Physical Sciences and Mathematics Commons^™

Determining The P-Wave Velocity Structure In The Near-Surface Of Nw Miami, Florida, Using Quarry Blasts, Elham Moslemi

USF Tampa Graduate Theses and Dissertations

The fact that Florida is an earthquake-free region has caused seismologists to pay less attention to it. Few earthquakes in this state mean it is not a usual practice to study the propagation of seismic waves. However, utilizing data from quarry blasts, we studied wave propagation in this region. The primary objective of the project is to investigate the near-surface P-wave velocity structure and factors that may affect it. We also analyzed the amplitude of signals versus distance and blast size. A network of up to 10 Raspberry Shake instruments around the NW Miami-Lakes mining area was deployed where four …

Examining Paleoshorelines In The Eastern Gulf Of Mexico: Insights On Sea Level History And Potential Areas Of Interest For Habitat Management, Catalina Rubiano

USF Tampa Graduate Theses and Dissertations

An inventory of multibeam bathymetry containing relict drowned and lithified paleoshorelines has been compiled and analyzed in the first ever shelf-wide investigation of paleo sea level indicators on the west Florida shelf (WFS). On the largest scale, the WFS is a wide and gently sloping terrain that is characterized by a carbonate-rich sediment regime. This framework coupled with the region’s tectonic stability provided a setting in which sea level changes since ~ 20 ka have been recorded to a remarkable degree of resolution in the form of paleoshorelines which formed at sea level and were subsequently drowned and preserved in …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Understanding Controls On Spring Hydrographs In An Eogenetic Karst Aquifer In North-Central Florida, Ryan Almeqhem

USF Tampa Graduate Theses and Dissertations

Florida has one of the largest karst aquifers in the United States, with a significant portion of its water resources originating from the eogenetic karst system in north central Florida. Despite the importance of this system, eogenetic karst still needs to be studied compared to telogenetic karst. The hydrological behavior of karst aquifers is complex, with numerous factors influencing the timing, magnitude, and shape of spring hydrographs. One hypothesis, by Florea and Vacher (2006), suggests that matrix permeability is the primary control of spring hydrographs in karst systems. However, this thesis challenges this hypothesis by presenting evidence that the recharge …

Detection Of Subsidence In West-Central Florida Using Persistent Scatterer Interferometry And Near-Surface Geophysics, Tonian R. Robinson

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three studies that employ Persistent Scatterer Interferometry (PSI, also known as PSInSAR) to better understand how subsidence in west-central Florida relates to underlying geological processes. In the first study, near-surface geophysical methods (Ground Penetrating Radar (GPR) and Electrical Resistivity (ERT)), terrestrial remote sensing applications (Light Detection and Ranging (LiDAR) and Structure from Motion (SfM)), and PSI were used to monitor the spatial and temporal behaviors of a suspected growing sinkhole in the Sandhill Boyscout Reservation, Hernando County, Florida. The survey area was located within and around a topographic low assumed to be the surface of the …

Flow Generation And Propagation From Headwater Wetlands To Downstream Waters, Leanne Marie Stepchinski

USF Tampa Graduate Theses and Dissertations

Headwater wetlands are connected to one another and to downstream waters by dynamic hydrologic flowpaths, functioning as integrated hydrologic networks at the watershed scale. Headwater wetlands perform a variety of hydrologic lag, sink, and source functions, including flow generation and propagation, thereby contributing to the natural flow regimes of downgradient waters. The functions of individual wetlands and their contributions to hydrologic connectivity and subsequently to the natural flow regime have been widely studied and are well understood. Comparatively, the functions and hydrologic connectivity within wetland complexes as a whole and their collective subsequent contributions to the natural flow regime of …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Applications Of Seismic And Geodetic Data To Earthquake Hazard Research, Mahsa Afra

USF Tampa Graduate Theses and Dissertations

Being a part of a seismically active zone, including large and crowded cities such asTehran, Qazvin and Semnan, Central Alborz experiences many local earthquakes. Knowl- edge of crustal velocity structure in this area is thus necessary considering its economical and political importance, a large concentration of population, and relatively poor construc- tion practice which increases the earthquake risks in this region. In second chapter of this thesis, we aim at obtaining the 3D crustal velocity structure of the Central Alborz region in northern Iran using local earthquake tomography. We also validate anomalies inferred from our velocity model using an independent …

