Physical Sciences and Mathematics Commons^™

Spectrum Analysis Of Thermally Driven Curvature Inversion In Strained Graphene Ripples For Energy Conversion Applications Via Molecular Dynamics, James M. Mangum, Md R. Kabir, Tamzeed B. Amin, Syed M. Rahman, Ashaduzzaman, Paul M. Thibado

Physics Faculty Publications and Presentations

The extraordinary mechanical flexibility, high electrical conductivity, and nanoscale instability of freestanding graphene make it an excellent candidate for vibration energy harvesting. When freestanding graphene is stretched taut and subject to external forces, it will vibrate like a drum head. Its vibrations occur at a fundamental frequency along with higher-order harmonics. Alternatively, when freestanding graphene is compressed, it will arch slightly out of the plane or buckle under the load. Remaining flat under compression would be energetically too costly compared to simple bond rotations. Buckling up or down, also known as ripple formation, naturally creates a bistable situation. When the …

Molecular Dynamics Simulations Of Liposomes: Structure, Dynamics, And Applications, Ehsan Khodadadi, Ehsaneh Khodadadi, Parth Chaturvedi, Mahmoud Moradi

Chemistry & Biochemistry Faculty Publications and Presentations

Liposomes are nanoscale, spherical vesicles composed of phospholipid bilayers, typically ranging from 50 to 200 nm in diameter. Their unique ability to encapsulate both hydrophilic and hydrophobic molecules makes them powerful nanocarriers for drug delivery, diagnostics, and vaccine formulations. Several FDA-approved formulations such as Doxil (R) (Baxter Healthcare Corporation, Deerfield, IL, USA), AmBisome (R) (Gilead Sciences, Inc., Foster City, CA, USA), and Onivyde (R) (Ipsen Biopharmaceuticals, Inc., Basking Ridge, NJ, USA) highlight their clinical significance. This review provides a comprehensive synthesis of how molecular dynamics (MD) simulations, particularly coarse-grained (CG) and atomistic approaches, advance our understanding of liposomal membranes. We …

Is Criticality A Unified Setpoint Of Brain Function?, Keith B. Hengen, Aaron Shew

Physics Faculty Publications and Presentations

Brains face selective pressure to optimize computation, broadly defined. This is achieved by mechanisms including development, plasticity, and homeostasis. Is there a universal optimum around which the healthy brain tunes itself, across time and individuals? The criticality hypothesis posits such a setpoint. Criticality is a state imbued with internally generated, multiscale, marginally stable dynamics that maximize the features of information processing. Experimental support emerged two decades ago and has accumulated at an accelerating pace despite disagreement. Here, we lay out the logic of criticality as a general computational endpoint and review experimental evidence. We perform a meta-analysis of 140 datasets …

Land8fire: A Complete Study On Wildfire Segmentation Through Comprehensive Review, Human-Annotated Multispectral Dataset, And Extensive Benchmarking, Anh Tran, Minh Tran, Esteban Marti, Jackson Cothren, Chase Rainwater, Sandra Eksioglu, Ngan Le

Electrical Engineering and Computer Science Faculty Publications and Presentations

Early and accurate wildfire detection is critical for minimizing environmental damage and ensuring a timely response. However, existing satellite-based wildfire datasets suffer from limitations such as coarse ground truth, poor spectral coverage, and class imbalance, which hinder progress in developing robust segmentation models. In this paper, we introduce Land8Fire, a new large-scale wildfire segmentation dataset composed of over 20,000 multispectral image patches derived from Landsat 8 and manually annotated for high-quality fire masks. Building on the ActiveFire dataset, Land8Fire improves ground truth reliability and offers predefined splits for consistent benchmarking. We evaluate a range of state-of-the-art convolutional and transformer-based models, …

Harnessing Emergent Multiple Scattering Resonances In A Photonic Glass Structure For Photoelectrochemical Energy Conversion, Ashlyn G. Descarpentrie, Robert H. Coridan

