Physical Sciences and Mathematics Commons^™

Shape Imprinting Due To Variable Disulfide Bonds In Polyacrylamide Gels, Andrew B. Greytak, Alexander Y. Grosberg, Toyoichi Tanaka

Faculty Publications

Through the use of variable disulfide crosslinkers, we have created polyacrylamide gels whose shape can be altered after polymerization. N,N'-bisacryloylcystamine is incorporated as a crosslinker, along with a smaller amount of a permanent crosslinker. After polymerization, the disulfide bonds are cleaved into thiols through reduction. By reoxidizing the thiols with the gel held in a new macroscopic shape, a new set of disulfide bonds is formed, and the gel is forced to adopt the new shape. Retension of the new shape improves with greater distortion from the original shape, as well as with increased concentration of variable …

Measurement Of Dijet Production In Neutral Current Deep Inelastic Scattering At High Q2 And Determination Of ΑS, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari

Faculty Publications

Dijet production has been studied in neutral current deep inelastic e+p scattering for 470 < Q2 < 20000 GeV2 with the ZEUS detector at HERA using an integrated luminosity of 38.4 pb-1. Dijet differential cross sections are presented in a kinematic region where both theoretical and experimental uncertainties are small. Next-to-leading-order (NLO) QCD calculations describe the measured differential cross sections well. A QCD analysis of the measured dijet fraction as a function of Q2 allows both a precise determination of αs(Mz) and a test of the energy-scale dependence of the strong coupling constant. A detailed analysis provides an improved estimate of the uncertainties of the NLO QCD cross sections arising from the paxton distribution functions of the proton. The value of αs(Mz), as determined from the QCD fit, is αs (MZ) = 0.1166 ± 0.0019(stat.)+0.0024-0.0044 (exp.) +0.00570.0044(th.). © 2001 Elsevier Science B.V.

Controls On Floc Size In A Continental Shelf Bottom Boundary Layer, Paul S. Hill, George Voulgaris, John H. Trowbridge

Faculty Publications

Simultaneous in situ observations of floc size, waves, and currents in a continental shelf bottom boundary layer do not support generally accepted functional relationships between turbulence and floc size in the sea. In September and October 1996 and January 1997, two tripods were deployed in 70 m of water on the continental shelf south of Woods Hole, Massachusetts. On one a camera photographed particles in suspension 1.2 m above the bottom that had equivalent circular diameters larger than 250 um, and on the other, three horizontally displaced acoustic current meters measured flow velocity 0.35 m above the bottom. The …

Image Reconstruction Using Data-Dependent Triangulation, Thomas W. Sederberg, Xiaohua Yu, Bryan S. Morse

Faculty Publications

Image reconstruction based on data-dependent triangulation with new cost functions and optimization can create higher quality images than traditional bilinear or bicubic spline reconstruction. The article presents a novel method for image reconstruction using a piecewise linear intensity surface whose elements don't generally align with the coordinate axes. This method is based on the technique of data-dependent triangulation (DDT) that N. Dyn et al. (1990) introduced and has proven capable of producing more pleasing reconstructions than axis-aligned methods.

Interpolating Implicit Surfaces From Scattered Surface Data Using Compactly Supported Radial Basis Functions, Bryan S. Morse, David T. Chen, Penny Rheingans, Kalpathi Subramanian, Terry S. Yoo

Faculty Publications

We describe algebraic methods for creating implicit surfaces using linear combinations of radial basis interpolants to form complex models from scattered surface points. Shapes with arbitrary topology are easily represented without the usual interpolation or aliasing errors arising from discrete sampling. These methods were first applied to implicit surfaces by Savchenko, et al. and later developed independently by Turk and O'Brien as a means of performing shape interpolation. Earlier approaches were limited as a modeling mechanism because of the order of the computational complexity involved. We explore and extend these implicit interpolating methods to make them suitable for systems of …

Effective Bandwidth For Traffic Engineering, Mark J. Clement, Rob Kunz, Seth Nielson, Quinn O. Snell

