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Articles 181 - 210 of 3930
Full-Text Articles in Physical Sciences and Mathematics
Developing A Remote Gamma-Ray Spectra Collection System (Rgscs) By Coupling A High Purity Germanium (Hpge) Detector With A Cosmicguard Background Reduction Device, Zaijing Sun, Krishnakumar Divakar Nangeelil, Haven Searcy
Developing A Remote Gamma-Ray Spectra Collection System (Rgscs) By Coupling A High Purity Germanium (Hpge) Detector With A Cosmicguard Background Reduction Device, Zaijing Sun, Krishnakumar Divakar Nangeelil, Haven Searcy
Health Physics and Diagnostic Sciences Faculty Research
Despite being widely used for high-resolution spectral analysis and quantifying low activity in natural samples, the operations and data analysis of High Purity Germanium (HPGe) gamma-ray detectors are seldom fully automated due to the excessive costs associated with commercially available automatic sample changing systems. This paper introduces the design and implementation of a cost-effective, customized remote gamma-ray spectra collection system centered around the HPGe detector coupled to a cosmic-ray veto background reduction device. The HPGe detector system, equipped with a Lynx DSA, is seamlessly integrated with an economically viable automatic sample changer. This sample vial changer is controlled by a …
Fluid Flow, Mineralization And Deformation In An Oceanic Detachment Fault: Microtextural, Geochemical And Isotopic Evidence From Pyrite At 13°30′N On The Mid-Atlantic Ridge, Andrew J. Martin, John W. Jamieson, Sven Petersen, Mostafa Fayek, Javier Escartin
Fluid Flow, Mineralization And Deformation In An Oceanic Detachment Fault: Microtextural, Geochemical And Isotopic Evidence From Pyrite At 13°30′N On The Mid-Atlantic Ridge, Andrew J. Martin, John W. Jamieson, Sven Petersen, Mostafa Fayek, Javier Escartin
Geoscience Faculty Research
Hydrothermal fluids in ultramafic-hosted hydrothermal systems associated with oceanic detachment faults can be more oxidizing compared to mafic-hosted vent sites. These fluids form a mineral assemblage of pyrite, magnetite and hematite. At 13°30′N on the Mid-Atlantic Ridge, chlorite-quartz breccias recovered from an exposed fault scarp contain pyrite, with abundant magnetite and hematite, indicating that the redox of the fluids was variable. In primary micron-scale zonations in pyrite, Ni, Co, and Se have a decoupled relationship, recording fluctuations in the chemical composition and temperature of hydrothermal fluid as the grains grew. Secondary zonations that erase and overprint primary zonations are limited …
The Behemoth Of The Last Ice Age: The Evolutionary Saga Of The Columbian Mammoth In North America, Nathaniel Valentine
The Behemoth Of The Last Ice Age: The Evolutionary Saga Of The Columbian Mammoth In North America, Nathaniel Valentine
Calvert Undergraduate Research Awards
The Columbian’s mammoth evolutionary history can be traced back to the origin of life and its evolutionary lineage can be tracked down by examining select species over geologic time. I conducted a literature review with multiple scientific journals to identify key transitional species that trace their lineage to the Columbian mammoth. Transitional species were selected from the Precambrian and the various periods of the Phanerozoic which exhibited vertebrate-like body structures and behaviors. Evidence suggests that early vertebrate-like animals were present by the Cambrian period. Mammal evolution would continue in the Mesozoic era and radiate in the Cenozoic era. The Columbian …
