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Full-Text Articles in Physical Sciences and Mathematics

Microservice Architecture For Social Media Data Collection, Analysis, And Dashboarding, Sai Ram Manohar Koya Dec 2024

Microservice Architecture For Social Media Data Collection, Analysis, And Dashboarding, Sai Ram Manohar Koya

Theses and Dissertations

This research presents a novel methodology for the collection, processing, and analysis of social media data using a microservices-based architecture. The proposed system integrates multiple data streams from various social media platforms, transforming this information into a unified, JSON-based DataObject model for seamless processing and analysis. Unlike monolithic architectures, the microservices approach offers scalability and flexibility, allowing the system to handle the high velocity, variety, and volume of unstructured social media data, including text, images, and videos. By leveraging NoSQL databases like MongoDB, the methodology efficiently manages data in a semi-structured format, supporting real-time analytics such as sentiment analysis, toxicity …


Exploration Of The Gap Between The Secure Web Application Development Competencies Needed By Industry And Those Competencies Provided By Graduates Of U.S. Undergraduate Software Engineering Programs, Gary Allen Harris Dec 2024

Exploration Of The Gap Between The Secure Web Application Development Competencies Needed By Industry And Those Competencies Provided By Graduates Of U.S. Undergraduate Software Engineering Programs, Gary Allen Harris

Theses and Dissertations

Literature demonstrates that threats and attacks on computer systems and networks have been around since the beginning of computing, and the number, severity, sophistication, and costs of attacks and data breaches are continuing to grow. Several studies suggest that one of the most common causes of data breaches is insecure web applications that contain vulnerable application code. These studies suggest that poor secure web application development practices are a prime cause of the susceptible web applications. Additionally, studies suggest that higher education is not meeting industry’s secure software/web application development needs. Employers have reported that they are not getting the …


Existence And Uniqueness Of Solutions Of Fourth Order Iterative Boundary Value Problems, Zach Whaley Dec 2024

Existence And Uniqueness Of Solutions Of Fourth Order Iterative Boundary Value Problems, Zach Whaley

Theses and Dissertations

In this dissertation, we study the fourth-order iterative differential equation \begin{displaymath} x^{(4)}(t) = \f(t, x(t), x^{[2]}(t), \dots, x^{[m]}(t)) \end{displaymath} where $x^{[2]}(t) = x(x(t))$ and $x^{[j]}(t) = x(x^{[j - 1]}(t))$ for $j > 2$. We consider the above equation with multiple sets of boundary conditions, and we state results on the existence and uniqueness of solutions for each set of boundary conditions. In Chapter 2, the boundary conditions are conjugate boundary conditions, \begin{align*} &x(-a) = -a, \ x'(-a) = b, \ x''(-a) = c, \ x(a) = a \\ &x(-a) = -a, \ x(a) = a, \ x'(a) = b, \ x''(a) …


Traveling Waves In Biological Population Models, Ahlam Alzahrani Dec 2024

Traveling Waves In Biological Population Models, Ahlam Alzahrani

Theses and Dissertations

In this thesis, we examine the existence of traveling waves in population models. We begin by exploring conditions under which traveling waves exist, even when the migration probability lacks a density function or, if the density function exists, it may be discontinuous. To address this, we impose certain conditions that ensure the monotonicity of the evolution operator, enabling the application of the Monotone Iteration Method. Next, we explore the existence of monotone traveling waves in a general class of integral-difference population models that depend on both the previous state and long-term memory, allowing for the consideration of multiple past states. …


Performance Prediction For Hub-Based Swarms, Puneet Jain Dec 2024

Performance Prediction For Hub-Based Swarms, Puneet Jain

Theses and Dissertations

Optimization problems lie at the core of improving performance in various tasks, ranging from day-to-day work scheduling to coordinating robots in a warehouse fulfillment center. Distributed swarm systems provide a robust and adaptive solution approach to many optimization problems. Instead of using one really sophisticated agent, multiple smaller less sophisticated agents can provide the flexibility to evaluate more options and still provide a "good" answer. This dissertation uses graphs to model, analyze, and simulate swarm behavior, primarily to predict the time-to-converge (TTC) and success probability. First, we use a bipartite model for the distributed best-of-N problem, and show how the …


Geomorphic Evolution Of St. Augustine Inlet, St. Johns County, Florida, Kristen Becker Dec 2024

Geomorphic Evolution Of St. Augustine Inlet, St. Johns County, Florida, Kristen Becker

