Physical Sciences and Mathematics Commons^™

Florida Fishery-Wide Reproductive Indices Of Stone Crab, Menippe Mercenaria, And Their Application To Stock Assessment And Management, Claire Elizabeth Crowley

USF Tampa Graduate Theses and Dissertations

The stone crab, Menippe mercenaria, supported the third most valuable fishery in Florida in 2016. Declining catch per unit effort (CPUE) and overall negative trend in landings since 2000 have raised concerns among fisherman, researchers, and fishery managers about the resiliency of the fishery. The Florida Fish and Wildlife Research Institute estimated that the Florida stone crab fishery has been overexploited since 1997. Overexploited fisheries, such as the commercial stone crab fishery, risk induced changes in life history parameters, such as age at maturation and reproductive output. In turn, these population-level changes have the potential to reduce the spawning …

Detecting Surface Oil Using Unsupervised Learning Techniques On Modis Satellite Data, Joshua Kidd

USF Tampa Graduate Theses and Dissertations

The release of crude oil or other petroleum based products into marine habitats can have a devastating impact on the environment as well as the local economies that rely on these waters for commercial fishing and tourism. The Deepwater Horizon catastrophe that started on April 20th 2010 leaked an estimated 4.4 million barrels of crude oil into the Gulf of Mexico over a 3 month period threatening thousands of species and crippling the gulf coast. The National Oceanic and Atmospheric Administration (NOAA) used several satellite remote sensing technologies to manually track and predict the extent and location of oil on …

The Impacts Of Population Density, And State & National Litter Prevention Programs On Marine Debris, Melissa Rose Brogle

USF Tampa Graduate Theses and Dissertations

Marine debris is improperly disposed of solid waste, also called litter, which is deposited in the marine environment (NOAA, 2010). Litter prevention techniques such as fines, cleanups, incentives, and others, can help to decrease litter, and ultimately decrease marine debris. This research analyzed 2000 and 2010 International Coastal Cleanup (ICC) data obtained from The Ocean Conservancy to ascertain whether certain litter prevention techniques did reduce amounts and types of marine debris found in coastal areas. The litter prevention techniques analyzed included state bottle bills, voluntary monofilament fishing line recycling programs, and the Keep America Beautiful (KAB) cigarette butt litter prevention …

Self-Assembly Of Self-Similar Structures By Active Tiles, Daria Karpenko

USF Tampa Graduate Theses and Dissertations

The natural capacity of DNA for molecular self-assembly has already been exploited to create DNA based tiles which can self-assemble into nano-scale arrays and carry out nano-scale computation. Thus far, however, all such self-assembly has been passive, in the sense that the binding capacities of a tile are never altered throughout the assembly. The idea of active tiles, tiles that can send signals to each other and activate latent binding sites, has been proposed but never incorporated into a formal model. Here, I present an extension of the existent abstract tile assembly model by defining an active tile assembly and …

Investigation And Synthesis Of Novel Graphene-Based Nanocomposites For Hydrogen Storage, Anthony Joseph D'Angelo

USF Tampa Graduate Theses and Dissertations

It is of great interest to develop and utilize a high surface area material with optimized hydrogen sorption properties. The need for a renewable energy source to replace automobile gasoline has become more critical in the past decade. Hydrogen is a viable fuel source for automobile usage; however, the question of how hydrogen will be safely and efficiently stored still remains. Critical factors for optimum hydrogen storage include ambient conditions and low activation temperature for adsorption and desorption phenomena. In order for optimum hydrogen adsorption to be achieved, the properties of (1) high surface area, (2) optimum hydrogen adsorption energy, …

Multidimensional Spectroscopy Of Semiconductor Quantum Dots, Jason Michael Bylsma

USF Tampa Graduate Theses and Dissertations

The coherent properties of semiconductor nanostructures are inherently difficult to measure and one-dimensional spectroscopies are often unable to separate inhomogeneous and homogeneous linewidths. We have refined and improved a method of performing multidimensional Fourier transform spectroscopy based on four-wave

mixing (FWM) experiments in the box geometry. We have modified our system with broadband beamsplitters in all interferometer arms, high-resolution translation stages and the ability to work in reflection geometry. By improving the phase-stability of our setup and scanning pulse delays with sub-optical cycle precision, we are able to

reproduce 2DFT spectra of GaAs multiple quantum wells. With the FWM signal …

A Principled Approach To Policy Composition For Runtime Enforcement Mechanisms, Zachary Negual Carter

