Physical Sciences and Mathematics Commons^™

Sediment Transport And Distribution Over Continental Shelves: A Glimpse At Two Different River-Influenced Systems, The Cariaco Basin And The Amazon Shelf., Laura Lorenzoni

USF Tampa Graduate Theses and Dissertations

The aim of this dissertation was to understand lithogenic suspended sediment transport mechanisms and distribution in two river-influenced margins: The Cariaco Basin, Venezuela, and the Amazon Shelf, Brazil. Lithogenic sediment input in the Cariaco Basin is controlled by small mountainous rivers (SMR), while in the Amazon Shelf it is dominated by the Amazon River, the largest river in the world in terms of freshwater discharge (~20% of global riverine discharge). Optical transmissometer measurements were coupled with particulate organic matter (POM) observations to understand changes in the geochemical composition of suspended sediment and spatial/temporal distributions over the two regions of interest. …

Production Of Bioactive Secondary Metabolites By Florida Harmful Bloom Dinoflagellates Karenia Brevis And Pyrodinium Bahamense, Cheska Burleson

USF Tampa Graduate Theses and Dissertations

Despite the critical role algae serve as primary producers, increases or accumulation of certain algae may result in Harmful Algal Blooms (HABs). Algal toxins from these blooms contribute significantly to incidences of food borne illness, and evidence suggests HABs are expanding in frequency and distribution. Mitigation of these HABs without knowledge of the ecological purpose and biochemical regulation of their toxins is highly unlikely. The production, function, and potential of secondary metabolites produced by the dinoflagellates Karenia brevis and Pyrodinium bahamense, were investigated.

Brevetoxins were demonstrated by two different methods to localize within the cytosol of Karenia brevis. …

Investigation Of Stress Changes At Mount St. Helens, Washington, And Receiver Functions At The Katmai Volcanic Group, Alaska, With An Additional Section On The Assessment Of Spreadsheet-Based Modules., Heather L. Lehto

USF Tampa Graduate Theses and Dissertations

Forecasting eruptions using volcano seismology is a subject that affects the lives and property of millions of people around the world. However, there is still much to learn about the inner workings of volcanoes and how this relates to the chance of eruption. This dissertation attempts to increase the breadth of knowledge aimed at helping to understand when a volcano is likely to erupt and how large that eruption might be. Chapters 2 and 3 focus on a technique that uses changes in the local stress field beneath a volcano to determine the source of these changes and help forecast …

A Study Of The Eastern Oyster, Crassostrea Virginica, In Tampa Bay: Effects Of Perkinsus Marinus On Reproduction And Condition, Bridgit Melora Mccrickard

USF Tampa Graduate Theses and Dissertations

Abstract

Five sites in Tampa Bay, Florida, were sampled monthly from February 2006 to January 2007. These sites were located at the mouth of the Alafia River, in an inlet of Cross Bayou, on the easement of Gandy Bridge, near mangrove in Manatee County, and an inlet of Salt Creek, off Bayboro Harbor. Standard methods were used to determine shell height and Condition Index (CI). Intensity and prevalence of Perkinsus marinus were analyzed using Ray's Thioglycollate medium test, while Haplosporidium nelsoni was studied by histological examination. Histological methods were also used to determine sex ratios, reproductive phases, and egg diameters. …

Design And Synthesis Of Protein-Protein Interaction Inhibitor Scaffolds, David B. Badger

USF Tampa Graduate Theses and Dissertations

Many currently relevant diseases such as cancer arise from altered biological pathways that rely on protein-protein interactions. The proteins involved in these interactions contain certain functional domains that are responsible for the protein's biological activities. These domains consist of secondary structural elements such as α-helices and Β-sheets which are at the heart of the protein's biological activity. Therefore, designing drugs that inhibit protein-protein interactions by binding to these key secondary structural elements should provide an effective treatment for many diseases. Presented in this dissertation are the designs, syntheses, and biological evaluations for both novel α-helix and novel Β-sheet mimics.