Theses and Dissertations

Tidal inlets interrupt longshore sediment transport, influencing adjacent beach morphology and allowing the exchange of water and sediment between the open oceans and protected back barrier bay. Inlets evolve through a combination of natural processes and are highly dynamic zones where sediment exchanges cause shifting shoreline positions nearby and create new morphological features. Barrier islands/beaches that are close in proximity to inlets evolve and are an important natural feature that dissipates wave energy and protects inland areas. Both natural and anthropogenic processes that affect barrier islands will be investigated during this study, including storm activity, waves, wind, water level, and …


Advanced Models For Linking Process In Data Washing Machine, Bushra Sajid Dec 2024

Advanced Models For Linking Process In Data Washing Machine, Bushra Sajid

Theses and Dissertations

Entity Resolution (ER) is a critical process in data integration and quality improvement that identifies and links multiple records referring to the same real-world entity. As data volumes and heterogeneity increase, traditional ER methods face new challenges, prompting research into more advanced techniques. The Proof-of-Concept Data Washing Machine (DWM), developed under the NSF DART Data Life Cycle and Curation research theme, aims to automatically detect and correct data quality errors through unsupervised entity resolution. Recent research focuses on enhancing DWM's effectiveness by replacing rule-based methods with machine learning and deep learning approaches, particularly in the linking process. Deep learning models, …


Design And Synthesis Of Bimetallic Catalyst And Multifunctional Peptide Catalysis For Organic Synthesis And Synthesis Of Proteolysis Targeting Chimeras (Protacs) For Sphk1 And Sphk2, Mariur Rodriguez Moreno Dec 2024

Design And Synthesis Of Bimetallic Catalyst And Multifunctional Peptide Catalysis For Organic Synthesis And Synthesis Of Proteolysis Targeting Chimeras (Protacs) For Sphk1 And Sphk2, Mariur Rodriguez Moreno

Theses and Dissertations

In the first part of this dissertation (chapters 1-4) we discuss the development of bimetallic and monometallic palladium complexes scaffolded on 2-phosphinoimidazole ligands and their application to cross-coupling reactions. Specifically, we discovered a bimetallic Pd(II) dimer that performs a tandem arylation/annulation reaction to produce naphthalene products from aryl iodides and ketones (Chapter 2). We then show that bimetallic Pd(II) and Pd (I) complexes have different activity in different transformations and that the starting oxidation state of our catalysts is important for reactivity (Chapter 3). For example, we demonstrate that our Pd(I) dimer is much more active in Buchwald- Hartwig amination …


Intramolecular Styryl Diels-Alder (Isda) Reaction For Synthesizing Derivatives Of Anticancer Lignans, Kriti Shrestha Dec 2024

Intramolecular Styryl Diels-Alder (Isda) Reaction For Synthesizing Derivatives Of Anticancer Lignans, Kriti Shrestha

Theses and Dissertations

Intramolecular Styryl Diels-Alder (ISDA) cycloaddition reactions are used widely in synthesizing complex natural products. They help synthesize polycyclic cores and form new chiral centers in the molecule. Among such natural products, lignans are considered important biomedical molecules due to their numerous pharmacological properties, such as antitumor, hepatoprotective, insecticidal, antifungal, antihypertensive, sedative, antioxidant, and antiparasitic. Numerous researchers have published their work in trying to synthesize different lignans for medicinal purposes. However, the lignans are challenging to synthesize because of their complex tetralin cores. This project focuses on synthesizing the polycyclic core for the analogs of anti-cancer compounds with ISDA reaction. The …


Identifying Fecal Contamination Sources In The Grand Bay National Estuarine Research Reserve, Amanda M. Free Dec 2024

Identifying Fecal Contamination Sources In The Grand Bay National Estuarine Research Reserve, Amanda M. Free

Theses and Dissertations

The Grand Bay National Estuarine Research Reserve (GNDNERR) has a history of elevated fecal coliform counts. However, the source of the contamination is not well understood. According to past sanitary surveys, there has been a history of malfunctioning residential septic systems and inadequate wastewater treatment in the upper watershed. Feral hogs (Sus scrofa) and birds are also abundant in the estuary and could be potential contributors to elevated fecal coliform levels. To better understand the temporal and spatial variation of fecal coliforms in the GNDNERR and inform oyster reef management, eight sites within the GNDNERR watershed were sampled monthly for …


A Comprehensive Performance Evaluation Of Proprietary And Open-Source Language Models In Closed And Open-Domain Tasks, Abhilash Kanduri Dec 2024