USF Tampa Graduate Theses and Dissertations

Runtime enforcement mechanisms are an important and well-employed method for ensuring an execution only exhibits acceptable behavior, as dictated by a security policy. Wherever interaction occurs between two or more parties that do not completely trust each other, it is most often the case that a runtime enforcement mechanism is between them in some form, monitoring the exchange. Considering the ubiquity of such scenarios in the computing world, there has been an increased effort to build formal models of runtime monitors that closely capture their capabilities so that their effectiveness can be analysed more precisely. While models have grown more …

Examining The Economic Costs And Sources Of Potable And Nonpotable Water In Northern Mexico, Kathryn Marie Marlor

USF Tampa Graduate Theses and Dissertations

Water availability and the cost of different water sources have been studied at great length. However, information is still needed to determine the policy directions to be undertaken by nations that have not yet achieved universal coverage of an improved water source. To further examine differences in water availability and pricing in the context of the developing world, three communities in Northern Mexico were surveyed to determine the differences in water distribution schemes and associated costs between rural and urban centers. It was observed that rural communities without a piped water supply paid 13 percent more for potable water supplies …

Design And Construction Of Functional Metal-Metalloporphyrin Frameworks, Le Meng

USF Tampa Graduate Theses and Dissertations

Porous metal-organic frameworks are a new type of functional materials with potential applications for gas storage, gas separation, catalysis, biomedical and chemical sensors. This thesis describes several porous metal-metalloporphyrin frameworks (MMPFs), which were synthesized with a series of transition metals and 5,15-bis(3,5-dicarboxyphenyl)-10,20-bis(2,6-dibromophenyl)porphine. Among these MMPFs, the cobalt MMPF (CoBrPTC) has a fcu structure, which represents the first porphyrin-based MOF with this topology. CoBrPTC was evaluated as heterogeneous catalyst and demonstrated interesting catalytic performances.

Willingness-To-Pay For Maintenance And Improvements To Existing Sanitation Infrastructure: Assessing Community-Led Total Sanitation In Mopti, Mali, Justin Vern Meeks

USF Tampa Graduate Theses and Dissertations

In recent years, much focus has been put on the sustainability of water and sanitation development projects. Experts in this field have found that many of the projects of the past have failed to achieve sustainability because of a lack of demand for water and sanitation interventions at a grassroots level. For years projects looked to create this demand through various subsidy schemes, with the "software" of behavior change and education taking a backseat to the "hardware" of infrastructure provision. Community-Led Total Sanitation (CLTS) is a fairly new way of looking at the issues of increasing basic sanitation coverage, promoting …

Developing Predictive Models For Lung Tumor Analysis, Satrajit Basu

USF Tampa Graduate Theses and Dissertations

A CT-scan of lungs has become ubiquitous as a thoracic diagnostic tool. Thus, using CT-scan images in developing predictive models for tumor types and survival time of patients afflicted with Non-Small Cell Lung Cancer (NSCLC) would provide a novel approach to non-invasive tumor analysis. It can provide an alternative to histopathological techniques such as needle biopsy. Two major tumor analysis problems were addressed in course of this study, tumor type classification and survival time prediction. CT-scan images of 109 patients with NSCLC were used in this study. The first involved classifying tumor types into two major classes of non-small cell …

Evidence For Viral Infection In The Copepods Labidocera Aestiva And Acartia Tonsa In Tampa Bay, Florida, Darren Stephenson Dunlap

USF Tampa Graduate Theses and Dissertations

Mesozooplankton are of critical importance to marine food webs by transferring energy from the microbial food web to higher trophic levels and depositing energy to the deeper ocean layers through fecal deposition. While decades of research have shown that viruses have significant impacts in the oceans, and infect a wide range of organisms from bacteria to whales, there is still little known about the impacts of viruses on the mesozooplankton community. As copepods are the most abundant mesozooplankton group, this study sought to characterize the viruses present in natural populations of the calanoid copepods Acartia tonsa and Labidocera aestiva in …

