Physical Sciences and Mathematics Commons^™

Synthesis, Modification, Characterization And Processing Of Molded And Electrospun Thermoplastic Polymer Composites And Nanocomposites, Tamalia Julien

USF Tampa Graduate Theses and Dissertations

This dissertation focuses on the versatility and integrity of a novel, ultrasoft polycarbonate polyurethane (PCPU) by the introduction of nanoparticles and lithium salts. Additionally, the research takes into account the use of electrospinning as a technique to create PCPU and polyimide (PI) fibers. These polymers are of interest as they offer a wide range of properties and uses within the medical and industrial fields.

An industrial batch of an ultrasoft thermoplastic polyurethane (TPU) was synthesized using a two-step process. The first was to create an end capped pre-polymer from methylene bis (4-cyclohexylisocyanate), and a polycarbonate polyol made up of 1,6- …

Geochemical Modeling Of Primary Morb Magmas: Implications For Parental Melting Regimes In Melt Lenses Along-Axis Of The Hess Deep Rift, Stephanie Michelle Drumm

USF Tampa Graduate Theses and Dissertations

The Hess Deep Rift in the East Pacific Rise is a mid-ocean ridge spreading center that produces melts which exhibit geochemical characteristics of evolved MORB. Using basaltic glass samples collected from multiple dive cruises that explored Hess Deep geology, volatile and chemical data were collected at USF using FTIR and EMPA, respectively. In addition, a data suite of samples of glass from Hess Deep were compiled from the EarthChem database. The intention was to use the data suite and models to compare the Hess Deep regime to analog models for mid-ocean ridge crystallization regimes and tectonic structures. The USF and …

The Stability Of Sand Waves In A Tidally-Influenced Shipping Channel, Tampa Bay, Florida, John Willis Gray

USF Tampa Graduate Theses and Dissertations

Tidally-influenced sandwaves are common coastal features present in various settings, including shipping channels. The main shipping channel in Tampa Bay under the Bob Graham Sunshine Skyway Bridge (a.k.a. the Skyway Bridge) contains such sandwave bedforms. Between the years 2000 and 2017, these bedforms have been surveyed with multibeam echosounders (MBES) on 21 occasions with ranging coverage and quality of returns. Surveys between 2000 and 2009 used a 300 kHz Kongsberg EM3000; surveys between 2015 and 2017 used a 400 kHz Reson Seabat 7125. For comparable surveys, bathymetry, backscatter, slope, curvature, planform curvature, and profile curvature maps were created and analyzed. …

Assessment Of Drinking Water Quality Management And A Treatment Feasibility Study For Brick By Brick Water Storage Tanks In Rakai Uganda, James V. Murduca

USF Tampa Graduate Theses and Dissertations

Reliable access to safe drinking water is one necessity for humans to live without concern for major health risks. The overall goal of this research is to improve the public health, through improved drinking water, for communities in the Rakai District in Uganda, directly, and other communities in the world, indirectly, via dissemination of knowledge. This study specifically assessed the knowledge of drinking water quality in regards to public health, their sanitation measures, and water treatment methods for users of Brick by Brick rainwater harvesting tanks in the Rakai District (N = 28) by using a knowledge, attitudes, and practice …

Improving The Security Of Building Automation Systems Through An Sel4-Based Communication Framework, Richard Habeeb

USF Tampa Graduate Theses and Dissertations

Existing Building Automation Systems (BASs) and Building Automation Networks (BANs) have been shown to have serious cybersecurity problems. Due to the safety-critical and interconnected nature of building subsystems, local and network access control needs to be finer grained, taking into consideration the varying criticality of applications running on heterogeneous devices. In this paper, we present a secure communication framework for BASs that 1) enforces rich access control policy for operating system services and objects, leveraging a microkernel-based architecture; 2) supports fine-grained network access control on a per-process basis; 3) unifies the security control of inter-device and intra-device communication using proxy …

Optimal Latin Hypercube Designs For Computer Experiments Based On Multiple Objectives, Ruizhe Hou

USF Tampa Graduate Theses and Dissertations

Latin hypercube designs (LHDs) have broad applications in constructing computer experiments and sampling for Monte-Carlo integration due to its nice property of having projections evenly distributed on the univariate distribution of each input variable. The LHDs have been combined with some commonly used computer experimental design criteria to achieve enhanced design performance. For example, the Maximin-LHDs were developed to improve its space-filling property in the full dimension of all input variables. The MaxPro-LHDs were proposed in recent years to obtain nicer projections in any subspace of input variables. This thesis integrates both space-filling and projection characteristics for LHDs and develops …

