Physical Sciences and Mathematics Commons^™

Belowground Biomass Of Spartina Alterniflora: Seasonal Variability And Response To Nutrients, Faith Armand Darby

LSU Doctoral Dissertations

Spartina alterniflora is a salt marsh macrophyte found from Canada to the Gulf of Mexico which often provides the dominant plant cover. Although S. alterniflora is well known for its high aboveground productivity, fifty to ninety percent of the total plant production occurs belowground. No previous studies address the seasonal variation of belowground biomass or the response of above-and belowground biomass to nutrients at the southern limits of its U. S. range. The objectives of this study were to: 1) document the seasonal variability of its above- and belowground biomass and test for responses to various combinations of N, P, …

Effective Bootstrapping Of Peer-To Peer Networks Over Mobile Ad-Hoc Networks, Wei Ding

LSU Doctoral Dissertations

Mobile Ad-hoc Networks (MANETs) and Peer-to-Peer (P2P) networks are vigorous, revolutionary communication technologies in the 21st century. They lead the trend of decentralization. Decentralization will ultimately win clients over client/server model, because it gives ordinary network users more control, and stimulates their active participation. It is a determinant factor in shaping the future of networking. MANETs and P2P networks are very similar in nature. Both are dynamic, distributed. Both use multi-hop broadcast or multicast as major pattern of traffic. Both set up connection by self-organizing and maintain connection by self-healing. Embodying the slogan "networking without networks," both abandoned traditional client/server …

Structural Characterization Of Poly(Heterocycles) Formed Using Oxidative Methods, Rebecca Marie Brauch

LSU Doctoral Dissertations

This research focused on elucidation of structural information for conducting polymer systems using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS). The structure of conducting polymer systems has been found to directly influence their physical properties. Poly(pyrrole) and poly(thiophene) are two of the most widely studied conducting polymers due to their high electrical conductivity, stability in the doped state, low toxicity, and current/potential applications. The purpose of this research was to apply MALDI-TOF MS to heterocyclic conducting polymers, specifically those of pyrrole and thiophene, to investigate structural properties of these polymers, with the specific aim of determining end group and …

Multianalyte Detection Of Breast Cancer By Fabrication Of Hybridmicroarrays On Polymer-Based Microanalytical Devices, Suying Wei

LSU Doctoral Dissertations

Breast cancer is one of the most common and fatal cancer diseases that affect women worldwide. As is true with most other cancer diseases, early detection of breast cancer is very crucial for proper medical treatment because treatment of advanced breast cancer will be much more difficult and inconsistent. Screening and testing of breast cancer biomarkers, either genetic or proteomic, are among techniques used for diagnosis of breast cancers. Nevertheless, none of the biomarkers is by itself sensitive and selective enough for diagnosis of breast cancer, and thus, multi-analyte assays towards detection of multiple breast cancer biomarkers from different classes …

Ontology-Based Methodology For Error Detection In Software Design, Allyson M. Hoss

LSU Doctoral Dissertations

Improving the quality of a software design with the goal of producing a high quality software product continues to grow in importance due to the costs that result from poorly designed software. It is commonly accepted that multiple design views are required in order to clearly specify the required functionality of software. There is universal agreement as to the importance of identifying inconsistencies early in the software design process, but the challenge is how to reconcile the representations of the diverse views to ensure consistency. To address the problem of inconsistencies that occur across multiple design views, this research introduces …

Two-Dimensional And High-Throughput Electrophoretic Separation Of Proteins Using Polymeric Microchips, Hamed Shadpour

LSU Doctoral Dissertations

A major task in proteomics is to identify proteins from a biological sample using two-dimensional (2-D) separation prior to mass spectrometry of peptides generated via proteolytic digestion of the proteins. For 2-D separations, microfluidic devices are superior to bench top and capillary-based systems since they potentially provide higher separation efficiencies due to the minimal dead volumes produced during peak transfer between the two separation dimensions. In addition, fast separations can be envisioned because the column lengths are typically shorter in microfluidic platforms without scarifying peak capacity. High-throughput capabilities are extremely desirable for many types of bio-analytical analyses, such as understanding …