Unlv Title Iii Aanapisi & Mcnair Scholars Institute Research Journal 2024, Jesica Godinez-Paredes, Kian Hassankhan, Apia Hickman, Robin Ruth Kee, Kevin Ayala Pineda, Briana Melendez, Kalli Ramos, Saturn L. Reyes, Fabian Leija, Selena Pepe, Silva Topchyan, Celeste Ainsley, Mayra Arzate, Jessica Balistreri, Zantana Ephrem, Mirella Jasso, Karl Panou, Nichole Pelaez, Miklo Alcala, Akshay Dave, Mey Mey Heng, Michael Finkle, Janessa Montenegro, Reynafe Naol Aniga, Victor Mejia, Angelica G. Diaz, Anayeli Flores-Garibay, Kari Lee Joe Goold, Samantha Hernandez, Lianelys Cabrera Martinez, Caitlin Reynolds, Kimberly N. Usbeck, Abdulrahman Alahdal, Angelica Diaz, Willaine Mae Kahano, Raquel Jackson, Cecia Ruiz-Hernandez, Kers Ung-Watson, Yessenia Henriquez, Vanessa Marie Booth, Alexia Brown, Darlyn Magana, Bianca Navarro, Nicholas Pereira, Gia Renemae Calip, Lucky Heng, Ralph Sagun, Lucas Abreu, Alexandra Maria Acosta, Tristan Benally, Cosset Hernandez Pena, Adrian Montenegro, Cierra Paaaina-Daquioag, Nicole Torosian, Tracy Fuentes, Julissa Martinez, Medina Mcallister, Michal Newhouse-Van Vlerin, Tiria Carr, Nima Abkenar, Isabella Aceituno, Yuhan Bi, Victoria Campos, Melika Cummings, Zachary J. Johnigan, Alexis Sotolongo-Marin
Unlv Title Iii Aanapisi & Mcnair Scholars Institute Research Journal 2024, Jesica Godinez-Paredes, Kian Hassankhan, Apia Hickman, Robin Ruth Kee, Kevin Ayala Pineda, Briana Melendez, Kalli Ramos, Saturn L. Reyes, Fabian Leija, Selena Pepe, Silva Topchyan, Celeste Ainsley, Mayra Arzate, Jessica Balistreri, Zantana Ephrem, Mirella Jasso, Karl Panou, Nichole Pelaez, Miklo Alcala, Akshay Dave, Mey Mey Heng, Michael Finkle, Janessa Montenegro, Reynafe Naol Aniga, Victor Mejia, Angelica G. Diaz, Anayeli Flores-Garibay, Kari Lee Joe Goold, Samantha Hernandez, Lianelys Cabrera Martinez, Caitlin Reynolds, Kimberly N. Usbeck, Abdulrahman Alahdal, Angelica Diaz, Willaine Mae Kahano, Raquel Jackson, Cecia Ruiz-Hernandez, Kers Ung-Watson, Yessenia Henriquez, Vanessa Marie Booth, Alexia Brown, Darlyn Magana, Bianca Navarro, Nicholas Pereira, Gia Renemae Calip, Lucky Heng, Ralph Sagun, Lucas Abreu, Alexandra Maria Acosta, Tristan Benally, Cosset Hernandez Pena, Adrian Montenegro, Cierra Paaaina-Daquioag, Nicole Torosian, Tracy Fuentes, Julissa Martinez, Medina Mcallister, Michal Newhouse-Van Vlerin, Tiria Carr, Nima Abkenar, Isabella Aceituno, Yuhan Bi, Victoria Campos, Melika Cummings, Zachary J. Johnigan, Alexis Sotolongo-Marin
McNair Journal
Journal articles based on research conducted by undergraduate students in the AANAPISI, LSAMP, and McNair Scholars Program.
Table of Contents
About AANAPISI
Dr. Chris Heavey, Interim President
Dr. Keith Rogers, Vice President for Student Affairs
Ms. Zhanna Aronov, Associate Vice President for Retention & Outreach
Zagamiite, Caal2si3.5o11, The Hexagonal High-Pressure Cas Phase With Dominant Si, As A Mineral From Mars, Chi Ma, Oliver Tschauner, John R. Beckett, Eran Greenberg, Vitali B. Prakapenka
Zagamiite, Caal2si3.5o11, The Hexagonal High-Pressure Cas Phase With Dominant Si, As A Mineral From Mars, Chi Ma, Oliver Tschauner, John R. Beckett, Eran Greenberg, Vitali B. Prakapenka
Geoscience Faculty Research
Within the Ca-Al-silicate system, dense, layered hexagonal phases occur at high temperatures and pressures between 20 and 23 GPa. They have been observed both in nature and in experiments. In this study, we describe the endmember with a dominant sixfold coordinated Si as a mineral zagamiite (IMA 2015-022a). This new mineral identified in Martian meteorites has a general formula of (Ca,Na)(Al,Fe,Mg)2(Si,Al,□)4O11, thus defining CaAl2Si3.5O11 as a previously unknown endmember of the hexagonal CAS phases. Zagamiite assumes space group P63/mmc with a unit cell of a = 5.403(2) Å, c = 12.77(3) Å, V = 322.9(11) Å3, and Z = 2. …
Synthesis Of Novel Disulfide Triazole Organophosphate Containing Fire Retardants, Parsa Asaei, Jun Yong Kang
Synthesis Of Novel Disulfide Triazole Organophosphate Containing Fire Retardants, Parsa Asaei, Jun Yong Kang
Undergraduate Research Symposium Posters
