Physical Sciences and Mathematics Commons^™

Magnetism In Complex Oxides Probed By Magnetocaloric Effect And Transverse Susceptibility, Nicholas Steven Bingham

USF Tampa Graduate Theses and Dissertations

Magnetic oxides exhibit rich complexity in their fundamental physical properties determined by the intricate interplay between structural, electronic and magnetic degrees of freedom. The common themes that are often present in these systems are the phase coexistence, strong magnetostructural coupling, and possible spin frustration induced by lattice geometry. While a complete understanding of the ground state magnetic properties and cooperative phenomena in this class of compounds is key to manipulating their functionality for applications, it remains among the most challenging problems facing condensed-matter physics today. To address these outstanding issues, it is essential to employ experimental methods that allow for …

Hydrogen Storage In Hypercrosslinked Polystyrene And Li-Mg-N-H Complex Hydride, Dervis Emre Demirocak

USF Tampa Graduate Theses and Dissertations

In this dissertation, hydrogen storage enhancement in hypercrosslinked polystyrene, effects of single walled carbon nanotubes (SWCNTs) supported ruthenium (Ru) catalyst on the kinetics and ammonia suppression in the LiNH2-MgH2 complex hydride system and the accuracy of hydrogen storage measurements are investigated in detail.

High surface area physisorption materials are of interest for room temperature hydrogen storage enhancement by spillover. Six different commercially available hypercrosslinked polystyrenes are screened by considering the specific surface area, average pore size, pore volume, and adsorption enthalpy. MN270 is selected mainly due to its high surface area and narrow pores for investigation of the spillover enhancement …

Modeling State Transitions With Automata, Egor Dolzhenko

USF Tampa Graduate Theses and Dissertations

Models based on various types of automata are ubiquitous in modern science. These models allow reasoning about deep theoretical questions and provide a basis for the development of efficient algorithms to solve related computational problems. This work discusses several types of automata used in such models, including cellular automata and mandatory results automata.

The first part of this work is dedicated to cellular automata. These automata form an important class of discrete dynamical systems widely used to model physical, biological, and chemical processes. Here we discuss a way to study the dynamics of one-dimensional cellular automata through the theory of …

A Study Of Permutation Polynomials Over Finite Fields, Neranga Fernando

USF Tampa Graduate Theses and Dissertations

Let p be a prime and q = p^k. The polynomial g_n,q isin F_p[x] defined by the functional equation Sigma_{a isin Fq} (x+a)ⁿ = g_n,q(x^q- x) gives rise to many permutation polynomials over finite fields. We are interested in triples (n,e;q) for which g_n,q is a permutation polynomial of F_q^e. In Chapters 2, 3, and 4 of this dissertation, we present many new families of permutation polynomials in the form of g_n,q. The permutation behavior of g_n,q is becoming increasingly more …

Spatial And Temporal Trends Of Snowfall In Central New York - A Lake Effect Dominated Region, Justin Joseph Hartnett

USF Tampa Graduate Theses and Dissertations

Central New York is located in one of the snowiest regions in the United States, with the city of Syracuse, New York the snowiest metropolis in the nation. Snowfall in the region generally begins in mid-November and lasts until late-March. Snow accumulation occurs from a multitude of conditions: frontal systems, mid-latitude cyclones, Nor'easters, and most notably lake-effect storms. Lake effect snowfall (LES) is a difficult parameter to forecast due to the isolated and highly variable nature of the storm. Consequently, studies have attempted to determine changes in snowfall for lake-effect dominated regions. Annual snowfall patterns are of particular concern as …

Spin Dependent Transport In Novel Magnetic Heterostructures, Priyanga Buddhika Jayathilaka

USF Tampa Graduate Theses and Dissertations

Magnetic oxides have become of interest source for spin transport devices due to their high spin polarization. But the real applications of these oxides remains unsatisfactory up to date, mostly due to the change of properties as a result of nano structuring. Magnetite (Fe₃O₄) is one such a material. High Curie temperature and the half metallicity of Fe₃O₄ make it a good potential candidate for spin transport devices. Studies have shown that the nano structuring Fe₃O₄ changes most of it's important properties. This includes high saturation magnetization and drop of …