An Ecological Assessment Of A Juvenile Estuarine Sportfish, Common Snook (Centropomus Undecimalis), In A Tidal Tributary Of Tampa Bay, Florida, Adam Benjamin Brame

USF Tampa Graduate Theses and Dissertations

The common snook, Centropomus undecimalis, is an estuarine dependent sport fish that relies upon subtidal wetlands as nursery habitat. Despite the economic and recreational significance of this species, there are portions of its life history and biology that are poorly understood, particularly its early life history. Understanding juvenile snook use of wetland habitats is crucial given the rapid loss and degradation of these areas to anthropogenic impacts. Young-of-the-year snook were collected in pond and creek habitats of a single wetland system to assess early life ecology and habitat use. Proxies of habitat quality were used to determine which habitats …

Overcoming Limitations Of Serial Audio Search, Isabela Cordeiro Ribeiro Moura Hidalgo

USF Tampa Graduate Theses and Dissertations

The typical approach for finding audio recordings, such as music and sound effects, in a database is to enter some textual information into a search field. The results appear summarized in a list of textual descriptions of the audio files along with a function for playing back the recordings. Exploring such a list sequentially is a time-consuming and tedious way to search for sounds. This research evaluates whether searching for audio information can become more effective with a user interface capable of presenting multiple audio streams simultaneously.

A prototype audio player was developed with a user interface suitable for both …

Removal Of Bisphenol A Model Compounds And Related Substances Using Octolig®, Rachael Josephine Alessio

USF Tampa Graduate Theses and Dissertations

Bisphenol A used in the production of polycarbonate plastics and epoxy resins is ubiquitous in the environment. The raw material is released to the environment during the manufacturing process and by leaching from consumer products. Recent studies are suggesting that low-dose amounts of Bisphenol A may have adverse health effects on humans. The possibility of removing Bisphenol A from natural water sources or from solvents used to extract the material from consumer products before they enter the market has been studied. The use of model compounds and related substances (4-isopropylphenol, 4-(t-butyl) phenol, and nitrophenols) have been used to study their …

Compound-Specific Stable Isotopic Analysis Of Protein Amino Acids: Ecological Applications In Modern And Ancient Systems, Greg Ellis

USF Tampa Graduate Theses and Dissertations

Stable isotopic analysis of the major biochemically important elements is an increasingly utilized tool in the study of ecology. Patterns of isotopic fractionation in carbon and nitrogen are used to determine trophic linkages, nutrient pathways, and sources of primary production in numerous contexts. Traditional techniques rely on measurements made of bulk samples such as tissue, but emerging methods using individual chemical compounds provide a means of achieving deeper understanding in a variety of inquiries.

Amino acids, as the building blocks of proteins, are the dominant nitrogen-bearing biomolecules and are a major constituent of all life. Patterns of isotopic fractionation during …

Synthesis And Characterization Of Nanocomposites For Electrochemical Capacitors, Farah Alvi

USF Tampa Graduate Theses and Dissertations

Presently there are deep concerns over the environmental consequences and the consumption of non-renewable energy sources, with the accelerated greenhouse effect, triggered enormous interest in the use of renewable energy sources e.g., solar, hydropower, wind and geothermal. However the intermittent nature of harvesting renewable energy sources has recently gained considerable attention in the alternative reliable, cost effective, and environmentally friendly energy storage devices. The supercapacitor and lithium ion batteries are considered more efficient electrical energy storage devices than conventional energy storage systems.

Both devices have many useful and important applications; they could be an excellent source for high power and …

A Ctd Biotag For Mid-Sized Marine Predators, Heather Broadbent

USF Tampa Graduate Theses and Dissertations

Biologging tools for investigating the study of fine-scale linkages between animal behavior and the physical microstructure of the marine habitat are technically limited by substantial size, high cost or low sensor resolution. However, recent advances in electronic technologies and process techniques present attractive alternatives to current tag designs. Motivated by the need for a low-cost, compact CTD biotag for medium-sized marine animals, the University of South Florida Center for Ocean Technology developed a multi-sensor biotag for quantitative measurements of ocean salinity. This dissertation describes the development and performance of a novel CTD biotag used for animal-borne measurements of the physical …

Vent-Fault Spatial Study Of Selected Volcanic Fields Of Southwestern North America And Mexico, Michelle Leonard