A Comprehensive Performance Evaluation Of Proprietary And Open-Source Language Models In Closed And Open-Domain Tasks, Abhilash Kanduri

Theses and Dissertations

As the field of Natural Language Processing (NLP) continues to evolve, evaluating the performance of both proprietary and open-source language models has become increasingly critical. This research provides a comprehensive analysis of proprietary models like GPT-3.5 Turbo, GPT-4, and GPT-4 Turbo, alongside open-source models such as FLAN-T5, GPT-Neo, and GPT-2. By leveraging traditional metrics like ROUGE and BLEU, as well as custom metrics including ReGrAde, Contextual Precision, and Faithfulness, the study evaluates these models across closed-domain tasks (e.g., factual question-answering) and open-domain tasks (e.g., creative writing and brainstorming). The proprietary models excelled in structured, fact-based tasks, while the open-source models …


Synergistic Adsorption Of Pb (Ii) From Aqueous Solution Using Calcined Biochar-Bentonite Clay Hybrid, Azeezat Faderera Abdul-Raheem Dec 2024

Synergistic Adsorption Of Pb (Ii) From Aqueous Solution Using Calcined Biochar-Bentonite Clay Hybrid, Azeezat Faderera Abdul-Raheem

Theses and Dissertations

The biochar-bentonite clay hybrid was prepared by coprecipitation with the goal of producing a material that can remove Pb (II) from aqueous solutions effectively. Incorporating bentonite clay onto the Douglas fir biochar (DFB-BTC) surface significantly improved the adsorption capacity by introducing more active sites, strengthening the structural properties, and promoting strong adsorbate interactions. The point of zero charge of the adsorbent was slightly higher than that of the pristine DFBC. All sorption experiments were performed at pH 5, and the system obeyed the Langmuir adsorption isotherm. The highest Langmuir adsorption capacities observed at 298, 308, and 318 K were 48, …


Algal Community Investigations: Present Day To Year-2100 For Mississippi Lakes And The Western Mississippi Sound, Emma Madison Tucker Dec 2024

Algal Community Investigations: Present Day To Year-2100 For Mississippi Lakes And The Western Mississippi Sound, Emma Madison Tucker

Theses and Dissertations

Algae play a key role in the aquatic environment as primary producers; however, they can form harmful algal blooms that are detrimental to the aquatic environment, people, and even the economy. It is generally believed that climate change will influence future algal blooms. The first study estimated algae community in three freshwater locations in Mississippi, Desoto Lake, White’s Creek Lake, and Columbus Lake, and one saline location, Western Mississippi Sound, using modern and new tools of the autonomous surface vessel, FlowCam, and EcoTaxa. From those results and leading into the second study was the application of four climate scenarios on …


Fisheries Management In Mississippi State-Operated Fishing Lakes: A Review And Look To The Future, Hayden Gregory Funk Dec 2024

Fisheries Management In Mississippi State-Operated Fishing Lakes: A Review And Look To The Future, Hayden Gregory Funk

Theses and Dissertations

The Mississippi Department of Wildlife, Fisheries and Parks currently manages 18 State Lakes and 17 State Park Lakes to provide public fishing opportunities. My goal was to conduct a comprehensive analysis of monitoring and management activities in State Lakes to enhance understanding of lake dynamics, further develop existing management initiatives, and identify alternative avenues for effective management. To achieve this objective, I have undertaken a comprehensive examination and synthesis of the historical background pertaining to State Lakes and conducted an analysis of pertinent data regarding lake characteristics such as the physical and chemical attributes of the lakes, the features of …


Impact Of Cascading Optical Processes On Spectroscopic Quantification Of Absorption And Scattering Properties Of Samples, Pathum Dilshan De Silva Wathudura Dec 2024

Impact Of Cascading Optical Processes On Spectroscopic Quantification Of Absorption And Scattering Properties Of Samples, Pathum Dilshan De Silva Wathudura

Theses and Dissertations

Light absorption and scattering are fundamental properties of matter, particularly significant in nanoscale materials. This study explores how cascading optical processes affect the experimental measurement of absorption and scattering intensities, along with scattering depolarization, in samples containing absorbers and scatterers. The experimental UV–vis spectrum results from the combination of absorption and scattering extinction spectra. However, the maximum measurable extinction may be limited by forward scattered light. Light absorption decreases the intensity of scattered light and influences scattering depolarization. While scattering can reduce absorption along the optical path to the detector, sufficient absorption of the scattered light may counterbalance this effect, …


