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Articles 1171 - 1200 of 1402
Full-Text Articles in Physical Sciences and Mathematics
Predicting Water Quality Effects On Bay Anchovy (Anchoa Mitchilli) Growth And Production In Chesapeake Bay: Linking Water Quality And Individual-Based Fish Models, Aaron Thomas Adamack
Predicting Water Quality Effects On Bay Anchovy (Anchoa Mitchilli) Growth And Production In Chesapeake Bay: Linking Water Quality And Individual-Based Fish Models, Aaron Thomas Adamack
LSU Doctoral Dissertations
Water quality in the Chesapeake Bay and the Patuxent River has decreased since the 1950s due to an increase in nutrient loadings. Increased nutrient loads have caused an increase in the extent and duration of hypoxic conditions. Restoration via large-scale reductions in nutrient loadings is now underway. How reducing nutrient loadings will affect water quality is well predicted; however the effect on fish is generally unknown as most water quality models do not include trophic levels higher than zooplankton. I combined two water quality models with bay anchovy models (Anchoa mitchilli) to examine the effects of changes in nutrient loadings …
Knowledge-Based Methods For Automatic Extraction Of Domain-Specific Ontologies, Janardhana R. Punuru
Knowledge-Based Methods For Automatic Extraction Of Domain-Specific Ontologies, Janardhana R. Punuru
LSU Doctoral Dissertations
Semantic web technology aims at developing methodologies for representing large amount of knowledge in web accessible form. The semantics of knowledge should be easy to interpret and understand by computer programs, so that sharing and utilizing knowledge across the Web would be possible. Domain specific ontologies form the basis for knowledge representation in the semantic web. Research on automated development of ontologies from texts has become increasingly important because manual construction of ontologies is labor intensive and costly, and, at the same time, large amount of texts for individual domains is already available in electronic form. However, automatic extraction of …
Application-Specific Reliable Data Transfer In Wireless Sensor Networks, Damayanti Datta
Application-Specific Reliable Data Transfer In Wireless Sensor Networks, Damayanti Datta
LSU Doctoral Dissertations
A wireless sensor network (WSN) is a collection of sensor nodes and base stations connected via wireless medium. It sends data collected from the nodes to the base stations for generating information. The size and low cost of the sensor nodes as well as the WSN's ability to connect without wired links are its key advantages which enable it to be deployed in hostile or inaccessible environments at low cost. However, WSNs suffer from high data loss due to the inherent weaknesses in a wireless transmission medium, transmission problems in hostile environments due to human interference, etc. and node failures …
Chemical Differences Of Atherosclerotic Plaques In Native And Bypass Human Coronary Arteries And Diseased And Non-Diseased Human Aortas, Samuel Jean Washington
Chemical Differences Of Atherosclerotic Plaques In Native And Bypass Human Coronary Arteries And Diseased And Non-Diseased Human Aortas, Samuel Jean Washington
LSU Doctoral Dissertations
ABSTRACT Cardiovascular disease, primarily atherosclerosis involves a number of distinct processes that are associated with plaque development. The use of differential gel electrophoresis to determine differences between proteins produced in native and bypass coronary arteries from the same heart has been studied. The analytical techniques presented in this study to characterize plaque samples include two dimensional gel electrophoresis, sodium dodecylsulfate polyacrylamide gel electrophoresis, mass spectrometry, differential gel electrophoresis, and high performance liquid chromatography. An overview of the stages involved in atherosclerosis and the theories implicated in the manifestation of atherosclerosis was presented. A design study using the Box Behnken method …
Interactions Of The Triaquatricarbonylrhenium(I) Cation With Nucleotides And Other N-Donor Ligands, Kristie Marie Adams
Interactions Of The Triaquatricarbonylrhenium(I) Cation With Nucleotides And Other N-Donor Ligands, Kristie Marie Adams
LSU Doctoral Dissertations
Transition metal centers possessing an octahedral geometry are useful for understanding the natural role of metal ions in biology. Complexes based on such metals might improve upon the widely used square planar Pt(II) anticancer drug cisplatin, cis-[Pt(NH3)2Cl2]. The octahedral triaquatricarbonylrhenium(I) cation, fac-[Re(CO)3(H2O)3]+, has been shown to possess anticancer activity. Furthermore, Re(I) complexes containing unstable rhenium isotopes have found utility as radiodiagnostic and radiotherapeutic agents. Thus, this work focuses on elucidating the fundamental coordination chemistry of fac-[Re(CO)3(H2O)3]+ …
Using Power Spectra To Look For Anisotropies In Ultra-High Energy Cosmic Ray Distributions, Megan Alicia Mcewen
Using Power Spectra To Look For Anisotropies In Ultra-High Energy Cosmic Ray Distributions, Megan Alicia Mcewen