The …

Hierarchy Of Supramolecular Synthons In The Of Design Multi-Component Crystals, Padmini Kavuru

USF Tampa Graduate Theses and Dissertations

Most of the biological systems in nature are sustained by molecular self-assemblies which are the finest examples of supramolecular architectures. Non-covalent interactions are key concepts which govern these molecular assemblies. Inspired by these examples crystal engineering emerged as an important tool in supramolecular chemistry which aids in the invention of new molecular structures with desired properties. Understanding of how the molecules interact at the molecular levels enables one to rationally design novel solid forms with modulated physicochemical properties. This feature of crystal engineering has heightened its position in materials chemistry and is currently one of the most well studied fields …

Assessment Of The Oxbow Morphology Of The Caloosahatchee River And Its Evolution Over Time: A Case Study In South Florida, Chloe Delhomme

USF Tampa Graduate Theses and Dissertations

The Caloosahatchee River, located in Southern Florida, was originally a meandering and relatively shallow river. During the 1920s, the Caloosahatchee River was channelized and became the C-43 canal. The channelization has significantly impacted the river ecosystem, particularly the oxbows. The oxbows are the U-shaped water bodies on each side of the river channel, which are the remnant bends of the original river. To understand how anthropogenic influence affects hydrologic systems, the proposed case study was designed to assess the geomorphic changes of the oxbows of the Caloosahatchee River, Florida. Understanding and documenting the evolution of river morphology is becoming increasingly …

On The Automatic Recognition Of Human Activities Using Heterogeneous Wearable Sensors, Oscar David Lara Yejas

USF Tampa Graduate Theses and Dissertations

Delivering accurate and opportune information on people's activities and behaviors has become one of the most important tasks within pervasive computing. Its wide spectrum of potential applications in medical, entertainment, and tactical scenarios, motivates further

research and development of new strategies to improve accuracy, pervasiveness, and eciency.

This dissertation addresses the recognition of human activities (HAR) with wearable sensors in three main regards: In the rst place, physiological signals have been incorporated as a new source of information to improve the recognition accuracy achieved by conventional approaches, which rely on accelerometer signals solely. A new HAR system, Centinela, was born …

A Location-Aware Architecture Supporting Intelligent Real-Time Mobile Applications, Sean J. Barbeau

USF Tampa Graduate Theses and Dissertations

This dissertation presents LAISYC, a modular location-aware architecture for intelligent real-time mobile applications that is fully-implementable by third party mobile app developers and supports high-precision and high-accuracy positioning systems such as GPS. LAISYC significantly improves device battery life, provides location data authenticity, ensures security of location data, and significantly reduces the amount of data transferred between the phone and server. The design, implementation, and evaluation of LAISYC using real mobile phones include the following modules: the GPS Auto-Sleep module saves battery energy when using GPS, maintaining acceptable movement tracking (approximately 89% accuracy) with an approximate average doubling of battery life. …

Citizen Action, Power Relations And Wetland Management In The Tampa Bay Urban Socio-Ecosystem, Cornelius Owusu Adjei

USF Tampa Graduate Theses and Dissertations

Wetlands are vital ecosystems that provide ecological, economic and social benefits to societies. In the Tampa Bay region in West Central Florida, a growing population has put immense pressure on wetlands. The situation has not gone unnoticed in the public domain with concerns raised about the need to formulate policies that would protect them. However, it has been difficult to ascertain the level of citizen involvement in the decision making process.

This study aimed at investigating whether the perceptions and concerns of citizens drove them to influence local water policy. Questionnaires were used to collect data from residents living in …

A Location-Based Incentive Mechanism For Participatory Sensing Systems With Budget Constraints, Luis Gabriel Jaimes

USF Tampa Graduate Theses and Dissertations

Participatory Sensing (PS) systems rely on the willingness of mobile users to participate in the collection and reporting of data using a variety of sensors either embedded or integrated in their

cellular phones. Users agree to use their cellular phone resources to sense and transmit the data of interest because these data will be used to address a collective problem that otherwise would

be very difficult to assess and solve. However, this new data collection paradigm has not been very successful yet mainly because of the lack of incentives for participation and privacy concerns. Without adequate incentive and privacy guaranteeing …

