Physical Sciences and Mathematics Commons^™

Coastal Upwelling Off The Rias Bajas, Galicia, Northwest Spain I: Hydrographic Studies, J. O. Blanton, L. P. Atkinson, F. Fernandez De Castillejo, A. Lavin Montero

CCPO Publications

Coastal upwelling occurs off the Rias Bajas of Spain between April and October. Superimposed on large-scale upwelling is a mesoscale regime of enhanced upwelling induced by topographic influences. We show that the region surrounding Cape Finisterre has intensified topographically induced upwelling.

The rias have a relatively unobstructed connection with the open ocean. Upwelling of high nitrate water on the continental shelf by Ekman transport sets up pressure gradients at the mouth of the rias that induce upwelled water to flow into the rias. Deep water in the rias responds directly to cycles of upwelling and downwelling on the continental shelf.

Trace-Elements In Ilmenite - A Way To Discriminate Provenance Or Age In Coastal Sands, Dennis A. Darby

OES Faculty Publications

Trace elements and Ti percentage in ilmenite grains magnetically separated from modern and late Pleistocene coastal sands of southeastern Virginia and northwestern North Carolina were used to distinguish different deposits. Multivariate analysis of ilmenite composition (Ti, Mn, Mg, Cr, V, Ni, and Cu) from coastal deposits and potential source rivers enabled the identification of dominant source rivers. Using the trace element content of one mineral instead of heavy-mineral suites eliminated most of the hydraulic sorting, selective weathering, and intrastratal solution problems that often obscure heavy-mineral provenance determinations. Most ilmenite grains lacked exsolution or twinning, which are common to ilmenite; however, …

Mass Spectrometric Studies Of Oxygen Isotope Exchange Reactions With Oxide Surfaces, Gayle J. Allen

Chemistry & Biochemistry Theses & Dissertations

Isotopic exchange reactions with the surface of amorphous silica and crystalline quartz were studied mass spectrometrically. A mixture of approximately 2%18_o2 in neon was used as the test gas, and was passed over the surface of the oxides. Measurements were taken as a function of temperature and residence time, for kinetic studies.

These studies clearly show a second order rate law for the surfaces examined. The rate constant on amorphous silica was 2.2xl0²L/mol/sec. The energy of activation was 35.3 kcal/mol and the frequency factor was l.35xl0⁹L/mol/sec. On the crystalline quartz the rate constant was 2.0xl0 …

Systematic Estimate Of Binding Energies Of Weakly Bound Diatomic Molecules, Linda L. Vahala, Mark D. Havey

Electrical & Computer Engineering Faculty Publications

There is often insufficient spectroscopic data for a full RKR inversion to yield a potential for weakly bound diatomic molecules. In these cases, parametrized functions such as the Morse or Thakkar potentials may be used to obtain estimates of the binding energy. The Thakkar potential is more flexible, and has been used successfully on some weakly bound systems. In the more usual case, the Thakkar parameter p, which determines long range behavior R^-p, is chosen by p=-a₁-1, where a₁ is the first Dunham coefficient; p is usually noninteger. The authors present …

The Marine Biogeochemistry Of Selenium: A Re-Evaluation, Gregory A. Cutter, Kenneth W. Bruland

OES Faculty Publications

Vertical and horizontal profiles from the North and South Pacific Oceans demonstrate the existence of three species of dissolved selenium: selenite, selenate, and organic selenide (operationally defined). In surface waters, organic selenide makes up about 80% of the total dissolved selenium, selenite concentrations are uniformly low, and selenate concentrations rise with increased vertical mixing. The organic selenide maximum (thought to consist of seleno-amino acids in peptides) coincides with the maxima of primary productivity, pigments, bioluminescence, and dissolved free amino acids. Deep ocean waters are enriched in selenite and selenate, while organic selenide is nondetectable. In suboxic waters of the tropical …

Episodic Nutrient Supply To A Kelp Forest Ecosystem In Southern California, Richard C. Zimmerman, James N. Kremer

OES Faculty Publications

Temporal patterns of nutrient input into a Southern California kelp forest were measured using traditional hydrocast sampling coupled with high frequency temperature profiling. Patterns of nutrient input were related to growth rates of Macrocystis pyrifera located in an adjacent kelp forest. There were 2 distinct components to the pattern of nutrient availability. The long term, or seasonal, component was consistent with large-scale storm-induced mixing and horizontal advection during winter months. In addition, vertical motions of the thermocline, bringing nutrients into the kelp forest, occurred throughout the year with a frequency of about 2 per day and were strongest during the …

Radiation Damage To Gaas Solar Cells Including Isotropic Effects, Larry Victor Stock