LSU Doctoral Dissertations
The origins and compositions of ultra-high energy cosmic rays (UHECR) remains a mystery to this day. The Pierre Auger Observatory (PAO) is being constructed now in the hopes that it will help solve this mystery by detecting more UHECR than any previous experiment. In this dissertation, I will discuss this experiment, and analyze the data collected so far by comparing it with simulated data from possible source distributions. In these simulations, I will track antiprotons, along with other possible cosmic ray primaries, through various models of galactic and extragalactic magnetic fields. Once they reach a certain distance, I will record …
Fabrication Of Dna Microarrays On Poly (Methylmethacrylate) Substrates For Biomolecular Reporting, Catherine N. Situma
Fabrication Of Dna Microarrays On Poly (Methylmethacrylate) Substrates For Biomolecular Reporting, Catherine N. Situma
LSU Doctoral Dissertations
DNA microarrays require the use of substrates with well-established surface modification / probe attachment chemistries. Glass/quartz have been widely adopted as typical support materials since their surface modification chemistries which involve the use of siloxane –based chemistries have been widely studied however; these chemistry is susceptible to hydrolytic cleavage especially at high or low pH values. Recently, polymers have been sought as alternative microarray support materials but their surface modification strategies are not well characterized compared to glass. This report will entail surface photo-modification of PMMA polymer substrates by UV irradiation which produces functional scaffolds of carboxylic groups that allow …
A Comparison Of Individual-Based And Matrix Projection Models To Applied To Fish Population And Community Dynamics, Shaye Ellen Sable
A Comparison Of Individual-Based And Matrix Projection Models To Applied To Fish Population And Community Dynamics, Shaye Ellen Sable
LSU Doctoral Dissertations
Matrix projection models and individual-based models (IBM) are commonly used for the analysis and management of fish populations. Matrix models break down the population into age or stage classes, while IBMs track individuals. I perform a series of quantitative comparisons between the predictions of the two modeling approaches using the IBM as the standard of comparison to demonstrate when individual variation, species interactions, and spatial heterogeneity adversely affect matrix model performance. I first evaluate the matrix approach for predicting yellow perch population responses when perch are involved in size-specific predator-prey interactions with walleye. I created density-dependent and stochastic age-structured and …
Sign Ambiguities Of Gaussian Sums, Heon Kim
Sign Ambiguities Of Gaussian Sums, Heon Kim
LSU Doctoral Dissertations
In 1934, two kinds of multiplicative relations, extit{norm and Davenport-Hasse} relations, between Gaussian sums, were known. In 1964, H. Hasse conjectured that the norm and Davenport-Hasse relations are the only multiplicative relations connecting the Gaussian sums over $mathbb F_p$. However, in 1966, K. Yamamoto provided a simple counterexample disproving the conjecture when Gaussian sums are considered as numbers. This counterexample was a new type of multiplicative relation, called a {it sign ambiguity} (see Definition ef{defi:of_sign_ambi}), involving a $pm$ sign not connected to elementary properties of Gauss sums. In Chapter $5$, we provide an explicit product formula giving an infinite class …
Factors Influencing The Spatial Distribution Of Natural Resource-Based Industries: The Softwood Lumber Industry In The United States South, Francisco Xavier Aguilar
Factors Influencing The Spatial Distribution Of Natural Resource-Based Industries: The Softwood Lumber Industry In The United States South, Francisco Xavier Aguilar
LSU Doctoral Dissertations
Expanding on the Theory of Location, New Economic Geography, and Porter's Theory of Clusters this dissertation attempts to identify key factors influencing the location of firms in a resource-based industry. The softwood lumber industry in the United States is used as a case study to test several hypotheses concerning these theories. Two U.S. regions, the West and the South, were selected for analysis because they account for over 70 percent of U.S lumber manufacturing capacity. A multi-disciplinary research approach involved three-stages. First, self-reported preferences were analyzed using common factor and conjoint analyses for preferences for location attributes. Surveys were sent …
Comparison Of Kp And Bbm-Kp Models, Gideon Pyelshak Daspan
Comparison Of Kp And Bbm-Kp Models, Gideon Pyelshak Daspan
LSU Doctoral Dissertations
In this dissertation we show that the solution of the pure initial-value problems for the KP and regularize KP equations are the same, to within the order of accuracy attributable to either, on the time scale from zero to epsilon to negative three halves power, during which nonlinear and dispersive effects may accumulate to make an order-one relative difference to the wave profiles.