Fire Retardants (FR) play a pivotal role in reducing smoke plume generation in wildland fires, which coincides with one of NSF EPSCoR’s HDRFS project objectives: investigating smoke plume dynamics. With the San Antonio Statement from 2010 banning halogenated FRs, there has been a push in research towards safer and better alternatives. The synthesis of a novel disulfide triazole organophosphate fire retardant (DSTP) would aid in NSF EPSCoR’s HDRFS research as a greener and better alternative. Therefore, our research aimed to i) develop a novel FR that harnesses the synergistic effects of phosphate-, disulfide-, and triazole-functionality that can be applied to …
Finding Diffs Of Pull Request Commits, Chalinee Karawek, John Businge
Finding Diffs Of Pull Request Commits, Chalinee Karawek, John Businge
Undergraduate Research Symposium Posters
Github is a social network that allows developers' projects to be forked for various uses, such as developing the existing repository or use the code to steer development into a new direction. As more forks are made, the more bugs that can occur due to new pull requests not synchronizing with the upstream repository. PaReco is a clone detection tool by Ramkisoen et al. (Ramkisoen et al. 2022) that identifies the changes inside the files inside a pull request by performing diff on every file. However, in this study, we take a different approach to identifying the changes inside the …
Different Canopy Covers Effect Microclimate: How The Urban Heat Island Effect Can Be Reduced In Las Vegas, Melanie Sanchez, Alison Sloat
Different Canopy Covers Effect Microclimate: How The Urban Heat Island Effect Can Be Reduced In Las Vegas, Melanie Sanchez, Alison Sloat
Undergraduate Research Symposium Posters
The purpose of my research was to investigate the effects that different canopy covers have on desert cities microclimates and how the City of Las Vegas can implement the best techniques to reduce temperatures in the hottest parts of town. I collected data on the different temperatures in two separate parts of the city (East Las Vegas, Midtown UNLV area) in one-hour intervals during two and three in the afternoon and surveyed four different areas on its tree canopy coverage. I also analyzed scientific peer reviewed studies which helped me see what other arid cities, like Phoenix, AZ, have done …
Third-Order Harmonic Generation In Few-Layer Graphene, Nicholas T. Pereira, Timothy Chung, Joshua O. Island
Third-Order Harmonic Generation In Few-Layer Graphene, Nicholas T. Pereira, Timothy Chung, Joshua O. Island
Undergraduate Research Symposium Posters
Optical harmonic generation is a phenomena that occurs in nonlinear materials and can be used to study the properties of those materials. For example, the nonlinear response of layered, two-dimensional (2D) materials can be used to characterize flake thickness, lattice and stacking symmetries, and crystal strain. Here, we study third harmonic generation (THG) in graphene and few-layer graphite as a precursor to investigating nonlinear optical properties of other 2D materials. We present a custom scanning setup for optical harmonic generation and present our results on few-layer flakes. These results provide a solid basis for future measurements of other new 2D …
Analysis Of Triton Cg 110 Foaming Characteristics For Use As A Potential Fire Suppressant, Addison Cobb, Jeremy Cho
Analysis Of Triton Cg 110 Foaming Characteristics For Use As A Potential Fire Suppressant, Addison Cobb, Jeremy Cho
Undergraduate Research Symposium Lightning Talks
Background: Per-FluoroAlkyls (PFAs) are incredibly stable molecules which do not biodegrade. These chemicals have been linked with a series of health issues and environmental problems.
Problem: PFAs have been identified in most drinking water supplies in the United States. Large Amounts of this is due to Aqueous Fire-Fighting Foams (AFFF’s), which contain PFAs, seeping into the groundwater supply.
Solution: While little can be done about PFAs currently in groundwater supplies, replacing PFA-based AFFFs with newer Eco-AFFFs can halt AFFF contamination, and maintain firefighting suppression.
