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LSU Doctoral Dissertations

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Full-Text Articles in Physical Sciences and Mathematics

Active Security Mechanisms For Wireless Sensor Networks And Energy Optimization For Passive Security Routing, Lydia Ray Jan 2005

Active Security Mechanisms For Wireless Sensor Networks And Energy Optimization For Passive Security Routing, Lydia Ray

LSU Doctoral Dissertations

Wireless sensor networks consisting of numerous tiny low power autonomous sensor nodes provide us with the remarkable ability to remotely view and interact with the previously unobservable physical world. However, incorporating computation intensive security measures in sensor networks with limited resources is a challenging research issue. The objective of our thesis is to explore different security aspects of sensor networks and provide novel solutions for significant problems. We classify security mechanisms into two categories - active category and passive category. The problem of providing a secure communication infrastructure among randomly deployed sensor nodes requires active security measurements. Key pre-distribution is …

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Detection Of Biologically Important Molecules, Kyukwang Kim Jan 2005

Detection Of Biologically Important Molecules, Kyukwang Kim

LSU Doctoral Dissertations

Anions play important roles in biological systems. The design of anion sensors has been of great interest. The selective detection of a specific anion is particularly challenging. In the first chapter, I describe the synthesis of a TBS-protected fluorescein dye (1.1) and its use for the selective detection of fluoride. Solutions of 1.1 either in DCM or in aqueous media at physiological pH show the excellent selectivity towards fluoride to afford color formation while solutions of other interfering anions remain colorless. The monitoring of homocysteine (Hcy) and cysteine (Cys) levels is important since they are biomarkers associated with Alzheimer’s and …

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Analytical Separations Using Polymetric Surfactants, Mary Waithira Kamande Jan 2005

Analytical Separations Using Polymetric Surfactants, Mary Waithira Kamande

LSU Doctoral Dissertations

The goal of the research presented in this dissertation is to develop effective analytical methods for the separation of both achiral and chiral analytes using polymeric surfactants. Three analytical techniques are employed to accomplish this objective: open-tubular capillary electrochromatography (OT-CEC), open-tubular capillary electrochromatography coupled to mass spectrometry (OT-CEC/MS), and micellar affinity gradient focusing (MAGF). This research work presents novel application of polymeric surfactants that contributes to improved separations of difficult to separate analytes. The first part focuses on the application of an achiral polyelectrolyte multilayer (PEM) coating using OT-CEC. The PEM coating consisting of the cationic polymer poly (diallyldimethylammonium chloride), …

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Characterization Of A Modified Poly(Propylene Imine) Dendrimer Host System, Amy D. Morara Jan 2005

Characterization Of A Modified Poly(Propylene Imine) Dendrimer Host System, Amy D. Morara

LSU Doctoral Dissertations

The research in this dissertation focuses on the design of a novel redox-responsive host system that has the ability to encapsulate guest molecules. The host at hand is a tri(ethylene oxide), TEO, pyrrole-terminated PPI dendrimer that possesses water-solubility as a result of the presence of the TEO chains on the pyrrole groups and redox-responsive activity from the pyrrole groups after their oligomerization. The pyrrole moieties at the periphery of the dendrimer exhibit the ability to be oligomerized by oxidation chemistry, and this is shown to aid in the retention and egress of guest molecules located within the dendrimer interior. These …

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An Evaluation Of The Enantiomeric Recognition Of Amino Acid Based Polymeric Surfactants And Cyclodextrins Using Spectroscopic And Chromatographic Methods, Bertha Cedillo Valle Jan 2005

An Evaluation Of The Enantiomeric Recognition Of Amino Acid Based Polymeric Surfactants And Cyclodextrins Using Spectroscopic And Chromatographic Methods, Bertha Cedillo Valle

