Physical Sciences and Mathematics Commons^™

Interdisciplinary Interspecies Pedagogies For Educating In The Anthropocene: Bringing Critical Animal Studies To Huxley College Of The Environment, Sarah R. (Sarah Rose) Olson

WWU Graduate School Collection

This report examines ENVS 499T Introduction to Critical Animal Studies: Theory, Agency, and Action, a 2-credit environmental humanities seminar designed as a M.Ed. in Environmental Education field project through Western Washington University’s (WWU) Huxley College of the Environment. ENVS 499T was created in response to a lack of critical animal studies course offering at WWU. The seminar was designed to provide WWU undergraduates with an opportunity to engage with interspecies ethical issues through an interdisciplinary lens. This report explores literature relevant to the design and implementation of this field project. It draws on scholars from critical animal studies and other …

Paleomagnetic And Structural Analysis Of Geothermal Drill Core From Akutan, Alaska, Molly Kathleen Johnson

WWU Graduate School Collection

Hot Springs Bay Valley (HSBV) geothermal resource area on Akutan Island, Alaska, has increased fluid output and temperature by almost a magnitude, between 1981 and 2012 (Bergfeld et al., 2014). These increases have been attributed to increased permeability along NW-SE trending faults that may have been activated during a seismic swarm in 1996. In 2010 two unoriented drill cores were collected in Hot Springs Bay geothermal resource area. In this study I reorient sections from one of the highly fractured cores with paleomagnetic data to test this model of geothermal reservoir evolution at Akutan. The core is composed of interlayered …

Plasmonic-Based Hybrid Nanomaterial: From Synthesis To Application, Maggie Wang

WWU Graduate School Collection

Gold nanoparticles, particularly gold nanorods, have been widely used as sensors and imaging agents due to their unique and tunable morphology-dependent properties and intriguing plasmonic resonance. However, the increasing need of new materials with enhanced properties and functionality led scientists to discover novel hybrid nanomaterials, which involves the formation of two or more components into one nanoplatform. Hence, gold nanorod-based hybrid nanomaterials exhibit simultaneous synergistic effects between the phenomenal plasmonic properties from gold nanorods and the intrinsic properties of the other constituents. The functionality of gold nanorod-based hybrid nanomaterials greatly increases due to its enhanced performance characteristics, which directly impacts …

Using Multispectral Imagery To Interrogate Deposition, Alteration, And Weathering Across Curiosity Rover’S Traverse In Gale Crater, Mars, Christina Seeger

WWU Graduate School Collection

Since landing in 2012, the Mars Science Laboratory (MSL) Curiosity rover has explored over 20 kilometers of Gale crater, climbing almost 400 meters in elevation. The fluvio-deltaic, lacustrine, and aeolian sediments in the crater have been well documented by Curiosity’s suite of in situ and remote science instruments. Indeed, they have traced chemical trends that track changes in lithology and diagenesis over the study area—though most instruments only sample individual rock, vein, and soil targets at a very small scale. The Mast Camera (Mastcam) has periodically acquired much larger (meter-scale) multispectral, visible to near-infrared observations of outcrops throughout this stratigraphic …

Modeling The Effects Of Climate Change On Streamflow And Stream Temperature In The South Fork Of The Stillaguamish River, Katherine Mary Clarke

WWU Graduate School Collection

The Stillaguamish River in northwest Washington State is an important regional water resource for local agriculture, industry, and First Nations tribes and a critical habitat for several threatened and endangered salmonid species, including the Chinook salmon. The river is currently subject to a temperature total maximum daily load, so it is important to understand how projected climate change will affect future stream temperatures and thus salmon populations. Snowpack is the main contributor to spring and summer streamflow and helps to mitigate stream temperatures as air temperatures rise through the summer in the South Fork of the Stillaguamish River. I used …

Crystal Mush Dynamics Of Mount St. Helens And Lassen Volcanic Center: Insights From Melt Inclusions And Titanium-In-Quartz Thermobarometry, Jeremy S. Rosen

WWU Graduate School Collection

In order to better understand magma chamber dynamics at Lassen Volcanic Center (LVC) and Mount St. Helens (MSH) I examine quartz cathodoluminescent textures along with trace element abundances in quartz and compositions of quartz-hosted melt inclusions from multiple samples over a wide range of ages (LVC: 116 ka-1915; MSH: 272 ka to 84 ka). I use melt inclusion compositions to estimate quartz crystallization temperatures using zircon saturation thermometry and titanium abundances in quartz are used to estimate quartz crystallization pressures. When examined from core to rim within an individual grain, these data, along with internal CL-zoning textures reveal the dynamic …