A Seismic Investigation Of Uturuncu Volcano And The Lazufre Volcanic Complex, Heather L. Mcfarlin

USF Tampa Graduate Theses and Dissertations

The following dissertation is a study of three seismological techniques used to determine the geophysical properties of two large, inflating magma bodies in the upper crust in South America: one under Uturuncu volcano and one beneath Lastarria and Cordon del Azufre volcanoes. First, I use the method of teleseismic receiver functions to image the top and bottom of the magma body beneath Uturuncu volcano. Depths to the top of this body vary between 6 and 12 km below sea level, while depths to the bottom vary between 13 and 22 km below sea level, with the thickness ranging from 6 …

Lithium And Lithium Isotope Behavior During High Temperature Solid/Fluid Exchanges: Examples From Iceland And The Izu-Bonin Forearc, Alex Maruszczak

USF Tampa Graduate Theses and Dissertations

The development of a method for lithium isotopic measurement was developed using a quadrupole, single-collector ICP-MS. Measured precision was ±1.00‰ 2σ over a 15-month period based on measurements of international rock standards. A 1-hour leach using cold, HCl was sufficient to remove alteration-related Li in minimally to moderately altered seafloor basalts. Measurements on the Holocene ages lavas from the neovolcanic zones of Iceland suggest no systematic Li isotopic variability among the differing Icelandic sources. Felsic samples from Hekla and Pumice contain elevated Li contents of >18ug/g while the tholeiitic and alkaline basalts are <8ug/g Li. Most of the island lies around MORB values of ~+3 to +5‰ with the exception of Western Volcanic Zone samples that show evidence for seawater inputs. The RN-17 drillcore, which penetrates >3000m through a hydrothermal system in the …

Land Use/Land Cover Uncertainty Analysis Using Hydrological Modeling In The Northern Watershed Of Lake Okeechobee, Andres Lora Santos

USF Tampa Graduate Theses and Dissertations

Over the past 150 years, Florida has undergone a major land-form transformation, transitioning from a natural to a primarily built environment. The state's population has grown exponentially, from less than 50,000 residents in the 1850s to approximately 22 million residents today. This population growth has led to significant changes in land use, including urbanization, mining, and agriculture. This trend is expected to continue, with projections indicating an increase in urbanization across the state. 2070 land use/land cover projections were used as input for the Watershed Assessment Model (WAM) to analyze the potential impact of these changes on flow, total nitrogen …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Volcano And Tectonic Hazard Modeling Using Interdisciplinary Geophysical And Geodetic Methods, Mitchell Scott Hastings

USF Tampa Graduate Theses and Dissertations

Volcanic and tectonic hazards such as volcanic eruptions, earthquakes and tsunamis present risks to about ~45% of the global population. They have caused at least 1.5 trillion dollars in damages worldwide since the start of the 20th century, and the costs are accelerating as population increases. In this dissertation, new data are combined with existing information and novel modeling approaches to quantify volcanic, earthquake and tsunami hazards.

The Blackfoot Reservoir Volcanic Field (BRVF) is a bimodal volcanic field on southeastern margin of the Eastern Snake River Plain in Idaho. In the BRVF, gravity anomalies reveal two shallow silicic intrusions that …

Functional Morphology And Taphonomy Of Ordovician–Silurian Diploporan Echinoderms, Stephen Ashley Hill

USF Tampa Graduate Theses and Dissertations

Diploporan echinoderms were one of the most speciose groups of stemmed echinoderms during the Ordovician. Despite this widespread abundance, the fossil record of diploporan fauna consists primarily of incomplete specimens, with complete specimens being rare. While the theca, or body, is more commonly preserved, the feeding appendages and the attachment structures (i.e. stems or holdfasts) are seldomly preserved. Insight into these features is highly valuable to the understanding the paleoecology, like the feeding and respiratory strategies, of these enigmatic creatures.