Physics Theses & Dissertations

A model is developed for the short circuit current of a GaAs solar cell due to radiation (proton or electron) induced defects in the crystal structure. This model is verified by a comparison with proton and electron irradiation results. For electron radiation and energetic protons (energy> 10 MeV), it is found that the damage in the crystal is independent of the angle of incidence. On the other hand, for lower energy proton radiation, the damage as a function of cell thickness is highly dependent on incident angle and energy. The cell's response to low energy protons is strongly dependent on …

Collision-Induced Bands Of Lithium-Rare Gas Molecules, Wen Jong Wang

Physics Theses & Dissertations

Lithium vapor is optically excited by two-step laser excitation of the 3d state in the presence of the rare gases He, Ne, Ar, Kr, and Xe. Collision induced bands are observed in Li-Ar, Li-Kr, and Li-Xe mixtures. The bands are believed to be due to transitions to the dissociating 2s~ ground state from states above the 2p state of the Li-RG molecules. The Li-Ar, Li-Kr, and Li-Xe 3sб -2sб collision induced bands are progressively shifted, for the heavier rare gases, further to the red of the asymptotic atomic Li 3s-2s energy difference. A qualitative comparison is made between the spectra …

The Effect Of Polynuclear Aromatic Hydrocarbons On The Fecundity Of Acartia Tonsa (Calanoid Copepoda), Juanita Y. Grabarczyk

OES Theses and Dissertations

The concentrations of polynuclear aromatic hydrocarbons (PNAHs) were determined for several stations in the Elizabeth River. Thirteen PNAHs of the sixteen EPA priority pollutant PNAHs were present in the particulate fraction. The concentrations ranged from 10.0 ng/1 to 1000 ng/1. Ten of the sixteen EPA priority pollutant PNAH were present in the dissolved phase. Concentrations ranged from 2.0 ng/1 to 100 ng/1.

The environmental PNAHs concentrations were used to determine test concentrations. Bioassays were conducted to determine the effects of indigenous concentrations of seven predominant PNAHs (0.01 mg/1 to 2.4 mg/1 concentrations) on the fecundity of Acartia tonsa (calanoid Copepoda). …

Close-Coupling Calculations For Naar, Nane, And Nahe, Linda Lindroth Vahala

Physics Theses & Dissertations

The non-adiabatic close-coupled theory, developed by Mies and by George, is employed in a time-independent molecular calculation for Na-rare gas collisions in a radiations field. The intensity of the Na D1/D2 lines is calculated for both blue- and red-wing excitation and is in good agreement with the experimental results of Havey, Copeland, and Wang for NaAr. The effects of different Born-Oppenheimer potentials on D1/D2 line intensity is considered by also treating NaNe and NaHe. The individual parity contributions to the line intensities are significantly different from each other.

Adaptations Of Dolphin Vision To The Oceanic Environment, Andre Rivamonte

OES Theses and Dissertations

The objective of this study has been to develop an hypothesis explaining comparable aerial and underwater visual acuity of the bottlenose dolphin, Tursiops truncatus. This objective was accomplished by integrating the findings of other dolphin researchers working in the fields of comparative psychology, histology and ophthalmology. Their combined results enabled the formulation of a schematic dolphin eye. It is proposed that a dolphin lens, similar to the spherical lens of teleost fish with a rigid core of uniformly high refractive index and a margin of radially decreasing refractive index, could function as a bifocal lens and compensate for the eye's …

The Effects Of Dominant Species Removal On Subtidal Community Development, H. Russell Barker Jr.

Biological Sciences Theses & Dissertations

Acrylic panels were used to follow the development of the fouling community at Channel Points, Lynnhaven Bay, Virginia, from April through October 1979. The roles of Membranipora tenuis, an encrusting ectoproct, and Molgula manhattensis, a solitary tunicate, were studied by removing each species from the developing community on a weekly basis.

Early colonization was dominated by Membranipora followed by Corophium spp. (Amphipoda), Polydora ligni (Polychaeta), and Balanus eberneus (Arthropoda). Molgula colonized the panels later in the study and became a dominant occupier of primary space by the end of the study.

The removal of Membranipora and Molgula …

The Distribution Of Phytoplankton In Frontal Regions Of The Lower Chesapeake Bay, Richard V. Lacouture

OES Theses and Dissertations

The spatial and temporal distribution of phytoplankton was measured in relation to frontal areas located in the entrance to the Chesapeake Bay. Phytoplankton biomass, taxonomy, and several physical parameters were measured on fifteen sampling cruises between September,1981 and February, 1983.