Spatial And Temporal Trends Of The Annual First Detections Of Paralytic Shellfish Toxin In Puget Sound, Wa, Margaret Taylor

WWU Graduate School Collection

Since the 1950s, the Washington State Department of Health has routinely monitored the suite of toxins in shellfish associated with Paralytic Shellfish Poisoning. These toxins, known collectively as Paralytic Shellfish Toxins, are produced by species of the marine dinoflagellate in the genus Alexandrium. The role of the monitoring program is primarily to protect public health and safety; and therefore, use of these data for long-term statistical analysis has been limited due to opportunistic and irregular sampling of various shellfish species in space and time. However, some studies suggest that initiation of these toxic events have recently shifted to earlier …

Carbodiimides: Templates For Covalent Adaptable Networks And Post Polymerization Modification, Alberto J Melchor Bañales

WWU Graduate School Collection

The global increase in plastic waste has negatively impacted the environment, human health, and economy. Plastics that lack recyclability, such as thermosets are some of the main culprits. To help address this issue, reactive functional groups can be incorporated in macromolecules, enabling straightforward post-polymerization modification (PPM) that can enhance their ability to be recycled. This thesis studied carbodiimides as a reactive functional group for facile PPM with amines through a catalyst-free transformation to N,Nʹ,Nʺ-trisubstituted guanidines. Small molecule studies showed that N,Nʹ,Nʺ-trisubstituted guanidines underwent a reversible thermal exchange reaction without a catalyst. The newly found thermal exchange reaction, termed thermal guanidine …

Synthesis And Characterization Of Earth Abundant Metal Phosphide Photocatalysts For The Reverse Water Gas Shift Reaction, John D. Springer

WWU Graduate School Collection

This thesis work focuses on the synthesis and characterization of photocatalysts composed of metal phosphide nanoparticles on a titania (TiO2) support for the conversion of carbon dioxide (CO2) to carbon monoxide (CO) via the reverse water gas shift (RWGS) reaction. The CO product can be subsequently converted to solar fuels such as methanol (CH3OH), thus lowering the carbon footprint associated with the combustion of liquid fuels. The photocatalysts are composed of a tunable light absorber, indium-gallium phosphide (InxGa1-xP), and nickel phosphide (Ni2P) as a co-catalyst, on TiO2. The photocatalysts are characterized using diffuse reflectance ultraviolet-visible (UV-Vis) spectroscopy to determine band …

Timing And Conditions Of Metamorphism In The Cascades Crystalline Core From Garnet Lu-Hf And Sm-Nd Geochronology, Peter Baker

WWU Graduate School Collection

The Chiwaukum Schist and Tonga Formation of Cascades Crystalline Core experienced three distinct metamorphic events: (M1) an early metamorphism that predates regional pluton emplacement, (M2) low-pressure contact metamorphism in the aureoles of the Mount Stuart batholith and Beckler Peak pluton, and (M3) regional Barrovian metamorphism. The timing of these distinct metamorphic events is critical to testing models for the tectonic evolution of the region and mechanisms that lead to burial of rocks within the orogen. I present new garnet Lu-Hf and Sm-Nd isochrons, average pressure and temperature calculations, and pseudosection modeling from the Chiwaukum Schist and Tonga Formation in order …

Organic Molecular Crystal Engineering Via Organic Vapor-Liquid-Solid Deposition, Griffin Reed

WWU Graduate School Collection

Control over the size, shape, topology, orientation, and crystallographic phase of organic molecular materials is critical for a wide array of applications ranging from optoelectronics to pharmaceutical development. Herein, we demonstrate a relatively low-cost approach for fabricating single crystals with controlled sizes, shapes, microscale periodic features, preferred orientations and specific molecular packing modes. These features allow for the fabrication of intricate arrangements of single crystals for incorporation into complex device architectures, and potentially the endowment of tailored optical, electronic, thermal, and mechanical properties onto these materials. Patterning is achieved by utilizing an organic-vapor-liquid-solid (OVLS) deposition scheme paired with traditional photolithography …

Forest Restoration Of The Exposed Lake Mills Bed: Assessing Vegetation, Ectomycorrhizae, And Nitrogen Relative To Riverbank Lupine (Lupinus Rivularis), James Kardouni