Analysis Of Cortical Evoked Auditory Response Detection In Adults Using Machine Learning, Pranavi Beerelli Dec 2024

Analysis Of Cortical Evoked Auditory Response Detection In Adults Using Machine Learning, Pranavi Beerelli

Theses and Dissertations

This study focuses on the use of machine learning (ML) techniques to automate the detection of Cortical Evoked Auditory Responses (CEARs), which are key in understanding how the auditory cortex processes sound stimuli. Traditionally, analyzing these auditory responses has relied on manual interpretation by audiologists, a process that can introduce variability and human error, particularly in complex cases. To address this challenge, the research utilizes advanced deep learning models, including Convolutional Neural Networks (CNNs), Long Short Term Memory (LSTM) networks, and Bidirectional LSTM (BiLSTM) architectures, to analyze Electroencephalography (EEG) data and classify the presence or absence of auditory responses automatically. …


Investigations Of Guayule Resin As A Wood Protectant, Queen Aguma Dec 2024

Investigations Of Guayule Resin As A Wood Protectant, Queen Aguma

Theses and Dissertations

Wood products are subject to deterioration by numerous processes, as a biological material. Today, a significant area of preservative development is the utilization of existing plant residues that have water-repelling, antibacterial, antifungal, and insecticidal properties as components of wood protectants. Parthenium argentatum, known as guayule (wy-oo-lee), is a promising wood protectant due to its resin. However, the resin's complicated chemical, physical, and solvent-resistant properties make it difficult to use. The primary goal of this study was to eliminate the use of any solvent and rely on thermal modification only to fractionate usable compounds from guayule resin. Utilizing heated dialysis and …


An Open-Source, Student-Centric Approach To The Cyber Kill Chain, Justin Lane Wooten Dec 2024

An Open-Source, Student-Centric Approach To The Cyber Kill Chain, Justin Lane Wooten

Theses and Dissertations

The cybersecurity landscape demands professionals with practical skills and a deep understanding of attack methodologies. However, many institutions face significant challenges in providing comprehensive cybersecurity education due to the high costs associated with commercial tools and platforms. This thesis presents a student-centric, open-source curriculum for teaching the Cyber Kill Chain, designed to bridge the gap between theoretical knowledge and real-world application while addressing the financial constraints faced by many educational institutions. Our approach leverages freely available tools and hands-on exercises to cover each phase of the Cyber Kill Chain, emphasizing ethical considerations and collaborative learning. We detail the curriculum development …


Multi-Cloud Identity Security Utilizing Self-Sovereign Identity, Morgan Lee Reece Dec 2024

Multi-Cloud Identity Security Utilizing Self-Sovereign Identity, Morgan Lee Reece

Theses and Dissertations

With the increasing use of multi-cloud environments, security professionals face challenges in configuration, management, and integration due to uneven security capabilities and features among providers. As a result, a fragmented approach toward security has been observed, leading to new attack vectors and potential vulnerabilities. Other research has focused on single-cloud platforms or specific applications of multi-cloud environments. Therefore, there is a need for a holistic security and vulnerability assessment and defense strategy that applies to multi-cloud platforms. This dissertation explores risk and vulnerability analysis to identify attack vectors from software, hardware, and the network, as well as interoperability security issues …


Deep Learning - Based Automated Detection And Classification Of Foreign Materials In Poultry Using Color And Hyperspectral Imaging, Rohini Maram Dec 2024

Deep Learning - Based Automated Detection And Classification Of Foreign Materials In Poultry Using Color And Hyperspectral Imaging, Rohini Maram

Theses and Dissertations

This thesis explores the use of Deep learning for detection and classification of small foreign materials (FMs) in poultry meat using color and hyperspectral imagery (HSI). The study employs You only look once (YOLO) object detection models on color images for precise localization, and one-dimensional convolutional neural network (1D CNN), two-dimensional convolutional neural network (2D CNN) was used on HSI (600 – 1700 nm) for classification. Twelve different FMs commonly known as polymers including PVC, PET, LDPE and HDPE, were examined using 52 color and 52 hyperspectral images. Four YOLO models (v5x, v7x, v8x, v10x) were implemented, trained, tested and …


Improved Vector Pruning For Partially Observable Markov Decision Processes, Thomas Jonathan Bowman Dec 2024

Improved Vector Pruning For Partially Observable Markov Decision Processes, Thomas Jonathan Bowman