Reduction In Needlestick Injuries Using A Novel Package Of Interventions, Kamal Thakor Patel

USF Tampa Graduate Theses and Dissertations

In 2015 Dr. Pratiksha Vaghela started the “Stop Poking Me” campaign which was aimed at curbing the increase in the number of needlesticks at the James A. Haley Veteran Affairs Hospital (JAHVA). The data for needlesticks was collected by the Occupational Medicine Clinic (OMC) between Oct 2013 and Oct 2016. We then obtained the original data from Dr. Vaghela’s project and compared the data to assess whether the new implementations have truly decreased the number of needlesticks. There was a 23.6% reduction in the number of needlesticks between 2013 and 2016 and even more importantly a 60.1% reduction between 2015 …

Design, Synthesis, Application Of Biodegradable Polymers, Mussie Gide

USF Tampa Graduate Theses and Dissertations

Bacterial infections have posed a serious threat to the public health due to the significant rise of the infections caused by antibiotic-resistant bacteria. There has been considerable interest in the development of antimicrobial agents which mimic the natural HDPs, and among them biodegradable polymers are newly discovered drug candidates with ease of synthesis and low manufacture cost compared to synthetic host defense peptides. Herein, we present the synthesis of biocompatible and biodegradable polymers including polycarbonate polymers, unimolecular micelle hyperbranched polymers and dendrimers that mimic the antibacterial mechanism of HDPs by compromising bacterial cell membranes. The developed amphiphilic polycarbonates are highly …

Quantifying The Effect Of Topographic Slope On Lava Flow Thickness: A First Step To Improve Lava Flow Volume Estimation Methods, Steven R. Rizo

USF Tampa Graduate Theses and Dissertations

The volume of lava flows provide important information on the magnitude of volcanic eruptions, and accurate volumes are necessary to produce reliable models of lava flow emplacement or constrain the internal structure of volcanoes. The most accurate lava flow volumes are obtainable when the topography before and after an eruption are both known, but information for the topography before lava flow emplacement is absent in non-historic lava flows. To calculate the volume of non-historic lava flows, this pre-emplacement topography needs to be reconstructed. Common methods for this include using inverse distance-weighted averages or global polynomial interpolation methods, but these can …

Reconstructing Historical Hurricane Tracks In The Atlantic Basin: Three Case Studies From The 1840s, Emily L. Cerrito

USF Tampa Graduate Theses and Dissertations

Analyzing past tropical cyclone activity enables researchers to recognize patterns of hurricane variability, estimate hurricane return periods, and assess local risk to future storms. This paleotempestology study used original primary data to make the historical record as comprehensive and accurate as possible for three major hurricanes: October 1844, October 1846, and September 1848. This thesis presents the reconstructed storm tracks, assesses the societal impacts, and evaluates the storm intensity of these three major hurricanes for the eastern U.S. and Cuba. The data utilized in this study include ship logbooks, newspapers, diaries, and instrumental meteorological records. A geographic information system (GIS) …

A Point Cloud Approach To Object Slicing For 3d Printing, William Edward Oropallo Jr.

USF Tampa Graduate Theses and Dissertations

Various industries have embraced 3D printing for manufacturing on-demand, custom printed parts. However, 3D printing requires intelligent data processing and algorithms to go from CAD model to machine instructions. One of the most crucial steps in the process is the slicing of the object. Most 3D printers build parts by accumulating material layers by layer. 3D printing software needs to calculate these layers for manufacturing by slicing a model and calculating the intersections. Finding exact solutions of intersections on the original model is mathematically complicated and computationally demanding. A preprocessing stage of tessellation has become the standard practice for slicing …

Parallelizing Tabu Search Based Optimization Algorithm On Gpus, Vinaya Malleypally

USF Tampa Graduate Theses and Dissertations

There are many combinatorial optimization problems such as traveling salesman problem, quadratic-assignment problem, flow shop scheduling, that are computationally intractable. Tabu search based simulated annealing is a stochastic search algorithm that is widely used to solve combinatorial optimization problems. Due to excessive run time, there is a strong demand for a parallel version that can be applied to any problem with minimal modifications. Existing advanced and/or parallel versions of tabu search algorithms are specific to the problem at hand. This leads to a drawback of optimization only for that particular problem. In this work, we propose a parallel version of …

