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Articles 1201 - 1230 of 1402
Full-Text Articles in Physical Sciences and Mathematics
Effects Of Diesel-Fuel And Copper Contaminants On Benthic Microalgae, Soraya Silva
Effects Of Diesel-Fuel And Copper Contaminants On Benthic Microalgae, Soraya Silva
LSU Doctoral Dissertations
Salt marshes are dynamic, highly productive habitats and serve as nursery grounds for many commercially and economically important species. Benthic microalgae (BMA) are considered an important food source for benthos and provide the principal source of nutrition that fuels secondary production. Estuarine sediments around the world are a repository for many contaminants from anthropogenic sources. In particular, hydrocarbons and metals are ubiquitous contaminants in coastal systems. The primary goal of this study was to study the effects of diesel fuel and copper, alone and in combination, on the BMA assemblage from a coastal salt marsh. To achieve this objective, salt …
Factors Influencing The Participation In Environmental Stewardship Programs: A Case Study Of The Agricultural And Forestry Sectors In Louisiana, Carrie Castille Mendoza
Factors Influencing The Participation In Environmental Stewardship Programs: A Case Study Of The Agricultural And Forestry Sectors In Louisiana, Carrie Castille Mendoza
LSU Doctoral Dissertations
Considerable research has been conducted to evaluate the adoption of agricultural best management practices and their overall impact on improving environmental quality. However, limited studies have been conducted to evaluate the behavioral factors that influence the adoption of these practices in the context of educational programs The goal of this study is to determine the factors that influence farmer conservation behavior that might lead to an increased probability of improving agriculture and forestry watersheds. A conceptual model was developed to identify the: 1) identify landowner participation in watershed conservation projects, and 2) determine the factors influencing agriculture and forestry landowners …
Porous Inorganic-Organic Materials Based On Beta-Diketone Ligands, Yixun Zhang
Porous Inorganic-Organic Materials Based On Beta-Diketone Ligands, Yixun Zhang
LSU Doctoral Dissertations
Synthesis and characterization of porous inorganic-organic materials have been studied mainly on two linear β-diketone multifunctional ligands: pyridine based pyacH and isocyanide based HacphNC. As a known ligand, the preparation of pyacH has been improved with higher yield. When pyacH reacts with Fe and Al metal salts, trigonal metal β-diketonate building blocks M(pyac)3 are produced. When pyacH reacts with zinc acetate, both trans and cis Zn(pyac)2 are produced, both isomers were isolated and characterized by single-crystal X-ray crystallography. Solutions of the trigonal building block Fe(pyac)3 generate various crystal structures on reaction with AgNO3 in CH3CN. When the concentration of AgNO3 …
Application Of Polymeric Microfluidic Devices For Separation Of Single-Stranded Dna, Shawn Llopis
Application Of Polymeric Microfluidic Devices For Separation Of Single-Stranded Dna, Shawn Llopis
LSU Doctoral Dissertations
Microsystems targeted for DNA sequencing, especially those focused on electrophoretic separations, are rapidly proving their viability to genomic research, mimicking the progress made when capillary electrophoresis developed from miniaturizing slab gel electrophoresis techniques. Being the more recent electrophoretic separation platform, the commercial availability of microchip electrophoresis devices remains relatively limited. To this extent, high-aspect ratio microstructures formed in thermo plastics have been developed using rapid fabrication methods from molding tools designed for mass replication of high-aspect ratio microfeatures. In this work, the choice and compatibility of poly(methylmethacrylate) (PMMA) – the primary substrate for DNA separations in this work – was …
Multianalyte Detection Of Breast Cancer By Fabrication Of Hybridmicroarrays On Polymer-Based Microanalytical Devices, Suying Wei
LSU Doctoral Dissertations
Breast cancer is one of the most common and fatal cancer diseases that affect women worldwide. As is true with most other cancer diseases, early detection of breast cancer is very crucial for proper medical treatment because treatment of advanced breast cancer will be much more difficult and inconsistent. Screening and testing of breast cancer biomarkers, either genetic or proteomic, are among techniques used for diagnosis of breast cancers. Nevertheless, none of the biomarkers is by itself sensitive and selective enough for diagnosis of breast cancer, and thus, multi-analyte assays towards detection of multiple breast cancer biomarkers from different classes …
Fabrication, Characterization And Properties Of Hiercchically Ordered Nanocomposites, Avinash Dundigalla
Fabrication, Characterization And Properties Of Hiercchically Ordered Nanocomposites, Avinash Dundigalla
LSU Doctoral Dissertations
