Physical Sciences and Mathematics Commons^™

Thermodynamic Analysis Of Digestate Pyrolysis Coupled With Co2 Sorption, Antonella Dimotta, Cesare Freda

Conference papers

To date the management of digestate is a crucial task for anaerobic digestion process. In the present work a strategy for digestate management is thermodynamically analyzed by a commercial software for process simulation called CHEMCAD®. Pyrolysis of digestate is simulated by a minimization of the free Gibbs energy. The sequestration of the carbon dioxide (CO2) released by the pyrolysis is investigated by the addition of calcium oxide, in order to reduce CO2 emissions. The effect of the pyrolysis temperature between 400–900 °C and of the CaO/digestate mass ratio between 0–0.5 was discussed, as well. The CHEMCAD application allowed to investigate …

Design And Fabrication Of Volume Holographic Optical Couplers For A Range Of Non-Normal Incidence Angles, Dipanjan Chakraborty, Rosen Georgiev, Sinead Aspell, Izabela Naydenova, Suzanne Martin

Conference Papers

A theoretical model has previously been developed to calculate the holographic recording beam angles required in air (at any recording wavelength) to produce a Volume Holographic Optical Element (VHOE) for operation as a coupler for different input and output angles. In this paper, the experimental study is extended to further validate the VHOE coupler design and fabrication approach for additional incident beam angles, comparing -40° -45° and -50° (in air). The output angle for each VHOE is +45° within the medium and the coupler operational wavelength is 633nm. Holographic recording in Bayfol HX 200 photopolymer at 532nm is used to …

Switch-On Luminescent Sensing Of Unlabelled Bacterial Lectin By Terbium(Iii) Glycoconjugate Systems, Karolina Wojtczak, Eva Zahorska, Ian J. Murphy, Finnja Koppel, Gordon Cooke, Alexander Titz, Joseph P. Byrne

Articles

Interactions of lectins with glycoconjugate-terbium(III) self-assembly complexes lead to sensing through enhanced lanthanide luminescence. This glycan-directed sensing paradigm detects an unlabelled lectin (LecA) associated with pathogen P. aeruginosa in solution, without any bactericidal activity. Further development of these probes could have potential as a diagnostic tool.

Protein Extraction And Purification By Differential Solubilization, Barry J. Ryan, Gemma K. Kinsella, Gary T. Henehan

Books/Book Chapters/ Proceedings

The preparation of purified soluble proteins for biochemical studies is essential and the solubility of a protein of interest in various media is central to this process. Selectively altering the solubility of a protein is a rapid and economical step in protein purification and is based on exploiting the inherent physicochemical properties of a polypeptide. Precipitation of proteins, released from cells upon lysis, is often used to concentrate a protein of interest before further purification steps (e.g., ion exchange chromatography, size exclusion chromatography etc).

Recombinant proteins may be expressed in host cells as insoluble inclusion bodies due to various influences …

Sustainable Utilisation And Management Of Food Waste For High-Value Products, Amit Jaiswal

Articles

Welcome to the Special Issue on “Sustainable Utilisation and Management of Food Waste for High-Value Products”. This Special Issue focuses on one of the most critical challenges facing our world today—the efficient management and utilisation of food waste. It presents a variety of scientific investigations from renowned scholars and researchers worldwide to address this challenge, covering an array of topics ranging from fundamental research to real-world applications. Food waste is a global dilemma that requires urgent attention. According to the Food and Agriculture Organization (FAO), approximately one-third of food produced for human consumption worldwide, or around 1.3 billion tons, is …

Development And Evaluation Of A Multifrequency Ultrafast Doppler Spectral Analysis (Mfudsa) Algorithm For Wall Shear Stress Measurement: A Simulation And In Vitro Study, Andrew Malone, Sean Cournane, Izabela Naydenova, James F. Meaney, Andrew J. Fagan, Jacinta Browne

