Physical Sciences and Mathematics Commons^™

Mems Mobile Gis: A Spatially Enabled Fish Habitat Management System, Andrea Rizzini, Keith Gardiner, Michela Bertolotto, James Carswell

Conference papers

Spatially enabled computing can provide assistance to both web-based and mobile users by exploiting positional information and associated contextual knowledge. The Mobile Environmental Management System (MEMS) is a proof of concept prototype that has been developed in order to simplify administrative duties of biologists at the Department of Fisheries and Oceans (DFO), Canada. MEMS aims to deliver contextaware functionality aided by visualization, analysis and manipulation of spatial and attribute datasets. The resulting application delivers a set of functions and services that aids the DFO’s biologists in making everyday management decisions

Serious Gordon Using Serious Games To Teach Food Safety In The Kitchen, Brian Mac Namee, Pauline Rooney, Patrick Lindstrom, Andrew Ritchie, Frances Boylan, Greg Burke

Conference papers

This paper will describe the development of Serious Gordon, an interactive digital game developed to tech the basics of kitchen food safety to workers in industries dealing with food. The motivations driving the development of the game will be described as will the development process itself. An initial evaluation of the game, from both a technical and pedagogical point of view, will be presented as will conclusions on the viability of using a commercial game engine for the purpose of developing educational games.

To Evaluate The Effects Of The Introduction Of A Smoke-Free Environment On The Lung Function Of Bar Workers In Dublin, Michele Agnew

Masters

It has long been recognised that exposure to environmental tobacco smoke (ETS) causes respiratory and cardio-vascular disease. A ban, prohibiting smoking in the workplace, was sanctioned by the Irish government and came into effect on 29 March, 2004. Bar staff were an ideal group to study the health effects of the introduction of this ban. Methods Workers were recruited through their Trade Union, Mandate, and 81 participated in the pre-ban phase of testing between September 2003 and March 2004. They attend the Respiratory Laboratory in St. James’s Hospital and underwent lung function tests and measurement of exhaled carbon monoxide (CO). …

The Use Of Task Based Mood-Induction Procedures To Generate High Quality Emotional Assets, Brian Vaughan, Charlie Cullen, Spyros Kousidis, Yi Wang, Ciaran Mcdonnell, Dermot Campbell

Conference papers

Detecting emotion in speech is important in advancing human-computer interaction, especially in the area of speech synthesis. This poster details experimental procedures based on Mood Induction Procedure 4, using performance related tasks to engender natural emotional responses in participants. These tasks are aided or hindered by the researcher to illicit the desired emotional response. These responses will then be recorded and their emotional content graded to form the basis of an emotional speech corpus. This corpus will then be used to develop a rule-set for basic emotional dimensions in speech.

Icing Location Client, Seamus Rooney, Keith Gardiner, James Carswell

Articles

The ICiNG (Innovative Cities for Next Generation) project is researching a multi-modal, multi-access model of e-Government. It develops the concept of a “thin-skinned City” that will be sensitive to both the citizen and the environment through the use of mobile devices, universal access gateways, social software and environmental sensors. Intelligent infrastructure will enable a Public Administration Services layer and a Communities layer. Communities will interact with the infrastructure to avail of ICiNG services created by the administration, and will also create their own information-based services.

An Event-Driven Approach To Computerizing Clinical Guidelines Using Xml, Bing Wu, Essam Mansour, Kudakwashe Dube, Jianxin Li

Conference Papers

Clinical events form the basis of patient care practice. Their computerization is an important aid to the work of clinicians. Clinical guidelines or protocols direct clinicians and patients on when and how to handle clinical problems. Thus, clinical guidelines are an encapsulation of clinical events. Hence, an event-driven approach to computerizing the management of clinical guidelines is worthy of investigation. In our framework, called SpEM, the main clinical guideline management dimensions are specification, execution, and manipulation. This paper presents an event-driven approach, within the context of the SpEM framework, to manage clinical guidelines. The event-driven approach is based on the …

Newly Identified Vitamin K-Producing Bacteria Isolated From The Neonatal Faecal Flora, Gordon Cooke, John Behan, Mary Costello

Articles

Fat-soluble vitamin K is an essential component of the blood clotting process. Menaquinones are the naturally occurring form of vitamin K identified in bacteria. Lipid extracts were made from three bacteria originally isolated from the human neonatal gut and identified as Enterobacter agglomerans, Serratia marcescens and Enterococcus faecium. Following preparative thin layer chromatography (TLC), the lipid extracts were subjected to liquid chromatography-mass spectrometry (LC-MS) analysis. Peak analysis of the LC-MS data showed that the three bacteria produce various forms of menaquinone.

