Physical Sciences and Mathematics Commons^™

Existence Of The Dielectric Constant In Rigid-Dipole Fluids: The Functional-Derivative Approach, John D. Ramshaw

Physics Faculty Publications and Presentations

In a previous article [J. Chem. Phys. 57, 2684 (1972)] sufficient conditions were established for the existence of the dielectric constant ɛ in rigid-dipole fluids. One of these conditions was an unrealistic restriction on the angular dependence of the direct correlation function c (12) at short range. Here it is shown that this restriction can be removed without altering the previous conclusions. Consequently, ɛ rigorously exists if c (12) depends only upon relative positions and orientations of molecules 1 and 2, and becomes asymptotic to -φd(12)/kT at long range, where φd(12) is the dipole-dipole potential. The development is based upon …

Hierarchical Restructuring And Catastrophe Theory, Martin Zwick

Complex Systems Faculty Publications and Presentations

John Platt's article, "Hierarchical Restructuring" (1970), has become something of a "mini-classic" in the systems literature, much like Herbert Simon's paper, "The Architecture of Complexity" (1962). Concerned with the phenomenology of structural change in social systems, in the personalities and psyches of individuals, and in biological and cultural evolution, it in fact quite nicely complements Simon's earlier emphasis on structure and stability. The purpose of this note is to point out a striking similarity between the images of transformation suggested by Platt, and some of the basic features of Rene Thom's catastrophe theory (1975), i.e. that this topological theory can …

Chlorine Distribution In The Idaho Batholith, Laurence Stewart Istas

Dissertations and Theses

Chlorine is thought to play a major role in the mobilization and concentration of base metals in the formation of ore deposits. The regional distribution of chlorine in the Idaho Batholith was studied to see if this could be related to mineralization or metallic provinces. One hundred forty-eight whole-rock samples, mineral separates, and standards were analyzed for chlorine by x-ray fluorescence.

The expected concentration of chlorine in the biotite fraction was not found. The chlorine was not significantly water leachable from the whole rock samples following normal grinding. The Idaho Batholith as a source for mineralizing chlorine was not established. …

Biostratigraphy Of The Snowshoe Formation (Jurassic) In The Izee Area, Grant County, Oregon, Paul Lawrence Smith

Dissertations and Theses

Using the standard Jurassic zonal scheme, this work attempts to determine the ages of the four members of the Snowshoe Formation that crop out in the Izee area. As a corollary, regional correlations are possible. The stratigraphic relationship between the Snowshoe Formation, the subjacent Hyde Formation and the superjacent Trowbridge Formation is also investigated.

Over one thousand fossils were collected from five stratigraphic sections and eight localities. The sections were measured using tape and compass techniques and the relative stratigraphic ranges of the fossils calculated using a computer program written specifically for this project. The ammonite fauna, dominated by the …

Electrical Conductivity Of Thin Lecithin-Cholesterol Membranes Due To 2,4-D, 2,4-Db, 2,4,5-T And 2,4-Dcp, Malkanthi Paulis

Dissertations and Theses

The effect of the following pesticides on DC electrical conductivity of lecithin-cholesterol membranes has been studied: endothall, paraquat, diquat, 2,4-D, 2,4-DB, 2,4,5-T, 2,4-DCP. It has been found that the ions of endothall, paraquat and diquat are essentially membrane impermeable and that they do not bind to the membrane surface. In contrast, 2,4-D, 2,4-DB, 2,4,5-T and 2,4-DCP induce electrical conductivity in lecithincholesterol membranes and in addition they also cause an increase in the nonactin-K⁺ membrane conductivity.