Bayesian Estimation Of Panel Data Fractional Response Models With Endogeneity: An Application To Standardized Test Rates, Lawrence Kessler

USF Tampa Graduate Theses and Dissertations

In this paper I propose Bayesian estimation of a nonlinear panel data model with a fractional dependent variable (bounded between 0 and 1). Specifically, I estimate a panel data fractional probit model which takes into account the bounded nature of the fractional response variable. I outline estimation under the assumption of strict exogeneity as well as when allowing for potential endogeneity. Furthermore, I illustrate how transitioning from the strictly exogenous case to the case of endogeneity only requires slight adjustments. For comparative purposes I also estimate linear specifications of these models and show how quantities of interest such as marginal …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

A Rheological Examination Of Polymer Composites: Including Functionalized Carbon Nanotubes, Viable Polyurethane Alternates, And Contact Lens Hydrogels, Bernard Knudsen

USF Tampa Graduate Theses and Dissertations

From medicine to aerospace, innovation in multiple fields will not occur without addressing current questions that still exist in polymer behavior and manipulation. This dissertation represents the research carried out over the course of three separate experiments using rheometry as the key technique to explore the behavior of polymer composites. In all three studies, polymer composites were investigated for changes to their known physical properties caused through the addition of a filler or functionalization.

Chapter Two examines the possibility of enhancing poly(4-methyl-1-pentene) through the use of soluble carbon nanotubes. In this series of experiments, carbon nanotubes were covalently functionalized using …

Do Personality Tests Have A Place In Academic Preparation Of Undergradute Hospitality Students, Gunce Malan

USF Tampa Graduate Theses and Dissertations

This is a descriptive study that poses the questions and discussion regarding use of personality tests in prediction of future job performance of the current undergraduate hospitality students. A gap exists between the perception of the skills and competencies of high performers and the perception of hospitality students (Berezina et al., 2011; Malan, Berezina & Cobanoglu, 2012). The purpose of this study is to investigate if personality tests will help in predicting the success of students in their preferred job setting as compared to current high performers (managers).

The use of personality tests increased substantially after 1988, when the government …

Biochemical Aspects Of The Thermal Sensitivity And Energy Balance Of Polar, Tropical And Subtropical Teleosts, Eloy Martinez

USF Tampa Graduate Theses and Dissertations

The maintenance of a functional energy balance in ectothermic fauna could be challenging in a thermally disparate environment. Biochemical adaptations at the enzyme and membrane levels allows for a set compensatory mechanism that allow the individual to maintain an energetic surplus, thus allocating energy for growth and reproduction. The present work describes how the energetic machinery in the cell, particularly the mitochondrion, could be affected by temperature changes. More specifically, this work aimed to determine how environmental temperature affects the mitochondria energetic performance of fishes from disparate thermal regimes.

Mitochondrial ATP production efficiency was evaluated in fishes from polar, tropical …

Reaction Enthalpy And Volume Profiles For Excited State Reactions Involving Electron Transfer And Proton-Coupled Electron Transfer, William Antonio Maza

USF Tampa Graduate Theses and Dissertations

Electron transfer, ET, and proton-coupled electron transfer, PCET, reactions are central to biological reactions involving catalysis, energy conversion and energy storage. The movement of electrons and protons in either a sequential or concerted manner are coupled in a series of elementary reaction steps in respiration and photosynthesis to harvest and convert energy consumed in foodstuffs or by absorption of light into high energy chemi-cal bonds in the form of ATP. These electron transfer processes may be modulated by conformational dynamics within the protein matrix or at the protein-protein interface, the energetics of which are still not well understood. Photoacoustic calorimetry …

Development Of Novel Nano-Composite Membranes As Introduction Systems For Mass Spectrometers: Contrasting Nano-Composite Membranes And Conventional Inlet Systems, Luis Miranda