A Framework For Participatory Sensing Systems, Diego Mendez Chaves

USF Tampa Graduate Theses and Dissertations

Participatory sensing (PS) systems are a new emerging sensing paradigm based on the participation of cellular users in a cooperative way. Due to the spatio-temporal granularity that a PS system can provide, it is now possible to detect and analyze events that occur at different scales, at a low cost. While PS systems present interesting characteristics, they also create new problems. Since the measuring devices are cheaper and they are in the hands of the users, PS systems face several design challenges related to the poor accuracy and high failure rate of the sensors, the possibility of malicious users tampering …

On Algorithmic Fractional Packings Of Hypergraphs, Jill Dizona

USF Tampa Graduate Theses and Dissertations

Let F₀ be a fixed k-uniform hypergraph, and let H be a given k-uniform hypergraph on n vertices. An F₀-packing of H is a family F of edge-disjoint copies of F₀ which are subhypergraphs in H. Let n_F0(H) denote the maximum size |F| of an F₀-packing F of H. It is well-known that computing n_F0(H) is NP-hard for nearly any choice of F₀.

In this thesis, we consider the special case when F₀ is a linear hypergraph, that is, when no two edges …

On The Design Of Socially-Aware Distributed Systems, Nicolas Kourtellis

USF Tampa Graduate Theses and Dissertations

Social media services and applications enable billions of users to share an unprecedented amount of social information, which is further augmented by location and collocation information from mobile phones, and can be aggregated to provide an accurate digital representation of the social world. This dissertation argues that extracted social knowledge from this wealth of information can be embedded in the design of novel distributed, socially-aware applications and services, consequently improving system response time, availability and resilience to attacks, and reducing system overhead. To support this thesis, two research avenues are explored.

First, this dissertation presents Prometheus, a socially-aware peer-to-peer service …

Surface Mass Transfer In Large Eddy Simulation (Les) Of Langmuir Turbulence, Cigdem Akan

USF Tampa Graduate Theses and Dissertations

Over the past century the study of gas exchange rates between the atmosphere and the ocean has received increased attention because of concern about the fate of greenhouse gases such as CO₂ released into the atmosphere. Of interest is the oceanic uptake of CO₂ in shallow water coastal regions as biological productivity in these regions is on average about three times larger than in the open ocean. It is well-known that in the absence of breaking surface waves, the water side turbulence controls gas transfer of sparingly soluble gases such as CO₂ from the air to the …

Wronskian, Grammian And Pfaffian Solutions To Nonlinear Partial Differential Equations, Alrazi Abdeljabbar

USF Tampa Graduate Theses and Dissertations

It is significantly important to search for exact soliton solutions to nonlinear partial differential equations (PDEs) of mathematical physics. Transforming nonlinear PDEs into bilinear forms using the Hirota differential operators enables us to apply the Wronskian and Pfaffian techniques to search for exact solutions for a (3+1)-dimensional generalized Kadomtsev-Petviashvili (KP) equation with not only constant coefficients but also variable coefficients under a certain constraint

(u_t + α ₁(t)u_xxy + 3α ₂(t)u_xu_y)_x +α ₃ (t)u_ty -α ₄(t)u_zz + α ₅(t)(u_x + α ₃(t)u_y) = …

Innovative Desalination Systems Using Low-Grade Heat, Chennan Li

USF Tampa Graduate Theses and Dissertations

Water and energy crises have forced researchers to seek alternative water and energy sources. Seawater desalination can contribute towards meeting the increasing demand for fresh water using alternative energy sources like low-grade heat. Industrial waste heat, geothermal, solar thermal, could help to ease the energy crisis.

Unfortunately, the efficiency of the conventional power cycle becomes

uneconomically low with low-grade heat sources, while, at the same time, seawater desalination requires more energy than a conventional water treatment process. However, heat discarded from low-grade heat power cycles could be used as part of desalination energy sources with seawater being used as coolant …

The Role Of Hsp70 In Cancer: A Study Of The Hsp70 / Akt Relationship, John Koren

USF Tampa Graduate Theses and Dissertations

The Hsp70 family of molecular chaperones is essential for

protein folding, re-folding misfolded client proteins, clearance

of aberrant client proteins, and can also inhibit programmed

cell death. There are two major cytosolic members of this

family: the constitutive Hsc70, and the inducible Hsp72. Under

stress conditions the Hsp70 family protects the cell from

protein related damage by the induction of Hsp72. Hsc70 and

Hsp72 are highly homologous with minor differences in

substrate binding. In cancers, Hsp72 is commonly induced and

this induction is thought to aid in cancer cell survival. In these

studies we demonstrate the differential regulation of the …

Paleobiological Assessment Of Controls Underlying Long-Term Diversity Dynamics, Andrés L. Cárdenas