LSU Doctoral Dissertations

The scope of this dissertation is to explore the enantiomeric recognition properties of amino acid based polymeric surfactants using a combination of analytical techniques including chromatographic and spectroscopic methods. Chapter 1 includes an introduction to chirality and chiral separations using capillary electrophoresis. Using cyclodextrin modified micellar electrokinetic chromatography (CD-MEKC), the enantioseparation of three binaphthyl derivatives using native alpha- and beta-cyclodextrins in combination with various diastereomers of chiral polymeric surfactants (PS) was examined. A reversal of enantiomeric order was observed with the enantiomers of (1,1 S-binaphthyl-2,2 S-diamine (BNA) and (1,1 S-binaphthol (BOH) due to a competition between the two chiral selectors …

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Hydrophobic Guar Gum Derivatives Prepared By Controlled Grafting Processes For Hydraulic Facturing Applications, Ahmad Bahamdan Jan 2005

Hydrophobic Guar Gum Derivatives Prepared By Controlled Grafting Processes For Hydraulic Facturing Applications, Ahmad Bahamdan

LSU Doctoral Dissertations

The synthesis of new water soluble guar gum derivatives is described. Introduction of polyalkoxyalkyleneamide grafts to guar gum or hydroxyopropyl guar was achieved in a three step process: carboxymethylation with sodium chloroacetate, esterification with dimethyl sulfate and amidation with a series of polyalkoxyalkylene-amines. The process steps were followed using infrared spectroscopy; the grafted guar derivatives were characterized using FT-IR and 1H NMR. A series of hydroxypropyl guar derivatives with degrees of carboxymethylations ranging from 0.15-0.25 were modified with polyalkoxyalkyleneamines with molecular weights ranging from 300-3000. The ratio of oxypropylene to oxoethylene units in the polyalkoxyalkyleneamines was varied from 9/1 …

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Wavelet Sets With And Without Groups And Multiresolution Analysis, Mihaela Dobrescu Jan 2005

Wavelet Sets With And Without Groups And Multiresolution Analysis, Mihaela Dobrescu

LSU Doctoral Dissertations

In this dissertation we study a special kind of wavelets, the so-called minimally supported frequency wavelets and the associated wavelet sets. Most of the examples of wavelet sets are for dilation sets which are groups. In this work we construct wavelet sets for which the dilation set, D, is of the form D=MN, where the product is direct, and so D is not necessarily group. In the second part of this dissertation we construct multiwavelets associated with MRA's and we generalize the rotations in the dilation sets to Coxeter groups.

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Aspects Of The Life History, Ecophysiology, Bioenergetics, And Population Dynamics Of The Cownose Ray, Rhinoptera Bonasus, In The Northern Gulf Of Mexico, Julie Ann Neer Jan 2005

Aspects Of The Life History, Ecophysiology, Bioenergetics, And Population Dynamics Of The Cownose Ray, Rhinoptera Bonasus, In The Northern Gulf Of Mexico, Julie Ann Neer

LSU Doctoral Dissertations

The cownose ray, Rhinoptera bonasus, is an elasmobranch commonly observed throughout the Gulf of Mexico. Cownose rays appear to be sensitive to water temperature. I performed laboratory experiments and collected field data to obtain basic life history information, and used the information to configure an individual-based bioenergetics model. The bioenergetics model was coupled to a matrix projection model, and the coupled models were used to predict how warmer and cooler water temperatures, compared to current conditions, would affect the growth and population dynamics of the cownose rays. The life history study determined weight at age, maturity by weight, and fecundity …

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Long-Term Freshwater Input And Sediment Load From Three Tributaries To Lake Pontchartrain, Louisiana, Kangsheng Wu Jan 2005

Long-Term Freshwater Input And Sediment Load From Three Tributaries To Lake Pontchartrain, Louisiana, Kangsheng Wu