One group of diploporan echinoderms which does have an extensive fossil record, is the Holocystites Fauna, primarily known from the …

A Technique-Based Approach To Structure-From-Motion: Applications To Human-Coastal Environments, Robert Van Alphen

USF Tampa Graduate Theses and Dissertations

Photogrammetry is a method by which physical information can be extracted from thecorrespondence of 2-dimensional images. In the geosciences, Structure-from-Motion (SfM) photogrammetry is a technique that has seen considerable interest in the past decade of research. Here I present three case studies of various scope and methodologies which can inform the use of SfM in the geosciences. First, I discuss the theoretical and algorithmic basis of SfM photogrammetry and its uses thus far in the geosciences. Chapters two through four show specific studies which highlight several approaches to SfM and the data which can be produced. Chapter five then concludes …

Determining Depth Of Closure Based On Time-Series Beach Profiles And Empirical Formulas: A Case Study Along The Florida Coast, Elizabeth Royer

USF Tampa Graduate Theses and Dissertations

Depth of closure (DOC) is defined as the most landward depth seaward of which there is no significant change in bed elevation and no significant net sediment exchange between the nearshore and the offshore over a certain period of time, such as 5 to 20 years. DOC is an essential parameter used in beach and shore protection, sediment management, and many other aspects of coastal studies. Taking advantage of advancements in wave hindcast and bathymetry measurement in the past 20 years (2000-2019), this study determined the DOC at 12 locations along the Florida coast, including three from the northwest Gulf …

Isotopic Study Of The Waters From The Sulphur Springs Catchment, Tampa, Florida, Esra Zengin

USF Tampa Graduate Theses and Dissertations

A stable isotope study was carried out using precipitation, spring water, groundwater well sample, and a seawater sample during the wet season in the Sulphur Springs watershed in Tampa, Florida. Studies that track long term isotopic variation over wet seasons are limited in the region. To fill this knowledge gap, this study aims to quantify the contributions of precipitation and diffuse sources to discharge in Sulphur Springs. A three-component mixing model was applied using δ18O and δ2H values to determine different source water contributions to spring water discharge. The three-component mixing model calculations suggest spring water consists mainly of diffuse …

Empirical And Modeled Δ13c And Δ15n Isoscapes In The Gulf Of Mexico And Their Application To Fish Eye Lens Migration Studies, Brianna Michaud

USF Tampa Graduate Theses and Dissertations

Isoscapes are depictions of the spatial patterns of isotopic values in a given area. Isoscapes can be created using measurements form samples (empirical isoscapes) or using statistical models of spatial isotopic variation (modeled isoscapes). Isoscapes have a wide variety of potential applications though, in the realm of marine ecology, they are most often used infer ecological processes, food web linkages, the origin of samples, and the movements of marine organisms.

However, to use isoscapes for these applications, it is necessary to have isoscapes at spatial scales relevant to the application in question. It is also necessary to have isoscapes that …

Factors Controlling Longshore Variations Of Beach Changes Induced By Hurricane Hermine Along Pinellas County Beaches, West-Central Florida, Wenhan Zhai

USF Tampa Graduate Theses and Dissertations

Hurricane Hermine, 2016, impacted the coast of west-central Florida and generated high waves superimposed on elevated wave levels which caused significant beach erosion. A total of 122 profiles, spaced about 300 m apart, were surveyed 2 weeks before and one week after the storm to examine the beach changes along three barrier islands along the coast of west-central Florida. including Sand Key, Treasure Island and Long Key. In order to investigates the longshore variations of beach/nearshore changes induced by storm, several parameters were defined and calculated including beach volume changes, berm height, beach width, foreshore slope, as well as sandbar …

Soil Accretion And Mass Accumulation In A Scrub And Fringe Mangrove Forest In Biscayne Bay, Florida, Jessica A. Jacobs

USF Tampa Graduate Theses and Dissertations

This study estimated soil accretion and mass (organic carbon (OC), total nitrogen (TN), and total soil) accumulation in a scrub and fringe mangrove forest in Biscayne Bay, FL, to assess how forests of different morphologies (scrub vs. fringe) have kept pace with recently accelerating rates of sea-level rise. Accretion rates (AR) were estimated using the Constant Initial Concentration (CIC) model of lead-210 deposition and it was determined that the scrub forest has accreted at 1.3 ± 0.2 mm yr-1 over 75 years and the fringe forest at 2.8 ± 0.4 mm yr-1 over 92 years. The fringe forest estimate met …