The objectives of this research are to study the structure, morphology and properties of poly(ethylene-oxide) (PEO)-clay nanocomposites using various imaging techniques. Optical Microscopy, Scanning Electron Microscopy, Environmental Scanning Electron Microscopy and Atomic Force Microscopy are used to image structures on all length scales. Complementary scattering experiments are discussed along with preliminary differential scanning calorimetry and Fourier Transform Infrared spectroscopy results. In particular we investigated the multilayered structures of PEO-Laponite and PEO-Montmorillonite multilayered films made from solution. The shear orientation of a polymer-clay network in solution combined with simultaneous solvent evaporation leads to supramolecular multilayer formation in the film. The resulting …
A Community Approach To Identifying Essential Fish Habitat Of Spotted Seatrout, Cynoscion Nebulosus, In Barataria Bay, La, Pamela Sharon Dawn Macrae
A Community Approach To Identifying Essential Fish Habitat Of Spotted Seatrout, Cynoscion Nebulosus, In Barataria Bay, La, Pamela Sharon Dawn Macrae
LSU Doctoral Dissertations
Louisiana wetlands are disappearing at a dramatic rate, providing an impetus for identifying essential fish habitat (EFH) in this region. The distribution, relative abundance, biomass, length and food web dynamics of spotted seatrout, Cynoscion nebulosus, as well as the fish assemblage structure were examined in Barataria Bay, LA, in relation to habitat type and physical/chemical properties of the water. All fish were collected from three sites located along a salinity gradient, each contained the three habitat types of interest: marsh edge, soft bottom and oyster shell, and were sampled monthly from May 2003 to May 2004 with gillnets. Habitat preference …
Ontology-Based Methodology For Error Detection In Software Design, Allyson M. Hoss
Ontology-Based Methodology For Error Detection In Software Design, Allyson M. Hoss
LSU Doctoral Dissertations
Improving the quality of a software design with the goal of producing a high quality software product continues to grow in importance due to the costs that result from poorly designed software. It is commonly accepted that multiple design views are required in order to clearly specify the required functionality of software. There is universal agreement as to the importance of identifying inconsistencies early in the software design process, but the challenge is how to reconcile the representations of the diverse views to ensure consistency. To address the problem of inconsistencies that occur across multiple design views, this research introduces …
Two-Dimensional And High-Throughput Electrophoretic Separation Of Proteins Using Polymeric Microchips, Hamed Shadpour
Two-Dimensional And High-Throughput Electrophoretic Separation Of Proteins Using Polymeric Microchips, Hamed Shadpour
LSU Doctoral Dissertations
A major task in proteomics is to identify proteins from a biological sample using two-dimensional (2-D) separation prior to mass spectrometry of peptides generated via proteolytic digestion of the proteins. For 2-D separations, microfluidic devices are superior to bench top and capillary-based systems since they potentially provide higher separation efficiencies due to the minimal dead volumes produced during peak transfer between the two separation dimensions. In addition, fast separations can be envisioned because the column lengths are typically shorter in microfluidic platforms without scarifying peak capacity. High-throughput capabilities are extremely desirable for many types of bio-analytical analyses, such as understanding …
Magnetic, Thermodynamic And Transport Properties Of The Magnetic Semiconductor Fe₁₋Xcoxs₂ And Superconducting Lasb₂, Song Guo
LSU Doctoral Dissertations
In recent years magnetic semiconductors have attracted a great deal of attention because it is thought that they can be used to generate spin polarized current in spintronics, an emerging field where the spin degree of freedom of charge carriers is utilized in microelectronic devices. In this dissertation work, we investigate the magnetic, thermodynamic, and transport properties of the magnetic semiconductor Fe1-XCoxS2 for x less than 0.14, the doping range where Insulator-to-Metal and paramagnetic-to-ferromagnetic transitions occur. We discovered that the Kondo effect is an important ingredient in the paramagnetic region of magnetic semiconductor Fe1-X …
Filippov's Operator And Discontinuous Differential Equations, Khalid Abdulaziz Alshammari
Filippov's Operator And Discontinuous Differential Equations, Khalid Abdulaziz Alshammari
LSU Doctoral Dissertations
The thesis is mainly concerned about properties of the so-called Filippov operator that is associated with a differential inclusion x'(t) ε F(x(t)) a.e. t ε [0,T], where F : Rn → Rn is given set-valued map. The operator F produces a new set-valued map F[F], which in effect regularizes F so that F[F] has nicer properties. After presenting its definition, we show that F[F] is always upper-semicontinuous as a map from Rn to the metric space of compact subsets of Rn endowed with the Hausdorff metric. Our main approach is to study the …
Integral Cohomology Of The Siegel Modular Variety Of Degree Two And Level Three, Mustafa Arslan
Integral Cohomology Of The Siegel Modular Variety Of Degree Two And Level Three, Mustafa Arslan
LSU Doctoral Dissertations
In this thesis work Deligne's spectral sequence Ep,qr with integer coefficients for the embedding of the Siegel modular variety of degree two and level three, A2(3) into its Igusa compactification, A2(3)*, is investigated. It is shown that E3 = E∞ and this information is applied to compute the cohomology groups of A2(3) over the integers.