Simulated Domain Wall Dynamics In Magnetic Nanowires, Andrew Kunz

Physics Faculty Research and Publications

The simulated domain wall dynamics in rectangular 10 nm thick, 2000 nm long Permalloy wires of varying width is presented. In the absence of an applied field the static domain wall length is found to be linearly dependent to the width of the nanowire. As magnetic fields of increasing strength are applied along the wire’s long axis, the domain wall motion changes from a uniform reversal to a steplike reversal. The onset of the stepping motion leads to a decrease in the domain wall speed. By continuing to increase the field it is possible to decrease the time between steps …

Synthetic Studies Directed Toward The Proposed Structure For Heteroscyphic Acid A, Subhabrata Chaudhury, Shukun Li, William A. Donaldson

Chemistry Faculty Research and Publications

A route to the carbon skeleton of the proposed structure for heteroscyphic acid A was developed utilizing a Mn(III)/Cu(II) mediated oxidative free-radical cyclization and nucleophilic addition to (3-methylpentadienyl)iron(1+) cation.

Thermal And Flame Properties Of Polyethylene And Polypropylene Nanocomposites Based On An Oligomerically–Modified Clay, Jinguo Zhang, David D. Jiang, Charles A. Wilkie

Chemistry Faculty Research and Publications

An oligomerically-modified clay was made using a surfactant which is the ammonium salt of an oligomer. The newly modified clay contains 37.5% inorganic clay and 62.5% oligomer. Polyethylene and polypropylene nanocomposites were made by melt blending the polymer with the oligomerically-modified clay in a Brabender mixer at various clay loadings. The structure of the nanocomposites was characterized by X-ray diffraction and transmission electron microscopy. Mechanical testing showed that the polyethylene nanocomposites had an enhanced Young's modulus and slightly decreased elongation, while the changes for polypropylene nanocomposites are small compared with the virgin polymers. The thermal stability and flame properties were …

Polystyrene Nanocomposites Based On An Oligomerically-Modified Clay Containing Maleic Anhydride, Xiaoxia Zheng, David D. Jiang, Charles A. Wilkie

Chemistry Faculty Research and Publications

An oligomerically-modified clay containing maleic anhydride was used to prepare polystyrene-clay nanocomposites by melt blending and the effect of this modified clay on the thermal stability and fire performance was studied. These nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, thermogravimetric analysis and cone calorimetry. The results show a mixed immiscible/intercalated/delaminated morphology. The maleic anhydride modified clay improved the compatibility between the clay and the polystyrene.

Janus Scorpionates:  Supramolecular Tectons For The Directed Assembly Of Hard−Soft Alkali Metallopolymer Chains, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, James R. Gardinier

Chemistry Faculty Research and Publications

A new scorpionate ligand [HB(mtda)₃^-] containing mercaptothiadiazolyl (mtda) heterocyclic rings with both hard nitrogen donors and soft sulfur donors has been prepared. This new ligand, the Janus scorpionate, is a hybrid of a tris(pyrazolyl)borate and a tris(mercaptoimidazolyl)borate. The differential hard/soft character of the dissimilar donor groups in this bridging ligand was exploited for the controlled solid-state organization of homometallic and heterometallic alkali metal coordination polymers. Remarkably, in the case of sodium, coordination polymers with both acentric (with NaS₃N₃H kernels) and centric (with alternating NaN₆ and NaS₆H₂ kernels) chains are …

Simultaneous Ejection Of Six Electrons At A Constant Potential By Hexakis(4-Ferrocenylphenyl)Benzene, Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, Rajendra Rathore

Chemistry Faculty Research and Publications

A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.

