrically distinct closed geodesics. Since any such orbifold of revolution can be regarded as a topological two-sphere with metric singularities, we will have extended Bangert’s theorem on the existence of infinitely many closed geodesics on any smooth Riemannian two-sphere. In addition, we give an example of a two-sphere cone-manifold of revolution which possesses a single closed geodesic, thus showing that Bangert’s result …

Lsuhsc Facilities Biweekly Update: January 2006, Lsuhsc Property And Facilities Management

LSUHSC Facilities Biweekly Updates: 2006

LSUHSC Facilities Biweekly Updates from January 13 and 27, 2006.

These updates describe damage and a timeline of repairs at the LSU Health Sciences Center - New Orleans campus due to Hurricane Katrina which made landfall August 29, 2005.

Lsuhsc Facilities Daily Update: January 2006, Lsuhsc Property And Facilities Management

LSUHSC Facilities Daily Updates: 2006

LSUHSC Dailly Facilities Updates from January 2006. These updates describe damage and a timeline of repairs at the LSU Health Sciences Center - New Orleans campus due to Hurricane Katrina which made landfall August 29, 2005.

Brittle Compressive Failure Of Ice: Proportional Straining Vs Proportional Loading, E. M. Schulson, D. Iliescu

Dartmouth Scholarship

Proportional straining experiments have been performed on columnar-grained S2 fresh- water ice biaxially compressed across the columns at –108C at a strain rate of (4.5 􏰀 1.5) 􏰁 10–3 s–1. The results are compared with those obtained earlier (Iliescu and Schulson, 2004) from the same kind of material deformed to terminal failure under the same conditions, but through proportional loading. The exercise shows that the biaxial strength is practically independent of the path taken, at least under low confinement where Coulombic shear faulting limits terminal failure. First-year sea ice is expected to exhibit the same behavior.

Vector Theory Of Spontaneous Lorentz Violation, Shu Hong Fung

Honors Theses

Classical electromagnetism predicts two massless propagating modes, which are known as the two polarizations of the photon. On the other hand, if the Lorentz symmetry of classical electromagnetism is spontaneously broken, the new theory will still have two massless Nambu-Goldstone modes resembling the photon. If the Lorentz symmetry is broken by a bumblebee potential that allows for excitations out of the minimum, then massive modes arise. Furthermore, in curved spacetime, such massive modes will be created through a process other than the usual Higgs mechanism because of the dependence of the bumblebee potential on both the vector field and the …

Near-Infrared Observations Of Comet-Asteroid Transition Objects, Julie Elaine Ziffer

Electronic Theses and Dissertations

The primary objective of this research is to characterize the surface composition of five comet-asteroid transition objects via near-infrared spectroscopy. The five targets include two asteroids with Tisserand invariants lower than 3.0 (1373 Cincinnati and 2906 Caltech), one asteroid that is likely an extinct comet (944 Hidalgo), one intermittent activity comet (162P/Siding Spring), and one nearly dormant comet (28P/Neujmin1). Previous research regarding cometary end states and dynamical and physical properties of comets and asteroids provides the foundation for this work. Focusing primarily on the 1-2.5 µm spectral region of the five target objects, this project specifically searches for mineral species …

Environmental Awareness Of Waterville Junior High School Students, Jenna Morrison

Honors Theses

An environmental awareness survey was designed to assess the influences of gender and grade level on the relationships among outdoor experience, environmental knowledge, and environmental behavior at Waterville Junior High School, Waterville, ME. Environmental awareness indicates a fundamental understanding of the natural world, which is essential for developing future sustainable development. The foundation and acquisition of environmental knowledge of Waterville Junior High School students was determined using the multiple-choice survey. A total of 125 sixth graders and 136 eighth graders were surveyed. 61% of sixth graders and 73% of eighth graders indicated that their most common source of environmental information …

Discovery Of Outlying High-Velocity Oxygen-Rich Ejecta In Cassiopeia A, Robert A. Fesen, Molly C. Hammell, Jon Morse, Roger A. Chevalier, Kazimierz J. Borkowski, Michael A. Dopita, Christopher L. Gerardy, Stephen S. Lawrence, John C. Raymond, Sydney Van Den Bergh

Dartmouth Scholarship

Analysis of broadband HST ACS and WFPC2 images of the young Galactic supernova remnant Cassiopeia A reveals a far larger population of outlying, high-velocity knots of ejecta with a broader range of chemical properties than previously suspected. ACS filte r flux ratios along with follow-up, ground-based spectra are used to investigate some of the kinema tic and chemical properties of these outermost ejecta. In this paper, we concentrate on a ≃ 1.5 sq arcmin region located along the eastern limb of the remnant where numerous outer emission knots are optica lly visible due to an interaction with a local circumstellar …