LSU Doctoral Dissertations

Lake Pontchartrain and the drainage basin have experienced environmental degradation because of human settlement, land use and climate changes. A thorough understanding of hydrologic trends and variability associated with the changes is critical for sustainable water resources management and ecosystem restoration in the region. This study examined freshwater inflow (1940-2002) and suspended solids loadings (1978-2001) from three upper Lake Pontchartrain watersheds that contribute to the lake estuary: the Amite, Tickfaw, and Tangipahoa river watersheds. The relationships of freshwater inflow and suspended solids loadings with climate variables and population growth were investigated. Using observed daily discharge, a spatially-distributed hydrologic model (SWAT) …

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The Stereoselective Synthesis Of The Butyrolactone-Bridged [8-5-5] Tricyclic Ring Systems Of (+/-)-Asteriscanolide Via The Titanium-Mediated Hetero-Pauson-Khand Reaction, Mohamed G. Sherriff Jan 2005

The Stereoselective Synthesis Of The Butyrolactone-Bridged [8-5-5] Tricyclic Ring Systems Of (+/-)-Asteriscanolide Via The Titanium-Mediated Hetero-Pauson-Khand Reaction, Mohamed G. Sherriff

LSU Doctoral Dissertations

The stereoselective construction of the tricyclic ring system of asteriscanolide from cyclooctadiene has been achieved. The synthesis involves two main steps; the synthesis of the aldehyde precursor(5)and the titanium-mediated cabocyclization of 5 to make the three rings of 43 stereoselectively.

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Shear Induced Orientation In Polymer-Clay Solutions And Their Influence On The Structure In Multilayered Films, Matthew Michael Malwitz Jan 2005

Shear Induced Orientation In Polymer-Clay Solutions And Their Influence On The Structure In Multilayered Films, Matthew Michael Malwitz

LSU Doctoral Dissertations

The influence of shear on viscoelastic solutions of poly(ethylene oxide) (PEO) and clay (Cloisite, CNA) was investigated by rheology and small angle neutron scattering (SANS) under shear. These measurements determined the shear-induced orientation of the clay and the polymer as well as their relaxation behavior after cessation of shear. Comparison of PEO-CNA solutions (~100 nm diameter platelets) to previously studied PEO-Laponite gels (~30 nm diameter platelets) found that the orientation of CNA platelets occurs at much lower shear rates. Additionally, the relaxation times were much longer for CNA platelets than for Laponite platelets. From these solutions and gels, multilayered nanocomposite …

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Separation And In Situ Catalytic Testing Of A Dirhodium Tetraphosphine Catalyst, Bobby Lloyd Barker Jan 2005

Separation And In Situ Catalytic Testing Of A Dirhodium Tetraphosphine Catalyst, Bobby Lloyd Barker

LSU Doctoral Dissertations

Attempts to study the asymmetric hydroformylation abilities of [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 were made through the separation of the enantiomers of et,ph-P4 using a chiral HPLC column. Efforts were also made to optimize the NiCl2 separation chemistry for the methyl analogue of et,ph-P4 for use in asymmetric hydroformylation. A study of hydroformylation of olefins using [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 in ionic liquids was also performed, leading directly to the important (and unexpected) effect of increased hydrogen pressure on [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 in the acetone/water system to …

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The Establishment, Expansion And Ecosystem Effects Of Phragmites Australis, An Invasive Species In Coastal Louisiana, Lee Ellis Stanton Jan 2005

The Establishment, Expansion And Ecosystem Effects Of Phragmites Australis, An Invasive Species In Coastal Louisiana, Lee Ellis Stanton

LSU Doctoral Dissertations

As biological invasions have become a common phenomenon throughout the world, ecologists have intensified efforts to understand why natural communities are susceptible to invasion. Invading species can cause shifts in community structure that result in irreversible changes to ecosystem function. Phragmites australis has rapidly spread in North American coastal wetlands during the past 50 years and has become a dominant feature in Northern Gulf of Mexico brackish marshes. The rate at which Phragmites is spreading or the mechanisms controlling its establishment in these marshes is unknown. My research objectives were to: (1) determine the spatial and temporal patterns of Phragmites …

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Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence Jan 2005

Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence

LSU Doctoral Dissertations

Magnetic resonance imaging (MRI) is a technique used primarily in medical settings to produce high quality images of the human body’s internal anatomy. Each image is of a thin slice through the body, with the typical distance between slices being a few millimeters. Brain segmentation is the delineation of one or more anatomical structures within images of the brain. It promotes greater understanding of spatial relationships to aid in such tasks as surgical planning and clinical diagnoses, particularly when the segmented outlines from each image slice are displayed together as a surface in three-dimensions. A review of the literature indicates …

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The Twiggs Clay: Mineralogy, Origin, And Industrial Properties Of An Upper Eocene Opaline Claystone In The Coastal Plain Province Of Georgia, U.S., Lori G. Eversull Jan 2005

The Twiggs Clay: Mineralogy, Origin, And Industrial Properties Of An Upper Eocene Opaline Claystone In The Coastal Plain Province Of Georgia, U.S., Lori G. Eversull

LSU Doctoral Dissertations

The Twiggs Clay is an upper Eocene claystone found as discontinuous deposits downdip of the Fall Line in the Coastal Plain Province of eastern and central Georgia. A distinctive facies of the Twiggs is found in two lenses near the town of Wrens. The nature, origin, and potential commercial application of this resource are examined. Four strata and two mineralogic assemblages are recognized in the Wrens deposit. The lower three strata are near white in color and very low in density. These strata are mineralogically similar and are composed predominantly of disordered silica and smectite. The smectite is dioctahedral, and …

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Efficient Automatic Correction And Segmentation Based 3d Visualization Of Magnetic Resonance Images, Mikhail V. Milchenko Jan 2005

Efficient Automatic Correction And Segmentation Based 3d Visualization Of Magnetic Resonance Images, Mikhail V. Milchenko

LSU Doctoral Dissertations

In the recent years, the demand for automated processing techniques for digital medical image volumes has increased substantially. Existing algorithms, however, still often require manual interaction, and newly developed automated techniques are often intended for a narrow segment of processing needs. The goal of this research was to develop algorithms suitable for fast and effective correction and advanced visualization of digital MR image volumes with minimal human operator interaction. This research has resulted in a number of techniques for automated processing of MR image volumes, including a novel MR inhomogeneity correction algorithm derivative surface fitting (dsf), automatic tissue detection algorithm …

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Parallel Molecular Dynamics Simulations Of Pressure-Induced Structural Transformations In Cadmium Selenide Nanocrystals, Nicholas Jabari Ouma Lee Jan 2005

Parallel Molecular Dynamics Simulations Of Pressure-Induced Structural Transformations In Cadmium Selenide Nanocrystals, Nicholas Jabari Ouma Lee

LSU Doctoral Dissertations

Parallel molecular dynamics (MD) simulations are performed to investigate pressure-induced solid-to-solid structural phase transformations in cadmium selenide (CdSe) nanorods. The effects of the size and shape of nanorods on different aspects of structural phase transformations are studied. Simulations are based on interatomic potentials validated extensively by experiments. Simulations range from 105 to 106 atoms. These simulations are enabled by highly scalable algorithms executed on massively parallel Beowulf computing architectures. Pressure-induced structural transformations are studied using a hydrostatic pressure medium simulated by atoms interacting via Lennard-Jones potential. Four single-crystal CdSe nanorods, each 44Å in diameter but varying in length, in the …

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Stability In Dynamical Polysystems, George Cazacu Jan 2005

Stability In Dynamical Polysystems, George Cazacu

LSU Doctoral Dissertations

A dynamical polysystem consists of a family of continuous dynamical systems, all acting on a given metric space. The first chapter of the present thesis shows a generalization of control systems via dynamical polysystems and establishes the equivalence of the two notions under certain lipschitz condition on the function defining the dynamics. The remaining chapters are focused on a basic theory of dynamical polysystems. Some topological properties of limit sets are described in Chapter 2. Chapters 3 and 4 provide characterizations for various notions of strong stability. Chapter 5 makes use of the theory of closed relations to study Lyapunov …