Articles

Cardiovascular pathology is the leading cause of death and disability in the Western world, and current diagnostic testing usually evaluates the anatomy of the vessel to determine if the vessel contains blockages and plaques. However, there is a growing school of thought that other measures, such as wall shear stress, provide more useful information for earlier diagnosis and prediction of atherosclerotic related disease compared to pulsed-wave Doppler ultrasound, magnetic resonance angiography, or computed tomography angiography. A novel algorithm for quantifying wall shear stress (WSS) in atherosclerotic plaque using diagnostic ultrasound imaging, called Multifrequency ultrafast Doppler spectral analysis (MFUDSA), is presented. …

Analog Holographic Wavefront Sensor For Defocus And Spherical Aberration Measurement Recorded In A Photopolymer, Emma Branigan, Suzanne Martin, Matthew Sheehan, Kevin Murphy

Articles

An analog holographic wavefront sensor (AHWFS), for measurement of low and high order (defocus and spherical aberration) aberration modes has been developed as volume phase holograms in a photopolymer recording medium. This is the first time that high order aberrations such as spherical aberration can be sensed using a volume hologram in a photosensitive medium. Both defocus and spherical aberration were recorded in a multi-mode version of this AHWFS. Refractive elements were used to generate a maximum and minimum phase delay of each aberration which were multiplexed as a set of volume phase holograms in an acrylamide based-photopolymer layer. The …

Improving The Angular Visibility Of Photopolymer-Based Reflection Holograms For Sensing Applications, Tatsiana Mikulchyk, Kevin Murphy, John Walsh, Suzanne Martin, Dervil Cody, Izabela Naydenova

Articles

Volume reflection hologram-based sensors are designed to visibly change colour in response to a target stressor or analyte. However, reflection holograms fabricated in thick photopolymer films are highly angularly selective, making these sensors challenging to view and interpret by non-experts. Here, the use of speckle holography to improve the visibility of reflection holograms is presented. A novel recording approach combining speckle recording techniques with Denisyuk reflection recording geometry is described. The recorded speckle reflection grating operates as a series of multiplexed reflection gratings with a range of spatial frequencies, capable of reflecting light at a wider range of angles. A …

Probe–Integrated Electrochemical Sensing Platform For Measuring Trace Levels Of Parathion Pesticides Residues In Water Using Au- Nanoparticles Anchored Nafion Nano Composite Modified Glassy Carbon Electrode, H. Alwael, S.H. Al-Sedran, Mohamed Oubaha, N.A.A. Asiri, A.S. Bashammakh, A.S. Alharthy, N.A. Albassami, T.N. Abduljabbar, G.I. Mohamed, H.M. Nassef, E.A. Bahaidarah, B.G. Alhogbi, M.S. El-Shahawi

Articles

Nanomaterial represents a principal driver to the adoption of electrochemical sensors for pesticides residues in water. Thus, the current strategy reports facile and highly sensitive electrochemical probe for monitoring parathion residues in water. The probe was based upon the use of Au nanoparticles (AuNPs) functionalized Nafion nanocomposites modified glassy carbon electrode (Au NPs/Nafion/GCE). The surface morphology, effective surface area and electrocatalytic performance of the Au NPs/Nafion/GCE were recorded and assigned using a scanning electron microscopy (SEM), cyclic voltammetry (CV) and electronic spectra. A straightforward protocol based upon combination of Au NPs/Nafion/GCE and square wave- adsorptive cathodic stripping voltammetry at pH …

Review-Electrode Kinetics And Electrolyte Stability In Vanadium Flow Batteries, Andrea Bourke, Daniela Oboroceanu, Nathan Quill, Catherine Lenihan, Maria Alhajji Safi Maria Alhajji Safi, Mallory A. Miller, Robert F. Savinell, Jesse S. Wainright, Varsha Sasikumarsp, Maria Rybalchenko, Pupak Amini, Niall Dalton, Robert P. Lynch, D. Noel Buckley