Theses and Dissertations

Exact dynamic programming algorithms for planning problems that are represented as partially observable Markov decision processes rely on a subroutine that removes, or ``prunes", dominated vectors from sets of vectors that represent piecewise-linear and convex value functions. The classic vector pruning subroutine solves one linear program per vector, where the number of variables is equal to the size of the state space and the number of constraints is equal to the number of vectors shown so far to be undominated. Thus, its scalability is limited not only by the number of linear programs it solves, but especially by their size. …


Engineering Functionalized Nanomaterials For Targeting And Ablating Biofilms On Surfaces, Dhanush Lakmal Yapa Amarasekara Dec 2024

Engineering Functionalized Nanomaterials For Targeting And Ablating Biofilms On Surfaces, Dhanush Lakmal Yapa Amarasekara

Theses and Dissertations

Biofilms on both the surface and interior of medical devices pose major challenges, including hindering device performance and serving as infection sources. These biofilms form a protective layer around bacteria, shielding them from the body’s immune system and antibiotics. This makes infections difficult to treat, as the bacteria within the biofilm are resistant to both antibiotics and immune defenses. Additionally, biofilms can induce inflammation and irritation in nearby tissues, leading to further health complications. Antibiotic resistance raises concerns about the emergence of multi-drug resistant (MDR) pathogens. MDR infections are difficult to treat, leading to prolonged hospital stays and the need …


Discrimination The Roles Of Anthropogenic Greenhouse Gases And Aerosols On Tropical Cyclone Frequency From Downscaling Cmip6 Models, George Gyabaah Dec 2024

Discrimination The Roles Of Anthropogenic Greenhouse Gases And Aerosols On Tropical Cyclone Frequency From Downscaling Cmip6 Models, George Gyabaah

Theses and Dissertations

Tropical cyclones (TCs) are devastating disasters, yet predicting their future activity remains highly uncertain. To better understand the impacts of different anthropogenic forcings, specifically greenhouse gases (GHG) and aerosols on the TCs, I downscaled the single forcing experiments of 11 CMIP6 models in the Columbia HAZard Model (CHAZ). This analysis focused on changes in the distribution of the North Atlantic (ATL) and Western North Pacific (WNP) basins and explored the shift in environmental variables that drive them. We then used the formulation of the genesis component of CHAZ as a constraint to quantify the relative contribution of each predictor relative …


Exploring Single Particles Through Optical Trapping And Advanced Laser Spectroscopy Techniques, Haifa Hassan Alali Dec 2024

Exploring Single Particles Through Optical Trapping And Advanced Laser Spectroscopy Techniques, Haifa Hassan Alali

Theses and Dissertations

This dissertation explores the innovative integration of optical trapping (OT) with advanced laser spectroscopy techniques to investigate the physicochemical properties of single particles from a variety of atmospheric aerosols, such as bioaerosols, terrestrial dust, and extraterrestrial dust. Each technique offers unique insights, significantly enhancing our understanding of these critical atmospheric components. The first work focuses on employing OT in conjunction with cavity ringdown spectroscopy (OT-CRDS) to measure the single-particle extinction of interplanetary dust particles at ultraviolet wavelengths (~308 nm). This method allows for the stable trapping of individual dust particles in air, facilitating precise characterization with minimal external interference. Our …


Biothermodynamics Of Metal And Dna Coordination To The Pneumococcal Transcription Factors Adcr, Scza, And Copr, Alexander James Cutright Dec 2024

Biothermodynamics Of Metal And Dna Coordination To The Pneumococcal Transcription Factors Adcr, Scza, And Copr, Alexander James Cutright

Theses and Dissertations

ransition metals are micronutrients that play critical roles in all forms of life, acting as stabilizing ions, catalytic centers, and as signaling ions. Due to their importance, classes of biomolecules have been designed with the sole purpose of regulating their intracellular concentrations. One group of which are transcription factors, which regulate intracellular metal concentration by activating or repressing transcription, dependent on metal availability. The activation of transcription factors by metal availability can be attested to conformational changes that are governed by both dynamics and thermodynamics. Due to the influential nature of transcription factors, their activity and activation mode have become …


Analysis Of Positive Solutions For Classes Of Nonlinear Boundary Value Problems, Bandar Alreshidi Dec 2024

Analysis Of Positive Solutions For Classes Of Nonlinear Boundary Value Problems, Bandar Alreshidi