Implications Of Mass Education On Chemistry Higher Education, Christine O'Connor

Articles

The following paper discusses the implications of government policy for widening access and participation in third level institutes. The increase in ‘non-traditional’ students has been widely recognised on an international scale; however, some issues of inequality still exist. The ‘struggles’ associated with widening participation and the creation of a ‘new’ student type are discussed, with particular reference to chemistry education. A change is needed with regard to the pedagogical approach taken by staff in order to cater for a diverse student body comprising a broad range of learner types, and this must be supported both at departmental and institutional levels. …

The Synthesis Of Zinc Oxide By Direct And Indirect Methods, Grainne Duffy

Masters

The synthesis of zinc oxide through three routes was investigated; carboxylic acid chelation, polymer assisted synthesis in an alcoholic medium and slow thermolysis of precursor. In the case of carboxylic acid chelation, it was determined that the rate at which the precursor is formed has a significant effect on the quality of zinc oxide particles produced. Investigation of the effect of concentration, pH and species of chelating agent used on the purity and structure of product was undertaken. Examination of the composition and morphology of materials produced revealed the presence of single-crystalline spheres, the packing density and aggregation morphology of …

Using Sketches And Knowledge Bases For Geo-Spatial Image Retrieval, Michela Bertolotto, James Carswell, E Mcloughlin, D O'Sullivan, C Wilson

Articles

This paper presents research in the field of knowledge management for geo-spatial imagery including scanned aerial photos and satellite images. We have developed a web-based system that allows users to query a database of images not only using metadata, but also drawing sketches of configurations of objects they are interested in as well as inputting textual descriptions of their intended task. Our system integrates case-based reasoning techniques to form a knowledge base from previously issued queries that can be exploited to improve future query processing and to build organizational memory through experience capture. The effective design and implementation of a …

Two Way Diffusion Model For The Recording Mechanism In A Self-Developing Dry Acrylamide Photopolymer, Suzanne Martin, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Vincent Toal

Conference Papers

In our most recent study [1] diffusion constants were measured in the simplified monoacrylamide version of a dry acrylamide based photopolymer holographic recording material developed in the Centre for Industrial and Engineering Optics. In this paper we report diffusion constants for the commonly used photopolymer formulation, which also contains the crosslinker bisacrylamide. A physical model for the recording mechanism is proposed which explains the two way diffusion observed in both systems, and is in agreement with much of the previously observed behaviour of the material, particularly in regard to dependence of diffraction efficiency growth on spatial frequency and persistence of …

Characterization Of An Acrylamide Based Photopolymer For Fabrication Of Liquid Crystal Devices, Pavani Kotakonda, Izabela Naydenova, Suzanne Martin, Vincent Toal

Conference Papers

Photopolymers are increasingly interesting as new materials for the fabrication of electro optical liquid crystal devices. Photoinduced surface relief gratings in dry, self developing acrylamide based photopolymers can be used to align liquid crystals (LCs) as an alternative to the rubbing technique. These optically recorded surface relief patterns can be used to fabricate electro-optical switchable LC Bragg gratings. An investigation of the dependence of photoinduced surface relief gratings on recording intensity and thickness of the photopolymer layer is reported. The surface relief gratings were filled with E7 LCs and a switchable LC diffraction grating was fabricated.

Potential Of Vibrational Spectroscopy In The Diagnosis Of Human Tumours., Eoghan O'Faolain

Doctoral

Just fewer than 20,000 people are annually diagnosed with some form of cancer in Ireland and one in three people are likely to contract some form of cancer by age 74. With the number of cases increasing at an annual rate of 2%, the early detection and treatment of cancer is becoming increasingly important. Both IR and Raman spectroscopy offer the potential for real time, quantitative detection of cancer and even precancer. This study investigates the potential of Raman and Fourier transform infrared, both benchtop and synchrotron spectroscopies for the detection of cervical cancer. The tissue was classified and its …

A Critical Appraisal Of The Opportunities Currently Available For A More Energy Conscious Approach To Residential Building In Ireland, John Mcdonagh, Louis Gunnigan

Conference papers

This paper focuses on the particular advantages which off-site housing construction has over the more traditional methods of building especially where the efficient use and conservation of energy is concerned. It will explain why modern innovative methods of house construction not only have a clear advantage environmentally (big reductions in CO2 emissions) but also deliver substantial benefits to the end user or householder especially in the form of lower energy bills.