Faculty Publications

In today’s Internet, demand is increasing for guarantees of speed and efficiency. Current routers are very limited in the type and quantity of observed data they can provide, making it difficult for providers to maximize utilization without the risk of degraded throughput. This research uses statistical data currents provided by router vendors to estimate the impact of changes in network configuration on the probability of link overflow. This allows service providers to calculate in advance, the effect of grooming on a network, eliminating the conservative trial-and-error approach normally used. These predictions are made using Large Deviation Theory, which focuses on …

Formation Of Rydberg Atoms In An Expanding Ultracold Neutral Plasma, Scott D. Bergeson, T. C. Killian, M. J. Lim, S. Kulin, R. Dumke, S. L. Rolston

Faculty Publications

We study the formation of Rydberg atoms in expanding plasmas at temperatures of 1–1000 K and densities from 10^5–10^10 cm^-3. Up to 20% of the initially free charges recombine in about 100 us, and the binding energy of the Rydberg atoms approximately equals the increase in the kinetic energy of the remaining free electrons. Three-body recombination is expected to dominate in this regime, yet most of our results are inconsistent with this mechanism.

What Determines The Emission Peak Energy Of The Blue Luminescence In Highly Mg-Doped P-Gan?, John S. Colton, P. Y. Yu

Faculty Publications

We report a study of the 2.8 eV blue luminescence (BL) in heaviliy Mg-doped p-GaN via resonant excitation with a tunable blue dye laser. The dependence of the BL on the excitation photon energy (Eex) is unlike that of the yellow luminescence found in n-type GaN. An Urbach-type band tail, with Urbach parameter of 33 meV is observed in the vicinity of the BL energy. We propose that the peak energy of the BL marks the transition from localized states to delocalized states within this band tail.

Blowup In A Mass-Conserving Convection-Diffusion Equation With Superquadratic Nonlinearity, Todd L. Fisher, Christopher P. Grant

Faculty Publications

A nonlinear convection-diffusion equation with boundary conditions that conserve the spatial integral of the solution is considered. Previous results on nite-time blowup of solutions and on decay of solutions to the corresponding Cauchy problem were based on the assumption that the nonlinearity obeyed a power law. In this paper, it is shown that assumptions on the growth rate of the nonlinearity, which take the form of weak superquadraticity and strong superlinearity criteria, are suffcient to imply that a large class of nonnegative solutions blow up in nite time.

Of Manatees, Mangroves, And The Mississippi River: Is There An Estuarine Signature For The Gulf Of Mexico?, R. Eugene Turner

Faculty Publications

Important parameters of estuarine variability include morphology, flushing times, nutrient loading rates, and wetland: water ratios. This variability both reflects and disguises underlying relationships between the physics and biology of estuaries, which this comparative analysis seeks to reveal, using the Gulf of Mexico (GOM) estuaries as a starting point. A question used to focus this analysis is: are the GOM estuaries unique? The GOM receives the Mississippi River, a uniquely large, world-class river, which dominates the freshwater and nutrient inflows to the GOM continental shelf, whose margins include 35 major estuarine systems. These GOM estuaries have 28% and 41% of …

Sr3Znpto6 And Sr3Cdpto6, Mark D. Smith, Hans Conrad Zur Loye

Faculty Publications

The flux synthesis of single crystals of the isostructural compounds tristrontium zinc platinum hexaoxide, Sr₃ZnPtO₆, and tristrontium cadmium platinum hexaoxide, Sr₃CdPtO₆, is reported. The compounds adopt the pseudo-one-dimensional rhombohedral K₄CdCl₆ structure type, and feature chains of face-shared distorted ZnO₆ or CdO₆ trigonal prisms and PtO₆ octahedra, surrounded by columns of Sr²⁺ ions. All transition metals are located on the threefold axis of symmetry, while the Sr²⁺ cations lie on twofold axes.