Influence Of Surface Chemistry On The Aggregation Of Beta Amyloid Peptide, Mariah Joan Wooldridge Mcmasters
Influence Of Surface Chemistry On The Aggregation Of Beta Amyloid Peptide, Mariah Joan Wooldridge Mcmasters
LSU Doctoral Dissertations
Alzheimer's disease is a progressive neurological ailment affecting 4.5 million aging Americans. The disease is characterized by the presence in the brain of self-assembled fibrils consisting of beta amyloid protein (Aβ). Soluble Aβ protein is present in normal human cerebrospinal fluid, but it is unclear what makes the protein aggregate into insoluble plaques. There is evidence that the Aβ fibril assembly is affected by interactions with biological surfaces, such as neuronal membranes. Here, surfaces consisting of self-assembled alkanethiol monolayers with different end groups were used to test the effect of surface chemistry on the structure and morphology of aggregates formed …
Infrared Laser Desorption/Ionization Mass Spectrometry: Fundamental And Applications, Mark Little
Infrared Laser Desorption/Ionization Mass Spectrometry: Fundamental And Applications, Mark Little
LSU Doctoral Dissertations
This dissertation on infrared laser desorption/ionization mass spectrometry encompasses fundamental studies of the desorption/ionization process and direct-from-gel laser desorption/ionization applications. Understanding of the fundamentals behind desorption and ionization can lead to improvements in the technique and to new applications. Experiments aimed at advancing this goal are wavelength studies and two-laser infrared/ultraviolet matrix-assisted laser desorption/ionization experiments. The direct-from-gel laser desorption/ionization application in which infrared laser desorption/ionization of analytes directly ionized after gel electrophoretic separation will also be presented. Protein and peptide standards were used as test analytes and the infrared lasers used were a 10.6 micrometers carbon-dioxide laser and a mid-IR …
Synthesis, Crystal Growth, Magnetic And Transport Properties Of Ln-M-X (Ln=Lanthanide, M=Transition Metal, X=In, Ga) Compounds, Willa Maria Williams
Synthesis, Crystal Growth, Magnetic And Transport Properties Of Ln-M-X (Ln=Lanthanide, M=Transition Metal, X=In, Ga) Compounds, Willa Maria Williams
LSU Doctoral Dissertations
ABSTRACT This dissertation focuses on the structural stability, magnetic and transport properties of ternary lanthanide compounds grown using indium and gallium flux. Single crystals of TbRhIn5 were synthesized using indium flux. TbRhIn5 is isostructural to the well known LnnMIn3n+2 (n = 1, 2, ∞; Ln = La, Ce; M = Rh, Ir) and adopts the HoCoGa5 structure type and crystallizes in the space group P4/mmm, Z = 1. Lattice parameters are a = 4.6000(6) Å and c = 7.4370(11) Å, V = 157.29(6) Å3. A sharp antiferromagnetic transition is observed at TN = 48 K for TbRhIn5. Single crystals of …
Topics In Quantum Topology, Khaled Moham Qazaqzeh
Topics In Quantum Topology, Khaled Moham Qazaqzeh
LSU Doctoral Dissertations
In chapter 1, which represents joint work with Gilmer, we define an index two subcategory of a 3-dimensional cobordism category. The objects of the category are surfaces equipped with Lagrangian subspaces of their real first homology. This generalizes the result of [9] where surfaces are equipped with Lagrangian subspaces of their rational first homology. To define such subcategory, we give a formula for the parity of the Maslov index of a triple of Lagrangian subspaces of a skew symmetric bilinear form over R. In chapter 2, we find two bases for the lattices of the SU(2)-TQFT-theory modules of the torus …
On Moment Conditions For The Girsanov Theorem, See Keong Lee
On Moment Conditions For The Girsanov Theorem, See Keong Lee
LSU Doctoral Dissertations
In this dissertation, the well-known Girsanov Theorem will be proved under a set of moment conditions on exponential processes. Our conditions are motivated by the desire to avoid using the local martingale theory in the proof of the Girsanov Theorem. Namely, we will only use the martingale theory to prove the Girsanov Theorem. Many sufficient conditions for the validity of the Girsanov Theorem have been found since the publication of the result by Girsanov in 1960. We will compare our conditions with some of these conditions. As an application of the Girsanov Theorem, we will show the nonexistence of an …