Effective Inter-Organizational Information And Communication Technology Adoption In Business-To-Business Customer Interface, Sanna Maria Kallioranta
Effective Inter-Organizational Information And Communication Technology Adoption In Business-To-Business Customer Interface, Sanna Maria Kallioranta
LSU Doctoral Dissertations
Past research has found that 80-90 percent of IT investments do not meet corporate performance objectives, primarily due to non-technical reasons such as human and organizational aspects. When Inter-organizational Information and Communication Technology (IICT) implementation is properly managed IICT can help manage the flow of goods, services, and information between business partners in the supplier-customer dyad, thus reducing transaction costs along the entire value chain. Using the underlying Resource-Based View theoretical foundation, this research approaches effective IICT implementation capability as a holistic organizational capability that extends beyond tangible IT resources. This research investigates business outcomes of IICT adoption in the …
Structural And Forecasting Softwood Lumber Models With A Time Series Approach, Nianfu Song
Structural And Forecasting Softwood Lumber Models With A Time Series Approach, Nianfu Song
LSU Doctoral Dissertations
The development of cointegration theories and the presence of nonstationarity in time series raised serious concerns about possible spurious estimations in forest products models. Based on the results of Hsiao (1997a, 1997b), all the virtues of two-stage least square (2SLS) hold if there are sufficient cointegration relations. Stationary null and nonstationary null unit root tests and monthly seasonal unit root tests were applied to the time series used in this dissertation. Cointegration tests with exogenous variables were performed to justify the 2SLS. A regional error correction model (ECM) with four regional lumber supply and demand equations and a U.S.-Canada supply …
A Computational Framework For The Structural Change Analysis Of 3d Volumes Of Microscopic Specimens, Madhusudhanan Balasubramanian
A Computational Framework For The Structural Change Analysis Of 3d Volumes Of Microscopic Specimens, Madhusudhanan Balasubramanian
LSU Doctoral Dissertations
Glaucoma, commonly observed with an elevation in the intraocular pressure level (IOP), is one of the leading causes of blindness. The lamina cribrosa is a mesh-like structure that provides axonal support for the optic nerves leaving the eye. The changes in the laminar structure under IOP elevations may result in the deaths of retinal ganglion cells, leading to vision degradation and loss. We have developed a comprehensive computational framework that can assist the study of structural changes in microscopic structures such as lamina cribrosa. The optical sectioning property of a confocal microscope facilitates imaging thick microscopic specimen at various depths …
River, Tidal And Wind Interactions In A Deltaic Estuarine System, Gregg Snedden
River, Tidal And Wind Interactions In A Deltaic Estuarine System, Gregg Snedden
LSU Doctoral Dissertations
The balance between river and marine influences is important in governing landscape sustainability in river deltas. River- and atmospherically driven sea level variability, sediment loading, and estuary-ocean exchange in the Mississippi River delta are examined in this study. Subtidal estuarine sea level variability in the Breton Sound estuary was driven by a combination of remote atmospheric forcing outside the estuary over the continental shelf and controlled river inputs through a gated diversion structure at the estuary head. The highly-frictional deltaic landscape acted as a low-pass filter to coastal fluctuations near the estuary mouth. When substantial quantities river water were discharged …
Classifying Quadratic Number Fields Up To Arf Equivalence, Jeonghun Kim
Classifying Quadratic Number Fields Up To Arf Equivalence, Jeonghun Kim
LSU Doctoral Dissertations
Two number fields K and L are said to be Arf equivalent if there exists a bijection T : ΩK → ΩL of places of K and of L such that KP and LTP are locally Arf equivalent for every place P ε ΩK. That is, |K*p/K*2p| = |L*TP/L*2TP|, type[( , )P] = type[( , )TP], and Arf(rP ) = Arf(rTP ) for every place P ε ΩK, where rP is the local …