Revisiting Darwin’S Little Pond As A Method To Liberate Phosphorus From Apatite Under Prebiotic Hadean Earth Conditions, Jennifer Lago

USF Tampa Graduate Theses and Dissertations

Phosphorus is an essential element for life as we know it. Phosphorus, mainly in the form of phosphate, is key to biologic functions such as genetic material, energy production, and cellular framework. As phosphorus is key to so many important biological functions it is of no wonder the question of how phosphorus was incorporated into life initially is a fundamental question in how life began.

During this time a prebiotic phosphorus source would need to have originated in rock, as phosphorus has not volatile source on Earth. The most prevalent mineral source on a prebiotic Earth would likely have been …

Resolution Of Lava Tubes With Ground Penetrating Radar, Sanaz Esmaeili

USF Tampa Graduate Theses and Dissertations

Finding habitable places to keep astronauts safe from surface radiation, magnetic storms, and temperature fluctuations will be an important component of future planetary exploration missions. Remote sensing surveys on other planets indicate the presence of lava tubes. Ground Penetrating Radar (GPR) has shown great potential for detection of tunnels in terrestrial environments. In this research, the capabilities of this near surface rapid exploratory tool for detection of lava tubes are investigated. This dissertation describes terrestrial examples of how GPR can be utilized to explore tubes and addresses the capabilities of GPR for resolving tube-related features such as the floor, fractures, …

Three-Dimensional Intrusion Geometries In The Monogenetic San Rafael (Utah) Sub-Volcanic Field Revealed By Nonlinear Inversion Of Magnetic Anomaly Data, Troy A. Berkey

USF Tampa Graduate Theses and Dissertations

Distributed volcanic fields are common on Earth and nearby planetary bodies. Unlike their central-vent counterparts, these volcanic centers are comprised of many individual basaltic magmatic dikes, which are often only expressed at the surface in the form of vents, domes, and lava flows. In situ imaging of the shallow (<1 km) subsurface can reveal important details about the 3D geometry of fissure systems that feed distributed eruptive centers, with implications for the nature of these eruptions: their mass flow rates, explosivity, durations, and volcanotectonic interaction. Luckily, dikes, sills, conduits and related near-surface structures tend to carry high remnant magnetizations, creating magnetic anomalies at the surface where sufficient magnetic contrast exists with the host rocks they intrude. In the San Rafael Sub-volcanic field (SRSVF), basaltic dikes intrude fractured and horizontally bedded Jurassic sandstones, now eroded to a depth of about 800 m beneath the paleo-surface. Detailed mapping and profiles with a Cs-vapor magnetometer reveal far more complex anomalies than can be attributed to simple planar dikes, including: sills, buds, and domes. We image these geometries using MagCube-parallel, an open-source nonlinear inversion code we developed that models complex geometry with multiple (<= 1,000) vertical-sided prisms. I show one normally polarized fissure system to include along strike: An ~3-14 m thick, ~50 m wide dome-like feature or laccolith at depths of ~9-20 m, a roughly vertical conduit ~15 m thick, ~36-50 m wide, at ~1-16 m depth near the center of the mapped fissure-like system, and a ~8-48 m. wide dike at ~2-17 m depth that is <1-6 m thick, with reducing magnitude northward. While model depth and thickness vary with magnetization contrast, the main geometric relationships do not. Magnetic mapping of a nearby fissure reveals the same types of structures. The implication of these structures is that the small-volume fissure eruptions were likely pulsatory, with episodes of horizontal intrusion of sills, and sufficient time to develop gravitational instabilities.