Supported Perovskite-Type Oxides: Establishing A Foundation For Co2 Conversion Through Reverse Water-Gas Shift Chemical Looping, Bryan J. Hare

USF Tampa Graduate Theses and Dissertations

Perovskite-type oxides show irrefutable potential for feasible thermochemical solar-driven CO₂ conversion. These materials exhibit the exact characteristics required by the low temperature reverse water-gas shift chemical looping process. These properties include structural endurance and high oxygen redox capacity, which results in the formation of numerous oxygen vacancies, or active sites for CO₂ conversion. A major drawback is the decrease in oxygen self-diffusion with increasing perovskite particle size. In this study, the La_0.75Sr_0.25FeO₃ (LSF) perovskite oxide was combined with various supports including popular redox materials CeO₂ and ZrO₂ along with more abundant …

Design And Implementation Of A Ferrocement Improved Cookstove In Rural Panama, Josh Donegan

USF Tampa Graduate Theses and Dissertations

Household air pollution contributes to the premature death of more than 4 million people annually. Improved cookstoves are one technological intervention that can potentially reduce exposure to household air pollution. However, improved cookstove implementation programs need to consider measures to increase sustainability and promote long-term adoption. The objectives of this research were 1) to develop and implement a new ferrocement cookstove for Peña Blanca, a rural indigenous community in the Ngäbe-Bugle region of Panama, 2) to evaluate its potential sustainability in comparison to the most common cooking technologies observed in the community, 3) to prepare a construction manual for the …

Effectiveness Of Biocide Substitution And Management Plan Implementation For The Control Of, Adelmarie Bones

USF Tampa Graduate Theses and Dissertations

After the notorious outbreak and discovery of Legionella bacteria in 1976, the waterborne pathogen was added to the list of disease-causing agents associated with the built environment. Legionella pneumophila was discovered when it was identified as the agent that caused 34 deaths and an outbreak of pneumonia-like symptoms in several attendees of the 1976 American Legion Convention held in Philadelphia (OSHA, 2017).

Recently published data from the year 2015 reported more than 6,000 Legionnaires’ cases identified in the United States (CDC, 2016). This is a concerning number given that one in every ten infected persons will die of the disease. …

Angiostrongylus Cantonensis: Epidemiologic Review, Location-Specific Habitat Modelling, And Surveillance In Hillsborough County, Florida, U.S.A., Brad Christian Perich

USF Tampa Graduate Theses and Dissertations

Angiostrongylus cantonensis is a parasitic nematode endemic to tropical and subtropical regions and is the leading cause of human eosinophilic meningitis. The parasite is commonly known as rat lungworm because the primary host in its lifecycle is the rat. A clinical overview of rat lungworm infection is presented, followed by a literature review of rat lungworm epidemiology, risk factors, and surveillance projects. Data collected from previous snail surveys in Florida was considered alongside elevation, population per square kilometer, median household income by zip code territory, and normalized difference vegetation index specific to the geographic coordinates from which the snail samples …

Strategies To Adjust For Response Bias In Clinical Trials: A Simulation Study, Victoria R. Swaidan

USF Tampa Graduate Theses and Dissertations

Background: Response bias can distort treatment effect estimates and inferences in clinical trials. Although prevention, quantification, and adjustments have been developed, current methods are not applicable when subject-level reliability is used as the measure of response bias. Thus, the objective of the current study is to develop, test, and recommend a series of bias correction strategies for use in these cases. Methods: Monte Carlo simulation and logistic regression modeling were used to develop the strategies, examining the collective impact of sample size (N), effect size (ES), reliability distribution, and response style on estimating the treatment effect size in a series …

Assessing The Impacts Of Climate Change On Streamflow And Reservoir Operation In Central Florida, Toni Panaou

USF Tampa Graduate Theses and Dissertations

Climate change is a global concern as it may affect many aspects of life, including water supply. A tool used to model climate change’s impacts is called a General Circulation Model (GCM). GCMs project future scenarios including temperature and precipitation, but these are designed at a coarse resolution and require downscaling for employment for regional hydrologic modeling. There is a vast amount of research on downscaling and bias-correcting GCMs data, but it is unknown whether these techniques alter precipitation signals embedded in these models or reproduce climate states that are viable for water resource planning and management. Using the Tampa, …

