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Optimization Of Starting Time And Period Of Induction And Inducer Concentration In The Production Of The Restriction Enzyme Ecori From Recombinant Escherichia Coli 294, Candan Yildir Tamerler, Z. İlsen Önsan, Betül Kirdar Jan 1998

Optimization Of Starting Time And Period Of Induction And Inducer Concentration In The Production Of The Restriction Enzyme Ecori From Recombinant Escherichia Coli 294, Candan Yildir Tamerler, Z. İlsen Önsan, Betül Kirdar

Turkish Journal of Chemistry

Induction parameters including inducer concentration, period of induction and the cell concentration at which inducer is to be added to the fermentation broth were optimized in order to increase the yield of the {\em Eco}RI restriction endonuclease isolated from recombinant {\em E. coli}. Bacterial cells harboring the plasmid pPG430 containing {\em Eco}RI endonuclease and the methylase genes under the control of {\em lac} promoter were used in the experiments where induction was accomplished by using lactose isopropyl-$\beta$-D-thiogalactoside (IPTG). An IPTG concentration of 0.1mM, the late exponential phase of growth (at an optical density of 1.2 at 595 nm) and an …


Removal Of Water-Soluble Cationic Dyes With Trisyl Silicas, Erdener Karadağ, Dursun Saraydin, Fatma Aydin Jan 1998

Removal Of Water-Soluble Cationic Dyes With Trisyl Silicas, Erdener Karadağ, Dursun Saraydin, Fatma Aydin

Turkish Journal of Chemistry

In this study, the adsorption of certain water-soluble cationic dyes, (basic blue 9, basic blue 12, basic blue 17, brilliant cresyl blue, janus green B, basic green 4, basic violet 1, basic violet 3, and thionin) onto TriSyl silicas by batch adsorption at 25^oC was investigated. In the adsorption experiments, Langmuir type adsorption in the Giles classification system was found. Binding parameters such as the initial binding constant (K$_i$), the equilibrium binding constant (K), monolayer coverage(n), site-size(u), maximum fractional occupancy ($\hat{\theta}$), and the thermodynamic parameter free energy of adsorption $(\Delta G)$ were calculated for TriSyl silica and cationic dye systems …


Reactions Of 4-Amino-4,5-Dihydro-1h-1,2,4-Triazol-5-Ones And 4-Amino-4h-1,2,4-Triazoles With Some Carboxylic Acid Anhydrides, Şule Bahçeci̇, Nurhan İnce, Asun İki̇zler Jan 1998

Reactions Of 4-Amino-4,5-Dihydro-1h-1,2,4-Triazol-5-Ones And 4-Amino-4h-1,2,4-Triazoles With Some Carboxylic Acid Anhydrides, Şule Bahçeci̇, Nurhan İnce, Asun İki̇zler

Turkish Journal of Chemistry

3-Alkyl(Aryl)-4-tetrachlorophthalimido-4,5-dihydro-1H-1,2,4-triazol-5-ones (2) and 3-alkyl(aryl)-4-(1,8-naphthalimido)-4,5-dihydro-1H-1,2,4-triazol-5-ones (3) were synthesized from the reactions of 3-alkyl(aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5-ones (1) with tetrachlorophthalic anhydride and 1,8-naphthalic anhydride, respectively. In addition, the reactions of 4-amino-4H-1,2,4-triazoles (4) with succinic anhydride and phthalic anhydride were studied.


Cu And Pb Adsorption On Some Bentonitic Clays, Oğuz İnel, Fehmi Albayrak, Ayşgül Aşkin Jan 1998

Cu And Pb Adsorption On Some Bentonitic Clays, Oğuz İnel, Fehmi Albayrak, Ayşgül Aşkin

Turkish Journal of Chemistry

Cu$^{2+}$ and Pb$^{2+}$ adsorption isotherms were measured on some clay samples obtained from various regions of Turkey. Also specific surface areas of clays were determined from adsorption data of ortho-phenanthroline(OP). The adsorptions of ions and OP were studied using the batch equilibration technique as a function of adsorbate concentration. The adsorption data, over the whole range of concentrations used, follow the Langmuir adsorption isotherm. The retention capacities of the adsorbates and the cation exchange capacities of the clays were determined. Plots of K$_d$, the distribution coefficient of ions between the solid and solution phases, vs. $\Gamma$, the surface density of …