Several statistical tests revealed that phytoplankton biomass did not accumulate at the fronts and that generally the distribution of phytoplankton biomass was homogenous across the frontal region. The cell count data indicated that the community structure of the phytoplankton assemblage was usually very similar on both sides of the front. The data which was concerned with temporal variations in the …

Determination Of N,N'-Diphenylguanidine In Biological Tissues And Fluids Using High Pressure Liquid Chromatography, Edward Sidney Hunter Iii

Chemistry & Biochemistry Theses & Dissertations

N,N'-Diphenylguanidine (DPG) is a potentially toxic compound used in the vulcanization of rubber products. Distribution of DPG in hybrid mice (C57BL/6J interbred with DAB₂) was determined following intraperitoneal injection. Urine, fecal material, whole blood and tissues were collected at various times after administration of DPG and the extracts analyzed for DPG by high pressure liquid chromatography. Recovery of DPG from spiked urine and whole blood exceed 90%, however, the recovery of DPG from spiked tissue samples was approximately 70%.

DPG concentration in whole blood reached a maximum within ten minutes and rapidly decreased through 180 minutes after administration …

The Effect Of Sea Nettle Abundance On The Food Chain Of The Lower Chesapeake Bay, Michael Glenn Kelly

OES Theses and Dissertations

The significance of sea nettle abundance on lower levels of the Chesapeake Bay food chain was examined in a field study and by the analysis of medusa gut contents. In the field study, the abundance of four levels of the food chain (Chlorophyll (a), copepods, the ctenophore Mnemiopsis leidyi, and the Schyphomedusa Chrysaora guinguecirrha) were monitored twice weekly at four stations from May 10 through September 30, 1982. The copepod standing stock declined sharply in late May when M. leidyi appeared, but rebounded a month later when C. guinguecirrha medusae reduced the ctenophore population. Despite the additional presence …

The Effects Of Dredged Materials On The Copeod, Acartia Tonsa, Renee Suzanne Crouch

Biological Sciences Theses & Dissertations

A study was conducted to determine the potential impact of open ocean disposal of sediments dredged from a highly industrialized seaport. Sediments from three potential dredge sites along the Southern Branch of the Elizabeth River, Hampton Roads, Virginia were evaluated for acute toxicity. The suspended particulate fractions of dredged materials were tested in a series of 96-hour, static bioassays using the calanoid copepod, Acartia tonsa Dana. Significant mortalities were observed for all three sites with the sediments from the most heavily industrialized site producing immediate and severe mortality. Analysis of results indicates that mortality was highly related to the volatile …

The Effect Of Crowding On Growth Of The Cichlid Fish, Oreochromis Mossambicus, Bonnie A. Barrows

OES Theses and Dissertations

It has been reported that the Java tilapia, Oreochromis mossambicus, displays hypersensitivity to a substance it produces when biomass levels in a flow-through culture system exceed 20 g/1, resulting in reduced growth and high mortality. Experiments on the growth of this species in small tanks were conducted in order to determine whether O. mossambicus produces a growth-inhibiting compound under crowded conditions. This species was successfully maintained at biomass levels of 38 g/1 and 57 g/1 with a total mortality of only 4.5%.

The Java tilapia can grow rapidly in small aquaria, as indicated by the data taken during Experiment …

Experiments Conducted On The Electron Beam Produced By A Dense Plasma Focus, Mark Steven Pronko

Electrical & Computer Engineering Theses & Dissertations

An experimental investigation was conducted using a 34-kJ Dense Plasma Focus (DPF) in which the possible enhancement of the electron beam was addressed. Electron beams ejected from the DPF have been observed to exceed 30 kA with pulse durations of a few nanoseconds. Enhancement was considered to be either an increase in the probability that the peak beam current exceeded some lower limit, or an increase in the mean energy of the beam electrons. The investigation was divided into two parts, each addressing one of the aspects of enhancement.

In the first part of the investigation, an axial magnetic field …

Treatment Process Optimization At The Lee Hall Water Treatment Plant Newport News, Virginia, Marcy Granum Garnett

Civil & Environmental Engineering Theses & Dissertations

Various methods can be used in operating a water treatment plant. It is desirable to produce good quality water as efficiently and economically as possible. This study evaluates each phase of operation at the Newport News (Lee Hall} water treatment plant for overall efficiency.

This study begins by giving a detailed description of the Lee Hall water treatment plant. The description includes sources of water, a description of each treatment process, a plan view of the treatment plant, and a flow diagram of the treatment plant.