Characterization Of Beta-Amyloid Peptide Aggregation And Acceleration With Non-Fibrillar Forming Peptide-Based Mediators, Nadia J. Edwin
Characterization Of Beta-Amyloid Peptide Aggregation And Acceleration With Non-Fibrillar Forming Peptide-Based Mediators, Nadia J. Edwin
LSU Doctoral Dissertations
Protein aggregation occurs under many circumstances, from the dynamic assembly of tubulin to form microtubules, the aggregation of actin into filaments, as well as plaque formation by amyloid precipitation. One important requirement in studying the mechanism of amyloid aggregation is the ability to monitor the growth kinetics over a wide range in size scales (10 nm to microns) with time that spans microseconds to seconds. Understanding the mechanisms of the aggregation may then lead to improved design of drugs to help control or suppress the aggregation process. In this dissertation, the physical characterization of the â-amyloid peptide and its interaction …
Limit Theorems For Weighted Stochastic Systems Of Interacting Particles, Jie Wu
Limit Theorems For Weighted Stochastic Systems Of Interacting Particles, Jie Wu
LSU Doctoral Dissertations
The goal of this dissertation is to (a) establish the weak convergence of empirical measures formed by a system of stochastic differential equations, and (b) prove a comparison result and compactness of support property for the limit measure. The stochastic system of size n has coefficients that depend on the empirical measure determined by the system. The weights for the empirical measure are determined by a further n-system of stochastic equations. There is a random choice among N types of weights. The existence and uniqueness of solutions of the interacting system, weak convergence of the empirical measures, and the identification …
Belowground Biomass Of Spartina Alterniflora: Seasonal Variability And Response To Nutrients, Faith Armand Darby
Belowground Biomass Of Spartina Alterniflora: Seasonal Variability And Response To Nutrients, Faith Armand Darby
LSU Doctoral Dissertations
Spartina alterniflora is a salt marsh macrophyte found from Canada to the Gulf of Mexico which often provides the dominant plant cover. Although S. alterniflora is well known for its high aboveground productivity, fifty to ninety percent of the total plant production occurs belowground. No previous studies address the seasonal variation of belowground biomass or the response of above-and belowground biomass to nutrients at the southern limits of its U. S. range. The objectives of this study were to: 1) document the seasonal variability of its above- and belowground biomass and test for responses to various combinations of N, P, …
Self-Assembly And Its Inhibition In Bolaform Amphiphilic Dendrimers, Jirun Sun
Self-Assembly And Its Inhibition In Bolaform Amphiphilic Dendrimers, Jirun Sun
LSU Doctoral Dissertations
Self-assembly is scientifically interesting, technologically important, and sometimes life-threatening. A striking example: Alzheimer’s disease is caused by the self-assembly of the â-amyloid fragment of amyloid precursor protein. Such natural amphiphiles normally are very expensive and complicated to isolate. Synthetic mimics that are much cheaper and easier to prepare can facilitate the development of efficient characterization methods, even as they suggest new materials science applications. Two-directional arborols are synthetic bolaform amphiphilic dendrimers. They dissolve in hot water and form reversible gels at room temperature. Bundles of fibrils, which are made by self-assembly of arborols, are found in the gels. The properties …
Investigation Into The Dirhodium-Catalyzed Hydroformylation Of 1-Alkenes And Preparation Of A Novel Tetraphosphine Ligand, Alexandre R. Monteil
Investigation Into The Dirhodium-Catalyzed Hydroformylation Of 1-Alkenes And Preparation Of A Novel Tetraphosphine Ligand, Alexandre R. Monteil
LSU Doctoral Dissertations
The reaction of the tetraphosphine ligand rac-et,ph-P4 (et,ph-P4 = PEt2CH2CH2(Ph)PCH2P(Ph)CH2CH2PEt2) with 2 equiv. of [Rh(nbd)2]+ (nbd = norbornadiene) generates [rac-Rh2(nbd)2(et,ph-P4)]2+, which is the precursor to a highly active and regioselective hydroformylation catalyst system. The “key” catalyst species generated under H2/CO pressure has been proposed to be the dihydrido complex [rac-Rh2H2(ì-CO)2(et,ph-P4)]2+, and represents one of the most dramatic example of homobimetallic …