Theses and Dissertations

In this dissertation, we study the existence and uniqueness of positive solutions for classes of nonlinear boundary value problems. In the first study, we the ��-superlinear case, we prove the existence of a large positive solution when a parameter is small and if, in addition, the reaction term satisfies a concavity-like condition at the origin, the existence of two positive solutions for a certain range of the parameter. In the ��-sublinear case, we establish the existence of a large positive solution when a parameter is large. We also investigate the number of positive solutions for the general ��-Laplacian with nonlinear …


Synthesis Of Glycan Antigens For Therapeutic Antibodies And Glycoconjugate Vaccines, Synthesis Of An Inflammatory Pentasaccharide, And Design And Synthesis Of Ceragenins For Use In Medical Devices And Osteomyelitis, Shawn Gubler Dec 2024

Synthesis Of Glycan Antigens For Therapeutic Antibodies And Glycoconjugate Vaccines, Synthesis Of An Inflammatory Pentasaccharide, And Design And Synthesis Of Ceragenins For Use In Medical Devices And Osteomyelitis, Shawn Gubler

Theses and Dissertations

A promising approach in combatting infections from antibiotic resistant bacteria/fungi is using therapeutic monoclonal antibodies (mAbs) that can bind the outer surfaces of microbes. We have developed a synthetic vaccine platform that can rapidly generate mAbs against surface glycans from desired strains, such as lipopolysaccharides and capsular polysaccharides. To create therapeutic antibodies against Ruminococcus gnavus, Burkholderia multivorans, and Staphylococcus aureus, we synthesize glycan antigens from each strain that are necessary for use in our glycoconjugate vaccine platform. Blooms of the Gram-positive bacterium Ruminococcus gnavus have been correlated with inflammatory bowel disease, and recently a polysaccharide produced by this organism was …


Sulfhydryl-Containing Compounds And Iron Homeostasis: Mechanisms Of Labile Iron Pool Dysregulation And Consequences For Cellular Health, Steven Lowell Mann Christiansen Dec 2024

Sulfhydryl-Containing Compounds And Iron Homeostasis: Mechanisms Of Labile Iron Pool Dysregulation And Consequences For Cellular Health, Steven Lowell Mann Christiansen

Theses and Dissertations

While iron's unique coordination chemistry and redox activity have resulted in its broad incorporation into biological systems, dysfunction in key iron-regulating mechanisms can transform these biochemical advantages into factors that contribute to several pathological conditions. This dissertation explores the complex interactions between iron and sulfhydryl-containing compounds (SCCs), with particular focus on glutathione's (GSH) role in stabilizing iron reactivity juxtaposed with homocysteine's (Hcy) ability to disrupt iron homeostasis and promote disease progression. Through rigorous biochemical analysis and experimentation, we demonstrate that Hcy disrupts iron regulation through several mechanisms: (1) Hcy competitively displaces protective iron-binding molecules in the Labile Iron Pool (LIP), …


Enhancing Cybersecurity Strategies Through Automated Cti Extraction, Risk Prioritization, And Privacy-Conscious Information Sharing, Spencer Rian Massengale Dec 2024

Enhancing Cybersecurity Strategies Through Automated Cti Extraction, Risk Prioritization, And Privacy-Conscious Information Sharing, Spencer Rian Massengale

Theses and Dissertations

Cybersecurity operations require the ability to collect and analyze large amounts of cyber threat intelligence (CTI) to assess risks and formulate defensive strategies against emerging threats. This task has become increasingly complex due to the rapid evolution of cyber threats and the growing volume of unstructured, natural-language CTI sources. The scale of data and analysis needed to utilize CTI effectively far exceeds humans' manual capacity, especially for organizations with limited resources. This research focuses on leveraging Large Language Models (LLMs) and machine learning techniques to enhance CTI extraction, risk assessment, and data sharing. We utilized LLMs to automate the extraction …


Raman Characterization Of Elastomeric Materials, Shane Michael Drake Dec 2024

Raman Characterization Of Elastomeric Materials, Shane Michael Drake

Theses and Dissertations

Raman spectroscopy is often used for material identification but may be used for characterization. This document focuses on using Raman measurements to characterize polymers, specifically the curing and aging mechanism for hydroxyl-terminated polybutadiene (HTPB). HTPB is a well-known elastomer used in sealants, non-slip surfaces, rocket repellants and plastic explosives. Raman spectroscopy was used to monitor urethane linkages that form from curing HTPB with a cyanate curing agent to suggest a curing mechanism for HTPB. Since this polymer is highly susceptible to oxidation, the methods used to characterize curing were also used for the aging process to see if urethane breakages …