Chemistry & Biochemistry Faculty Publications and Presentations

Light trapping nanostructures are often necessary to improve carrier collection yields in semiconductor photoelectrodes with intrinsically poor electron transport. Photonic crystal templates can generate tailorable light trapping via periodic and precise nanostructure, though this is not a scalable strategy for photoelectrochemical (PEC) applications. It is therefore critical to identify alternative mechanisms for light trapping that tolerate disorder. Light trapping in disordered media is generated by the diffusive transport caused by multiple scattering. In some cases, multiple scattering can generate resonances that resemble those observed in photonic crystals. While resonant multiple scattering is a disorder tolerant light trapping mechanism, it is …

Autoregressive Temporal Modeling For Advanced Tracking-By-Diffusion, Pha Nguyen, Rishi Madhok, Bhiksha Raj, Khoa Luu

Electrical Engineering and Computer Science Faculty Publications and Presentations

Object tracking is a widely studied computer vision task with video and instance analysis applications. While paradigms such as tracking-by-regression,-detection,-attention have advanced the field, generative modeling offers new potential. Although some studies explore the generative process in instance-based understanding tasks, they rely on prediction refinement in the coordinate space rather than the visual domain. Instead, this paper presents Tracking-by-Diffusion, a novel paradigm for object tracking in video, leveraging visual generative models via the perspective of autoregressive models. This paradigm demonstrates broad applicability across point, box, and mask modalities while uniquely enabling textual guidance. We present DIFTracker, a framework that utilizes …

Simulation Of Photochemical Effects On Air Quality, Grace Li

Chemical Engineering Undergraduate Honors Theses

Nitrogen dioxide (NO₂) and ozone (O₃) are both EPA criteria air pollutants in the troposphere, largely generated by combustion and therefore present in significant concentrations in urban areas. Sunlight facilitates chemical reactions between pollutants and ambient air. Aerosols modulate the amount of available energy required to drive such photochemical reactions, ultimately impacting air quality. Simulating photolysis rates with FastJX software is a resource-efficient strategy to study how these aerosols can affect air quality.

Tree-Based Differential Item Functioning Detection Methods: Exploring Their Performance In Diverse Measurement Scenarios, Nana Amma Berko Asamoah

Graduate Theses and Dissertations

Despite the availability of numerous methods for detecting differential item functioning (DIF), the continued development and evaluation of innovative, data-driven approaches remains essential. Tree-based methods, in particular, represent a significant advancement in DIF detection. Unlike some traditional techniques, they can simultaneously screen multiple variables for DIF without discretizing continuous variables, and do not require the pre-specification of focal and reference groups; capabilities that are especially valuable in today’s diverse and multifaceted assessment contexts. However, research systematically examining the performance of these methods under realistic measurement conditions is limited. This dissertation, in three simulation studies, critically examines the robustness and practical …

How To Do Things With Little Talking Tubes: Nonideal Speech Acts In The Digital Age, Anthony Holdier

Graduate Theses and Dissertations

In this work, I develop a view about what it means to share a social or conversational context with others, as well as what is normatively entailed by doing so. Working from a broadly Austinian perspective about the moral foundations of language use and how we use words to position ourselves within social space, as well as from a generally Stalnakerian social ontology (demarcating groups by dint of aligned or overlapping sets of commitments), I present three papers demonstrating how nonidealized, ordinary language philosophy can make sense of complex, real-world phenomena. Through analyses of heretical utterances, context collapse, and chatbot …

Sustainability: Buzz Word Or Future Of Fashion? Measuring The Feasibility Of Outright Sustainability Among Fast Fashion’S Biggest Agents, Ryan Miller