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Capillary And Microchip Gel Electrophoresis Using Multiplexed Fluorescence Detection With Both Time-Resolved And Spectral-Discrimination Capabilities: Applications In Dna Sequencing Using Near-Infrared Fluorescence, Li Zhu Jan 2005

Capillary And Microchip Gel Electrophoresis Using Multiplexed Fluorescence Detection With Both Time-Resolved And Spectral-Discrimination Capabilities: Applications In Dna Sequencing Using Near-Infrared Fluorescence, Li Zhu

LSU Doctoral Dissertations

Increasing the information content obtainable from a single assay and system miniaturization has continued to be important research areas in analytical chemistry. The research presented in this dissertation involves the development of a two-color, time-resolved fluorescence microscope for the acquisition of both steady-state and time-resolved data during capillary and microchip electrophoresis. The utility of this hybrid fluorescence detector has been demonstrated by applying it to DNA sequencing applications. Coupling color discrimination with time-resolved fluorescence offers increased multiplexing capabilities because the lifetime data adds another layer of information. An optical fiber-based fluorescence microscope was constructed, which utilized fluorescence in near-IR region, …

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Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi Jan 2005

Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi

LSU Doctoral Dissertations

Novel symmetric and asymmetric water-soluble tetrabenzoporphyrin are synthesized in relatively good yields. These compounds are synthesized by the condensation of butanopyrrole with several aldehydes that contain masked water solubilizing groups followed by metal insertion, oxidation and demetallation and deprotection of the masked solubilizing groups. The biological evaluation (in vitro and in vivo) studies are described in addition to the photophysical evaluations of the corresponding compounds. A novel versatile route to the syntheses of novel free-bases and metallo-benzoylbiliverdin is discussed. The treatment of metal free-dodecasubstituted porphyrin with sodium nitrite and trifluoroacetic acid at room temperature in the presence of oxygen affords …

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Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson Jan 2005

Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson

LSU Doctoral Dissertations

Body size is highly variable among geese, both at intra- and interspecific levels. Interspecific variation in several behaviors has been attributed to differences in body size in geese: incubation constancy, tendency to maintain family units, and time spent foraging. Body size has important physiological implications for birds, mostly because mass-specific metabolic rate is greater for birds of smaller mass. The Body-size Hypothesis predicts that smaller species deplete their energy reserves at relatively faster rates than do larger species. Hypotheses and conclusions concerning effects of body size on waterfowl behavior often are based on comparisons of species that confront different climates, …

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Medical Image Enhancement, Alina Monica Trifas Jan 2005

Medical Image Enhancement, Alina Monica Trifas

LSU Doctoral Dissertations

Each image acquired from a medical imaging system is often part of a two-dimensional (2-D) image set whose total presents a three-dimensional (3-D) object for diagnosis. Unfortunately, sometimes these images are of poor quality. These distortions cause an inadequate object-of-interest presentation, which can result in inaccurate image analysis. Blurring is considered a serious problem. Therefore, “deblurring” an image to obtain better quality is an important issue in medical image processing. In our research, the image is initially decomposed. Contrast improvement is achieved by modifying the coefficients obtained from the decomposed image. Small coefficient values represent subtle details and are amplified …

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Enantioselective Syntheses And Chemical Investigations Of Plant-Derived Bioactive Volatile Compounds, Anne Marie Sauer Jan 2005

Enantioselective Syntheses And Chemical Investigations Of Plant-Derived Bioactive Volatile Compounds, Anne Marie Sauer

LSU Doctoral Dissertations

Research, inspired by nature, provides ample opportunity for discovery, ingenuity, and creative endeavor. For these reasons, the work and accomplishments presented herein focus on the total syntheses and related investigations of a variety of natural product derivatives, specifically (+)-nootkatone and jasmone. While the former consists of several independent projects: (a) an enantioselective synthetic route to (+)-nootkatone and derivatives, (b) examination of the valencane ring system, (c) determination of the absolute configuration of (+)-nootkatone, and (d) rearrangements of various sesquiterpenoid derivatives; the latter focuses on the construction ofƒndelta, epsilon-unsaturated carbonyl compounds, hetero Pauson-Khand substrates, via [3,3]-sigmatropic rearrangements.