Graph-Based Latent Embedding, Annotation And Representation Learning In Neural Networks For Semi-Supervised And Unsupervised Settings, Ismail Ozsel Kilinc

USF Tampa Graduate Theses and Dissertations

Machine learning has been immensely successful in supervised learning with outstanding examples in major industrial applications such as voice and image recognition. Following these developments, the most recent research has now begun to focus primarily on algorithms which can exploit very large sets of unlabeled examples to reduce the amount of manually labeled data required for existing models to perform well. In this dissertation, we propose graph-based latent embedding/annotation/representation learning techniques in neural networks tailored for semi-supervised and unsupervised learning problems. Specifically, we propose a novel regularization technique called Graph-based Activity Regularization (GAR) and a novel output layer modification called …

Investigation Of Sediment Ridges Using Bathymetry And Backscatter Near Clearwater, Florida, Lewis Stewart

USF Tampa Graduate Theses and Dissertations

Changes in sediment morphology on the West Florida Shelf is investigated over a 14-year time period using multibeam bathymetry and backscatter in water depths between 10 m and 20 m, off the coast of Indian Rocks Beach, Pinellas County, Florida. Bathymetric surveys collected in 2002 (Kongsberg EM 3000 at 300 kHz) and 2016 (Reson 7125 at 400 kHz) were processed using CARIS Hips and Sips to create bathymetric maps and backscatter images. These data were then interpreted and compared in order to test hypotheses and answer questions related to sediment migration and sediment volume change.

The following questions prompted this …

Design And Simulation Of A Miniature Cylindrical Mirror Auger Electron Energy Analyzer With Secondary Electron Noise Suppression, Jay A. Bieber

USF Tampa Graduate Theses and Dissertations

In the nanoscale metrology industry, there is a need for low-cost instruments, which have the ability to probe the structrure and elemental composition of thin films. This dissertation, describes the research performed to design and simulate a miniature Cylindrical Mirror Analyzer, (CMA), and Auger Electron Spectrometer, (AES). The CMA includes an integrated coaxial thermionic electron source. Electron optics simulations were performed using the Finite Element Method, (FEM), software COMSOL. To address the large Secondary Electron, (SE), noise, inherent in AES spectra, this research also included experiments to create structures in materials, which were intended to suppress SE backgound noise in …

Context-Based Human Activity Recognition Using Multimodal Wearable Sensors, Pratool Bharti

USF Tampa Graduate Theses and Dissertations

In the past decade, Human Activity Recognition (HAR) has been an important part of the regular day to day life of many people. Activity recognition has wide applications in the field of health care, remote monitoring of elders, sports, biometric authentication, e-commerce and more. Each HAR application needs a unique approach to provide solutions driven by the context of the problem. In this dissertation, we are primarily discussing two application of HAR in different contexts. First, we design a novel approach for in-home, fine-grained activity recognition using multimodal wearable sensors on multiple body positions, along with very small Bluetooth beacons …

Investigating Marine Resources In The Gulf Of Mexico At Multiple Spatial And Temporal Scales Of Inquiry, Joshua Paul Kilborn

USF Tampa Graduate Theses and Dissertations

The work in this dissertation represents an attempt to investigate multiple temporal and spatial scales of inquiry relating to the variability of marine resources throughout the Gulf of Mexico large marine ecosystem (Gulf LME). This effort was undertaken over two spatial extents within the greater Gulf LME using two different time-series of fisheries monitoring data. Case studies demonstrating simple frameworks and best practices are presented with the aim of aiding researchers seeking to reduce errors and biases in scientific decision making. Two of the studies focused on three years of groundfish survey data collected across the West Florida Shelf (WFS), …

The Performance Of Multilevel Structural Equation Modeling (Msem) In Comparison To Multilevel Modeling (Mlm) In Multilevel Mediation Analysis With Non-Normal Data, Thanh Vinh Pham

USF Tampa Graduate Theses and Dissertations

The mediation analysis has been used to test if the effect of one variable on another variable is mediated by the third variable. The mediation analysis answers a question of how a predictor influences an outcome variable. Such information helps to gain understanding of mechanism underlying the variation of the outcome. When the mediation analysis is conducted on hierarchical data, the structure of data needs to be taken into account. Krull and MacKinnon (1999) recommended using Multilevel Modeling (MLM) with nested data and showed that the MLM approach has more power and flexibility over the standard Ordinary Least Squares (OLS) …

Imaging Wetland Hydrogeophysics: Applications Of Critical Zone Hydrogeophysics To Better Understand Hydrogeologic Conditions In Coastal And Inland Wetlands And Waters, Christine Marie Downs

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three projects utilizing electric and electromagnetic (EM) methods to better understand critical-zone hydrogeologic conditions in select Florida wetlands and waters.