USF Tampa Graduate Theses and Dissertations

This dissertation presents the development of novel nano-composite membranes as introduction systems for mass spectrometers. These nano-composite membranes incorporate anodic aluminum oxide (AAO) membranes as templates that can be used by themselves or modified by a variety of chemical deposition processes. Two types of nano-composite membranes are presented. The first nano-composite membrane has carbon deposited within the pores of an AAO membrane. The second nano-composite membrane is made by coating an AAO membrane with a thin polymer film. The following chapters describe the transmission properties these nano-composite membranes and compare them to conventional mass spectrometry introduction systems. The nano- composite …

Dynamic Processes In Network Goods: Modeling, Analysis And Applications, Arnut Paothong

USF Tampa Graduate Theses and Dissertations

The network externality function plays a very important role in the study of economic network industries. Moreover, the consumer group dynamic interactions coupled with network externality concept is going to play a dominant role in the network goods in the 21st century. The existing literature is stemmed on a choice of externality function with certain quantitative properties. The utility function coupled with the network externality function is used to investigate static properties of rational equilibrium. The aim of this work is to systematically initiate a development of quantitative effects of the concept of network externality and its influence on the …

Prevention And Detection Of Intrusions In Wireless Sensor Networks, Ismail Butun

USF Tampa Graduate Theses and Dissertations

Wireless Sensor Networks (WSNs) continue to grow as one of the most exciting and challenging research areas of engineering. They are characterized by severely constrained computational and energy

resources and also restricted by the ad-hoc network operational

environment. They pose unique challenges, due to limited power

supplies, low transmission bandwidth, small memory sizes and limited energy. Therefore, security techniques used in traditional networks cannot be directly adopted. So, new ideas and approaches are needed, in order to increase the overall security of the network. Security applications in such resource constrained WSNs with minimum overhead provides significant challenges, and is the …

Toward More Composable Software-Security Policies: Tools And Techniques, Daniel Lomsak

USF Tampa Graduate Theses and Dissertations

Complex software-security policies are dicult to specify, understand, and update. The

same is true for complex software in general, but while many tools and techniques exist

for decomposing complex general software into simpler reusable modules (packages, classes,

functions, aspects, etc.), few tools exist for decomposing complex security policies into simpler

reusable modules. The tools that do exist for modularizing policies either encapsulate

entire policies as atomic modules that cannot be decomposed or allow ne-grained policy

modularization but require expertise to use correctly.

This dissertation presents a policy-composition tool called PoliSeer [27, 26] and the

PoCo policy-composition software-security language. PoliSeer is …

Control Of Smart Building Using Advanced Scada, Vivin Thomas Samuel

USF Tampa Graduate Theses and Dissertations

ABSTRACT

For complete control of the building, a proper SCADA implementation and the optimization strategy has to be build. For better communication and efficiency a proper channel between the Communication protocol and SCADA has to be designed.

This paper concentrate mainly between the communication protocol, and the SCADA implementation, for a better optimization and energy savings is derived to large scale industrial buildings. The communication channel used in order to completely control the building remotely from a distant place. For an efficient result we consider the temperature values and the power ratings of the equipment so that while controlling the …

Optimized Correlation Of Geophysical And Geotechnical Methods In Sinkhole Investigations: Emphasizing On Spatial Variations In West-Central Florida, Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

Abstract

Sinkholes and sinkhole-related features in West-Central Florida (WCF) are commonly identified using geotechnical investigations such as standard penetration test (SPT) borings and geophysical methods such as ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Geophysical investigation results can be used to locate drilling and field testing sites while geotechnical investigation can be used to ground truth geophysical results. Both methods can yield complementary information. Geotechnical investigations give important information about the type of soil, groundwater level and presence of low-density soils or voids at the test location, while geophysical investigations like GPR surveys have better spatial coverage and …

Argumentation As A Lens To Examine Student Discourse In Peer-Led Guided Inquiry For College General Chemistry, Ushiri Kumarihamy Kulatunga

USF Tampa Graduate Theses and Dissertations

This dissertation work entails three related studies on the investigation of Peer-Led Guided Inquiry student discourse in a General Chemistry I course through argumentation. The first study, Argumentation and participation patterns in general chemistry peer-led sessions, is focused on examining arguments and participation patterns in small student groups without peer leader intervention. The findings of this study revealed that students were mostly engaged in co-constructed arguments, that a discrepancy in the participation of the group members existed, and students were able to correct most of the incorrect claims on their own via argumentation.