Adaptive Scalable Protocols For Heterogeneous Wireless Networks, Vamsi Krishna Paruchuri
Adaptive Scalable Protocols For Heterogeneous Wireless Networks, Vamsi Krishna Paruchuri
LSU Doctoral Dissertations
The focus of this dissertation is to propose analytical models to study the impact of collisions and interference in heterogeneous wireless networks and propose simple scalable and lightweight protocols that use these models to adapt to network conditions thus increasing efficiency, decreasing energy consumption and prolonging network lifetime. The contributions of this dissertation are multifold and are summarized as follows: - Analytical models to study the impact of collisions and interference on both broadcast and unicast messages. These analytical models are incorporated into the proposed protocols to adapt to the prevailing network conditions to improve their performance. - Optimized Flooding …
Nutrient Constraints On Plant Community Production And Organic Matter Accumulation Of Subtropical Floating Marshes, Guerry O., Jr. Holm Jr.
Nutrient Constraints On Plant Community Production And Organic Matter Accumulation Of Subtropical Floating Marshes, Guerry O., Jr. Holm Jr.
LSU Doctoral Dissertations
In the cycle of delta growth and decay, peat-forming wetlands span a time and space continuum. Later in the delta cycle, freshwater floating marshes become increasingly removed from external sediment subsidy and internal nutrient cycling controls plant productivity and organic matter accumulation. An interesting question is whether increased external nutrient loading can affect the basic processes that lead to peat formation—plant production and organic matter decomposition. I conducted several field studies to understand whether belowground organic matter accumulation and decomposition were affected with increased nutrient exposure; in addition, the plant community was monitored over three years. A laboratory soil respiration …
Population Boundaries And Gravitational-Wave Templates For Evolving White Dwarf Binaries, Ravi Kumar Kopparapu
Population Boundaries And Gravitational-Wave Templates For Evolving White Dwarf Binaries, Ravi Kumar Kopparapu
LSU Doctoral Dissertations
We present results from our analysis of double white dwarf (DWD) binary star systems in the inspiraling and mass-transfer stages of their evolution. Theoretical constraints on the properties of the white dwarf stars allow us to map out the DWD trajectories in the gravitational-wave amplitude-frequency domain and to identify population boundaries that define distinct sub-domains where inspiraling and/or mass-transferring systems will and will not be found. We identify for what subset of these populations it should be possible to measure frequency changes and, hence, directly follow orbit evolutions given the anticipated operational time of the proposed space-based gravitational-wave detector, LISA. …
Applications Of Titanium-Mediated Reductive Coupling And Cyclocarbonylation Reactions Toward Natural Product Synthesis, Maria A. Appeaning
Applications Of Titanium-Mediated Reductive Coupling And Cyclocarbonylation Reactions Toward Natural Product Synthesis, Maria A. Appeaning
LSU Doctoral Dissertations
Previous work in our laboratory has demonstrated not only a synthetic value of tandem reductive cyclization - carbonylation reactions in the preparation of complex molecules but also the interesting stereoselectivity observed therein. The first part of this work employs the titanium-mediated cyclocarbonylation of tethered dienals for the synthesis of prostaglandin analogues, in particular PGF2α and methyl jasmonate. Based on this hetero Pauson-Khand strategy, we have established an efficient racemic route to both the prostaglandin and the methyl jasmonate core skeletons. Moderate to excellent selectivities with regard to the hetero Pauson-Khand reaction were observed in both cases. The second part …
Synthesis, Characterization And Properties Of Cooper(Ii) Beta-Diketonate Macrocycles, Sylvester Burton
Synthesis, Characterization And Properties Of Cooper(Ii) Beta-Diketonate Macrocycles, Sylvester Burton
LSU Doctoral Dissertations