USF Tampa Graduate Theses and Dissertations

Of fundamental concern in volcanic hazard and risk assessment studies of volcanic systems is what role crustal structures might play in the ascent of magma through the crust. What are the processes that govern the spatial distribution and timing of eruptions, especially in populated areas or near sensitive facilities? Many studies have drawn the conclusion that faults play a critical role as easily–exploitable crustal weaknesses along which magma can ascend. Great care must be used when assuming a causative relationship between patterns of vents and faults especially when such relationships may be incorporated into hazard assessment models or other forecasting …

Thermal Determinants Of Nest Site Selection In Loggerhead Sea Turtles, Caretta Caretta, At Casey Key, Florida, Lindsey Nicole Flynn

USF Tampa Graduate Theses and Dissertations

Many environmental cues are thought to influence nest site selection by loggerhead sea turtles, Caretta caretta, and much debate exists over the possible influence of sand temperature. This study had two primary objectives: (1) to measure thermal differences across transects of a major nesting beach of Casey Key (28.7 N, 82.3 W), Florida and (2) to evaluate thermal pattern variation that influenced nesting patterns of adult female loggerhead sea turtles. A secondary objective of this study was to determine the efficacy of infrared thermometers to collect sand surface temperatures in the field.

Temperature data were collected from 145 nest …

Extraction Of Text Objects In Image And Video Documents, Jing Zhang

USF Tampa Graduate Theses and Dissertations

The popularity of digital image and video is increasing rapidly. To help users navigate libraries of image and video, Content Based Information Retrieval (CBIR) system that can automatically index image and video documents are needed. However, due to the semantic gap between low-level machine descriptors and high-level semantic descriptors, the existing CBIR systems are still far from perfect. Text embedded in multi-media data, as a well-defined model of concepts for humans' communication, contains much semantic information related to the content. This text information can provide a much truer form of content-based access to the image and video documents if it …

Basal Graph Structures For Geometry Based Organization Of Wide-Baseline Image Collections, Aveek Shankar Brahmachari

USF Tampa Graduate Theses and Dissertations

We propose algorithms for organization of images in wide-area sparse-view datasets. In such datasets, if the images overlap in scene content, they are related by wide-baseline geometric transformations. The challenge is to identify these relations even if the images sparingly overlap in their content. The images in a dataset are then grouped into sets of related images with the relations captured in each set as a basal (minimal and foundational) graph structures. Images form the vertices in the graph structure and the edges define the geometric relations between the images. We use these basal graphs for geometric walkthroughs and detection …

Hamiltonian Sets Of Polygonal Paths In 4-Valent Spatial Graphs, Tilahun Abay Muche

USF Tampa Graduate Theses and Dissertations

Spatial graphs with 4–valent rigid vertices and two single valent endpoints, called assembly graphs, model DNA recombination processes that appear in certain species of ciliates. Recombined genes are modeled by certain types of paths in an assembly graph that make a ”oper pendicular ” turn at each 4–valent vertex of the graph called polygonal paths. The assembly number of an assembly graph is the minimum number of polygonal paths that visit each vertex exactly once. In particular, an assembly graph is called realizable if the graph has a Hamiltonian polygonal path.

An assembly graph ɣ^{^} obtained from a given …

Global Csr And Photographic Credibility: Exploring How International Companies Portray Efforts Through Photographs In Csr Reports, Janel Lynn Norton

USF Tampa Graduate Theses and Dissertations

We are living in the age of the visual. Imagery is an important element in constructing and deriving meaning through symbols, colors, and context. Images may hold persuasive power, be used as evidence, or simply provide a moment of beauty. Organizations rely on photographs to help them convey an image to their stakeholders within annual reports. Telling an organizations' story through photographs has become an intrinsic part of their efforts to convey sustainability. We live in the age of transparency, and organizations that construct an image that is not truthful will face consequences in today's socially connected and conscious world. …

Occurrence, Toxicity, And Diversity Of Pseudo-Nitzschia In Florida Coastal Waters, Sheila O'Dea