Comments On The Mechanism Of Aging Of Antimony Doped Tin Oxide Based Electrochromic Devices, Joo C. Chan, Nicole A. Hannah, Shankar B. Rananavare, Laura Yeager, Liviu Dinescu, Ashok Saraswat, Pradeep Iyer, James P. Coleman

Chemistry Faculty Publications and Presentations

Electrochromic effects of antimony doped tin oxide (ATO) nanoparticles are investigated to probe device yellowing (degradation). Voltage vs contrast ratio curves exhibit hysteresis, i.e., image-sticking phenomena due to irreversible charge insertion. X-ray, impedance and optical b* studies suggest that the yellowing/charge trapping is nanoparticle size-dependent with 4 nm size particles exhibiting the least yellowing. Yellowing results in increased impedances of electrode–electrolyte interface and electrode corrosion. Plausible sources of discoloration are formation of insulating complex alkali oxide film, carrier inversion (n-to-p type) through electrochemical Li doping, redeposition of the corroded electrode material and perhaps residual concentration of charge-transfer species.

Two Way Diffusion Model For The Recording Mechanism In A Self-Developing Dry Acrylamide Photopolymer, Suzanne Martin, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Vincent Toal

Conference Papers

In our most recent study [1] diffusion constants were measured in the simplified monoacrylamide version of a dry acrylamide based photopolymer holographic recording material developed in the Centre for Industrial and Engineering Optics. In this paper we report diffusion constants for the commonly used photopolymer formulation, which also contains the crosslinker bisacrylamide. A physical model for the recording mechanism is proposed which explains the two way diffusion observed in both systems, and is in agreement with much of the previously observed behaviour of the material, particularly in regard to dependence of diffraction efficiency growth on spatial frequency and persistence of …

On The Use Of Gaussian Filter Functions For Adaptive Optics, Merfit Assad

Electronic Theses and Dissertations

For adaptive optic systems, the use of aperture filter functions calculated using various Zernike modes can be useful in removing lower-order aberrations caused by atmospheric turbulence. Traditionally, these filter functions are calculated using the step function depicting a hard aperture that introduces integrals that are sometimes difficult to integrate and must be done numerically. The Gaussian method can be used in place of the conventional method for calculating the aperture filter functions. Evaluation of the Gaussian approximation for modeling a finite receiver aperture can be made by comparison of reduction in phase variance with results achieved using the conventional method. …

Analytical Potential Of Polymerized Liposomes Bound To Lanthanide Ions For Qualitative And Quantitative Analysis Of Proteins, Marina Santos

Electronic Theses and Dissertations

One of the intriguing features of biological systems is the prevalence of highly selective and often very strong interactions among different cellular components. Such interactions play a variety of organizational, mechanical, and physiological roles at the cellular and organism levels. Antigen-antibody complexes are representative examples of highly selective and potent interactions involving proteins. The marked specificity of protein-antibody complexes have led to a wide range of applications in cellular and molecular biology related research. They have become an integral research tool in the present genomic and proteomic era. Unfortunately, the production of selective tools based on antigen-antibody interactions requires cumbersome …

Design And Optimization Of Nano-Optical Elements By Coupling Fabrication To Optical Behavior, Raymond Rumpf

Electronic Theses and Dissertations

Photonic crystals and nanophotonics have received a great deal of attention over the last decade, largely due to improved numerical modeling and advances in fabrication technologies. To this day, fabrication and optical behavior remain decoupled during the design phase and numerous assumptions are made about "perfect" geometry. As research moves from theory to real devices, predicting device behavior based on realistic geometry becomes critical. In this dissertation, a set of numerical tools was developed to model micro and nano fabrication processes. They were combined with equally capable tools to model optical performance of the simulated structures. Using these tools, it …

Predicting Surface Scatter Using A Linear Systems Formulation Of Non-Paraxial Scalar Diffraction, Andrey Krywonos

Electronic Theses and Dissertations

Scattering effects from rough surfaces are non-paraxial diffraction phenomena resulting from random phase variations in the reflected wavefront. The ability to predict these effects is important in a variety of applications including x-ray and EUV imaging, the design of stray light rejection systems, and reflection modeling for rendering realistic scenes and animations of physical objects in computer graphics. Rayleigh-Rice (small perturbation method) and Beckmann-Kirchoff (Kirchhoff approximation) theories are commonly used to predict surface scatter effects. In addition, Harvey and Shack developed a linear systems formulation of surface scatter phenomena in which the scattering behavior is characterized by a surface transfer …