Simulating Protein Evolution Via Thermodynamic Models, Yanlong Xu
Simulating Protein Evolution Via Thermodynamic Models, Yanlong Xu
LSU Doctoral Dissertations
Natural proteins are results of evolution and they need to maintain certain thermodynamic stabilities in order to carry out their biological functions. By simulating protein evolution based on thermodynamic rules, we could reconstruct the evolution trajectory and analyze the evolutionary dynamics of a protein population, and further understand the protein sequence-structure-function relationship. In this study, we have used both a simplified lattice model and a high-resolution atomic model to simulate protein evolution processes. With the lattice model, we have investigated general theoretical questions about how protein structural designability would affect protein evolution, particularly how it would affect protein recombination and …
Effective Bootstrapping Of Peer-To Peer Networks Over Mobile Ad-Hoc Networks, Wei Ding
Effective Bootstrapping Of Peer-To Peer Networks Over Mobile Ad-Hoc Networks, Wei Ding
LSU Doctoral Dissertations
Mobile Ad-hoc Networks (MANETs) and Peer-to-Peer (P2P) networks are vigorous, revolutionary communication technologies in the 21st century. They lead the trend of decentralization. Decentralization will ultimately win clients over client/server model, because it gives ordinary network users more control, and stimulates their active participation. It is a determinant factor in shaping the future of networking. MANETs and P2P networks are very similar in nature. Both are dynamic, distributed. Both use multi-hop broadcast or multicast as major pattern of traffic. Both set up connection by self-organizing and maintain connection by self-healing. Embodying the slogan "networking without networks," both abandoned traditional client/server …
Development Of Analytical Techniques For The Analysis Of Submicron Particles And Protein Aggregates, Yohannes H. Rezenom
Development Of Analytical Techniques For The Analysis Of Submicron Particles And Protein Aggregates, Yohannes H. Rezenom
LSU Doctoral Dissertations
The goal of the research presented in this dissertation is to develop analytical techniques for the analysis of heterogeneous mixtures of submicron particles and protein aggregates. In Chapter 2, a simple and reproducible technique for constructing perfectly aligned gaps in fused-silica capillaries has been developed for postcolumn reagent addition with capillary electrophoresis (CE) to take advantage of laser-induced fluorescence (LIF) detection. This technique uses laser ablation with a Nd:YAG laser to create gaps of 14.0 ¡Ó 2.2 ƒÝm. These structures have been used for reagent addition for postcolumn derivatization with LIF detection and have been tested for the separation of …
Representation Properties Of Definite Lattices In Function Fields, Jean Edouard Bureau
Representation Properties Of Definite Lattices In Function Fields, Jean Edouard Bureau
LSU Doctoral Dissertations
This work is made of two different parts. The first contains results concerning isospectral quadratic forms, and the second is about regular quadratic forms. Two quadratic forms are said to be isospectral if they have the same representation numbers. In this work, we consider binary and ternary definite integral quadratic form defined over the polynomial ring F[t], where F is a finite field of odd characteristic. We prove that the class of such a form is determined by its representation numbers. Equivalently, we prove that there is no nonequivalent definite F[t]-lattices of rank 2 or 3 having the same theta …
An Inverse Homogenization Design Method For Stress Control In Composites, Michael Stuebner
An Inverse Homogenization Design Method For Stress Control In Composites, Michael Stuebner
LSU Doctoral Dissertations
This thesis addresses the problem of optimal design of microstructure in composite materials. The work involves new developments in homogenization theory and numerical analysis. A computational design method for grading the microstructure in composite materials for the control of local stress in the vicinity of stress concentrations is developed. The method is based upon new rigorous multiscale stress criteria connecting the macroscopic or homogenized stress to local stress fluctuations at the scale of the microstructure. These methods are applied to three different types of design problems. The first treats the problem of optimal distribution of fibers with circular cross section …