The second study, Exploration of peer leader …

Tracking Atlantic Hurricanes Using Statistical Methods, Elizabeth Caitlin Miller

USF Tampa Graduate Theses and Dissertations

Creating an accurate hurricane location forecasting model is of the utmost importance because of the safety measures that need to occur in the days and hours leading up to a storm's landfall. Hurricanes can be incredibly deadly and costly, but if people are given adequate warning, many lives can be spared. This thesis seeks to develop an accurate model for predicting storm location based on previous location, previous wind speed, and previous pressure. The models are developed using hurricane data from 1980-2009.

Impacts Of The Anomalous Mississippi River Discharge And Diversions On Phytoplankton Blooming In Northeastern Gulf Of Mexico, Brendan O'Connor

USF Tampa Graduate Theses and Dissertations

On April 20, 2010 a tragic explosion aboard the Deepwater Horizon (DWH) drilling rig marked the beginning of one of the worst environmental disasters in history. For 87 days oil and gas were released into the Gulf of Mexico. In August 2010, anomalous phytoplankton activity was identified in the Northeastern Gulf of Mexico, using the Fluorescence Line Height (FLH) ocean color product. The FLH anomaly was bound by approximately 30-28 degrees North and 90 and 86 degrees West and there was a suggestion that this anomaly may have occurred due to the presence of oil. This study was designed to …

Applications Of Agent Based Approaches In Business: A Three Essay Dissertation, Shankar Prawesh

USF Tampa Graduate Theses and Dissertations

The goal of this dissertation is to investigate the enabling role that agent based simulation plays in business and policy. The aforementioned issue has been addressed in this dissertation through three distinct, but related essays. The first essay is a literature review of different research applications of agent based simulation in various business disciplines, such as finance, economics, information systems, management, marketing and accounting. Various agent based simulation tools to develop computational models are discussed. The second essay uses an agent-based simulation approach to study important properties of the widely used most popular news recommender systems (NRS). This essay highlights …

Optimization In Non-Parametric Survival Analysis And Climate Change Modeling, Iuliana Teodorescu

USF Tampa Graduate Theses and Dissertations

Many of the open problems of current interest in probability and statistics involve complicated data

sets that do not satisfy the strong assumptions of being independent and identically distributed. Often,

the samples are known only empirically, and making assumptions about underlying parametric

distributions is not warranted by the insufficient information available. Under such circumstances,

the usual Fisher or parametric Bayes approaches cannot be used to model the data or make predictions.

However, this situation is quite often encountered in some of the main challenges facing statistical,

data-driven studies of climate change, clinical studies, or financial markets, to name a few. …

Agricultural And Domestic Waste Contamination In Chilibre Panama And Potential Low-Cost Best Managament Practices, Christopher Etienne Weekes

USF Tampa Graduate Theses and Dissertations

Abstract

Sanitation coverage in the Republic of Panama is 5 to 10 percent below the Millennium Development Goals targets set for the country. Population growth, urbanization, unplanned development and waste mismanagement have resulted in improvised trash sites and waste discharges into river systems that are important components of the biologically diverse natural environment of Panama. The study sought to investigate and estimate the burden of waste from domestic and agricultural sources in three regions of the Chilibre corrigimiento (district). It was hypothesized that the water quality and land cover data would reflect that the most populated region in the study …

A Modeling Investigation Of Human Exposure To Select Traffic-Related Air Pollutants In The Tampa Area: Spatiotemporal Distributions Of Concentrations, Social Distributions Of Exposures, And Impacts Of Urban Design On Both, Haofei Yu