The compounds 2,4-D, 2,4-DB, 2,4,5-T and 2,4-DCP basically behave as class II uncouplers. The kinetic scheme of charge transfer across the membrane, based on …

Stratigraphy, Structure, And Petrology Of The Snoqualmie Pass Area, Washington, Lawrence A. Chitwood

Dissertations and Theses

The Snoqualmie pass area lies about 50 mi (80 km) east of Seattle, Washington, along the crest of the Cascade Range. Five stratified units, forming a composite section over 22,000 ft (6700 m) thick, are recognized in the area. They were deformed and later intruded by granodiorite and quartz monzonite porphyry of the Snoqualmie batholith (middle Miocene). The oldest unit, the Denny Formation (Permian), 7000 ft (2100 m) thick, consists of interstratified basalt, andesite and dacite volcanic rocks and limestone and chert beds. This formation is unconformably overlain by a thick conformable sequence of early Tertiary strata which are subdivided, …

The Addition Of Sf5br To Unsaturated Systems, Qui-Chee Wendy Wang

Dissertations and Theses

Addition reactions of pentafluorosulfur bromide with unsaturated substrates were studied and four new compounds containing the pentafluorosulfur group have been prepared.

The mechanism for these reactions seems to involve a radical addition pathway. In reaction with CH₂=CFC1, CF₃C≡CH and CH₃C≡CH the SF₅ radical attacks the carbon atoms carrying the most hydrogens. The reaction with CF₂=CHCl is interesting, as by analogy with other fluoroolefins, the SF₅ primary attack should occur.at the CHCl group, however, SF₅CF₂CHC1Br was found as the only product for this reaction. The reaction of …

Debye–Hückel Theory For Rigid‐Dipole Fluids, John D. Ramshaw

Physics Faculty Publications and Presentations

The dipolar analog of classical linearized Debye–Hückel theory is formulated for a finite fluid system of arbitrary shape composed of rigid polar molecules. In contrast to the ionic case, the dipolar Debye–Hückel (DDH) theory is nonunique due to an inherent arbitrariness in the choice of a local field E*. This nonuniqueness is expressed in terms of a parameter ϑ related to the ellipticity of the spheroidal cavity used to define E*. The theory then leads to an expression for the direct correlation function c (ϑ) as a function of ϑ. Only the short‐range part of c (ϑ) depends upon ϑ; …

The Geology Of The Castle Rock Area, Grant, Harney And Malheur Counties, Oregon, John David Wood

Dissertations and Theses

The geology of the Castle Rock area aids in the understanding of Cenozoic volcanic stratigraphy and structures in an area where these volcanic rocks thin near the margins of the pre-Tertiary basement rocks and structural trends are overlapping. The Castle Rock area is unique in several aspects and is important in understanding and interpreting the geology in adjacent regions which have all been studied, at least on a regional basis. Intrusive ash-flow bodies of the Dinner Creek Ash-Flow Tuff, well-exposed sections of complexly interstratified volcanic rocks and well-exposed faults, and of high amount of erosional relief are features which make …

The Chemistry Of Chromium (Vi) And Chromium (V) Oxide Fluorides, Patrick Jay Green

Dissertations and Theses

New preparative routes to chromyl fluoride were sought. It was found that chlorine monofluoride reacts with chromium trioxide and chromyl chloride to produce chromyl fluoride. Attempts were made to define a mechanism for the reaction of ClF and Cr0₃ in light of by-products observed and previous investigations. Carbonyl fluoride and chromium trioxide react to form chromyl fluoride and carbon dioxide. A mechanism was also proposed for this reaction. Chromium trioxide with MoF₆ or WF₆ reacts to produce chromyl fluoride and the respective oxide tetrafluoride.

Structural Geology Of The Northeast Quarter Of The Dutchman Butte Quadrangle, Southwest Oregon, Rauno K. Perttu

Dissertations and Theses

The northeast quarter of the Dutchman Butte quadrangle straddles the boundary of the Mesozoic Klamath Mountains province and the Tertiary Coast Range province. The boundary in this area is controlled by a major easttrending fault zone, herein named the Canyonville fault zone. Jurassic Rogue, Dothan, and Otter Point Formations have been offset right-laterally at least 40 kilometers. In latest Jurassic and early Cretaceous time, the fault zone formed the shoreline along which sediments of the Myrtle Group were deposited.

Movement on the Canyonville fault zone becale down-to-the-north in Eocene time forming the southern margin of the Eocene Coast Range basin. …

The Effect Of A Magnetic Field On The Leclanché Cell, Walter Edward Socha

Dissertations and Theses

The effect of a magnetic field on an electrochemical system, the Leclanche cell, was investigated. Experiments show that there is an increase power output and charge passed when a cell is discharged in an applied magnetic field.