Apparel Merchandising and Product Development Undergraduate Honors Theses

Abstract

The fashion industry is currently experiencing unsustainable rates of pollution within its supply chains. The rapid increase in demand for short lead times perpetrated by large-scale retailers has led to hazardous practices negatively affecting both the environmental conditions and working conditions of producing countries. With this increased pressure, relationships between brands and suppliers have become untenable. Limited transparency and imbalanced power dynamics at the hand of the industry’s leading retailers require restructuring in order to build more sustainable and equitable supply-chain practices. Further, governmental regulation is currently limited in its capacity to enforce sustainable business practices on a global …

Yizhi Sun: Profile Of The Newest Chbc Faculty Member., Danna Jaimes-Fajardo, Jeremy J. Smith, Lutishoor Salisbury

University Libraries Faculty Publications and Presentations

Presents the research profile of Yizhi Sun, Assistant Professor, Chemistry and Biochemistry department. It highlights his research interests, education, and impact of his research.

Automated Chick Sexing Using Computer Vision, Marta Veganzones Rodriguez

Graduate Theses and Dissertations

This thesis presents two complementary approaches to chick sexing, a critical task in poultry production that demands accurate and early gender identification. By investigating both facial and vent-based modalities, we present two complementary methods that aim to improve the efficiency, scalability, and ethical standards of gender classification in day-old chicks through the use of computer vision and deep learning. The first approach draws inspiration from human facial gender recognition to introduce facial chick sexing, a minimally invasive technique that eliminates the need for expert knowledge. This system encompasses a complete pipeline that includes image acquisition, facial detection and alignment, keypoint …

Cotton Yield And Tissue-Potassium Response To Potassium Fertilization, Maria Paula Ramos Do Prado

Graduate Theses and Dissertations

Potassium (K) deficiency is a common yield-limiting factor in cotton (Gossypium hirsu tum L.) production across the U.S. Cotton Belt. Adequate fertilizer-K management is paramount to ensure optimum plant growth and development, minimizing yield losses. Currently, fertilizer K recommendations for cotton in Arkansas are derived from expected yield responses of other crops, with no calibrated fertilizer-K rates or critical tissue-K concentrations defined to maxim ize crop yield. Our research objectives were i) to investigate cotton yield response and fiber qual ity to K fertilization on soils with different K availability; ii) to correlate relative yield with tis sue-K concentrations at …

Algorithmic Recourse In Sequential Decision-Making For Long-Term Fairness, Francisco Gumucio

Graduate Theses and Dissertations

Algorithmic decision-making systems are increasingly being deployed in high-stakes domains such as criminal justice, education, and financial services. While machine learning models have demonstrated significant utility in automating complex decisions, they have also raised substantial concerns regarding fairness and equity. Much of the existing work in algorithmic fairness has focused on static, one-shot settings, where interventions are aimed at miti- gating bias in a single decision. However, many real-world systems operate sequentially, where decisions made at one point in time can influence future outcomes through dynamic feedback loops. In such scenarios, addressing fairness at only one decision point can be …

Explainable Machine Learning Surrogate Modeling For Exit Gradient Prediction In Hydraulic Structures Using Numerical Simulations, Prayas Rath, Jianting Zhu, Kevin M. Befus

Geosciences Faculty Publications and Presentations

Accurate prediction of exit gradients is essential for designing impounding hydraulic structures, such as dams and levees, to mitigate seepage-induced piping failures. Conventional analytical methods often neglect boundary effects and anisotropy, limiting their applicability in complex geological settings. This study develops an XGBoost-based machine learning surrogate model trained and tested on 8,000 MODFLOW numerical simulations to predict exit gradients under varying hydraulic and geological conditions. The data set covers numerous parameters, including anisotropy, head differences, structure width, cut-off wall depth, aquifer thickness, and uninterrupted riverbed length. The coefficient of determination for test data is 0.88, demonstrating reliable exit gradient prediction …

A Multi-Source Remote Sensing-Based Geocommunication Tool For Global Flood Monitoring And Management, Ebrahim Hamidi, Brad Peter, Hamed Moftakhari, Hamid Moradkhani