USF Tampa Graduate Theses and Dissertations

Deciphering the factors underlying both long-term patterns of diversity and taxonomic turnover rates (i.e., extinction, and origination) has been one of Paleobiology's major foci for the past three decades. The importance of documenting these components is that they will expand our ability to interpret and model the evolutionary processes underlying those trends, highlight the evolutionary impact of historical events, and contribute to the formulation of robust predictions about the future of global diversity in response to the current anthropologically driven environmental changes. Accordingly, the first part of this study examines the possible occurrence of global marine evolutionary environmental controls into …

Pfaffian And Wronskian Solutions To Generalized Integrable Nonlinear Partial Differential Equations, Magdy Asaad

USF Tampa Graduate Theses and Dissertations

The aim of this work is to use the Pfaffian technique, along with the Hirota bilinear method to construct different classes of exact solutions to various of generalized integrable nonlinear partial differential equations. Solitons are among the most beneficial solutions for science and technology, from ocean waves to transmission of information through optical fibers or energy transport along protein molecules. The existence of multi-solitons, especially three-soliton solutions, is essential for information technology: it makes possible undisturbed simultaneous propagation of many pulses in both directions.

The derivation and solutions of integrable nonlinear partial differential equations in two spatial dimensions have been …

Fishermen, Politics, And Participation: An Ethnographic Examination Of Commercial Fisheries Management In St. Croix, U.S. Virgin Islands, Cynthia Grace-Mccaskey

USF Tampa Graduate Theses and Dissertations

Currently, there is widespread debate regarding the overall status of the world's fisheries, with some researchers projecting their total collapse in only a few decades, and others concluding the situation is not quite as bleak. Additional debates include what strategies should be used to manage fisheries at various scales, and further research is needed to determine which strategies are most appropriate for use in particular situations and locales, as context is critical.

Recently, prominent common pool resources scholars have expressed the need for ethnographic approaches to studying resource management institutions in order to move beyond the current focus of simply …

Hydrophilic Polymers Of Poly (2-Hydroxy Ethyl Methacrylate) With Tunable Properties For Drug Release, Sequestration Of Blistering Agent, Preparation Of Ultra-Strong Hydrogels & Thermal Stability Of Various Organic Azides, Ramakanth Ananthoji

USF Tampa Graduate Theses and Dissertations

The design and synthesis of new finely tunable porous materials has spurred interest in developing novel uses in a variety of systems. Zeolites, inorganic materials with high thermal and mechanical stability, in particular, have been widely examined for use in applications such as catalysis, ion exchange and separation. A relatively new class of inorganic-organic hybrid materials known as metal-organic frameworks (MOFs) has recently surfaced, and many have exhibited their efficiency in potential applications such as ion exchange and drug delivery. A more recent development is the design and synthesis of a subclass of MOFs based on zeolite topologies (i.e. ZMOFs), …

A Spatially Explicit Agent Based Model Of Muscovy Duck Home Range Behavior, James Howard Anderson

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Research in GIScience has identified agent-based simulation methodologies as effective in the study of complex adaptive spatial systems (CASS). CASS are characterized by the emergent nature of their spatial expressions and by the changing relationships between their constituent variables and how those variables act on the system's spatial expression over time. Here, emergence refers to a CASS property where small-scale, individual action results in macroscopic or system-level patterns over time. This research develops and executes a spatially-explicit agent based model of Muscovy Duck home range behavior. Muscovy duck home range behavior is regarded as a complex adaptive spatial system …

Protein Profiling Of Adenine Nucleoside And Nucleotide Analogs Binding Proteins Using N6-Biotinylated-8-Azidoadenosine Analogs As Affinity Based Protein Profiling Probes, Shikha Mahajan