Formula: Sr₃ZnPtO₆ and Sr₃CdPtO₆

First-Principles Elastic Constants And Electronic Structure Of Α-Pt2si And Ptsi, Gus L. W. Hart, O. Beckstein, J. E. Klepeis, O. Pankratov

Faculty Publications

We have carried out a first-principles study of the elastic properties and electronic structure for two room-temperature stable Pt silicide phases, tetragonal α-Pt2Si, and orthorhomic PtSi. We have calculated all of the equilibrium structural parameters for both phases; the a and c lattice constants for α-Pt2Si and the a, b, and c lattice constants and four internal structural parameters for PtSi. These results agree closely with experimental data. We have also calculated the zero-pressure elastic constants, confirming prior results for pure Pt and Si and predicting values for the six (nine) independent, nonzero elastic constants of α-Pt2Si (PtSi). These calculations …

Bistable Operation Of A Two-Section 1.3-Mm Inas Quantum Dot Laser—Absorption Saturation And The Quantum Confined Stark Effect, Xiaodong Huang, A. Stintz, Hua Li, Audra Rice, G. T. Liu, L.F. Lester, Julian Cheng, K.J. Malloy

Faculty Publications

Room temperature, continuous-wave bistability was observed in oxide-confined, two-section, 1.3- m quantum-dot (QD) lasers with an integrated intracavity quantum-dot saturable absorber. The origin of the hysteresis and bistability were shown to be due to the nonlinear saturation of the QD absorption and the electroabsorption induced by the quantum confined Stark effect.

Measurement Of Dijet Cross Sections For Events With A Leading Neutron In Photoproduction At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari

Faculty Publications

Differential cross sections for dijet photoproduction in association with a leading neutron using the reaction e+ + p → e+ + n + jet + jet + Xr have been measured with the ZEUS detector at HERA using an integrated luminosity of 6.4 pb-1. The fraction of dijet events with a leading neutron in the final state was studied as a function of the jet kinematic variables. The cross sections were measured for jet transverse energies EjetT > 6 GeV, neutron energy En > 400 GeV, and neutron production angle θn < 0.8 mrad. The data are broadly consistent with factorization of the lepton and hadron vertices and with a simple one-pion-exchange model. © 2001 Elsevier Science B.V. All rights reserved.

Neutrino Reactions On The Deuteron, S. Nakamura, T. Sato, Vladimir Gudkov, K. Kubodera

Faculty Publications

The cross sections for the ν-d and ν̅ -d reactions are calculated for incident energy up to E_ν=170 MeV with the use of a phenomenological Lagrangian approach. We assess and improve the reliability of the employed calculational method by examining the dependence of the results on various input and approximations that go into the calculation. The main points of improvement over the existing work are (1) use of the “modern” NN potentials, (2) use of the more accurate nucleon weak-interaction form factors, and (3) monitoring the strength of a vertex that governs the exchange-current contribution, with the use …

Diamagnetic Persistent Current In Diffusive Normal-Metal Rings, E. M.Q. Jariwala, P. Mohanty, M. B. Ketchen, Richard A. Webb

Faculty Publications

We have measured a diamagnetic persistent current with flux periodicities of both h/e and h/2e in an array of thirty diffusive mesoscopic gold rings. At the lowest temperatures, the magnitudes of the currents per ring corresponding to the h/e- and h/2e-periodic responses are both comparable to the Thouless energy E_c≡ħ/τ_D, where τ_D is the diffusion time. Taken in conjunction with earlier experiments, our results strongly challenge the conventional theories of persistent current. We consider a new approach associated with the saturation of …

Process For Immobilizing Waste Using Bagasse (Us Patent 6174275), Michael A. Janusa

Faculty Publications

No abstract provided.