The Effectof Lanthanum And Barium Additives On The Thermal Stabilization Of \Gamma-Al_2o_3, A. İnci İşli̇, A. Erhan Aksoylu, Z. İlsen Önsan Jan 1998

The Effectof Lanthanum And Barium Additives On The Thermal Stabilization Of \Gamma-Al_2o_3, A. İnci İşli̇, A. Erhan Aksoylu, Z. İlsen Önsan

Turkish Journal of Chemistry

The effect of La and Ba additives on the thermal stabilization of $\gamma$-Al$_2$O$_3$ was investigated through total-surface-area measurements. The parameters considered were additive content, calcination temperature, and calcination period. The effect of precalcination was also studied. It was found that thermal stabilization caused by 3 wt\% La and Ba is superior to 6 wt \% La or Ba, and the positive effect of 3 wt\% La and 3 wt\% Ba are almost identical. The nearly threefold increase in the total surface area of 3 wt\% La or Ba doped samples calcined above the $\gamma - \alpha$ phase-transition temperature indicates that …


Synthesis Of New Bisamidoxime Ligands And Their Monocharged Metal Complexes, Niyazi Biçak, Tülay Atay Jan 1998

Synthesis Of New Bisamidoxime Ligands And Their Monocharged Metal Complexes, Niyazi Biçak, Tülay Atay

Turkish Journal of Chemistry

This paper describes the synthesis of two new bisamidoxime ligands with dithioether connecting groups. The ligands were obtained from ethane dithiol in two steps; i) cyanoalkylation ii) oximation with hydroxylamine. Cyanoalkylation of ethanedithiol was carried out by condensing with chloro acetonitrile and base-catalysed addition of acrylonitrile, yielding bis(cyanomethylthio) ethane and bis(cyanoethyl thio) ethane, respectively. Upon subsequent oximation with hydroxylamine, these bisnitrile compounds gave corresponding bis(amidoxime) ligands in reasonable yields. The ligands behave as tetradentate ligands and on interaction with Cu(II), Ni(II), Co(II) chlorides produces monocharged metal complexes in a [ML]$^+$Cl$^-$ composition.


Gas Chromatography In The Low Concentration Determination Of Nitrous Oxide And Volatile Anaesthetics, Ahmet Uyanik Jan 1998

Gas Chromatography In The Low Concentration Determination Of Nitrous Oxide And Volatile Anaesthetics, Ahmet Uyanik

Turkish Journal of Chemistry

A previously reported single-column gas chromatographic separation method was modified for dual-detection gas chromatography (TCD+FID) and evaluated for the low concentration analysis of volatile anaesthetics (halothane, isoflurane) and nitrous oxide. It was found that no serious problem occurs in the determination of volatile anaesthetics with FID ($


Crystal Structure Of Dichlorodiaquabis-(P- Dimethylaminobenzaldehyde)Manganese(Ii), Veysel T. Yilmaz, Turan K. Yazicilar, Halis Ölmez, R. Alan Howie Jan 1998

Crystal Structure Of Dichlorodiaquabis-(P- Dimethylaminobenzaldehyde)Manganese(Ii), Veysel T. Yilmaz, Turan K. Yazicilar, Halis Ölmez, R. Alan Howie

Turkish Journal of Chemistry

The crystal structure of dichlorodiaquabis-($p$-dimethylaminobenzaldehyde)manganese(II), [MnCl$_2$(OH$_2$)$_2$(C$_9$H$_{11}$NO)$_2$], was determined from X-ray intensity data. The structure consists of the isolated molecules of the complex. The central Mn atom in the complex is coordinated by txo $p$-dimethylaminobenzaldehyde and two water molecules and also two chlorine atoms, resulting in a distorted octahedral environment. The same molecules or ions occupy {\it trans} positions. The crystal structure is stabilized by weak hydrogen bonds present between the isolated molecules.