Geosciences Faculty Publications and Presentations

Global warming is expected to increase the frequency of extreme flooding, making rapid and accurate flood mapping crucial for effective risk assessment. Many governmental agencies and organizations are developing flood risk assessment tools; however, due to the lack of observational records, some rely on probabilistic generated data, uncalibrated simulations, or terrain-based methods, all of which are subject to various types of uncertainty. Although remote sensing provides valuable flood data with global coverage, single-source reliance is constrained by satellite revisit rates, resolution, weather conditions, and sensor limitations. To address these challenges, this study introduces a user-friendly application on the Google Earth …

Crystal Structures Of Escherichia Coli Glucokinase And Insights Into Phosphate Binding, Joseph Andrews, Joshua Sakon, Chenguang Fan

Chemistry & Biochemistry Faculty Publications and Presentations

Here, we report the crystal structure of Escherichia coli glucokinase (GLK), which has phosphate bound in the cleft between the alpha and beta domains adjacent to the active site. A ternary complex consisting of GLK, glucose and phosphate is also reported in this work. Diffraction data were collected at 2.63 angstrom resolution for the phospate-bound form (R-work/R-free = 0.191/0.230) and at 2.54 angstrom resolution for the ternary complex (R-work/R-free = 0.202/0.258), both at 297 K. A B-factor analysis of the phosphate-bound GLK structure revealed consistently lower values for phosphate-interacting basic residues in the alpha 4, alpha 5 and alpha 9 …

Synthesis, Structural Characterization And Optical Studies Of Silver-Indium-(Zinc)-Chalcogenide Fluorescent Quantum Dots, Sujal Acharya

Graduate Theses and Dissertations

Developing a non-toxic, high-performance fluorescent nanomaterial is crucial for overcoming the environmental and health restrictions of current cadmium, and lead based quantum dots (QDs), which limit the application of quantum dots in optoelectronics and bioimaging. In this thesis, we synthesized environmentally friendly AgInS2 QDs by a colloidal method, systematically altering the In/Ag precursor ratio from 2 to 6 to study the impact on their optical and photophysical properties. Our goals were to find the optimal stoichiometry for maximum quantum efficiency and stability. We also investigated further improving optical and photophysical properties through shelling with ZnS. The emission spectra appeared broad, …

Contrastive Loss In Recommendation Systems, Maryam Aghamohammadghasem

Graduate Theses and Dissertations

A recommendation system is a bridge between users and products, which is widely used in e-commerce such as Amazon and Netflix. This study investigates the use of Graph Neural Networks (GNNs), Light Graph Convolution Network(LightGCN) and Graph Sample and Aggregate (GraphSAGE), in the recommendation system on two categories of Amazon review datasets ( "All Beauty" and "Tools and Home Improvement"). The novelty of this work includes combining supervised and self-supervised learning through Weighted Approximate Rank Pairwise (WARP) and Information Noise-Contrastive Estimation (InfoNCE) losses, to optimize the embeddings of users and recommended items in the shape of a ranking list. The …

Utilizing The Horseshoe Prior In Exploratory Factor Analysis And Gaussian Graphical Networks, James Thomas Roddy

Graduate Theses and Dissertations

High-dimensional data analysis frequently involves extracting meaningful structure from noisy, sparse signals. In recent years, Bayesian shrinkage priors—particularly global-local shrinkage priors—have emerged as powerful tools for inducing sparsity while preserving signal fidelity. Among these, the Horseshoe prior has gained notable attention for its capacity to simultaneously shrink irrelevant parameters and retain substantial signals. This dissertation explores the Horseshoe prior as a unified framework for sparse Bayesian inference across theory, simulation, and real-world application. The first component develops new theoretical results establishing the asymptotic Bayes optimality of the Horseshoe prior in Gaussian graphical models (GGMs). We consider sparse precision matrix estimation …