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Radiative Transfer Modeling Of Thermal Infrared Emissivity Spectra: Applications To Martian Regolith Observations, Karly Mariah Pitman Jan 2005

Radiative Transfer Modeling Of Thermal Infrared Emissivity Spectra: Applications To Martian Regolith Observations, Karly Mariah Pitman

LSU Doctoral Dissertations

Satellite and rover remote sensing of planetary regolith surfaces, in the form of thermal infrared emissivity spectra taken at nadir and off-nadir angles of emergence from the surface, requires use of theoretical models for interpretation of constituent grain physical properties. However, such models have remained in stasis in recent years, with nearly a ten-year gap in significant advances. To date, no radiative transfer model (semiempirical, exact, or hybrid solution) has been able to adequately predict the nadir emissivity behavior of simple mineral assemblages. Few measurements have been attempted in the laboratory or field regarding directional emissivity effects of planetary regoliths; …

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Stm And Arpes Studies Of Epitaxial Multilayer Ag On Cu(110) And Ni(110), Weichang Zhao Jan 2005

Stm And Arpes Studies Of Epitaxial Multilayer Ag On Cu(110) And Ni(110), Weichang Zhao

LSU Doctoral Dissertations

Ag nanostructures of multilayer coverages (< 30 monolayers) epitaxially self-assembled on Cu(110) and Ni(110) have been explored by scanning tunneling microscopy (STM), angle-resolved photoelectron emission spectroscopy (ARPES), and low energy electron diffraction (LEED). We have studied varied nanostructure morphologies self-assembled depending on different deposition/annealing processes and coverages, their atomic structures, growth behaviors and mechanisms, and the electronic structures of nanowires. At nominal coverages of 1.2 ML < ¦È < ~10 ML, there are two epitaxial structures on Cu(110) and Ni(110). One is a Ag(110) multilayer film, which has a superstructure with lateral periodic units of eight and three/four substrate lattice constants along [¯110] and along [001] respectively. Another is that of Ag(110) nanowires surrounded by pseudohexagonal Ag(111) monolayer. The Ag(110) nanowires are triangular in cross section. The two side surfaces are faceted and the long axis is atomically straight along [¯110]. Typical lengths are within the range of 100 ~ 5000 Å, widths 70 ~ 300 Å, side slopes 10 ~ 30º, and heights 5 ~ 60 Å. The Ag nanowires present extraordinary anisotropy with observed aspect ratios (length:width) of up to 20:1. The Ag(110) nanowires are in-registry with the substrate along [001], but not along [¯110]. At coverages of ~ 10 ML < ¦È < ~25 ML, there also exist two different nanostructures, the nanowires and a Ag(110) atomically-flat film with some pits as deep as down to the substrate and a one-dimensional quasiperiodic superstructure along [001]. There are two basic separations of the superstructural stripes: one is three lattices wide (~11 Å) and the other is two lattices wide (~7 Å). Both of nanostructures are stable at temperature up to at least 200 ¡ãC and not inter-transformable. The growth of the nanowires is driven by the elastic strain mechanism, but the growth of the atomically-flat film is driven by electronic growth mechanism originated from the electron quantum confinement in the vertical direction of the film. The ARPES of the nanowires shows dispersion in the vertical and the [¯110] directions, but no dispersion in the [001] direction because of the limited width (~ 200 Å).