WWU Graduate School Collection

This thesis investigated the managed revegetation outcomes of the exposed Lake Mills reservoir bed was investigated following the Glines Canyon dam removal on the Elwha River located in the Pacific Northwest, United States. During the following four years of restoration, one seeded species, riverbank lupine (Lupinus rivularis), quickly established on the coarse textured terraces that also had low organic matter (OM) and low soil nitrogen (N) levels. Nitrogen-fixing lupines may facilitate plant recruitment and conifer establishment, while demonstrating a relationship with ectomycorrhizal (ECM) communities which perform essential forest ecosystem functions. The purpose of this study was to investigate lupine’s influence …

The Effectiveness Of Large Woody Debris Placement At Improving Freshwater Rearing Habitat And Enhancing Juvenile Salmon (Oncorhynchus Spp.) Production, Caroline J. Walls

WWU Graduate School Collection

The decline of Pacific salmon (Oncorhynchus spp.) is well-documented, and freshwater habitat degradation is a primary contributor. Despite decades of river restoration, salmon populations have not significantly recovered. Large woody debris (LWD) placement is one of the most common forms of restoration. To evaluate the effectiveness of this restoration method, I analyzed long-term monitoring data from 16 LWD placement projects throughout Washington State, implemented between 2004 and 2015. Each project followed a multiple Before-After, Control-Impact study design, which monitored physical habitat and fish populations. I used a series of linear mixed models to evaluate both habitat and fish response. …

Allylic Benzoate Reductions: A Study On Stereospecificity, Michael A. Leitch

WWU Graduate School Collection

Herein we report results from experiments aimed at better understanding SmI2(H2O)n reductions of allylic benzoates adjacent to a trisubstituted alkene. When flanked by both a chelating group and stereodirecting group, these reactions can occur with complete regioselectivity and good diastereoselectivity (up to 90:10). Initial experiments suggested that the reaction was stereospecific to alkene geometry. However, further experimentation has revealed that the alkene stereospecificity is substrate dependent. For instance, if the geminal alkene substituents are alkyl, results show the reaction to be stereospecific, but if one of the substituents is a phenyl group the reaction is still stereoselective but not stereospecific. …

Synthetic Studies On Guaipyridine Alkaloids: Rupestines B And C, Evangeline Starchman

WWU Graduate School Collection

The rupestines, a family of guaipyridine alkaloids, are isolated from the plant Artemisia rupestris. Historically, this plant was used intraditional Chinese medicine due to its reported antitumor, antibacterial, and antiviral activities as well as reported protection of the liver. The rupestines can only be isolated from their parent plant in small quantities, making the total synthesis of these guaipyridine alkaloids of particular interest. Cananodine, anotherguaipyridine alkaloid, is a biologically active compound that can be isolated in small quantities from the fruits of Cananga odorata and displays activity against two types of hepatocellular carcinoma cell lines. It is hypothesized that the …

Effects Of Anthropogenic Forest Stresses On The Distribution And Abundance Of The Olympic Torrent Salamander (Rhyacotriton Olympicus) In The Olympic National Forest And Olympic National Park, Travis Macneil Kurtz

WWU Graduate School Collection

Salamanders worldwide are faced with habitat loss, and much of the remaining habitat is under the constant pressure of degradation. The forests of the North American Pacific Northwest are no exception. The primary anthropogenic forces impacting the stability of lotic salamander populations on the Olympic peninsula are commercial timber harvest and culverts necessitated by roads crossing streams to facilitate the removal of timber from these forests.

In this study, I conducted stream surveys on 139 headwater stream reaches in 77 streams in mature and recently harvested forests both above and below culverts on forest roads in Washington’s Olympic National Forest …

Activation Of Nitrite And Carbon Dioxide By Cobalt Centered Redox Active Ligand Featuring A Hemilabile Pendant Amine, Douglas F. Baumgardner

WWU Graduate School Collection

Carbon dioxide (CO₂) and bioavailable nitrogen in the form of nitrates (NO₃^-) and nitrites (NO₂^-) are serious environmental pollutants. However, without economic incentives there is little interest in remediation of these pollutants outside of laboratory scale experiments. CO₂ can be converted to carbon monoxide (CO), a valuable building block in Fischer-Tropsch sourced fuel, and NO₃^- and NO₂^- can be converted to ammonia, another important chemical building block. However, both require effective, low-cost catalysts to be financially viable options. This thesis seeks to demonstrate the conversion of CO …

Incorporating Characteristics Of Gene Drive Engineered Ae. Aegypti As Methods To Reduce Dengue And Zika Virus Into The Bayesian Network – Relative Risk Model, Using Ponce, Puerto Rico As A Case Study, Steven R. Eikenbary