Ab Initio Molecular Dynamics Simulations Of Methylaluminoxane (Mao) Synthesis By Hydrolysis Of Trimethylaluminum, Lacramioara Negureanu
Ab Initio Molecular Dynamics Simulations Of Methylaluminoxane (Mao) Synthesis By Hydrolysis Of Trimethylaluminum, Lacramioara Negureanu
LSU Doctoral Dissertations
MAO is the co-catalyst in the metallocene catalytic systems, which are widely used in single site olefin polymerization due to their high stereoselectivity. To date, the precise structure of MAO, the particular compound or compounds catalytically active in MAO, have eluded researchers. MAO, a white amorphous powder, is not a good sample for a direct spectroscopic characterization, and its NMR spectra are broad and almost featureless. Many structural models have been proposed but none are generally accepted. In the first part of this work the MAO formation mechanism was addressed. Molecular dynamics simulations at MP2 configuration interaction theory level have …
Syntheses And Biological Evaluation Of Water Soluble Carboranylporphyrins For Application In Boron Neutron Capture Therapy, Vijay Gottumukkala
Syntheses And Biological Evaluation Of Water Soluble Carboranylporphyrins For Application In Boron Neutron Capture Therapy, Vijay Gottumukkala
LSU Doctoral Dissertations
The goal of the research presented in this dissertation is to develop novel water soluble carboranylporphyrins that can deliver therapeutic dosage of boron specifically to tumors for application in boron neutron capture therapy. In order to accomplish this goal novel water soluble tetra(nido-carboranyl)porphyrin and the octa(nido-carboranyl)porphyrin with high boron contents are synthesized by the condensation of the carborane substituted benzaldehyde with the pyrrole under acidic conditions. These porphyrins are made water soluble by the deboronation of the closo-carboranes to afford the corresponding amphiphilic nido-carborane cages. The low cytotoxicity, high cellular uptake and intracellular localization of these carboranylporphyrins in tumor cells …
Some Factors Affecting The Interfacial Interaction At Thermomechanical Pulp Fiber And Polypropylene Interphase, Sangyeob Lee
Some Factors Affecting The Interfacial Interaction At Thermomechanical Pulp Fiber And Polypropylene Interphase, Sangyeob Lee
LSU Doctoral Dissertations
This dissertation focused on some selected factors that influence the interfacial interactions at the interphase between wood based materials and thermoplastic surfaces. Several treatments were applied to enhance interfacial properties. In general, interfacial properties were altered by physical and chemical surface modification. Study of the interfacial interactions between wood fiber surfaces as a reinforced material and thermoplastics as a matrix material is important to understand fundamentals of wood fiber-plastic composites (WPC). This study represents fundamental research to define treatment effects on surfaces of wood pulp fibers and polypropylene (PP) film. Two thermosets, ion implantations, and maleic anhydride (MA) grafting were …
Structural Characterization Of Poly(Heterocycles) Formed Using Oxidative Methods, Rebecca Marie Brauch
Structural Characterization Of Poly(Heterocycles) Formed Using Oxidative Methods, Rebecca Marie Brauch
LSU Doctoral Dissertations
This research focused on elucidation of structural information for conducting polymer systems using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS). The structure of conducting polymer systems has been found to directly influence their physical properties. Poly(pyrrole) and poly(thiophene) are two of the most widely studied conducting polymers due to their high electrical conductivity, stability in the doped state, low toxicity, and current/potential applications. The purpose of this research was to apply MALDI-TOF MS to heterocyclic conducting polymers, specifically those of pyrrole and thiophene, to investigate structural properties of these polymers, with the specific aim of determining end group and …