Semiclassical Application Of The Mo”Ller Operators In Reactive Scattering, Sophya Garashchuk, John C. Light

Faculty Publications

Mo\ller operators in the formulation of reaction probabilities in terms of wave packet correlation functions allow us to define the wave packets in the interaction region rather than in the asymptotic region of the potential surface. We combine Mo\ller operators with the semiclassical propagator of Herman and Kluk. This does not involve further approximations and can be used with any initial value representation (IVR) semiclassical propagator. Time propagation in asymptotic regions of the potential due to Mo\ller operators reduces the oscillations of the propagator integrand and improves convergence of the results with respect to the number of trajectories. The effectiveness …

An Ellam Scheme For Multidimensional Advection-Reaction Equations And Its Optimal-Order Error Estimate, Hong Wang, Xiquan Shi, Richard E. Ewing

Faculty Publications

We present an Eulerian-Lagrangian localized adjoint method (ELLAM) scheme for initial-boundary value problems for advection-reaction partial differential equations in multiple space dimensions. The derived numerical scheme is not subject to the Courant-Friedrichs-Lewy condition and generates accurate numerical solutions even if large time steps are used. Moreover, the scheme naturally incorporates boundary conditions into its formulation without any artificial outflow boundary conditions needed, and it conserves mass. An optimal-order error estimate is proved for the scheme. Numerical experiments are performed to verify the theoretical estimate.

Molecular Simulations Of Sound Wave Propagation In Simple Gases, Alejandro Garcia, N. Hadjiconstantinou

Faculty Publications

Molecular simulations of sound waves propagating in a dilute hard sphere gas have been performed using the direct simulation Monte Carlo method. A wide range of frequencies is investigated, including very high frequencies for which the period is much shorter than the mean collision time. The simulation results are compared to experimental data and approximate solutions of the Boltzmann equation. It is shown that free molecular flow is important at distances smaller than one mean free path from the excitation point.

An Alternative Use For Bagasse: Stabilizing Agent For Lead Waste, Michael A. Janusa

Faculty Publications

Bagasse amounts to one- third of the cane ground and supplies fuel for the generation of steam in raw factories; however, most factories have an excess of bagasse during regular grinding season. Another method for the utilization of bagasse was investigated using bagasse as a stabilizing agent for heavy metal waste solidified /stabilized in cement. Lead nitrate was used as the model heavy me ta l waste with a 10 or 15 per cent lead by weight to cement loading. Samples were cured for 7, 14, and 28 days at 24°C. Samples containing bagasse typically resulted in TCLP extract lead …

A Preliminary Assessment Of Tidal Flooding Along The New Hampshire Coast: Past, Present And Future, Larry G. Ward, Jamie R. Adams

Faculty Publications

This report presents the results of a preliminary study that examines several critical coastal issues for New Hampshire including sea level fluctuations (past, present and future), shoreline migrations, and tidal flooding. Included are: 1) an analysis of sea level changes over the Holocene and resulting shoreline migrations, 2) an assessment of low-lying areas with elevations below selected tidal flooding datums in coastal areas, and 3) an assessment of increases in low-lying areas that are potentially at risk to tidal flooding over the next century due to sea level rise.

Semiclassical Application Of The Mo/Ller Operators In Reactive Scattering, Sophya V. Garashchuk, J. C. Light

Faculty Publications

Mo/ller operators in the formulation of reaction probabilities in terms of wave packet correlation functions allow us to define the wave packets in the interaction region rather than in the asymptotic region of the potential surface. We combine Mo/ller operators with the semiclassical propagator of Herman and Kluk. This does not involve further approximations and can be used with any initial value representation (IVR) semiclassical propagator. Time propagation in asymptotic regions of the potential due to Mo/ller operators reduces the oscillations of the propagator integrand and improves convergence of the results with respect to the number of trajectories. The effectiveness …

Self-Assembly Of A Bis-Urea Macrocycle Into A Columnar Nanotube, Linda S. Shimizu, Mark D. Smith, A. D. Hughes, Ken D. Shimizu

Faculty Publications

A bis-urea macrocycle 1 was synthesized and shown to form extended nanotubular columns byX-ray crystallography.