A Practical Synthesis Of Bridged Diarylacetylenes, Ruchi Shukla, Daniel M. Brody, Sergey V. Lindeman, Rajendra Rathore

Chemistry Faculty Research and Publications

An efficient and practical synthesis of bridged diarylacetylenes in multigram quantities has been successfully carried out using high-yielding (classical) synthetic methods and readily available starting materials. The structural analysis of the representative bridged diarylacetylenes by X-ray crystallography strongly suggests that conformations, bending of the linear triple bond, and the angle between the mean planes of aromatic rings in various bridged diarylacetylenes are governed by the p−π conjugation among the aromatic rings and the ethereal groups. Furthermore, the synthetic scheme also allows the preparation of (appropriately) bromo-substituted bridged diarylacetylenes which hold potential for their future usage for the preparation of polymeric …

Ligand-Promoted Solvent-Dependent Ionization And Conformational Equilibria Of Re(Co)3Br[Ch2(S-Tim)2] (Tim = 1-Methylthioimidazolyl). Crystal Structures Of Re(Co)3Br[Ch2(S-Tim)2] And {Re(Co)3(Ch3Cn)[Ch2(S-Tim)2]}(Pf6), Rosalice M. Silva, Brendan J. Liddle, Sergey V. Lindeman, Mark D. Smith, James R. Gardinier

Chemistry Faculty Research and Publications

The compounds Re(CO)₃Br[CH₂(S-tim)₂] (1) and {Re(CO)₃(CH₃CN)[CH₂(S-tim)₂]}(PF₆) (2), where tim is 1-methylthioimidazolyl, were prepared in high yields and characterized both in the solid state and in solution. The solid-state structures show that the ligand acts in a chelating binding mode where the eight-member chelate ring adopts twist-boat conformations in both compounds. A comparison of both solid-state IR data for CO stretching frequencies and the solution-phase voltammetric measurements for the Re^1+/2+ couples between 1, 2, …

Highly Cooperative Tetrametallic Ruthenium-Μ-Oxo-Μ-Hydroxo Catalyst For The Alcohol Oxidation Reaction, Chae S. Yi, Tonya N. Zeczycki, Ilia A. Guzei

Chemistry Faculty Research and Publications

The tetrametallic ruthenium-oxo-hydroxo-hydride complex {[(PCy₃)(CO)RuH]₄(μ₄-O)(μ₃-OH)(μ₂-OH)} (1) was synthesized in two steps from the monomeric complex (PCy₃)(CO)RuHCl (2). The tetrameric complex 1 was found to be a highly effective catalyst for the transfer dehydrogenation of alcohols. Complex 1 showed a different catalytic activity pattern toward primary and secondary benzyl alcohols, as indicated by the Hammett correlation for the oxidation reaction of p-X-C₆H₄CH₂OH (ρ = −0.45) and p-X-C₆H₄CH(OH)CH₃ (ρ = +0.22) (X = …

On Moment Conditions For The Girsanov Theorem, See Keong Lee

LSU Doctoral Dissertations

In this dissertation, the well-known Girsanov Theorem will be proved under a set of moment conditions on exponential processes. Our conditions are motivated by the desire to avoid using the local martingale theory in the proof of the Girsanov Theorem. Namely, we will only use the martingale theory to prove the Girsanov Theorem. Many sufficient conditions for the validity of the Girsanov Theorem have been found since the publication of the result by Girsanov in 1960. We will compare our conditions with some of these conditions. As an application of the Girsanov Theorem, we will show the nonexistence of an …

Applications Of Titanium-Mediated Reductive Coupling And Cyclocarbonylation Reactions Toward Natural Product Synthesis, Maria A. Appeaning

LSU Doctoral Dissertations

Previous work in our laboratory has demonstrated not only a synthetic value of tandem reductive cyclization - carbonylation reactions in the preparation of complex molecules but also the interesting stereoselectivity observed therein. The first part of this work employs the titanium-mediated cyclocarbonylation of tethered dienals for the synthesis of prostaglandin analogues, in particular PGF_2α and methyl jasmonate. Based on this hetero Pauson-Khand strategy, we have established an efficient racemic route to both the prostaglandin and the methyl jasmonate core skeletons. Moderate to excellent selectivities with regard to the hetero Pauson-Khand reaction were observed in both cases. The second part …

Synthesis Of Glycosylamides And Carbohydrate Fused Heterocycles, Michael De Castro

Seton Hall University Dissertations and Theses (ETDs)

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Transfer Of Training From Flight Training Devices To Flight For Ab-Initio Pilots, Nickolas D. Macchiarella, Pamela K. Arban, Shawn M. Doherty