Synthesis And Characterization Of Amorphous-Liquid Crystalline Poly(Vinyl Ether) Block Copolymers, İ. Ersin Serhatli, Müge Serhatli Jan 1998

Synthesis And Characterization Of Amorphous-Liquid Crystalline Poly(Vinyl Ether) Block Copolymers, İ. Ersin Serhatli, Müge Serhatli

Turkish Journal of Chemistry

A new series of amorphous-liquid crystalline poly(vinyl ether) block copolymers was synthesized using living cationic polymerization and free-radical polymerization techniques. Vinyl ether monomer was polymerized using a trifluoromethane sulfonic acid and methyl triflouoromethanesulfonate/tetrahydrothiophene initiator system in dichloromethane at -18^oC, and quantitatively terminated with labile azo compounds in order to obtain poly(vinyl ether) with well-defined molecular weight and end groups. This polymer was used in a subsequent blocking step in which azo groups were decomposed at 80^oC in the presence of methyl methacrylate and styrene monomer. In both copolymers, blocks of different chemical composition were segregated in the solid and melt-phase …


Potential Utilization Of Fusel Oil: A Kinetic Approach For Production Of Fusel Oil Esters Through Chemical Reaction, Zeki Küçücük, Kadim Ceylan Jan 1998

Potential Utilization Of Fusel Oil: A Kinetic Approach For Production Of Fusel Oil Esters Through Chemical Reaction, Zeki Küçücük, Kadim Ceylan

Turkish Journal of Chemistry

Fusel oil is a by-product of the distillation of ethyl alcohol from the fermentation of molasses and contains mainly C3-C5 alcohols. Acetic acid and butyric acid esters of its major alcohol components have economic value as chemicals for flavor and fragrance manufacturing. This study presents some data regarding the uncatalyzed esterification of fusel oil with acetic acid, propionic acid and butyric acid. The reactions were carried out at two temperatures, i.e., $45^{\circ}$C and under the reflux conditions ($80-85^{\circ}$C). The composition of raw fusel oil and the reaction mixtures were determined by gas chromatography. The reaction rate constants for the formation …


Electrochemical Polymerization And Analysis Of Some Aniline Derivatives, Bekir Sari, Muzaffer Talu Jan 1998

Electrochemical Polymerization And Analysis Of Some Aniline Derivatives, Bekir Sari, Muzaffer Talu

Turkish Journal of Chemistry

In this study, conductive homopolymers of o-chloroaniline, p-bromoaniline and N-methylaniline were synthesized electrochemically in perchloric acidic solution and their properties were analyzed. Initially, the maximum oxidation potential values of these monomer solutions were determined by Cyclic Voltammetry (CV). Their conductive polymers were then synthesized under a nitrogen atmosphere using a potentiostat. FTIR spectra were taken in order to analyze the structural properties of the resulting polymers. Thermogravimetric analysis (TGA) was conducted and surface micrographs were taken by a Scanning Electron Microscope (SEM). The conductivity levels of the polymers were determined by the Four Probe technique. Magnetic properties of the samples …


Electron Spectroscopy For Material Characterization, Ş. Süzer Jan 1998

Electron Spectroscopy For Material Characterization, Ş. Süzer

Turkish Journal of Chemistry

Basic principles of the two electron spectroscopic techniques, the x-ray photoelectron spectroscopy, XPS, and the Auger electron spectroscopy, AES, are given. Their utilization in material characterization are introduced through examples with application of these techniques to various surface related problems.