Structure Determination Of Ba8Corh6O21, A New Member Of The 2h-Perovskite Related Oxides, Hans Conrad Zur Loye, M. D. Smith, K. E. Stitzer, A. El Abed, J. Darriet

Faculty Publications

Single crystals of Ba₈CoRh₆O₂₁ were grown out of a potassium carbonate flux. The structure was solved by a general method using the superspace group approach. The superspace group employed was R3m(00γ)0s with a = 10.0431(1) Å, c₁ = 2.5946(1) Å and c₂ = 4.5405(1) Å, V = 226.60(1) ų. Ba₈CoRh₆O₂₁ represents the first example of an m = 5, n = 3 member of the A_3n+3mA'_nB_3m+nO_9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting of six …

Measurement Of Open Beauty Production In Photoproduction At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari

Faculty Publications

The production and semi-leptonic decay of heavy quarks have been studied in the photoproduction process e+p → e+ + dijet + e- + X with the ZEUS detector at HERA using an integrated luminosity of 38.5 pb-1. Events with photon-proton centre-of-mass energies, Wγp, between 134 and 269 GeV and a photon virtuality, Q2, less than 1 GeV2 were selected requiring at least two jets of transverse energy Ejet1(2)T > 7(6) GeV and an electron in the final state. The electrons were identified by employing the ionisation energy loss measurement. The contribution of beauty quarks was determined using the transverse momentum of …

Measurement Of The Neutral Current Cross Section And F2 Structure Function For Deep Inelastic E+P Scattering At Hera, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari, A. Pesci

Faculty Publications

The cross section and the proton structure function F2 for neutral current deep inelastic e+p scattering have been measured with the ZEUS detector at HERA using an integrated luminosity of 30 pb-1. The data were collected in 1996 and 1997 at a centre-of-mass energy of 300 GeV. They cover the kinematic range 2.7 < Q2 < 30000 GeV2 and 6-10-5 < cursive Greek chi < 0.65. The variation of F2 with cursive Greek chi and Q2 is well described by next-to-leading-order perturbative QCD as implemented in the DGLAP evolution equations.

Search For Resonance Decays To A V̄ Plus Jet In E+P Scattering At Desy Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Lacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari

Faculty Publications

A study of the v̄-jet mass spectrum in e+p→v̄X events at a center-of-mass energy 300 GeV has been performed with the ZEUS detector at the HERA collider at DESY using an integrated luminosity of 47.7 pb-1. The mass spectrum is in good agreement with that expected from standard model processes over the v̄-jet mass range studied. No significant excess attributable to the decay of a narrow resonance is observed. By using both e+p→>e+X and e+p-vX data, mass-dependent limits are set on the s-channel production of scalar and vector resonant states. Couplings to first-generation quarks are considered and limits are …

Design Of Peptides With, Α,Β-Dehydro-Residues: A Dipeptide With A Branched Β-Carbon Dehydro-Residue At The (I+1) Position, Methyl N-(Benzyloxycarbonyl)-Α,Β-Didehydrovalyl-L-Tryptophanate, Vijayaraghavan Rangachari, Pravindra Kumar, Sharmistha Dey, Tej P. Singh

Faculty Publications

The structure of the title peptide, C₂₅H₂₇N₃O₅, has been determined and its conformation analysed. Values of the standard peptide torsion angles are φ(1) = -44.2 (3)°, ψ(1) = 135.9 (2)°, φ(2) = -141.6 (2)° and ψ(T/2) = 168.0 (2)°. The crystal structure is stabilized by an intermolecular hydrogen bond, with an N···O distance of 2.919 (3)Å, which is formed between screw-axis-related NH and CO groups of dehydrovaline residues.

Dynamics Of Stars And Globular Clusters In M87, Aaron J. Romanowsky, C. S. Kochanek

Faculty Publications

We examine the dynamics of the stars and globular clusters in the nearby giant elliptical galaxy M87 and constrain the mass distribution, using all the available data over a large range of radii, including higher order moments of the stellar line-of-sight velocity distributions and the discrete velocities of over 200 globular clusters. We introduce an extension of spherical orbit modeling methods that makes full use of all the information in the data and provides very robust constraints on the mass models. We conclusively rule out a constant mass-to-light ratio model and infer that the radial density profile of the galaxy's …