Articles

Two aspects of vanadium flow batteries are reviewed: electrochemical kinetics on carbon electrodes and positive electrolyte stability. There is poor agreement between reported values of kinetic parameters; however, most authors report that kinetic rates are faster for VIV/VV than for VII/VIII. Cycling the electrode potential increases the rates of both reactions initially due to roughening but when no further roughening is observed, the VII/VIII and VIV/VV reactions are affected oppositely by the pretreatment potential. Anodic pretreatment activates the electrode for the VII/VIII reaction, and deactivates it for VIV/VV. Three states of the carbon surface are suggested: reduced and oxidized states …

Effects Of Flexibility In Coarse-Grained Models For Bovine Serum Albumin And Immunoglobulin G, Frank Hirschmann, Hender Lopez, Felix Roosen-Runge, Tilo Seydel, Frank Schreiber, Martin Oettel

Articles

We construct a coarse-grained, structure-based, low-resolution, 6-bead flexible model of bovine serum albumin (BSA, PDB: 4F5S), which is a popular example of a globular protein in biophysical research. The model is obtained via direct Boltzmann inversion using all-atom simulations of a single molecule, and its particular form is selected from a large pool of 6-bead coarse-grained models using two suitable metrics that quantify the agreement in the distribution of collective coordinates between all-atom and coarse-grained Brownian dynamics simulations of solutions in the dilute limit. For immunoglobulin G (IgG), a similar structure-based 12-bead model has been introduced in the literature [Chaudhri …

Global Short-Term Mortality Risk And Burden Associated With Tropical Cyclones From 1980 To 2019: A Multi-Country Time-Series Study, Wenzhong Huang, Shansan Li, Thomas Vogt, Rongbin Xu, Shilu Tong, Tomas Molina, Pierre Masselot, Antonio Gasparrini, Ben Armstrong, Mathilde Pascal, Dominic Roye, Chris Fook Sheng Ng, Ana Maria Vicedo-Cabrera, Joel Schwartz, Eric Lavigne, Haidong Kan, Patrick J. Goodman, Ariana Zeka, Masahiro Hashizume, Magali Hurtado Dias, Cesar De La Cruz Valencia, Xerxes Seposo, Baltazar Nunes, Joana Madureira, Ho Kim, Whanhee Lee, Aurelio Tobias, Carmen Iniguez, Yue Leon Guo, Shih-Chun Pan, Antonella Zanobetti, Tran Ngoc Dang, Do Van Dung, Tobias Geiger, Christian Otto, Amanda Johnson, Simon Hales, Pei Yu, Zhengyu Yang, Elizabeth A. Ritchie, Yuming Guo

Articles

The global spatiotemporal pattern of mortality risk and burden attributable to tropical cyclones is unclear. We aimed to evaluate the global short-term mortality risk and burden associated with tropical cyclones from 1980 to 2019.

Use Of Machine Learning Methods In Automatic Assessment Programming Assignments, Botond Tarcsay

Masters

Programming has become an important skill in today’s world and is taught widely both in traditional settings and online. Instructors need to assess increasing amounts of student work. Unit testing can contribute to the automation of the grading process; however, it cannot assess the structures, style and partially correct source code or differentiate between levels of achievement. The topic of this thesis is an investigation into the use of machine learning methods for assessing the correctness and quality of code, with the ultimate goal of assisting instructors in the grading process. In this research, we have used nine different machine …

Collective Relaxation Processes In Nonchiral Nematics, Neelam Yadav, Yuri Panarin, Wanhe Jiang, Georg H. Mehl, Jagdish Vij

Articles

Nematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequency range 1 Hz to 10 MHz over a wide temperature range. The studied compound displays three nematic phases under cooling from the isotropic phase: ubiquitous nematic N; high polarizability NX; and ferroelectric nematic NF. Two collective processes were observed. The dielectric strength and relaxation frequency of one of the processes P2 showed a dependence on the thickness of the cell. The process P1 is …