WWU Graduate School Collection

This study proposes the use of the Bayesian network relative risk model (BN-RRM) to estimate the risk associated with the release of gene drives as vectors to control disease, using Ponce, Puerto Rico as a case study. Bayesian networks are an appropriate risk assessment tool for quantitatively and probabilistically examining complex systems involving multiple stressors acting on multiple endpoints in a wide variety of situations. The emerging field of synthetic biology has the capacity to drastically alter ecological systems with the use of gene drive engineered organisms as a method to alter population dynamics. The purpose of the release of …

Land, Body, Liberation: An Ecofeminist Pedagogical Approach To Place-Based Education, Amy L. Fitkin

WWU Graduate School Collection

Within this project I applied an ecofeminism framework to the tangible practices of place-based education regarding issues of social justice-based sustainability efforts. In order to recognize the impact of identity-based privileges, I explore how place-based education promotes the development of problem-solving skills, critical-thinking techniques and building meaningful relationships within a community. These goals were achieved by shifting the white settler colonist understanding of human conquest and subjugation over land and bodies from an anthropocentric lens to an androcentric lens. In other words, illuminating the oppressive role the patriarchy has continued to play in exploiting natural "resources" and the bodies of …

Slip Rates And Kinematics Of Active Crustal Faults In The Central Oregon Cascades, Katherine Alexander

WWU Graduate School Collection

New cosmogenic ³He chronologies and surficial geologic mapping constrain the age of glacial deposits and slip rates of predominantly normal faults in the White Branch and Dilman Meadows fault zones in central Oregon, USA, over the last ca. ~80 kyr. Our mapping of glacial landforms and deposits distinguishes three primary episodes of glacial deposition in the White Branch fault zone. Twenty-two new cosmogenic ³He surface exposure dates indicate that the youngest glacial unit represents a last glacial maximum deposit (ca. 19.4 +10.1/-6.2 kyr). Mapping of outwash terrace surfaces and deposits in the Dilman Meadows fault zone, constrained by …

Conifer Establishment And Encroachment On Subalpine Meadows Around Mt. Baker, Wa, Ben Hagedorn

WWU Graduate School Collection

The subalpine ecotone is experiencing significant change in habitat availability and connectivity as a result of climate change and climate variability. To understand how these changes vary temporally and spatially in the Pacific Northwest, we collected cross-sections and counted whorls of conifers along four transects around Mt. Baker, Washington in the North Cascades. In addition to the samples collected, we also gathered data on microsite conditions that impact seedling establishment. Using partial correlation analyses, we compared establishment dates to climate variables in five-year bins, and used normal correlation analyses along with other statistical tests to determine the effect of various …

Testing The Potential For Using Structure From Motion Photogrammetry Methods To Estimate Seasonal Mass Balance On Lower Easton Glacier, Mount Baker, Wa, Elizabeth Kimberly

WWU Graduate School Collection

The traditional glaciological method of measuring glacier mass balance is labor-intensive and relies on broad extrapolation of sparse ablation stake data collected in the field to assess mass change across the glacier. In contrast, digital elevation models (DEMs) obtained from unmanned aerial vehicle (UAV) imagery and Structure-from-Motion (SfM) photogrammetry resolve a spatially distributed data set of surface elevation change. In this study, I compare seasonal mass balance estimated by field-based glaciological methods and UAV-SfM methods during summer 2018 on the Easton Glacier, Mount Baker, WA. Total snow and ice surface melt was measured at five ablation stakes between May 20th …

Incorporating Climate Change Predictions In Ecological Risk Assessment: A Bayesian Network Relative Risk Model For Chinook Salmon In The Skagit River Watershed, Eric J. Lawrence

WWU Graduate School Collection

Climate change is expected to have widespread impacts on future ecosystem services in the Puget Sound and around the world. It is important that climate change be included in ecological risk assessment so that changing climate variables and potential interactive effects with chemical stressors can be taken into account. In this research, I focused on the question of how water temperature changes generated by climate change interact with organophosphate pesticide toxicity to affect Chinook salmon (Oncorhynchus tshawytscha) population size in the Skagit River, WA. To answer this question, I conducted an ecological risk assessment using the Bayesian network …

Bio-Preservation Potential Of Sediment In Eberswalde Crater, Mars, Cory Hughes

WWU Graduate School Collection

Within Eberswalde crater, Mars, is one of the most well-preserved river delta deposits identified within Mars’ rock record, and visually traceable from the deposit, is the partially-intact watershed that fed the paleo-lake that once resided within the crater basin. Aqueous alteration minerals, smectite clays and opaline silica, have been previously identified within the deposit, however the origin of those minerals is not well understood. Through analysis of topographic and hyperspectral data, we seek to ascertain the origin and provenance of these minerals to better understand their formative conditions and formation age. We will also assess Eberswalde crater’s potential as a …

Clam Garden Bivalve Dietary Responses And Trophic Shifts In Relation To Environment, Octavio Cruz

WWU Graduate School Collection

Clam gardens are a method of Indigenous aquaculture, involving altering of beach gradients, to increase clam habitat that have been used since pre-contact. Ecological examinations of clam gardens have been increasingly led by First Nations groups, as restoration projects begin on clam gardens aiming to re-establish pre-contact conditions.