USF Tampa Graduate Theses and Dissertations

Identification of differential expressions of proteins in proteomic profiles of biological samples shows great potential as a valuable technique for the early diagnosis of various diseases. An important challenge in modern protein profiling approaches is to reduce the complexity of the samples by limiting the number of proteins that need to be evaluated for distinction in the expression between normal and deceased cells. In this research, an affinity based approach for the enrichment of nucleotide and nucleoside binding proteins from a complex cell proteome has been developed. To achieve this goal, new N6-biotinylated-8-azido-adenosine probes (AdoRs) have been designed and synthesized …

Team-Teaching Experiences Of A Mathematician And A Mathematics Teacher Educator: An Interpretative Phenomenological Case Study, Sarah K. Bleiler

USF Tampa Graduate Theses and Dissertations

In recent years, experts and organizations involved in mathematics education have emphasized the importance of collaboration between mathematicians and mathematics teacher educators as a means of improving the professional preparation of mathematics teachers. While several such collaborative endeavors have been documented in the extant literature, most research reports have focused on the products, rather than the process, of collaboration. The purpose of this interpretative phenomenological case study is to gain an understanding of the lived experiences of a mathematician and a mathematics teacher educator as they engaged in a team-teaching collaboration within the context of prospective secondary mathematics teacher preparation. …

Crystal Engineering Of Multi-Component Crystal Forms: The Opportunities And Challenges In Design, Heather Dawn Marie Clarke

USF Tampa Graduate Theses and Dissertations

There is heightened interest to diversify the range of crystal forms exhibited by active pharmaceutical ingredients (APIs) in the pharmaceutical industry. The crystal form can be regarded as the Achilles' heel in the development of an API as it directly impacts the physicochemical properties, performance and safety of the API. This is of critical importance since the crystal form is the preferred method of oral drug delivery by industry and regulatory bodies. The ability to rationally design materials is a lucrative avenue towards the synthesis of functional molecular solids with customized physicochemical properties such as solubility, bioavailability and stability. Pharmaceutical …

Functional Magnetic Nanoparticles, James Gass

USF Tampa Graduate Theses and Dissertations

Nanoparticle system research and characterization is the focal point of this research and dissertation. In the research presented here, magnetite, cobalt, and ferrite nanoparticle systems have been explored in regard to their magnetocaloric effect (MCE) properties, as well as for use in polymer composites. Both areas of study have potential applications across a wide variety of interdisciplinary fields.

Magnetite nanoparticles have been successfully dispersed in a polymer. The surface chemistry of the magnetic nanoparticle proves critical to obtaining a homogenous and well separated high density dispersion in PMMA. Theoretical studies found in the literature have indicated that surface interface energy …

Temporal And Spatial Analysis Of Monogenetic Volcanic Fields, Koji Kiyosugi

USF Tampa Graduate Theses and Dissertations

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geochemical, radiometric and geophysical data.

We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan. E-W elongated volcano distribution, which is identified by a nonparametric kernel method, is found to be consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting …

Algorithms For Visual Maritime Surveillance With Rapidly Moving Camera, Sergiy Fefilatyev

USF Tampa Graduate Theses and Dissertations

Visual surveillance in the maritime domain has been explored for more than a decade. Although it has produced a number of working systems and resulted in a mature technology, surveillance has been restricted to the port facilities or areas close to the coastline assuming a fixed-camera scenario. This dissertation presents several contributions in the domain of maritime surveillance. First, a novel algorithm for open-sea visual maritime surveillance is introduced. We explore a challenging situation with a camera mounted on a buoy or other floating platform. The developed algorithm detects, localizes, and tracks ships in the field of view of the …

Low Level Exposure To Air Pollution And Risk Of Adverse Birth Outcomes In Hillsborough County, Florida, Maria B. Mainolfi

USF Tampa Graduate Theses and Dissertations

In this retrospective cohort from 2002 through 2007, 104,003 singleton live births in Hillsborough County, Florida were analyzed to elucidate the relationship between feto-infant morbidity outcomes and prenatal exposure to six criteria air pollutants. This study is based on three linked databases: The Florida Hospital Discharge database; The vital statistics records of singleton live births; Air Pollution meteorological data from the Environmental Protection Agency. There are six common air pollutants, particulate matter 2.5 (PM2.5), particulate matter 10 (PM10), ground-level ozone (O3), carbon monoxide (CO), nitrogen (NOx), and lead (Pb). These pollutants are harmful to human health and the environment. The …