Preface : Fruit And Vegetable Waste Utilization And Sustainability, Sachin A. Mandavgane, Ipsita Chakravarty, Amit Jaiswal

Books/Book Chapters

Fruits and vegetables are an important source of nutrition and a key element of a healthy balanced diet. Several organizations such as the World Health Organization (WHO), Food and Agriculture Organization of United Nations (FAO), and Food Health England suggest consuming more than 400 g of fruits and vegetables per day (roughly five portions per day) to improve overall health and reduce the risk of certain cardiovascular diseases and cancer; subsequently, consumption and production of fruits and vegetables are on the rise. The increased consumption/production of fruits and vegetables has resulted in huge quantities of waste (approximately 42% of the …

Investigation Of Oleic Acid As A Dispersant For Hydroxyapatite Powders For Use In Ceramic Filled Photo-Curable Resins For Stereolithography, Brendan Kennedy, Eamonn De Barra, Stuart Hampshire, Maura Kelleher

Articles

Stereolithography allows production of porous hydroxyapatite scaffolds for bone regeneration but is limited by the challenging rheology of ceramic filled resins. Oleic acid, a natural fatty acid, was applied in concentrations of 0.0–0.3 wt% to improve the rheological properties of HAp resins for the fabrication of solid cylinders and scaffolds by digital light processing (DLP) printing in a wiperless system. Bonding by chemisorption was confirmed by FTIR analysis. The powders were then incorporated into a photo-curable resin of 1–6 hexanediol diacrylate at 18–30 vol%. The shear viscosity and sedimentation rates of photocurable resins containing HAp powder decreased with increasing concentration …

Pro-Environmental Diversification Of Pasture-Based Dairy And Beef Production In Ireland, The United Kingdom And New Zealand: A Scoping Review Of Impacts And Challenges, Maria Markiewicz-Keszycka, Aileen Carter, Donal O'Brien, Maeve Henchion, Simon Mooney, Paul Hynds

Articles

Grass-fed dairy and beef products are valued by consumers for their unique nutrient profile, enhanced animal welfare and lower environmental footprint compared to conventional produce derived from animals reared indoors on higher volumes of concentrate feeds (O'Callaghan et al., Reference O'Callaghan, Vázquez-Fresno, Serra-Cayuela, Dong, Mandal, Hennessy, McAuliffe, Dillon, Wishart, Stanton and Ross2018; Moscovici Joubran et al., Reference Moscovici Joubran, Pierce, Garvey, Shalloo and O'Callaghan2021). For the current study, pasture-based production of dairy and beef is defined as a system within which cattle graze freely outdoors on green pasture for ≥6 months per year, using grazed grass as the primary feed …

Selection And Characterization Of Bacteriocinogenic Lactic Acid Bacteria From The Intestine Of Gilthead Seabream (Sparus Aurata) And Whiting Fish (Merlangius Merlangus): Promising Strains For Aquaculture Probiotic And Food Bio-Preservation, Sarah Cheriet, Sana Lenglitz, Amel Romdhani, Paul Hynds, Mohamed Salah Abbassi, Taofik Ghrairi

Articles

This study sought to evaluate the probiotic properties and the food preservation ability of lactic acid bacteria isolates collected from the intestines of wild marine fishes (gilthead seabream (Sparus aurata) (n = 60) and whiting fish (Merlangius merlangus) (n = 40)) from the Mediterranean sea in the area of Mostaganem city, Algeria. Forty-two isolates were identified as: Enterococcus durans (n = 19), Enterococcus faecium (n = 15), Enterococcus faecalis (n = 4), Lactococcus lactis subp. lactis (n = 3), and Lactobacillus plantarum (n = 1). All isolates showed inhibition to at least one indicator strain, especially against Listeria monocytogenes, Staphylococcus …

Color-Changing Reflection Hologram For Quality Assurance Of Therapeutic Ultrasound Systems, Tatsiana Mikulchyk, John Walsh, Jacinta Browne, Izabela Naydenova, Dervil Cody