Classifying Advanced Persistent Threat Stages And Techniques Via Graph-Enhanced Network Flow Representations, Md Taef Uddin Nadim

Graduate Theses and Dissertations

Advanced Persistent Threats (APTs) are complex, stealthy attacks that involve multiple stages and many attack techniques used in each stage, making them difficult to defend against. Although many solutions can detect APTs, most of them only detect the existence of attack, but cannot produce fine-grained classification over the stage of the APT and the specific attack technique used. Some existing solutions can classify the stages of APT, but few of them provide attack technique classification, and existing work do not provide interpretability for the classification or countermeasures for the attack. In this thesis work, we propose a solution named CAPTure, …

Strain Induced Quantum Emitters In Monolayer Wse₂: Fabrication And Characterization Of Dimple Dot Devices, Garrett Maxwell Kitterman

Graduate Theses and Dissertations

Strain induced defects in monolayer tungsten diselenide (WSe₂) give rise to localized exciton funnels, offering a promising approach for the development of tunable quantum emitters. The quantum devices fabricated for this thesis used a modified dimple dot geometry, in which nano indentation creates a strain profile on the monolayer WSe₂. This allows for the funneling of excitons to a confined region. These strain induced funnels enable localized emission from single excitons in WSe₂. Device fabrication was carried out through mechanical exfoliation, dry transfer, and electron beam lithography of Cr/Au gates on a SiO₂ substrate. These devices were then characterized using …

Factors Influencing The Transition To Renewable Energy In Small- To Mid-Sized American Communities, Hanan Wehbi, Nathan Kemper

Environmental Dynamics Faculty Publications and Presentations

Background The transition to renewable energy is essential for addressing climate change and fostering sustainable communities. This involves planning and determining where, when, and how to deploy renewable energy technologies. This requires supportive policies and regulations to accommodate renewable energy sources and manage impact, as well as engagement with local communities and stakeholders to secure their support and participation in the transition process. Methods This study evaluates the impact of governance at various levels-community, county, and state-on renewable energy adoption in 87 small- to mid-sized U.S. communities with populations below 100,000. Using a multi-faceted analytical approach, this research reviews comprehensive …

Framework For Mapping Sublimation Features On Mars’ South Polar Cap Using Object-Based Image Analysis, Racine D. Cleveland, Vincent F. Chevrier, Jason A. Tullis

Geosciences Faculty Publications and Presentations

Mars’ south polar cap hosts dynamic landforms known as Swiss cheese features (SCFs), which form through the sublimation of carbon dioxide (CO2) ice driven by the planet’s extreme seasonal and diurnal solar insolation cycles. These shallow, rounded depressions—first identified by Mars Global Surveyor in 1999 and later monitored by the Mars Reconnaissance Orbiter (MRO)—have been observed to increase in size over time. However, large-scale analysis of SCF formation and growth has been limited by the slow and labor-intensive nature of manual mapping techniques. This study applies object-based image analysis (OBIA) to automate the detection and measurement of SCFs using High-Resolution …

Exploring The Promise And Limitations Of Point-Charge-Free Potentials For Hydrocarbon Modeling, Raymond Weldon, Feng Wang

Chemistry & Biochemistry Faculty Publications and Presentations

Models for hydrated and neat hydrocarbons are developed with the adaptive force matching method using either B3LYP-D3(BJ) or MP2 as reference. Hydrocarbons, being non-polar, present an opportunity to explore the possibility of creating force fields without modeling electrostatics. For liquid methane, ethane, cyclopentane, and cyclohexene, models without partial charges achieved excellent agreement with experiments when fitted against MP2 reference with SAPT dispersion. In aqueous solutions, models without solute partial charges maintain high quality for saturated hydrocarbons but exhibit reduced accuracy for cyclohexene. Notably, liquid methane's weak intermolecular interactions make it particularly sensitive to the choice of reference method. Our findings …