Publications

The application of flight simulation to meet pilot training needs continues to evolve. Flight simulations built with powerful and inexpensive computers are making high fidelity simulation available as a medium for training ab-initio pilots at Pilot Schools and Training Centers. The researchers conducted an 18-month study that applied an experimental flight-training curriculum comprised of 60% flight training device (FTD) flight and 40% airplane flight to certify Private Pilots under Federal Aviation Regulation (FAR) Part 142. The results from the research provided data to ascertain the effective transfer for each flight-training task. Ab-initio student pilots practiced each task to standard in …

Research-Based Web Design & Usability Guidelines [2006 Edition], Michael O. Leavitt, Ben Shneiderman, Robert W. Bailey, Carol Barnum, John Bosley, Barbara Chaparro, Joseph Dumas, Melody Y. Ivory, Bonnie John, Hal Miller-Jacobs, Sanjay J. Koyani, James R. Lewis, Stanley Page, Judith Ramey, Janice (Ginny) Redish, Jean Scholtz, Steve Wigginton, Cari A. Wolfson, Larry E. Wood, Don Zimmerman

Publications

The new edition of the U.S. Department of Health and Human Services’ (HHS) Research-Based Web Design and Usability Guidelines. These guidelines reflect HHS’ commitment to identifying innovative, research-based approaches that result in highly responsive and easy-to-use Web sites for the public.

These guidelines help move us in that direction by providing practical, yet authoritative, guidance on a broad range of Web design and communication issues. Having access to the best available research helps to ensure we make the right decisions the first time around and reduces the possibility of errors and costly mistakes.

Assessing Trace Evidence Left By Secure Deletion Programs, Paul Burke, Philip Craiger

Publications

Secure deletion programs purport to permanently erase files from digital media. These programs are used by businesses and individuals to remove sensitive information from media, and by criminals to remove evidence of the tools or fruits of illegal activities. This paper focuses on the trace evidence left by secure deletion programs. In particular, five Windows-based secure deletion programs are tested to determine if they leave identifiable signatures after deleting a file. The results show that the majority of the programs leave identifiable signatures. Moreover, some of the programs do not completely erase file metadata, which enables forensic investigators to extract …

Cool White Dwarfs In The Sloan Digital Sky Survey, Mukremin Kilic, Jeffrey A. Munn, Hugh C. Harris, James W. Liebert, Ted Von Hippel, Kurtis A. Williams, Travis S. Metcalfe, D. E. Winget, Stephen E. Levine

Publications

A reduced proper motion diagram utilizing Sloan Digital Sky Survey (SDSS) photometry and astrometry and USNO-B plate astrometry is used to separate cool white dwarf candidates from metal-weak, high-velocity, mainsequence Population II stars (subdwarfs) in the SDSS Data Release 2 imaging area. Follow-up spectroscopy using the Hobby-Eberly Telescope, the MMT, and the McDonald 2.7 m telescope is used to demonstrate that the white dwarf and subdwarf loci separate cleanly in the reduced proper motion diagram and that the contamination by subdwarfs is small near the cool white dwarf locus. This enables large, statistically complete samples of white dwarfs, particularly the …

The White Dwarf Luminosity Function From Sloan Digital Sky Survey Imaging Data, Hugh C. Harris, Jeffrey A. Munn, Mukremin Kilic, James W. Liebert, Kurtis A. Williams, Ted Von Hippel, Stephen E. Levine, David G. Monet, Daniel J. Eisenstein, S. J. Kleinman, T. S. Metcalfe, Atsuko Nikka, D. E. Winget, J. Brinkmann, Masataka Fukugita, G. R. Knapp, Robert H. Lupton, J. Allyn Smith, Donald P. Schneider