Articles

The acoustic output of clinical therapeutic ultrasound equipment requires regular quality assurance (QA) testing to ensure the safety and efficacy of the treatment and that any potentially harmful deviations from the expected output power density are detected as soon as possible. A hologram, consisting of a reflection grating fabricated in an acrylate photopolymer film, has been developed to produce an immediate, visible, and permanent change in the color of the reconstructed hologram from red to green in response to incident ultrasound energy. The influence of the therapeutic ultrasound insonation parameters (exposure time, ultrasound power density, and proximity to the point …

The Development Of Optomechanical Sensors—Integrating Diffractive Optical Structures For Enhanced Sensitivity, Faolan Radford Mcgovern, Aleksandra Hernik, Catherine M. Grogan, George Amarandei, Izabela Naydenova

Conference Papers

The term optomechanical sensors describes devices based on coupling the optical and mechanical sensing principles. The presence of a target analyte leads to a mechanical change, which, in turn, determines an alteration in the light propagation. Having higher sensitivity in comparison with the individual technologies upon which they are based, the optomechanical devices are used in biosensing, humidity, temperature, and gases detection. This perspective focuses on a particular class, namely on devices based on diffractive optical structures (DOS). Many configurations have been developed, including cantilever- and MEMS-type devices, fiber Bragg grating sensors, and cavity optomechanical sensing devices. These state-of-the-art sensors …

The Proof Is In The Pudding – Using Perceived Stress To Measure Short-Term Impact In Initiatives To Enhance Gender Balance In Computing Education, Alina Berry, Sarah Jane Delany

Academic Posters Collection

The problem of gender imbalance in computing higher education has forced academics and professionals to implement a wide range of initiatives. Many initiatives use recruitment or retention numbers as their most obvious evidence of impact. This type of evidence of impact is, however, more resource heavy to obtain, as well as often requires a longitudinal approach. There are many shorter term initiatives that use other ways to measure their success.

First, this poster presents with a review of existing evaluation measures in interventions to recruit and retain women in computing education across the board. Three main groups of evaluation come …

Evaluation Of Gender-Based Differences In Primary School Maths Education: The Potential Of Digital Games, Maíra Amaral

Academic Posters Collection

Digital Game-Based Learning is shown to be a more effective instructional method than traditional instruction, however less effective than other technology-supported instruction according to Byun and Joung (2018). Regarding gender aspects, according to findings by Mclaren and colleagues in 2022, girls may learn more mathematics from digital learning games than boys. In their study, even reporting greater behavioural and cognitive engagement, boys did not learn more with the game than girls.

Using Machine Learning For Web Accessibility, Tlamelo Makati

Academic Posters Collection

This research will explore the potential of machine learning to enhance web accessibility. Web accessibility is typically defined in terms of Web Accessibility Guidelines (WCAG), which states that everyone should be able to perceive, operate, understand and interpret the web regardless of disability or use of assistive technology. We would like to consult digital accessibility experts through interviews and focus groups to understand the web accessibility auditing and remediation processes in detail, with a focus on web navigation. An important goal of this work is to establish development processes where all stakeholders can leverage machine-learning tools to produce more accessible …

Detecting Road Intersections From Satellite Images Using Convolutinal Neural Networks, Fatmaelzahraa Eltaher Ph.D, Luis Miralles-Pechuán, Jane Courtney, Susan Mckeever

Academic Posters Collection

The location of intersections is an important consideration for vulnerable road users such as People with Blindness or Visually Impairment (PBVI) or children. Route planning applications, however, do not give information about the location of intersections as this information is not available at scale. In this paper, we propose a deep learning framework to automatically detect the location of intersections from satellite images using convolutional neural networks. For this purpose, we labelled 7,342 Google maps images from Washington, DC, USA to create a dataset. This dataset covers a region of 58.98 km$^{2}$ and has 7,548 intersections. We then applied a …

Application Of The Two-Variable Model To Simulate A Multisensory Reaction-Time Task, Rebecca Brady, John Butler

Academic Posters Collection

To navigate the world in an efficient manner, the brain seamlessly integrates signals received across multiple sensory modalities. Behavioral studies have suggested that multisensory processing is a winner-take-all sensory response mechanism to some optimal combination of sensory signals. In addition, multiple sensory cues are not always beneficial with some studies showing maladaptive multisensory processing as an identifier of older adults prone to falls from age matched healthy controls.