Fatty Acid Composition And Cholesterol Content Of Some Turkish Fish Species, Sedat İmre, Serap Sağlik Jan 1998

Fatty Acid Composition And Cholesterol Content Of Some Turkish Fish Species, Sedat İmre, Serap Sağlik

Turkish Journal of Chemistry

It is well known that fish lipids are effective against cardiovascular diseases due to their high contents of polyunsaturated omega-3 (n-3) fatty acids. In order to determine a suitable fish diet, the fatty acid compositions and total lipid and cholesterol contents of 9 common fish species obtained from the central fish market in Ğstanbul were determined. Palmitic (C-16:0) and oleic acid (C-18:1) were the predominant saturated and monounsaturated fatty acids. The predominant polyunsaturated fatty acids were eicosapentaenoic (C-20:5) acid and docosahexaenoic (C-22:6) acid. The amounts of cholesterol in fish lipids did not differ significantly. Sardine ({\it Sardina pilchardus}) and mackerel …


Voltammetric Determination Of Thioridazine Hydrochloride, İnci Bi̇ryol, Saadet Dermi̇ş Jan 1998

Voltammetric Determination Of Thioridazine Hydrochloride, İnci Bi̇ryol, Saadet Dermi̇ş

Turkish Journal of Chemistry

This study describes the optimal conditions for the determination of Thioridazine HCl (Tz-HCl) in 0.2 M sulphuric acid by voltammetry using ruthenium (Ru), platinum (Pt) and glassy carbon (GC) electrodes. A new and sensitive method is described for electrochemical determination of Tz-HCl in the concentration range $5.10^{-5} - 10^{-3}$ M (20.35-407 $\mu$gml$^{-1}$); $6.10^{-4} - 10^{-2}$ M (244.2 - 4070 $\mu$gml$^{-1}$); $10^{-4} - 10^{-3}$ M (40,7 - 407 $\mu$gml$^{-1}$), with Ru, Pt and glassy carbon electrodes, respectively. The method was applied successfully to the determination of Tz-HCl in pure form or incorporated in their representative pharmaceutical preparations. The precision of the …


Polarographic Studies On The Kinetics Of The Electrode Reaction Of 4-Benzoyl-1,5 Diphenyl Pyrazole-3-Carboxylic Acid, M. Veri̇rşen, S. Erturan Jan 1998

Polarographic Studies On The Kinetics Of The Electrode Reaction Of 4-Benzoyl-1,5 Diphenyl Pyrazole-3-Carboxylic Acid, M. Veri̇rşen, S. Erturan

Turkish Journal of Chemistry

The polarographic behavior of 4-Benzoyl-1,5 diphenyl pyrazole-3- Carboxylic acid (BDPPCA) in aqueous ethanol solution (76 \% v/v) at 25^oC was studied as a function of pH using Mcl buffer solution. One well-defined wave was obtained in the pH range of 3.3-5.4. This wave, corresponding to two electron reduction processes, was irreversible and diffusion controlled. However, in the pH range of 5.4-7.4 a single reversible and diffusion-controlled wave involving two electrons resulted. The kinetic parameters $(n_a, k^o_{f,h})$ were calculated by Koutecky's method. A tentative mechanism was put forward for the reduction process of depolarizer. Furthermore, the effects of different supporting electrolytes …


Determination Of Structure-Toxicity Relationship Of Amphiprotic Compounds By Means Of The Inhibition Of The Dehydrogenase Activity Of Pseudomonas Putida, Ş. Gül, D. Öztürk Jan 1998

Determination Of Structure-Toxicity Relationship Of Amphiprotic Compounds By Means Of The Inhibition Of The Dehydrogenase Activity Of Pseudomonas Putida, Ş. Gül, D. Öztürk

Turkish Journal of Chemistry

Aliphatic and aromatic alcohols are amphiprotic compounds which have both polar and nonpolar parts in their structure. These compounds were studied with respect to the nonreactive toxic effects on the microorganism {\it Pseudomonas putida}. The toxicity of these chemicals to aerobic bacterium {\it P. putida} was measured in terms of inhibition of dehydrogenase activity. The test results, expressed as concentration of chemicals 50\% effective in inhibition (IC$_{50}$), were correlated with their physicochemical properties such as aqueous solubility (S) and octanol-water partition coefficient (P).