Regularity, Uniqueness And The Relative Size Of Small And Large Scales In Sqg Flows, Z. Akridge, Z. Bradshaw

Mathematical Sciences Faculty Publications and Presentations

The problems of regularity and uniqueness are open for the supercritically dissipative surface quasi-geostrophic equations in certain classes. In this note we examine the extent to which small or large scales are necessarily active both for the temperature in a hypothetical blow-up scenario and for the error in hypothetical non-uniqueness scenarios, the latter understood within the class of Marchand's solutions. This extends prior work for the 3D Navier-Stokes equations. The extension is complicated by the fact that mild solution techniques are unavailable for supercritical SQG. This forces us to develop a new approach using energy methods and Littlewood-Paley theory.

A Contextual Analysis Of The Early Work Of Andrzej Trautman And Ivor Robinson On Equations Of Motion And Gravitational Radiation, Donald Salisbury, Daniel Kennefick

Physics Faculty Publications and Presentations

In the mid-1950s, Andrzej Trautman published a series of papers connected with his dissertation work written under Leopold Infeld. In these, he drew upon the slow motion approximation developed by Infeld, the general covariance-based strong conservation laws enunciated by Bergmann and Goldberg, the Riemann tensor attributes explored by Goldberg and related geodesic deviation exploited by Pirani, the permissible metric discontinuities identified by Lichnerowicz, O'Brien and Synge, and finally Petrov's classification of vacuum spacetimes. With several significant additions he produced a comprehensive overview of the state of research in equations of motion and gravitational waves that was presented in a widely …

A Comprehensive Systematic Review Of Machine Learning Applications In Assessing Land Use/Cover Dynamics And Their Impact On Land Surface Temperatures, Rasool Vahid, Mohamed Aly

Environmental Dynamics Faculty Publications and Presentations

In a world experiencing rapid urbanization, the phenomenon of land surface temperature (LST) variation has invited substantial attention due to its profound impact on the environment and human well-being. Changes in land use and land cover (LULC) within urban areas significantly influence the dynamics of LST and are a major driver of urban eco-environmental change. The complex connections between LULC dynamics, LST, and climate change are investigated in this systematic review, with a focus on the combined effects of these variables and the use of Machine Learning (ML) techniques. The data in this study, based on peer-reviewed publications from the …

Stratigraphic Evidence Of Backwater Morphodynamics And Lowland River Deltas In The Northern Hemisphere Of Mars, C.M. Hughes, J.B. Shaw, A.M. Fernandes, T.E. Swanson

Geosciences Faculty Publications and Presentations

Backwater morphodynamics describe feedbacks between hydraulics and sedimentation in fluvio-deltaic systems in the coastal backwater zone. On Earth, normalized channel belt width decreases approaching the coastline and drops sharply at the start of the backwater zone. This systematic decrease allows a backwater/belt-width window to be defined, one backwater length upstream from the coast with normalized widths from 2 to 6. We use the backwater/belt-width window to interpret backwater morphodynamics and estimate backwater length on Mars using narrowing channel belts at Aeolis Dorsa. We measure nine belts from martian delta deposits and compare normalized width to distance upstream from an ancient …

Perchlorate Brine Formation From Frost At The Viking 2 Landing Site, Vincent F. Chevrier

Geosciences Faculty Publications and Presentations

The presence and stability of brines on Mars’s surface remain a significant mystery in planetary exploration. Previous mechanisms proposed for brine formation include melting of ice-salt mixtures and salt deliquescence. However, melting lacks a recharge mechanism, and deliquescence is impeded by Mars’s extreme surface aridity. This study explores an underexplored process: the role of seasonal frost in brine formation. Utilizing meteorological data from the Viking 2 lander—the only mission, with Phoenix, to observe in situ water frost formation—I demonstrate that brines can form over approximately 30 sols at the end of winter as frost sublimates. The stable brines exhibit a …