This dissertation deals with the synthesis and properties of multidentate β-diketone ligands and their transition-metal complexes. (1) We prepared two bis(β-diketones), C1BAH2 and p-XBAH2 (see sketch below), determined their crystal structures, and studied their reactions with copper(II). We envisioned that they would form macrocyclic complexes with 3-6 metal atoms. In both cases, although the initial products are soluble, as expected for the desired molecular products, we were unable to isolate well-behaved molecular solids. In the case of C1BAH2, this may be because the cyclic product requires an unusual combination of conformations of …
A Neural Network Model For Classification Of Coastal Wetlands Vegetation Structure With Moderate Resolution Imaging Spectro-Radiometer (Modis) Data, Evaristo Joseph Liwa
A Neural Network Model For Classification Of Coastal Wetlands Vegetation Structure With Moderate Resolution Imaging Spectro-Radiometer (Modis) Data, Evaristo Joseph Liwa
LSU Doctoral Dissertations
Mapping coastal marshes is an important component in the management of coastal environments. Classification of marshes using remote sensing data has traditionally been performed by employing either parametric supervised classification algorithms or unsupervised classification algorithms. The implementation of these conversional classification methods is based on the underlying distributions concerning the probability density functions (PDF). Neural networks provide a practical approach to this classification because they are essentially non-parametric data transformations that are not restricted by any underlying assumptions. The major objective of this study was to evaluate the ability of neural networks using Moderate Resolution Imaging Spectro-radiometer (MODIS) data to …
Crystal Growth And The Search For Highly Correlated Ternary Intermetallic Antimonides And Stannides, Evan Lyle Thomas
Crystal Growth And The Search For Highly Correlated Ternary Intermetallic Antimonides And Stannides, Evan Lyle Thomas
LSU Doctoral Dissertations
This dissertation describes the crystal growth, chemical structures, and efforts made towards the understanding of the physical properties of novel ternary rare-earth intermetallics, which may display signature behavior such as superconductivity, heavy fermion behavior, intermediate valence, and/or large magnetoresistance. To address the problem of correlating these characteristics with structural features, several ternary antimony- and tin-containing phases, Ln-T-X (Ln = lanthanide; T = Co, Ni, Pd; X = Sn, Sb), have been synthesized in single crystalline form by metallic flux-growth methods and characterized by X-ray diffraction. The antimonide compounds LnNi1-xSb2 (Ln = Y, Gd-Tb, Er, Yb), alpha, beta-LnNiSb3 (Ln = La, …
Circuits And Structure In Matroids And Graphs, Brian Daniel Beavers
Circuits And Structure In Matroids And Graphs, Brian Daniel Beavers
LSU Doctoral Dissertations
This dissertation consists of several results on matroid and graph structure and is organized into three main parts. The main goal of the first part, Chapters 1-3, is to produce a unique decomposition of 3-connected matroids into more highly connected pieces. In Chapter 1, we review the definitions and main results from the previous work of Hall, Oxley, Semple, and Whittle. In Chapter 2, we introduce operations that allow us to decompose a 3-connected matroid M into a pair of 3-connected pieces by breaking the matroid apart at a 3-separation. We also generalize a result of Akkari and Oxley. In …
Numerical Techniques For Fresnel Diffraction In Computational Holography, Richard Patrick Muffoletto
Numerical Techniques For Fresnel Diffraction In Computational Holography, Richard Patrick Muffoletto
LSU Doctoral Dissertations
Optical holography can produce very realistic virtual images due to its capability to properly convey the depth cues that we use to interpret three-dimensional objects. Computational holography is the use of digital representations plus computational methods to carry out the holographic operations of construction and reconstruction. The large computational requirements of holographic simulations prohibit present-day existence of real-time holographic displays comparable in size to traditional two-dimensional displays. Fourier-based approaches to calculate the Fresnel diffraction of light provide one of the most efficient algorithms for holographic computations because this permits the use of the fast Fourier transform (FFT). The limitations on …