The ecological argument for off-site systems is a very powerful one but on its own is still unlikely to be the prime driver for widespread implementation. That growth is …

$H$-Vectors Of Generalized Associahedra And Noncrossing Partitions, Colum Watt, Thomas Brady, Christos A. Athanasiadis, Jon Mccammond

Articles

A uniform proof is given that the entries of the $h$-vector of the cluster complex $\Delta (\Phi)$, associated by S. Fomin and A. Zelevinsky to a finite root system $\Phi$, count elements of the lattice $\mathbf{L}$ of noncrossing partitions of corresponding type by rank. Similar interpretations for the $h$-vector of the positive part of $\Delta (\Phi)$ are provided. The proof utilizes the appearance of the complex $\Delta (\Phi)$ in the context of the lattice $\mathbf{L}$ in recent work of two of the authors, as well as an explicit shelling of $\Delta (\Phi)$.

The Nonlinear Amplification Of Magnetic Fields By Cosmic Rays At Supernova Remnant Shocks, Brian Reville, Peter Duffy, Stephen O'Sullivan

Conference papers

A central problem in the theory of cosmic ray acceleration at supernova shock fronts is the generation of turbulent magnetic fields needed to scatter particles across a shock front. In this paper we build on previous studies [1], [2] into the effect of streaming cosmic rays produced by the outer shocks of supernova remnants on the stochastic component of the magnetic field. A three dimensional, MHD code has been constructed which demonstrates the nonlinear growth of the turbulent field.

Characterization Of An Acrylaminde Based Photopolymer For Fabrication Of Liquid Crystal Devices, Pavani Kotakonda

Conference Papers

Photopolymers are increasingly interesting as new materials for the fabrication of electro optical liquid crystal devices. Photoinduced surface relief gratings in dry, self developing acrylamide based photopolymers can be used to align liquid crystals (LCs) as an alternative to the rubbing technique. These optically recorded surface relief patterns can be used to fabricate electro-optical switchable LC Bragg gratings. An investigation of the dependence of photoinduced surface relief gratings on recording intensity and thickness of the photopolymer layer is reported. The surface relief gratings were filled with E7 LCs and a switchable LC diffraction grating was fabricated.

Measured Stark Widths And Shifts Of The Neutral Argon Spectral Lines In 4s–4p And 4s–4p′ Transitions, Vladimir Milosavljevic, Albert R. Ellingboe, Stevan Djenize

Articles

We investigate the Stark widths (W) and the shift (d), of the seven neutral argon (Ar I) spectral lines from the 4s–4p and 4s–4p′ transitions. The line shapes are measured in a linear, low-pressure, optically thin pulsed arc discharge at about 16 000 K electron temperature (T) and about 7.0 × 10²² m^{− 3} electron density (N). The new data separates the electron width (W_e) and ion width W_i from the total Stark width (W_t), as well the separation of electron total Stark …

Implications Of Mass Education On Chemistry Higher Education, Christine O'Connor

Conference Papers

The following paper discusses the implications of government policy on widening of participation at third level institutes. The increase in ‘non-traditional’ students has been widely recognised on an international scale; however some inequality issues still exist. The ‘struggles’ associated with widening of participation and creating a ‘new’ student type is discussed in particular reference to chemistry education. A change in mindset of staff on their pedagogical approach to cater for a diverse student body with a broad range of learner types is required. This must be supported from a departmental and institutional level. A look at the literature to investigate …

Spirobicyclic Diamines 1: Synthesis Of Proline-Derived Spirolactams Via Thermal Intramolecular Ester Aminolysis, Fintan Kelleher, Sinead Kelly

Articles

Proline derived [4.4]-spirolactams have been synthesised in good yields by a reductive-amination reaction followed by thermal cyclisation of the resulting amine onto the proline ester group in refluxing toluene. The synthesis of the corresponding [4.5]-spirolactams by the same method gave much reduced yields.