Comparison Of Different Production Processes For Bioethanol, B. Çaylak, Fazilet Vardar Sukan Jan 1998

Comparison Of Different Production Processes For Bioethanol, B. Çaylak, Fazilet Vardar Sukan

Turkish Journal of Chemistry

In this study, ethanol was produced with the microorganism {\em Saccharomyces cerevisiae} by using sucrose as a substrate. Batch processes were tested by using the same substrate, microorganism and medium composition. {\em Saccharomyces cerevisiae}, used in the free form in the first group of experiments, was immobilized by different methods. In the second group of experiments agar, sponge and a natural material called luffa cylindrica fiber were used as support materials. The batch processes with free and immobilized microorganisms were compared with respect to efficiency and yield.


The Effectof Temperature On The Dynmaic Viscosity Of Acetone Sunflower-Seed Oil Mixtures, Hüseyin Topallar, Yüksel Bayrak Jan 1998

The Effectof Temperature On The Dynmaic Viscosity Of Acetone Sunflower-Seed Oil Mixtures, Hüseyin Topallar, Yüksel Bayrak

Turkish Journal of Chemistry

The effect of acetone on the dynamic viscosity of sunflower-seed oil was studied under a dynamic heating regime at temeparuters ranging from 25^oC to 50^oC at 5^oC intervals. Acetone dramatically reduced the viscosity of sunflower-seed oil. The reduction of viscosity was far less with further addition of acetone. A linear relationship was found between the density of sunflower-seed oil and temperature. The influence of a solvent on the density of the sunflower-seed oil/acetone solution can be accounted for by the mixing theory of ideal solutions, whereas the effect of temperature on the dynamic viscosity of the oil solution is best …


Further Studies On The Reaction Of Unsaturated Acids With O-Phenylenediamine And 4-Substituted O-Phenylenediamines In Acid Medium, Mashooda Hasan, Shagufta Munawar, Naeema Khan, Zahida Maqbool Jan 1998

Further Studies On The Reaction Of Unsaturated Acids With O-Phenylenediamine And 4-Substituted O-Phenylenediamines In Acid Medium, Mashooda Hasan, Shagufta Munawar, Naeema Khan, Zahida Maqbool

Turkish Journal of Chemistry

Condensation of methylcrotonic acid with 4-chloro-o-phenylenediamine in 4N HCl yielded 5-chloro-2-(1-isobutenyl)benzimidazole and 7-chloro-4, 4-dimethyl-1,3,4,5-tetrahydro-2H-1,5-benzodiazepin-2-one. Methacrylic acid when condensed with o-phenylenediamine in 4N HCl yielded the already reported 3-methyl-1,2,4,5-tetrahydro-2H-1,5-benzodiazepin-2-one and 2(2-propenyl)benzimidazole. Condensation of methacrylic acid with 4-chloro-o-phenylenediamine in 4N HCl yielded 5-chloro-2(2-propenyl)benzimidazole. The structures of all the purified compounds were confirmed with the help of mass and $^1$H NMR spectral analysis.


Solvent Extraction Of La^{3+} Withethylenediamine-N,N'-Ditetradecyl-N,N'-Diacetic Acid(Eddat) In Dichloromethane, Mürüvvet Yurdakoç, Halil Hoşgören Jan 1998

Solvent Extraction Of La^{3+} Withethylenediamine-N,N'-Ditetradecyl-N,N'-Diacetic Acid(Eddat) In Dichloromethane, Mürüvvet Yurdakoç, Halil Hoşgören

Turkish Journal of Chemistry

Ethylenediamine-N,N'-ditetradecyl-N,N'-diacetic acid (EDDAT) was synthesized for the solvent extraction of La$^{3+}$. EDDAT was prepared from ethylenediamine-N,N'-diacetic acid (EDDA) and tetradecyl bromide in a basic n-amylalcohol-ethanol-water solvent system. The structure of this new extracting reagent was identified according to spectroscopic data, i.e. $^{13}$C NMR, $^1$H NMR, and elemental analysis results. The solvent extraction of La$^{3+}$ with EDDAT in dichloromethane was studied as a function of parameters of the aqueous and organic phases. The optimal extraction conditions were determined. The extraction yield increased with a decrease in hydrogen ions in the aqueous phase. Stripping of the La$^{3+}$ loaded organic phase was achieved …