USF Tampa Graduate Theses and Dissertations

Increasing vehicle dependence in the United States has resulted in substantial emissions of traffic-related air pollutants that contribute to the deterioration of urban air quality. Exposure to urban air pollutants trigger a number of public health concerns, including the potential of inequality of exposures and health effects among population subgroups. To better understand the impact of traffic-related pollutants on air quality, exposure, and exposure inequality, modeling methods that can appropriately characterize the spatiotemporally resolved concentration distributions of traffic-related pollutants need to be improved. These modeling methods can then be used to investigate the impacts of urban design and transportation management …

A Polarizable And Transferable Carbon Dioxide Potential For Materials Simulation, Ashley Lynn Mullen

USF Tampa Graduate Theses and Dissertations

Intermolecular potential energy functions for CO₂ have been developed from first principles for use in heterogeneous systems, including one with explicit polarization. The intermolecular potentials have been expressed in a transferable form and parameterized from nearly exact electronic structure calculations. Models with and without explicit many-body polarization effects, known to be important in simulation of interfacial processes, are constructed. The models have been validated on pressure-density isotherms of bulk CO₂ and adsorption in three metal-organic framework (MOF) materials. The present models appear to offer advantages over high quality fluid/liquid state potentials in describing CO₂ interactions in interfacial …

Weather Patterns Associated With Green Turtle Hypothermic Stunning Events In St. Joseph Bay And Mosquito Lagoon, Florida, Kelsey Roberts

USF Tampa Graduate Theses and Dissertations

January of 2010 brought record-breaking cold temperatures to Florida. Such freeze events can upset vulnerable populations of marine life and other species that rely on stable water temperatures. Sea turtles are one group of species that are particularly susceptible to abrupt drops in water temperature. When water temperatures drop below 10°C, a mass hypothermic stunning, or cold-stunning, event for sea turtles can be expected, with many debilitated turtles washing onshore with a very limited time window to be rehabilitated (Foley et al. 2007). The species of sea turtle that appears to cold-stun with the most frequency is the green turtle, …

Spatial Distribution Of Nitrogen Oxides, Benzene, Toluene, Ethylbenzene, And Xylenes In Hillsborough County, Florida: An Investigation Of Impacts Of Urban Forests On Ambient Concentrations Of Air Pollutants Associated With Traffic, Jill Sears

USF Tampa Graduate Theses and Dissertations

Urban air pollution is responsible for high levels of morbidity and mortality in exposed populations due to its effects on cardiovascular and respiratory function. Transportation-related air pollutants account for the majority of harmful air pollution in urban areas. Forests are known to reduce air pollution through their ability to facilitate dry deposition and atmospheric gas exchange. This work characterizes the interactions between transportation air pollutants and urban forests in Hillsborough County, Florida. A highly spatially resolved passive air sampling campaign was conducted to characterize local concentrations of nitrogen oxides, benzene, toluene, ethylbenzene, and xylenes (BTEX) in Hillsborough County, Florida. Sampling …

Age Dependent Analysis And Modeling Of Prostate Cancer Data, Nana Osei Mensa Bonsu

USF Tampa Graduate Theses and Dissertations

Growth rate of prostate cancer tumor is an important aspect of understanding the natural history of prostate cancer. Using real prostate cancer data from the SEER database with tumor size as a response variable, we have clustered the cancerous tumor sizes into age groups to enhance its analytical behavior. The rate of change of the response variable as a function of age is given for each cluster. Residual analysis attests to the quality of the analytical model and the subject estimates. In addition, we have identified the probability distribution that characterize the behavior of the response variable and proceeded with …

The Combined Effects Of Light And Temperature On Coral Bleaching: A Case Study Of The Florida Reef Tract Using Satellite Data, Brian Burnel Barnes

USF Tampa Graduate Theses and Dissertations

Coral reefs are greatly impacted by the physical characteristics of the water surrounding them. Incidence and severity of mass coral bleaching and mortality events are increasing worldwide due primarily to increased water temperature, but also in response to other stressors. This decline in reef health demands clearer understanding of the compounding effects of multiple stressors, as well as widespread assessment of coral reef health in near-real time.

Satellites offer a means by which some of the physical stressors on coral reefs can be measured. The synoptic spatial coverage and high repeat sampling frequency of such instruments allow for a quantity …