Publications

A sample of white dwarfs is selected from the Sloan Digital Sky Survey (SDSS) Data Release 3 using their reduced proper motions, based on improved proper motions from combined SDSS and USNO-B data. Numerous SDSS and follow-up spectra (Kilic and coworkers) are used to quantify completeness and contamination of the sample; kinematicsmodels are used to understand and correct for velocity-dependent selection biases.A luminosity function is constructed covering the range 7 < Mbol < 16, and its sensitivity to various assumptions and selection limits is discussed. The white dwarf luminosity function based on 6000 stars is remarkably smooth and rises nearly monotonically to Mbol=15.3. It then drops abruptly, although the small number of low-luminosity stars in the sample and their unknown atmospheric composition prevent quantitative conclusions about this decline. Stars …

Book Review: The Amateur Astronomer's Introduction To The Celestial Sphere, T. D. Oswalt

Publications

This document is Dr. Oswalt’s review of The Amateur Astronomer's Introduction to the Celestial Sphere by William Millar. Cambridge, 2006 299p, 052167123X $40.00, 9780521671231 $40.00.

Fact Sheet, Yale University Office Of Institutional Research

Fact Sheets

No abstract provided.

Circulation, Vol. 13, No. 1, Center For Coastal Physical Oceanography, Old Dominion University, John M. Klinck

CCPO Circulation

Winter 2006 issue of CCPO Circulation featuring article "Biological Processes in Bivalves as Revealed by Numerical Models" by Dr. John Klinck

Loop Current Warming By Hurricane Wilma, Lie-Yauw Oey, Tal Ezer, Dong-Ping Wang, S. J. Fan, Xun-Qiang Yin

CCPO Publications

Hurricanes mix and cool the upper ocean, as shown here in observations and modeling of the Caribbean Sea and the Gulf of Mexico during the passage of hurricane Wilma. Curiously, the upper ocean around the Loop Current warmed prior to Wilma's entrance into the Gulf. The major cause was increased volume and heat transports through the Yucatan Channel produced by storm-induced convergences in the northwestern Caribbean Sea. Such oceanic variability may have important impacts on hurricane predictions.

Topographic Influence On Overflow Dynamics: Idealized Numerical Simulations And The Faroe Bank Channel Overflow, Tal Ezer

CCPO Publications

Properties of the North Atlantic Deep Water (NADW) depend on mixing that occurs in the Denmark Strait (DS) and the Faroe Bank Channel (FBC) overflow regions. How the sill's topography in those regions may affect mixing processes and downstream variability is thus investigated using a high-resolution terrain-following ocean model. Model results agree with observations that show enhanced mixing and entrainment downstream from the sill; however, mixing seems to occur over a longer distance downstream from the FBC sill and more abruptly downstream from the DS sill. Sensitivity experiments with various FBC sill widths demonstrate that the narrow sill is responsible …

Ocean Warming And Freshening In The Northern Gulf Of Alaska, Thomas C. Royer, Chester E. Grosch

CCPO Publications

Water column temperatures on the shelf in the northern Gulf of Alaska have increased more than 0.8 degrees C and vertical density stratification has increased since 1970 near Seward, Alaska throughout the 250 m depth. This high latitude marine system has low water temperatures, high rates of precipitation, glacial melting, high wind speeds and high rates of biological productivity. A more than 300 km alongshore shift ( locally westward) of isotherms is suggested. The observations are consistent with a conceptual ocean-atmosphere circulation model that employs coastal freshwater discharge, glacial ablation and wind forcing. Positive regional feedback mechanisms accelerate the discharge …

Vertical Distribution Of Decapod Larvae In The Entrance Of An Equatorward Facing Bay Of Central Chile: Implications For Transport, Beatriz Yannicelli, Leonardo R. Castro, Arnoldo Valle-Levinson, Larry Atkinson, Dante Figueroa

CCPO Publications

Two short biophysical surveys were carried out in order to assess how the decapod crustacean larvae vertical distribution and circulation patterns in an equatorward facing embayment (Gulf of Arauco, 37° S; 73° W) influenced larval transport into and out of the Gulf. The embayment is located at the upwelling area of south central Chile and features a deep (60 m) and a shallow (25 m) pathway of communication with the adjacent coastal ocean. Profiles of zooplankton, temperature, salinity, dissolved oxygen and current velocity were measured during a 22-h period at the shallow entrance to the gulf. In addition, three zooplankton …