Separation Of Molybdenum, Vanadium And Nickel By Liquid-Liquid Extraction, T. Coşar, R. Zi̇yadanoğullari Jan 1998

Separation Of Molybdenum, Vanadium And Nickel By Liquid-Liquid Extraction, T. Coşar, R. Zi̇yadanoğullari

Turkish Journal of Chemistry

Elements in the ash of asphaltites that is used in thermal central for power generation units are Mo, V, U, Ti and Ni. The main goal of this study was to separate molybdenum, vanadium and nickel from the aqueous solution. The quantities of the above elements in solution were in the range of 50-80 ppm. The separate these elements from solution, the liquid-liquid extraction method was applied to samples. Alamine 336 was used as extractant. During the reduction-oxidation processes, single and multiple extraction methods were applied to the solution in combination. The quantities of molybdenum, vanadium and nickel in the …


Potentiometric Investigation Of The Effects Of Several Substituents On The Basicity Of Benzilidene-O-Hydroxyaniline, Esma Kiliç, Orhan Atakol, E. Canel, Zehra Ali̇beşeoğlu, Turgut Gündüz, Fitnat Köseoğlu Jan 1998

Potentiometric Investigation Of The Effects Of Several Substituents On The Basicity Of Benzilidene-O-Hydroxyaniline, Esma Kiliç, Orhan Atakol, E. Canel, Zehra Ali̇beşeoğlu, Turgut Gündüz, Fitnat Köseoğlu

Turkish Journal of Chemistry

Chloro-, bromo-, iodo-, nitro-, methoxy- and hydroxy-substituted benzilidene-o-hydroxyaniline were prepared in order to investigate the effects of substituents on the basicity of benzilidene-o-hydroxyaniline. For each substituent, three isomers -- ortho, meta and para -- were synthesised. Schiff bases were titrated potentiometrically with perchloric acid in nitrobenzene solvent at $25^{\circ}$C. All compounds gave well-shaped titration curves, from which half-neutralisation potentials were calculated. The trend in the values of half-neutralisation potentials of Schiff bases were explained in terms of the nature of the substituents. The applicability of the Hammett equation to the effect of substituents in Schiff bases in nitrobenzene solvent was …


On The Türker Angles In The Theory Of Total \Pi-Electron Energy, Ivan Gutman Jan 1998

On The Türker Angles In The Theory Of Total \Pi-Electron Energy, Ivan Gutman

Turkish Journal of Chemistry

The Türker angles $\theta, \alpha$ and $\beta$ are quantities invented by Lemi Türker, and are used in the theory of total $\pi$-electron energy $(E)$ of unsaturated conjugated hydrocarbons. We report here expressions for $\theta, \alpha$ and $\beta$ in terms of $E$ and the parameters $n$ (= half the number of carbon atoms) and $e$ (= the number of carbon-carbon bonds). The forms of these expressions are remarkably similar. Numerical calculation performed on a representative set of benzenoid hydrocarbons reveals that the dependence of the angles $\alpha$ and $\beta$ on molecular structure is very similar, and that their ratio is almost …


Thermal Behaviour Of Some Azo Dyes Containing Sterically Hindered And Water-Soluble Groups, Hasan Kocaokutgen, Zerrin Heren Jan 1998

Thermal Behaviour Of Some Azo Dyes Containing Sterically Hindered And Water-Soluble Groups, Hasan Kocaokutgen, Zerrin Heren

Turkish Journal of Chemistry

Thermal behaviour of six azo dyes containing steric hindered groups such as tert-butyl, sec-butyl and isopropyl, were investigated by means of thermogravimetry (TG), differential thermal analysis (DTA) and differential thermogravimetry (DTG). The thermal decomposition points and amount of volatile pyrolysis products, were determined in nitrogen atmosphere using TG, DTA and DTG curves.