First, a time-lapse electrical resistivity (ER) survey was conducted in section of mangrove forest on a barrier island in southeast Florida to image changes in pore-water salinity in the root zone. ER data show the most variability in the root zone over a 24-hour period, and, generally, the ground is more resistive during the day than overnight.

Second, a suite of three-dimensional forward models, based on varying lateral boundaries and conductivities typical of a coastal wetland, …

Resolving Chronological And Temperature Constraints On Antarctic Deglacial Evolution Through Improved Dating Methodology, Cristina Subt

USF Tampa Graduate Theses and Dissertations

In order to determine the timing of Antarctic ice sheet retreat and advance during the Late Quaternary, various tools are used to measure the age of marginal marine sediments. Carbonate 14C dating is a well-established approach, but requires foraminiferal microfossils, shells or other carbonate materials that are rare in most Antarctic regions, and may also suffer from vital effects, which can result in variability of up to 500 years in living organisms. Bulk acid insoluble organic (AIO) 14C dates are frequently as an alternative, but this approach works best where high productivity and sedimentation rates reign, and not too well …

Bayesian Inference On Quantile Regression-Based Mixed-Effects Joint Models For Longitudinal-Survival Data From Aids Studies, Hanze Zhang

USF Tampa Graduate Theses and Dissertations

In HIV/AIDS studies, viral load (the number of copies of HIV-1 RNA) and CD4 cell counts are important biomarkers of the severity of viral infection, disease progression, and treatment evaluation. Recently, joint models, which have the capability on the bias reduction and estimates' efficiency improvement, have been developed to assess the longitudinal process, survival process, and the relationship between them simultaneously. However, the majority of the joint models are based on mean regression, which concentrates only on the mean effect of outcome variable conditional on certain covariates. In fact, in HIV/AIDS research, the mean effect may not always be of …

Generalized D-Kaup-Newell Integrable Systems And Their Integrable Couplings And Darboux Transformations, Morgan Ashley Mcanally

USF Tampa Graduate Theses and Dissertations

We present a new spectral problem, a generalization of the D-Kaup-Newell spectral problem, associated with the Lie algebra sl(2,R). Zero curvature equations furnish the soliton hierarchy. The trace identity produces the Hamiltonian structure for the hierarchy. Lastly, a reduction of the spectral problem is shown to have a different soliton hierarchy with a bi-Hamiltonian structure. The first major motivation of this dissertation is to present spectral problems that generate two soliton hierarchies with infinitely many commuting conservation laws and high-order symmetries, i.e., they are Liouville integrable.

We use the soliton hierarchies and a non-seimisimple matrix loop Lie algebra in order …

Metal-Organic Frameworks And Mof-Derived Carbon Materials For Fuel Cell Applications, Kia Williams

USF Tampa Graduate Theses and Dissertations

Rapid industrial globalization and technological development and energy consumption across the globe has significantly increased in response to mounting energy needs. The necessity for alternative and sustainable energy conversion devices has become apparent with the growth of energy utilization. In recent years, many research efforts have been made in the development of low-cost, efficient, environmentally friendly energy conversion devices. One type of energy conversion device, polymer electrolyte membrane fuel cells (PEMFCs), uses hydrogen oxidation at the anode and oxygen reduction at the cathode, with a solid-state proton conducting membrane between to generate energy with water as a by-product. PEMFCs use …

Design, Synthesis, Applications Of Polymers And Dendrimers, Alekhya Nimmagadda

USF Tampa Graduate Theses and Dissertations

WHO has reported that antibiotic resistance is the third major cause of human death all over the globe. Recent study, has focused on the development of new antibacterial resistance drugs. Herein, we tried to synthesis a series of polymers that can mimic the HDPs. HDPs can target the bacterial cell membrane and they have less chances to develop bacterial resistance. We synthesized the amphiphilic polycarbonates that are highly selective to Gram-positive bacteria, including multidrug resistant pathogens. The membrane disruption activity of these polymers was proved by fluorescence and TEM studies and the drug resistance study showed that the polymers don’t …