Investigating Van Der Waals Josephson Junctions With 2h-Nbse2 And 1t’-Wte2, Kristine Lorraine Haley
Investigating Van Der Waals Josephson Junctions With 2h-Nbse2 And 1t’-Wte2, Kristine Lorraine Haley
UNLV Theses, Dissertations, Professional Papers, and Capstones
Josephson junctions have garnered significant attention due to their unique electronic properties and applications in quantum devices. In this thesis, we investigate the fabrication processes and characterization of two-dimensional (2D) Josephson junctions consisting of layered van der Waals materials: niobium diselenide (2H-NbSe2) and few layered tungsten ditelluride (1T’-WTe2). The reduction of dimensionality can bring forth unique characteristics in certain materials that are not seen in their bulk counterparts, making them prime candidates for physical exploration. 2H-NbSe2 is an s-wave superconductor at temperatures near and below 7 K. 1T’-WTe2 is a semimetal in bulk but …
On The Synthesis Of Heavy Rare Earth Solid Solutions And Their Hydrides, Joshua R. Van Cleave
On The Synthesis Of Heavy Rare Earth Solid Solutions And Their Hydrides, Joshua R. Van Cleave
UNLV Theses, Dissertations, Professional Papers, and Capstones
The theoretical predictions and results from the (La,Y)Hx ternary hydride solution provided evidence toward phase stability at comparatively lower pressures, as consequence the (Yb,Lu)Hx and (Tm,Lu)Hx ternary hydrides are studied here with pressures up to 25 GPa in the diamond anvil cell. The onset of an unknown feature in the XRD pattern coincides with crystallographic plane distortions in the tetragonal lattice of ytterbium hydride at their laser-heated interface, possibly driven by a solid solution of Lu-Yb. Findings in collected Raman spectra and X-ray diffraction patterns in an Ar environment suggest potential stability of the FCC and high-temperature HCP …
Sensitive Capacitance Measurements Of The Quantum Hall Effect In Graphene, Vergil Schreiber, Justin Alvarez, Joshua Island
Sensitive Capacitance Measurements Of The Quantum Hall Effect In Graphene, Vergil Schreiber, Justin Alvarez, Joshua Island
Undergraduate Research Symposium Podium Presentations
Research on how electrons respond to confinement holds potential for breakthroughs in quantum computing and more energy efficient electronics. In intense magnetic fields and near-zero temperatures, electrons in confined to 2D display unique quantum behaviors. These conditions quantize electron motion into circular orbits, resulting in discrete Landau energy levels.
Beyond Corporate Greenwashing: Discourse Of A 'Just' Electric Energy Transition Materialized At The Thacker Pass Lithium Mine, Laekyn Kelley
Beyond Corporate Greenwashing: Discourse Of A 'Just' Electric Energy Transition Materialized At The Thacker Pass Lithium Mine, Laekyn Kelley
UNLV Theses, Dissertations, Professional Papers, and Capstones
Thacker Pass in Northern Nevada is a rich desert ecosystem with spiritual significance to local Indigenous peoples, and it is also the site for what will be, for now, the United States’ largest open-pit lithium mine. Lithium is one mineral constituent of electric batteries which are essential to current U.S. electric energy transition policy, a transition which policymakers and other public groups have called on to be done in a way which is just. However, what exactly a just electric energy transition looks like in places like Thacker Pass is under continued negotiation in theoretical and practical senses. Existing research …
Development, Voice, And Vulnerability: A Rhetorical Analysis Of The Policy-Making Discourse Regarding The Paris Agreement As An Organizational Response To Climate Change, David Almanza-Canas
Development, Voice, And Vulnerability: A Rhetorical Analysis Of The Policy-Making Discourse Regarding The Paris Agreement As An Organizational Response To Climate Change, David Almanza-Canas
UNLV Theses, Dissertations, Professional Papers, and Capstones
On December 12, 2015, the Paris Agreement was officially ratified by 196 sovereign entities. This treaty represents a global call to action to ameliorate the impact of human activities on our environment, and it creates a means of cooperation through financial support and transparent industrial practices with the goal of promoting accountability across the world. This treaty and the discourse surrounding it present fertile ground for the academic understanding of persuasive practices in policy-making. By examining the rhetorical implications of the Paris Agreement as a global policy, scholars can gain new insight about the communities represented in the conversation as …
Investigation Of The Chemical And Electronic Structure Of A 2h Phase Mos2 Single Crystal, Mary Blankenship
Investigation Of The Chemical And Electronic Structure Of A 2h Phase Mos2 Single Crystal, Mary Blankenship
UNLV Theses, Dissertations, Professional Papers, and Capstones
Molybdenum disulfide has a wide range of applications in energy conversion devices, like thin-film solar cells, batteries, bio sensors, and more. Although the properties of MoS2 and other transition metal dichalcogenides (TMDC) have been widely studied, disagreements and discrepancies regarding its electronic structure remain.