Ecology Of Lesser Scaup Amphipods In The Upper-Midwest: Scope And Mechanisms Of The Spring Condition Hypothesis And Implications For Migration Habitat Conservation, Michael Jason Anteau
Ecology Of Lesser Scaup Amphipods In The Upper-Midwest: Scope And Mechanisms Of The Spring Condition Hypothesis And Implications For Migration Habitat Conservation, Michael Jason Anteau
LSU Doctoral Dissertations
I tested the scope of the Spring Condition Hypothesis in explaining the continental population decline of lesser scaup (Aythya affinis; hereafter scaup) and explored potential mechanisms affecting female body condition to assist conservation efforts for population recovery. Lipid reserves of females currently are lower than historical values during spring migration throughout Iowa, Minnesota, and North Dakota; females catabolized lipids throughout this area (indexed by concentrations of plasma-lipid metabolites, which accounted for 75% of the variation in mass change). My results indicate that a large segment of the continental scaup population likely is affected by decreased lipid reserves, which could cause …
High Harmonic Generation By Short Laser Pulses: Time-Frequency Behavior And Applications To Attophysics, Mitsuko Murakami
High Harmonic Generation By Short Laser Pulses: Time-Frequency Behavior And Applications To Attophysics, Mitsuko Murakami
LSU Doctoral Dissertations
High harmonic generation (HHG) is a process in which noble gas atoms excited by an intense laser field at frequency ω1 emit radiation of higher frequencies that are odd integer multiples of ω1. Driven by an infrared laser, high harmonic radiation can span from the optical into the extreme ultraviolet (XUV) frequency range. In this thesis, I study HHG using short laser pulses by solving the time-dependent Schrödinger equation (TDSE). In particular, I will focus on calculating and controlling the time-dependent instantaneous frequency (chirp) of high harmonics. The harmonic chirp is a direct consequence of the atom-field …
Integrating Micro-Scale Separations To Matrix Assisted Laser Desorption And Ioniation Time Of Flight Mass Spectrometry (Maldi-Tof-Ms) For Protein Analysis, Harrison K. Musyimi
Integrating Micro-Scale Separations To Matrix Assisted Laser Desorption And Ioniation Time Of Flight Mass Spectrometry (Maldi-Tof-Ms) For Protein Analysis, Harrison K. Musyimi
LSU Doctoral Dissertations
This dissertation describes the integration of micro-scale separations to matrix assisted laser desorption and ionization time-of-flight mass spectrometry (MALDI TOF MS) for protein analysis. MALDI MS provides unsurpassed accurate mass measurements of intact bio-molecules, for example peptides and proteins, which in turn generate high molecular specificity enabling the identity, function and structure of these molecules to be characterized. However, in order to realize the full potential of MS in proteomic studies, integrated sample processing on automated and high throughput platforms is required to address the complexity, diversity and the dynamic range of proteomic analysis. The work described here contributes towards …
Direct Detection Of Homocysteine And Syntheses Of Lanthanide Complexes As Biosensors, Weihua Wang
Direct Detection Of Homocysteine And Syntheses Of Lanthanide Complexes As Biosensors, Weihua Wang
LSU Doctoral Dissertations
At elevated levels, homocysteine (Hcy) is a risk factor for cardiovascular diseases and Alzheimer’s disease. It’s also implicated in a number of other diseases such as neural tube defects, pregnancy complications, and renal failures. The monitoring of Hcy levels in plasma is of current concern. To date, the biochemical mechanism by which Hcy is involved in disease states is unclear. Herein, we describe highly selective colorimetric methods for the direct determination of Hcy. Inexpensive, commercially available materials are reported. The results show potential application for the detection of Hcy in human blood plasma. Additionally, new HPLC postcolumn detection methods for …