A stalwart of modelling sensory decision-making is the work by (Wong &Wang, 2006) but to date almost all of this research has been focused on unisensory tasks. We extend the reduced two-variable …

Enhancing Health Data Representation For Older Adults: Unlocking Opportunities, Peterson Jean

Academic Posters Collection

The prevalence of off-the-shelf wearable devices increases the monitoring and measurement of critical physiological parameters like activity, sleep, heart rate, and blood pressure. However, the accessibility of health data representations poses challenges for older adults, who often struggle to understand the criticality of their own health data without assistance. This poster highlights the challenges older adults face in accessing their health data from wearable technologies, specifically focusing on data representations.

To address these challenges, it proposes a methodology that involves a heuristic evaluation of existing data representations with experts and accessibility studies with older adults using a mixed methods approach …

Computer Science Outreach To Inform Secondary School Students’ Perceptions Of Computer Science: Preliminary Findings, Karen Nolan, Roisin Faherty, Keith Quille, Keith Nolan, Amanda O'Farrell, Brett A. Becker

Academic Posters Collection

This poster describes a longitudinal K-12 outreach programme to promote Computer Science in Ireland, which ran over a three-year period from 2017- 2020. A pilot phase was conducted in the first year from 2017-2018 with 2900 students participating. The implementation phase began in 2018, when 7320 students participated across the 2018-2019 and 2019-2020 academic years. The programme consisted of a free onsite school delivery of a two-hour camp that introduced students to a range of Computing topics: addressing computing perceptions, introduction to coding, and exploration of computational thinking. Schools self-selected, and the programme reached a large number of schools with …

Investigating The Use Of Conversational Agents As Accountable Buddies To Support Health And Lifestyle Change, Ekaterina Uetova, Dympna O'Sullivan, Lucy Hederman, Robert J. Ross

Academic Posters Collection

The poster focuses on the role of conversational agents in promoting health and well-being. Results of the literature review indicate that negative emotions can hinder individuals from taking necessary actions related to their health. The study concludes that understanding and addressing emotional barriers is essential to facilitating early access to health services and improving well-being. The poster outlines plans to investigate motivation strategies, develop a prototype conversational agent based on user study insights and chat log data, and incorporate emotion regulation to effectively manage users' emotional experiences.

Improve Engagement With Full Labs And Motivated Students: Interactive Labs Via Low Stakes Assessment, Susan Mckeever, Patricia O'Byrne, Amanda O'Farrell

Academic Posters Collection

Poor engagement and attendance is an endemic problem at third level, particularly post covid. Our approach shows how the use of regular in-lab assessment and challenges can dramatically increase student participation and learning. Using three case studies, we demonstrate how we have successfully used this low-stakes assessment approach to improve student outcomes, across a range of modules.

Attention-Based Gender-Stereotype Detection, Manuela Nayantara, Sarah Jane Delany

Academic Posters Collection

Gender stereotypes are perceptions about the typical physical, emotional, and social characteristics of individuals. Unlike gender bias which can result in the systematic and unfair treatment of individuals based on their gender, gender stereotypes do not always perpetuate a negative impact. Hence, there is no solid definition that frames what is considered a gender-stereotype in text. In addition, there is also a lack of labelled gender-stereotype datasets. This has led to most of the work in literature being about gender bias and not gender stereotypes. Therefore, in our research, we frame a clear definition of what constitutes a gender-stereotype in …