Possible explanations for the effect and descriptions of attempts to verify these explanations are presented.

"Nuclear Power: Its Role In Our Future", Betsy Macinness, Dave Ferg, Rudi Nussbaum, Tom Davis, Sandra Kiefer

Special Collections: Oregon Public Speakers

No abstract provided.

Geology Of The Breitenbush Hot Springs Area, Cascade Range, Oregon, Clifford Michael Clayton

Dissertations and Theses

The Breitenbush Hot Springs area lies on the boundary of folded middle to late Tertiary Western Cascade rocks and younger High Cascade rocks. Within the mapped area the Western Cascade rocks are represented by four formations. The Detroit Beds, a sequence of interstratified tuffaceous sandstone, mudflow breccia, and tuff, is overlain unconformably by the Breitenbush Tuff. The Breitenbush Tuff consists of three units of welded pumice-rich crystal-vitric ash-flow tuffs interbedded with tuffaceous sedimentary rocks. The Outerson Formation unconformably overlies the Breitenbush Tuff and consists primarily of basaltic lava and breccia.

The Outerson Formation includes three localized members: a basal, glassy, …

Qsim2: A Low-Budget Heuristic Approach To Modeling And Forecasting, Wayne Wakeland

Complex Systems Faculty Publications and Presentations

This paper contains a description of a simple mathematical framework and modeling process which can be used to study a large class of socio-techno-natural systems. Models may be designed using intuitive notions or data to help specify the variables, parameters and interrelationships, which, with the aid of a computer program, can be used to forecast system behavior under various assumptions. Two example models are described.

Polymerization Of Amino Acids On Kaolinite, Z. Badri Adnani-Gleason

Dissertations and Theses

In the origin of life on the primitive earth a major step must have involved the condensation of amino acids to form the first polypeptides. Several suggestions as to how this might have occurred have been made by other workers. One of the more appealing proposals is that the polymerization was catalyzed by clay minerals. It has been reported, for example, that L-apartic acid polymerizes significantly faster than D-aspartic in the presence of kaolinite in aqueous suspension at 90˚. In this work an attempt was made to repeat this report and extend the pH range to include values presumably present …

"The Search For Extra-Terrestrial Life", Donald L. Devincenzi

Special Collections: Oregon Public Speakers

No abstract provided.

Isolation And Characterization Of Two Sterols From The Green Alga, Selenastrum Capricornutum, Raymond Mark Owings

Dissertations and Theses

The green alga, Selenastrum capricornutum, was cultured in artificial nutrient medium utilizing five-gallon carboys, each of which contained 16 1. of culture. The algal cells were separated from the nutrient medium by continuous-flow centrifugation at 7500 RPM, and were then lyophilized. The lyophilized cells were extracted by refluxing with ether, acetone, and chloroform:methanol (2:1). Free sterols and sterol esters were separated from the crude extract using preparative thin-layer chromatography. Sterol esters were saponified and both the sterols and the fatty acids were recovered.

Individual sterols were separated from the free sterol fraction using argentation thin-layer chromatography. Gas chromatograms, mass …

The Dynamics Of An Hcp Crystal With A Substitutional Defect, Pramod C. Karulkar

Dissertations and Theses

We examine the problem of the dynamics of a hexagonal close packed crystal with a single substitutional impurity. The effects of the mass and the force constant changes due to the introduction of the impurity atom are taken into account assuming nearest neighbor interactions under the harmonic approximation. Using Green’s function and group theoretical methods, the equations of motion for the perturbed normal modes are obtained in an exact form. The calculations are performed by allowing for very general force constant changes which can have noncentral as well as central contributions. Further, by assuming central forces, we simplify the equations …

The Effect Of Human Activity On The Middle Course Of The Tualatin River, Oregon, Lolita M. Carter

Dissertations and Theses

A diurnal study of biological, chemical, and physical parameters was made on the middle course of the, Tualatin River, which drains a 1840 km² (711 mi²) basin adjacent to metropolitan Portland, Oregon. This portion of the river lies along land in transition of use from rural agriculture to highly urbanized development.