USF Tampa Graduate Theses and Dissertations

Domoic acid (DA), a potent neurotoxin that has the potential to cause amnesic shellfish poisoning (ASP), is produced by members of the marine diatom genus Pseudo-nitzschia. Outbreaks of ASP in humans and of DA poisoning in birds and marine mammals have been reported across the United States and Canada since the late 1980's. Pseudo-nitzschia species can be extremely abundant in Florida waters, with densities often exceeding 10⁶ cells/L, and sometimes exceeding 10⁷ cells/L. Based on preliminary data, it is evident that at least nine species of Pseudo-nitzschia are found in Florida coastal waters. At least six of …

Statistical Content In Middle Grades Mathematics Textbooks, Maria Consuelo (Suzie) Capiral Pickle

USF Tampa Graduate Theses and Dissertations

Statistical Content in Middle Grades Mathematics Textbooks

Maria Consuelo (Suzie) Capiral Pickle

Abstract

This study analyzed the treatment and scope of

statistical concepts in four, widely-used, contemporary, middle

grades mathematics textbook series: Glencoe Math Connects,

Prentice Hall Mathematics, Connected Mathematics Project, and

University of Chicago School Mathematics Project. There were

three phases for the data analysis. Phase 1 addressed the location

and sequence of the statistical concepts. Phase 2 focused upon an

examination of the lesson narrative, its components and scope.

Phase 3 analyzed the level of cognitive demand required of the

students to complete the exercises, and the total …

Novel Blends Of Sulfur-Tolerant Water-Gas Shift Catalysts For Biofuel Applications, Timothy Michael Roberge

USF Tampa Graduate Theses and Dissertations

As traditional sources of energy become depleted, significant research interest has gone into conversion of biomass into renewable fuels. Biomass-derived synthesis gas typically contains concentrations of approximately 30 to 600 ppm H2S in stream. H2S is a catalyst poison which adversely affects downstream processing of hydrogen for gas to liquid plants. The water-gas shift reaction is an integral part of converting CO and steam to H2 and CO2. Currently, all known water-gas shift catalysts deactivate in sulfur concentrations typical of biomass-derived synthesis gas. Novel catalysts are needed to remain active in the presence of sulfur concentrations in order to boost …

Natural And Anthropogenic Influences On The Morphodynamics Of Sandy And Mixed Sand And Gravel Beaches, Tiffany Roberts

USF Tampa Graduate Theses and Dissertations

Beaches and coastal environments are dynamic, constantly shaped and reshaped by natural processes and anthropogenic modifications. The morphodynamics and influence of natural and anthropogenic factors of two different coasts at various temporal and spatial scales are discussed.

To quantify the performance of several beach nourishment projects at annual temporal and kilometer spatial scales on three adjacent microtidal low-wave energy barrier islands in west-central Florida, a total of 5,200 beach and nearshore-profiles spaced at 300 m were surveyed monthly to bi-monthly from 2006-2010. Beach nourishment performance is most significantly influenced by the interruption of longshore sediment transport by complex tidal-inlet processes. …

On The Spatial And Temporal Variability Of Upwelling In The Southern Caribbean Sea And Its Influence On The Ecology Of Phytoplankton And Of The Spanish Sardine (Sardinella Aurita), Digna Tibisay Rueda-Roa

USF Tampa Graduate Theses and Dissertations

The Southern Caribbean Sea experiences a strong upwelling process along the coast from about 61°W to 75.5°W and 10-13°N. In this dissertation three aspects of this upwelling system are examined: (A) A mid-year secondary upwelling that was previously observed in the southeastern Caribbean Sea between June-July, when land based stations show a decrease in wind speed. The presence and effects of this upwelling along the whole southern Caribbean upwelling system were evaluated, as well as the relative forcing contribution of alongshore winds (Ekman Transport, ET) and wind-curl (Ekman Pumping, EP). (B) Stronger upwelling occurs in two particular regions, namely the …

Sea Surface Height: A Versatile Climate Variable For Investigations Of Decadal Change, Philip Robert Thompson

USF Tampa Graduate Theses and Dissertations

Decadal variations in climate are important, because the magnitude of sustained decadal change is often much larger than the often discussed background trends. Climate variability at interannual and longer periods is most often discussed in the context of climate modes defined by sea level pressure (SLP) and sea surface temperature (SST) patterns. However, SLP and SST are not capable descriptors of ocean dynamics. The approximately two decades of global sea surface height (SSH) measurements from satellite altimetry reveal substantial low-frequency redistributions of heat and salt in the ocean, which may or may not be related to defined climate modes. In …