In this thesis, a highly-oriented synthetic 2H phase MoS2 single crystal is investigated using a toolchest of spectroscopic techniques to uncover its chemical and electronic properties. Lab-based x-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), inverse photoemission spectroscopy (IPES), and low energy electron diffraction (LEED) were performed at UNLV and combined with resonant inelastic soft …
Travel Time Theory For Traffic Conservation Laws With Applications, Sergio Contreras
Travel Time Theory For Traffic Conservation Laws With Applications, Sergio Contreras
UNLV Theses, Dissertations, Professional Papers, and Capstones
Travel time is an important concept in various intelligent transportation system (ITS) applications. The concept is used in a wide array of applications, such as system planning, system performance, and optimization. Reducing the time required to travel between different points on a network is an important goal. Benefits include reducing time wasted in traveling, and keeping travelers satisfied. Thus, studying and reducing travel time in ITS is beneficial in different applications.
The classic density-based Lighthill Whitman Richards (LWR) equation for modeling traffic flow is the starting point in this dissertation. A more recent travel time dynamics function built on top …
Examining Covid-19 Vaccine Hesitancy Among The Nevada African American Population Using The Social-Ecological Model, Katelyn Faulk
Examining Covid-19 Vaccine Hesitancy Among The Nevada African American Population Using The Social-Ecological Model, Katelyn Faulk
UNLV Theses, Dissertations, Professional Papers, and Capstones
In Nevada, COVID-19 vaccines have been widely available to the general population since March 2021; however, even with the wide availability of these vaccines only 40% of the African American population in Nevada has been fully vaccinated against COVID-19 as of May 2023. This is problematic as it has been shown that the African American population is disproportionately affected by COVID-19 with higher rates of cases, hospitalizations, and deaths when compared to other races or ethnicities. Through the literature, it has also been well documented that African Americans may experience hesitancy toward these vaccinations for a multitude of reasons including …
Scalable Algorithm Design And Performance Analysis For Graph Motifs Discovery, Md Abdul Motaleb Faysal
Scalable Algorithm Design And Performance Analysis For Graph Motifs Discovery, Md Abdul Motaleb Faysal
UNLV Theses, Dissertations, Professional Papers, and Capstones
Discovering motifs or structural patterns, such as communities, is a significant graph application utilized for classifying groups in social and business networks, identifying similar proteins, detecting anomalous behavior in the cybersecurity domain, and finding critical entities in rumor propagation or infectious disease spreading. Existing state-of-the-art techniques for community discovery face challenges related to scalability, performance limitations, and methodological inaccuracies. The objective of this doctoral dissertation is to introduce novel parallel algorithms and propose high-performance computing architecture designs to address the performance constraints of current community detection approaches when processing large-scale social and biological data. This research focuses on two main …
An Evaluation Of Lead Concentration In Commercially Available Tiles, Daidre N. Gamboa
An Evaluation Of Lead Concentration In Commercially Available Tiles, Daidre N. Gamboa
UNLV Theses, Dissertations, Professional Papers, and Capstones
Workers in the manufacturing and construction industries are at risk of lead exposure in projects that involve removal or installation of tiles, and other individuals exposed to lead, including children may also be at risk. The concern with lead in tiles is thought to be related to the glazing process or the country where the tile was produced. Multiple regulations are in place in the U.S. to protect people from lead exposure, including through surface coatings or painted surfaces. But these regulations do not cover glazed tiles. This study examined whether there are differences in lead concentration in (1) tiles …
Investigating A Passive Treatment System For The Removal Of Nutrients From Urban Runoff, Jasminn Gray
Investigating A Passive Treatment System For The Removal Of Nutrients From Urban Runoff, Jasminn Gray
UNLV Theses, Dissertations, Professional Papers, and Capstones