There is no nutrient loading of the river from farming practices because there was no return of water from summer, sprinkler irrigation of commercial crops. However, irrigation significantly reduces the volume of water in the river in the summers.

Effluents from sewage treatment plants flowing into …

Studies In Transition Metal Chemistry, Steven David Brown

Dissertations and Theses

The electronic and vibrational spectra of liquid chromium pentafluoride have been investigated. They were found to be consistent with a d¹ system that is extensively fluorine-bridged at room temperature. The vibrational spectra were not consistent with C_4v or D_3h monomers.

"Large Systems", Richard Ernest Bellman

Special Collections: Oregon Public Speakers

No abstract provided.

"The Ore Plan: A Practical Application Of The Systems Approach To Solid Waste Management In Oregon", Richard Duncan

Special Collections: Oregon Public Speakers

No abstract provided.

"The Curious Behavior Of Complex Systems: Lessons From Biology", Heinz Von Foerster

Special Collections: Oregon Public Speakers

No abstract provided.

"A Philosophy For Complexity", Charles West Churchman

Special Collections: Oregon Public Speakers

No abstract provided.

"Education For Managing Complexity", Harold A. Linstone

Special Collections: Oregon Public Speakers

No abstract provided.

The Development Of An Arsenic(V) Selective Electrode, Sandra Gee Kang

Dissertations and Theses

The object of this research was to develop an arsenic(V) selective electrode. The electrode is based on a solid state membrane prepared by pressing a precipitate of silver arsenate-silver sulfide into a pellet. After the electrode was made, experiments were designed to check for three general characteristics of the electrodes: dependence of potential on pH for constant arsenic(V) concentration; dependence of potential on arsenic(V) concentrations at constant pH and extent of interference due to phosphate and arsenic(III) ions. From these measurements, it was found that Ag₂HAs0₄ was formed originally in the membranes containing a small fraction of …

Characterization Of Zinc-Containing Metalloproteins By Resonance Raman Spectroscopy, Robert Edward Derry

Dissertations and Theses

Cobalt-substituted carboxypeptidase and carbonic anhydrase were chosen as candidates for resonance Raman spectroscopy because they possess visible absorption due to the Co(II)-protein complex. However, no evidence for resonance-enhanced peaks due to the cobalt-containing chromophore was found with laser excitation near the visible absorption bands (514.5 nm) or closer to the ultraviolet absorption bands (457.9nm).

Arsanilazocarboxypeptidase and model azotyrosine compounds were selected for a Raman spectroscopic investigation because they have intense absorption bands in the visible region. All of these substances yielded similar resonance Raman spectra. Although there was no evidence for specific zinc-ligand vibrations, shifts in vibrational frequencies of the …

Alumina-Catalyzed Cope Rearrangement, Paul Jhy-Shing Wang

Dissertations and Theses

The alumina-catalyzed Cope rearrangements of meso- and dl-3,4-diphenylhexa-1,5-diene were examined in detail, following up a preliminary observation by H. Berg at Portland State University. Commercial column-chromatography grade alumina was employed, and was further activated before use by heating at 650-700° for four hours.

Using a ratio of 20 mg of dl-3,4-diphenylhex-l,5-diene to 1 g of alumina in heptane, the Cope rearrangement was complete within 15 minutes at room temperature to give exclusively trans,trans-1,6-diphenylhexa-1,5-diene. This was identified.by melting point, infrared spectroscopy and vapor phase chromatography.

The catalyzed rearrangement of meso-3,4-diphenylhexa-l,5-diene was run using the same diene …

The Effects Of Pentachlorophenol On The Electrical Conductivity Of Lipid Bilayer Membranes, William Harvey Perman

Dissertations and Theses

The effects of pentachlorophenol (PCP), a widely used pesticide, on the electrical characteristics of lipid bilayer membranes has been studied. When a small amount of PCP (even at a concentration of a few micromoles per liter) is present in the electrolytic solution surrounding the membrane, the electrical conductivity of the membrane significantly increases. The present work was concerned with detailed measurements of the changes in the conductivity caused by PCP under chemically controlled conditions. The experimental results were analyzed to determine the permanent species in the membrane, and an attempt was made to correlate the data with existing models of …