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Belowground Productivity Of Mangrove Forests In Southwest Florida, Beatriz Eugenia Giraldo Sánchez Jan 2005

Belowground Productivity Of Mangrove Forests In Southwest Florida, Beatriz Eugenia Giraldo Sánchez

LSU Doctoral Dissertations

Studies in belowground dynamics are limited mainly due to the difficulty of studying roots despite wide recognition of its importance. This dissertation focused on methods for analyzing mangrove roots, root responses to phosphorus and flooding, and variation in root production between forest types. Techniques to separate live and dead roots such as colorimetric, fluorescence, buoyancy, and visual assessment were compared. The traditional method of visual assessment combined with root buoyancy was accurate, fast, and applicable to larger samples. Additionally, techniques such as rhizotrons, root ingrowth cores, and root image analysis were useful to study mangrove roots. Root and litter production, …

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Nutrient Interactions, Plant Productivity, Soil Accretion, And Policy Implications Of Wetland Enhancements In Coastal Louisiana, Christopher Brantley Jan 2005

Nutrient Interactions, Plant Productivity, Soil Accretion, And Policy Implications Of Wetland Enhancements In Coastal Louisiana, Christopher Brantley

LSU Doctoral Dissertations

Ecosystem response, stakeholder interactions, and the policy implications to a wetland assimilation project are reported here for the City of Mandeville, St. Tammany Parish, Louisiana. Between September 1998 and October 2004, input of secondarily treated wastewater effluent was found to have a net positive effect on the downstream wetland receiving basin. The major hydrologic inputs to the system are the effluent, precipitation, and back water flooding from Lake Pontchartrain. Nutrient levels were generally low except in the immediate vicinity of the outfall and removal efficiencies of N and P ranged from 44% to 87% and 25% to 93%, respectively. On …

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Multiscale Strain Analysis, Timothy Donald Breitzman Jan 2005

Multiscale Strain Analysis, Timothy Donald Breitzman

LSU Doctoral Dissertations

The mathematical homogenization and corrector theory relevant to prestressed heterogeneous materials in the linear-elastic regime is discussed. A suitable corrector theory is derived to reconstruct the local strain field inside the composite. Based on this theory, we develop an inexpensive numerical method for multi scale strain analysis within a prestressed heterogeneous material. The theory also provides a characterization of the macroscopic strength domain. The strength domain places constraints on the homogenized strain field which guarantee that the actual strain in the heterogeneous material lies inside the strength domain of each material participating in the structure.

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An Empirical Study Of Imputation Techniques For Software Data Sets, Sumanth Yenduri Jan 2005

An Empirical Study Of Imputation Techniques For Software Data Sets, Sumanth Yenduri

LSU Doctoral Dissertations

Software Project Effort/Cost/Time Estimation has been one of the hot topics of research in the current software engineering industry. Solutions for effort/cost/time estimation are in great demand. Knowledge of accurate effort/cost/time estimates early in the software project life cycle enables project managers manage and exploit resources efficiently. The constraints of cost and time can also be met. To this day, most companies rely on their historical database of past project data sets to predict estimates for future projects. Like other data sets, software project data sets also suffer from numerous problems. The most important problem is they contain missing/incomplete data. …

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Comparative Studies Of Sperm Cryopreservation Of Diploid And Tetraploid Pacific Oysters, Qiaoxiang Dong Jan 2005

Comparative Studies Of Sperm Cryopreservation Of Diploid And Tetraploid Pacific Oysters, Qiaoxiang Dong

LSU Doctoral Dissertations

This dissertation addressed comparative studies of sperm cryopreservation of diploid and tetraploid Pacific oysters, Crassostrea gigas, with an emphasis on the development of standardized and optimized protocols. This includes comparative ultrastructural differences between sperm from diploid and tetraploid oysters, methods for the rapid estimation of sperm concentration, optimization of cryopreservation, and evaluation of the mechanisms for sperm agglutination (formation of clumps or elongated "noodles") in thawed samples. Currently, cryopreserved sperm has not been commercialized in any aquatic species, and standardization and optimization could greatly benefit the potential commercialization of its use. In oysters specifically, cryopreserved sperm from tetraploids would facilitate …

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