The Environmental Protection Agency recognizes urban runoff as a major contributor of surface water pollution with nutrients as the second largest cause of surface water impairment in the United States. While a water quality standard of 100 lbs/day total phosphorus load allocation for all nonpoint sources is permitted for the Las Vegas Valley (LVV) under the National Pollutant Discharge Elimination System, currently there is not a counterpart standard for nitrogen. With the continued development of the LVV and the depletion of the quantity of water in Lake Mead due to the ongoing drought, the concentrations of phosphorus and nitrogen species …
The Room Temperature Electrolysis Of F-Elements In Aqueous And Ionic Liquid Media: Synthesis, Dissolution, And Reduction, Phillip George Hammer
The Room Temperature Electrolysis Of F-Elements In Aqueous And Ionic Liquid Media: Synthesis, Dissolution, And Reduction, Phillip George Hammer
UNLV Theses, Dissertations, Professional Papers, and Capstones
Procuring F-element metals is no simple task and often requires the use of caustic and hazardous materials at high temperatures. These materials are invaluable for a variety of scientific missions ranging from the elucidation of fundamental properties, as fast spectrum nuclear fuel forms, to pit production modernizing our nuclear stockpiles. Metallic actinide materials are essential to strategic and critical materials recovery, the nuclear energy sector, and weapons production. Room temperature electrolysis is envisioned as a process to recover laboratory scale (milligram to gram) quantities of actinide metals. This process closes the uranium chemical loop allowing the reclamation of materials for …
The Impact Of The Covid-19 Pandemic Response On Food Safety Violations Observed In Southern Nevada Food Establishments, Samantha Morales
The Impact Of The Covid-19 Pandemic Response On Food Safety Violations Observed In Southern Nevada Food Establishments, Samantha Morales
UNLV Theses, Dissertations, Professional Papers, and Capstones
Food poisoning is a common term used to describe what is actually foodborne illness. Despite the fact these illnesses can become deadly, foodborne illnesses are endemic and common in the United States. Nonetheless, they are completely preventable simply by following proper food safety procedures. The Food and Drug Administration identified the most common foodborne pathogens responsible for most foodborne infections, as well as the five risk factor categories to target in order to decrease the risk of cases and outbreaks.
To ensure foodborne outbreaks and cases are prevented, health authorities are tasked with conducting routine inspections on permitted food establishments. …
Examining The Spatial Periodicity Of Force Chains And Strain Localization In Polycrystal Models, Richard D. Panduro-Allanson
Examining The Spatial Periodicity Of Force Chains And Strain Localization In Polycrystal Models, Richard D. Panduro-Allanson
UNLV Theses, Dissertations, Professional Papers, and Capstones
Shear strain localization is typical in deforming rocks and is vital for developing faults and tectonic boundaries. There are various proposed drivers of shear localization (temperature, fluid, phase transformation, and microstructure); we will explore the effects of elastic heterogeneity (a microstructural influence) on shear localization in polycrystal models. Elastic heterogeneity can lead to varied stress states in material and drive shear localization. Previous simulations of elastically heterogeneous polycrystal models have shown that the stress distribution can be described as forming an anastomosing pattern of high-stress streams parallel to the compression direction. This anastomosing patterning resembles force chains; linear, high-stress features …
Implementation Of Adas And Autonomy On Unlv Campus, Zillur Rahman
Implementation Of Adas And Autonomy On Unlv Campus, Zillur Rahman
UNLV Theses, Dissertations, Professional Papers, and Capstones
The integration of Advanced Driving Assistance Systems (ADAS) and autonomous driving functionalities into contemporary vehicles has notably surged, driven by the remarkable progress in artificial intelligence (AI). These AI systems, capable of learning from real-world data, now exhibit the capability to perceive their surroundings via a suite of sensors, create optimal routes from source to destination, and execute vehicle control akin to a human driver.