Crystal And Molecular Structure Of Tris(2,6-Dichlorophenyl) Thiophosphate, Veysel T. Yilmaz, Mustafa Odabaşoğlu, R. Alan Howie Jan 1998

Crystal And Molecular Structure Of Tris(2,6-Dichlorophenyl) Thiophosphate, Veysel T. Yilmaz, Mustafa Odabaşoğlu, R. Alan Howie

Turkish Journal of Chemistry

The crystal structure of tris(2,6-dichlorophenyl)thiophosphate was determined by single crystal X-ray diffractometry. The structure consists of isolated molecules and each unit cell contains 8 molecules of the compound. The crystal system is monoclinic with a space group of C2/c. The P atom is bonded to three O atoms and one S atom in a distorted tetrahedron environment.


Alkaline Rocks And Geodynamics, Bernard Bonin Jan 1998

Alkaline Rocks And Geodynamics, Bernard Bonin

Turkish Journal of Earth Sciences

Origin of A-type alkali feldspar granites is currently the subject of a world-wide debate. Contrasting hypotheses have been proposed, which range from an entirely crustal origin to an almost complete mantle derivation. A-type alkali feldspar granites belong to either unimodal granite (rhyolite)-dominated association, or bimodal gabbro (basalt)-granite (rhyolite) suite. It is argued that (i) the ultimate mantle origin of basic to intermediate rocks is beyond doubt, (ii) highly evolved felsic rocks may be produced by other processes besides crustal involvement through anatexis and (iii) large volumes of felsic rocks are a normal and direct consequence of extensive crystal fractionation processes. …


Resonans Reflectionless Absorption Ofelectromagnetic Waves In Solutions, E. Salaev, E. Gasimov, S. Azizov, J. Qajar Jan 1998

Resonans Reflectionless Absorption Ofelectromagnetic Waves In Solutions, E. Salaev, E. Gasimov, S. Azizov, J. Qajar

Turkish Journal of Physics

No abstract provided.


Generalized Inverse Estimator And Comparison With Least Squares Estimator, S. Sakallıoğlu, F. Akdeniz Jan 1998

Generalized Inverse Estimator And Comparison With Least Squares Estimator, S. Sakallıoğlu, F. Akdeniz

Turkish Journal of Mathematics

Trenkler [13] described an iteration estimator. This estimator is defined as follows: for $0 < \gamma < 1/\lambda_i \max$ \[ \hat{\beta}_{m, \gamma} = \gamma \sum^m_{i=0} (1-\gamma X'X)^i X'y , \] where $\lambda_i$ are eigenvalues of $X'X$. In this paper a new estimator (generalized inverse estimator) is introduced based on the results of Tewarson [11]. A sufficient condition for the difference of mean square error matrices of least squares estimator and generalized inverse estimator to be positive definite (p.d.) is derived.


High-Power Diffusion Cooling Planar Waveguide Co_{2} Laser, E. Taal, M. S. Kiliçkaya Jan 1998

High-Power Diffusion Cooling Planar Waveguide Co_{2} Laser, E. Taal, M. S. Kiliçkaya

Turkish Journal of Physics

A diffusion-cooled CO_{2} laser using a coaxial waveguide is investigated theoretically. The resonator extracting the laser beam consits of two annular plane mirrors enclosing the two ends of the waveguide. A theoretical resonator model based on the vector modes of propagation in a dielectric coaxial waveguide is described.


Alpha Particle Fragments Produced From Multifragmentation Of ^{16}O+^{16}O, M.Y.H. Farag Jan 1998

Alpha Particle Fragments Produced From Multifragmentation Of ^{16}O+^{16}O, M.Y.H. Farag

Turkish Journal of Physics

Angular distribution for alpha particles produced from multifragmentation of ^{16}O + ^{16}O reactions are calculated using the statistical scission model. The alpha particles are sequentially emitted from long lived states of primary fragments populated in these reactions. Eight alpha particles are produced in these reactions. The calculations are carried out for different energies and for different nuclear temperatures. The variances of this multifragmentation process have been numerically calculated. The obtained results are in good agreement with previous calculations.