The Importance Of Lithologic Variability And Stratigraphic Architecture In The Development Of Eogenetic Karst Systems, Nicholas J. Soto-Kerans

USF Tampa Graduate Theses and Dissertations

Integrative characterizations of karst systems on low-lying eogenetic carbonate platforms are rare and often limited to areas of direct observation where caves can be entered and explored. Because hydraulic properties of eogenetic limestones have been implicitly assumed to be homogeneous, classical models of carbonate island karst development stressed the importance of geochemical interfaces in controlling cave and vug development. These studies have explained the largest cavern systems as results of either 1) mixing dissolution at platform margins or 2) microbially-mediated dissolution processes at water tables.

New data from core descriptions and wireline logs obtained in 18 boreholes drilled in the …

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …

Slow Slip Events And The Earthquake Cycle, Nicholas K. Voss

USF Tampa Graduate Theses and Dissertations

Slow Slip Events (SSEs) represent a new type of strain release along faults, which have onlybeen recognized as a global phenomena with the growth of precision space-borne geodetic techniques. These events represent an important part of the strain budget on faults, sometimes bounding the area of co-seismic release and perhaps limiting the amount of seismic energy release. SSEs have also been suggested to proceed large megathrust earthquakes including the great 2011 Tohoku and 2015 Iquique earthquakes. I document a series of SSE along the Nicoya Peninsula in Costa Rica. These events take place both before and after the 2012 M7.6 …

Assessing Morphological Response And Vulnerability Of Barrier Islands To Extreme Storms In Northwest Florida, Jacob Adam

USF Tampa Graduate Theses and Dissertations

Barrier islands shield the mainland coast from the effects of extreme storms such as increased wave energy and storm surge. During these events, however, barrier morphology can be altered by erosive forces. Thus, compromising the protection offered and leading to increased impact on the mainland. The St. Joseph Peninsula, located in the Northwest of the Gulf of Mexico, is one such barrier at threat from storm-induced erosion. Presented here is an assessment of morphology change induced by two major storms to impact the peninsula, Hurricanes Dennis 2005 and Michael 2018. These changes characterize the erosive/depositional patterns that can be expected …

Factors Controlling Longshore Variations Of Beach Changes Induced By Tropical Storm Eta Along Pinellas County Beaches, West-Central Florida, Francesca Luisa Toledo Cossu

USF Tampa Graduate Theses and Dissertations

Tropical Storm Eta impacted the coast of west-central Florida from November 11 to 12, 2020, and generated high waves over elevated water levels for over 20 hours. A total of 148 beach and nearshore profiles, spaced about 300 m apart, were surveyed one to two weeks before and one to eight days after the storm to examine the beach changes along four barrier islands, including Sand Key, Treasure Island, Long Key and Mullet Key. Storm waves superimposed on elevated water levels reached the toe of dunes, causing modest dune erosion as well as overwash in some areas. Most of the …

Geological And Geochemical Analysis Of Phosphorus Bearing Minerals And Natural Glasses On Earth And In Meteorites: Implications Of The Origin Of Life, Tian Feng

USF Tampa Graduate Theses and Dissertations

Phosphorus is a key element in biogenic molecules and the mineral schreibersite is a major reactive phosphorus source for organic compounds on the prebiotic Earth. In this dissertation, a suite of reactions of phosphorus species, which originate from schreibersite minerals on chondrite meteorites and on the early Earth, have been studied to determine the intermediate geochemical pathways between phosphides and common minerals on meteorites and on the early earth.

I first investigated a unique blue fulgurite that was studied to clarify if this blue color was caused by rich phosphorus content, as has been reported for impact glasses that also …

Ware And Tear In Ancient Tampa Bay: Ceramic Elemental Analyses From Pinellas County Sites, Mckenna Loren Douglass

USF Tampa Graduate Theses and Dissertations

This research tested a null hypothesis on whether ceramics from a variety of archaeological sites around the Pinellas County peninsula were sourced locally for their materials. The sites in this study include Weeden Island (8PI1-5-6-A/B/C/D), Bayshore Homes (8PI41), Yat Kitischee (8PI1753), and Maximo Point (8PI19). Since there were multiple sites that I assessed in the Tampa Bay, Florida area, I focused on one cultural period, Safety Harbor (AD 900-1500), and the ceramics created during it at the various locations. My research questions included: Were materials locally sourced for ceramic production at each of these sites? If not, what is the …