Within the context of this thesis, we undertake a comprehensive exploration of three distinct yet interrelated ADAS and Autonomy projects. Our central objective is the implementation of autonomous driving(AD) technology at UNLV campus, culminating in …
Actinide Behavior In Soft Ligand Environments And Higher Oxidation States Of Neptunium In Aqueous Media With Solid-State Synthesis Of Np(Vii) Compounds, Kelly Floyd Seeley
Actinide Behavior In Soft Ligand Environments And Higher Oxidation States Of Neptunium In Aqueous Media With Solid-State Synthesis Of Np(Vii) Compounds, Kelly Floyd Seeley
UNLV Theses, Dissertations, Professional Papers, and Capstones
The fundamental properties of Uranium and Neptunium were investigated with Powder X-Ray Diffraction (PXRD) to study the behavior or 5f electrons with chalcogen, alkali metals, and alkaline earth metals. Two novel compounds were generated: NaCuUS3 and NaCuNpS3. There are several crystal structures that form in the family of AMM’Q (A = s-block, M = d-block, M’ = d-block or f-block, and Q = chalcogen), with oxidation states of A1+, M1+, M’4+, and Q2- ions from the family of type I compounds. Work was continued to …
Interaction Of Technetium (Iv) With Dibutyl Phosphate In N-Dodecane, Jonathan George
Interaction Of Technetium (Iv) With Dibutyl Phosphate In N-Dodecane, Jonathan George
UNLV Theses, Dissertations, Professional Papers, and Capstones
During the reprocessing of nuclear fuel, the degradation of tributylphosphate (TBP) occurs as a result of radiolytic and thermal processes. These processes lead to the formation of minor amounts of dibutyl phosphate (HDBP). However, the presence of DBP poses a challenge in the partitioning of uranium (U), plutonium (Pu), and technetium (Tc) due to its chelating effects. The chelation of these elements by HDBP can interfere with their intended separation and purification, thereby impacting the efficiency and effectiveness of the reprocessing process. In this study, X-ray Absorption Fine Structure (XAFS) spectroscopy is employed to investigate the speciation of Tc following …
New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott
New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott
UNLV Theses, Dissertations, Professional Papers, and Capstones
Investigation into seamounts that stem from intraplate volcanism—that is volcanism occurring far from plate boundaries—presents an opportunity to deconvolve processes associated with mantle compositional heterogeneities and melting dynamics. Upwelling and decompression of thermochemically anomalous mantle plumes is the primary mechanism for significant intraplate volcanism; however, many seamounts dotted across the Pacific Plate do not correlate spatially, temporally, or geochemically with mantle plume volcanism. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism are the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present merged multibeam (<100 m) and satellite altimetry bathymetric maps of the Geologist Seamounts region, new 40 …100>
Water Efficiency & Sustainability In The Mountain West, 2022, Zachary Billot, Caitlin J. Saladino, William E. Brown Jr.
Water Efficiency & Sustainability In The Mountain West, 2022, Zachary Billot, Caitlin J. Saladino, William E. Brown Jr.
Environment
This fact sheet analyzes the effectiveness of state-level policies related to water usage, conservation, and sustainability for the Mountain West states of Arizona, Colorado, Nevada, New Mexico, and Utah in 2022. The original data are published in the “2022 State Policy Scorecard for Water Efficiency and Sustainability” report written by the Alliance for Water Efficiency.
The High Pressure Dependence Of X-Ray Induced Decomposition Of Cadmium Oxalate, Adrian F. Lua Sanchez, Petrika Cifligu, Marc Graff, Michael Pravica, Pradip K. Bhowmik, Changyong Park, Egor Evlyukhin
The High Pressure Dependence Of X-Ray Induced Decomposition Of Cadmium Oxalate, Adrian F. Lua Sanchez, Petrika Cifligu, Marc Graff, Michael Pravica, Pradip K. Bhowmik, Changyong Park, Egor Evlyukhin
Physics & Astronomy Faculty Research
The high proclivity of x rays to destabilize and distort molecular structures has been previously utilized in the synthesis of novel compounds. Here, we show that x-ray induced decomposition of cadmium oxalate induces chemical and structural transformations only at 0.5 and 1 GPa. Using x-ray diffraction and Raman spectroscopy, the synthesized product is identified as cadmium carbonate with cadmium oxalate remnants, which is stable under ambient conditions. At ambient and >1 GPa pressures, only degradation of the electronic density distribution is observed. The transformation kinetics are examined in terms of Avrami’s model, which demonstrates that despite the necessity of high …