Spirobicyclic Diamines 2: Synthesis Of Homochiral Diastereoisomeric Proline Derived [4,4]-Spirolactams, Fintan Kelleher, Sinead Kelly

Articles

L-Proline derived diastereoisomeric [4.4]-spirolactams have been prepared by a reductive-amination reaction of (R)- or (S)-alanine methyl ester followed by thermal cyclisation of the resulting amine onto the proline ester group in refluxing toluene. Under similar conditions (R)- or (S)-phenylalanine methyl ester gave no cyclisation products, while R- or S-a-methylbenzylamine required treatment with NaNH₂ in refluxing toluene to induce cyclisation giving diastereoisomeric [4.4]-spirolactams

The Sonic Representation Of Mathematical Data, Charlie Cullen

Doctoral

Conveying data and information using non-speech audio is an ever growing field of research. Existing work has been performed investigating sonfication and its applications, and this research seeks to build upon these ideas while also suggesting new areas of potential. In this research, initial work focused on the sonification of DNA and RNA nucleotide base sequences for analysis. A case study was undertaken into the potential of rhythmic parsing of such data sequences, with test results indicating that a more effective method of representing data in a sonification was required. Sonification of complex data such as DNA and RNA was …

A Computational Model Of The Referential Semantics Of Projective Prepositions, John D. Kelleher, Josef Van Genabith

Conference papers

In this paper we present a framework for interpreting locative expressions containing the prepositions in front of and behind. These prepositions have different semantics in the viewer-centred and intrinsic frames of reference (Vandeloise, 1991). We define a model of their semantics in each frame of reference. The basis of these models is a novel parameterized continuum function that creates a 3-D spatial template. In the intrinsic frame of reference the origin used by the continuum function is assumed to be known a priori and object occlusion does not impact on the applicability rating of a point in the spatial template. …

Feature Based And Feature Free Textual Cbr: A Comparison In Spam Filtering, Sarah Jane Delany, Derek Bridge

Conference papers

Spam filtering is a text classification task to which Case-Based Reasoning (CBR) has been successfully applied. We describe the ECUE system, which classifies emails using a feature-based form of textual CBR. Then, we describe an alternative way to compute the distances between cases in a feature-free fashion, using a distance measure based on text compression. This distance measure has the advantages of having no set-up costs and being resilient to concept drift. We report an empirical comparison, which shows the feature-free approach to be more accurate than the feature-based system. These results are fairly robust over different compression algorithms in …

Interface Design Requirements For Playing Pong With A Single Switch Device, Brian Mac Namee, John Gilligan

Conference papers

Motivated by a desire for increased accessibility in digital games, in this paper we consider the design requirements for an interface to a variation of the game Pong for single-switch users. We consider the issues in the design of accessible interfaces for games and propose a set of interface configurations for playing Pong, using this as a proof of concept for more elaborate games.

Proximity In Context: An Empirically Grounded Computational Model Of Proximity For Processing Topological Spatial Expression., John D. Kelleher, Geert-Jan Kruijff, Fintan Costello

Conference papers

The paper presents a new model for context-dependent interpretation of linguistic expressions about spatial proximity between objects in a natural scene. The paper discusses novel psycholinguistic experimental data that tests and verifies the model. The model has been implemented, and enables a conversational robot to identify objects in a scene through topological spatial relations (e.g. ''X near Y''). The model can help motivate the choice between topological and projective prepositions.

Incremental Generation Of Spatial Referring Expressions In Situated Dialogue, John D. Kelleher, Geert-Jan Kruijff

Conference papers

This paper presents an approach to incrementally generating locative expressions. It addresses the issue of combinatorial explosion inherent in the construction of relational context models by: (a) contextually defining the set of objects in the context that may function as a landmark, and (b) sequencing the order in which spatial relations are considered using a cognitively motivated hierarchy of relations, and visual and discourse salience.

Bluetooth Assassin: A Location-Based Game For Mobile Devices, Miao Wang, Brian Mac Namee

Conference papers

This short paper will describe Bluetooth Assassin, a location-based game developed for mobile devices.

Impact Of Dietary Carotenoid Deprivation On Macular Pigment And Serum Concentrations Of Lutein And Zeaxanthin, James Loughman, John Nolan, Stephan Beatty

Articles

No abstract provided.

A Chloride Selective Calix[4]Arene Optical Sensor Combining Urea Functionality With Pyrene Excimer Transduction, Benjamin Schazmann, Dermot Diamond

Articles

A neutral 2-site chloride selective compound has been developed (3), based on a 1,3- alternate tetrasubstituted calix[4]arene providing a preorganised supramolecular scaffold. The resultant supramolecular cavity is amongst the first to combine urea functional groups bridged with single methylene spacers to pyrene moieties. It combines a naturally and synthetically proven H-bonding system with the elegant ratiometric fluorescent signalling properties of an intramolecular pyrene excimer system, triggered by conformational changes upon anion coordination. The excimer emission of 3 is quenched, with a simultaneous rise in the monomer emission solely by the chloride anion amongst a wide variety of anions tested. 3 …