The purpose of this study was to measure condition indices of traditionally-harvested littleneck clams (Leukoma staminea), dietary parameters and beach-level oceanographic conditions were used to investigate differences between clam gardens from non-walled beaches in Kanish Bay, Quadra Island, British Columbia. I utilized non-metric multidimensional scaling, distance-based redundancy analysis, and Bayesian 3-source isotopic …

Development Of Ti-Dftb: Transition Dipole Moment Calculations In A Time-Independent Density Functional Tight-Binding Framework, Megan Deshaye

WWU Graduate School Collection

Here we discuss the development of a time-independent excited state computational method that consists of three augmentations to the semi-empirical electronic structure package, DFTB+ 19.1. The density functional based tight binding method (DFTB) is an approximation of Kohn-Sham (KS) density functional theory (DFT) wherein the energy functional is expanded to second order with respect to density fluctuations. Application of a delta self-consistent field (delta-SCF) approach within DFTB has allowed for the variationally optimized calculation of spin-purified excited state (ES) properties, and forms the foundation of our time-independent DFTB (TI-DFTB) framework. Selection of KS spin orbitals based on the character of …

Can Arbuscular Mycorrhizal Fungi Protect Rubus Idaeus From The Effects Of Soil-Borne Disease And Parasitic Nematodes?, Erika Whitney

WWU Graduate School Collection

Chemical controls for agricultural pests and diseases can have detrimental effects on human health and the environment. One alternative is to introduce soil microbes, such as arbuscular mycorrhizal fungi (AMF), that can improve crop resilience to pests and pathogens. While many plants form symbioses with AMF, not all crops benefit from inoculation. We conducted three studies that questioned the effect of AMF from various sources on R. idaeus growth and resilience to pests/pathogens. First, in a small observational study, we investigated whether AMF colonization of raspberry roots covaried with stand vigor. In two subsequent greenhouse experiments, we asked (1) if …

Wave Runup And Morphologic Change On A Mixed-Sediment Beach In The Salish Sea, Wa, Avery Maverick

WWU Graduate School Collection

A primary threat to coastal regions is extreme water levels from tides, storm surges, and waves which drive coastal evolution. Predicting wave runup, the vertical extent of wave uprush on a beach above still water level, and the morphologic responses to storms within the Salish Sea is complex because of the high variability of shoreline exposure to waves and wind, morphology, coastal landforms, and tide range across the region. As part of a USGS study, this project was designed to assess how wave energy offshore drives runup, validate existing runup models (van der Meer, 2002; Stockdon et al., 2006; Didier …

Lsc Fabrication And Design: Bulk Polymerization And Ultrathin Architectures, Justin T. Doyle

WWU Graduate School Collection

Renewable energy technologies that access underutilized spaces in the built environment will need to be implemented, on a large scale, to curtail trending increases in global temperature. Luminescent Solar Concentrators (LSCs) are one such technology. They employ luminophores doped into polymer sandwiched in between glass plates, that redirect sunlight to the device periphery where photovoltaics are attached, producing power. Current devices do not have high enough efficiencies for commercialization. One of the biggest barriers is fluorophore aggregation which causes waveguide refractive index fluctuations which result in parasitic losses from the waveguide. In this work Copper Indium Disulfide/Zinc Sulfide (CIS/ZnS) quantum …

Engineering Class A Sortases: Activity And Selectivity Of Hybrid And Ancestral Variants, Sarah Struyvenberg

WWU Graduate School Collection

Bacterial sortases are cysteine transpeptidases that anchor virulence factors to the surface of bacterial cells. Sortases are a powerful tool utilized for protein engineering that allow researchers to modify proteins at the protein level, not the DNA level. However, important limitations to utilization of sortases for engineering purposes exist; namely, SrtA from S. aureus is a relatively modest enzyme compared to other SrtA enzymes and is very specific for the LPXTG motif. Previous work from our collaborators and others revealed that sortases from different species can recognize alternative sequences and that activities can vary widely. We were curious about how …