Based on the raw water data, flow rates, and the treatment plant characteristics, the …

The Relationship Of Size Class Distribution To Migratory Behavior In Brown Shrimp (Penaeus Aztecus) In Pamlico Sound, North Carolina, Mario A. Paula

OES Theses and Dissertations

The potential of migratory timing information for dynamic yield estimation in the North Carolina brown shrimp fishery has been shown. The present research investigates the influence of size class distribution on the quantitative characterization of migratory timing in the brown shrimp. Catch and nominal effort data were stratified into count size ranges and the time density model of Mundy (1979) was specified for each stratum. The recruitment patterns of the shrimp into the fishery was also investigated.

The stratification of time densities by size class has shown a definite pattern in the migratory behavior of the brown shrimp. It appears …

The Growth And Feeding Behavior Of Juvenile Spot, Leiostomus Xanthurus Lacepede, In The Nursery Region Of The James River, Virginia, John Thomas Mccambridge Jr.

OES Theses and Dissertations

The in situ growth and feeding behavior of juvenile spot, Leiostomus xanthurus Lacepede, was investigated for populations in the nursery area of the James River, Virginia. Growth of juvenile spot was found to be fairly rapid (11.34 mm/month, standard length) during their first summer in the nursery grounds, but it levelled off in the autumn. The mean size of spot after the first year was calculated to be 195 mm total length. The weight-length relationship was log W = -5.018 + 3.246(log L), where W = wet weight in grams and L = standard length in millimeters.

Juvenile spot appeared …

Simultaneous Functional Hermaphroditism In The Shrimp Hippolysmata Wurdemanni (Gibbes) (Decopoda: Caridea: Hippolytidae), Marie Hollister Bundy

OES Theses and Dissertations

The caridean shrimp Hippolysmata wurdemanni Gibbes was studied from a histological and a behavioral basis and was found to be a protandric hermaphrodite which later adopts simultaneous functional hermaphroditism. When the animal reaches a certain size, the androgenic gland degenerates, the male secondary sexual characteristics are lost, and vitellogenesis occurs in the anterior portion of the gonad. The animals do not lose the ability to function as males as evidenced by the presence of mature sperm in the gonad and the gonadal lumen of gravid shrimp, and the ability of both members of an isolated pair of shrimp to repeatedly …

A Model Of The Population Dynamics Of The Blue Crab In Chesapeake Bay, Betty Springer Hester

OES Theses and Dissertations

This study has particular application to the blue crab fisheries in Chesapeake Bay, an economically important industry whose successful management has been hindered by relatively poor understanding of the population dynamics. Recent biological studies have indicated a systematic spawning behavior which seems designed for ejection of larvae seaward from the bay entrance where they spend their pre-metamorphosis stages in the neuston. A physical mechanism for retention of the larvae in sufficient proximity to the bay entrance for their return at the proper time which involves the action of wind stress in shallow waters is proposed. Since the supply of blue …

A Study Of Increased Flow Off The Eastern Seaboard Of The United States Within Four Synoptic Flow Patterns During The Winter Months, John Dale Liechty

OES Theses and Dissertations

A study of increased winds during the winter season off the United States Eastern Seaboard was made in each of four synoptic flow patterns: prefrontal; postfrontal; northeast; and southerly. Eight years of synoptic data for the months October through March from two pairs of stations were utilized. Each pair consisted of one land and one sea station; of the sea stations, Frying Pan Light was located in or near the warmer water of the Gulf Stream while Chesapeake Light was situated in colder, coastal water. Both land stations were situated in the vicinity of the coast.

A statistical analysis was …

Viscous Modeling And Computation Of Leading-And Trailing-Edge Vortex Cores Of Delta Wings, Balakrishnan Lakshmanan

Mechanical & Aerospace Engineering Theses & Dissertations

A Finite-Difference method is presented for calculating steady quasi-axisymmetric flow of an incompressible fluid at large Reynolds number. Approximations of the boundary-layer type are employed to reduce the Navier-Stokes equations to a pair of non-linear parabolic equations. Along with the governing equations, initial conditions are specified at some upstream cross section and boundary conditions are specified at the axis of symmetry and on the outer bounding surface.

The governing equations are replaced by a set of quasilinear finite-difference equations. The solution is obtained by a marching technique, which proceeds step-by-step in the axial direction. At each axial station, an iterative …

Polychlorinated Biphenyl Levels In The Ocean Scallop (Placopecten Magellanicus) Gmelin From The Philadelphia Sewage Sludge Disposal Site, Guy Jeffrey Hall

OES Theses and Dissertations

Ocean Scallops (Placopecten magellanicus) were sampled from stations in and around the Philadelphia Disposal Site. Each sample was dissected and aliquots of adductor muscle and reproductive tissue were chemically extracted for Polychlorinated Biphenyls (PCBs). A perchlorinated procedure outlined by Diosady et al., 1972, Aromour, 1973 and Crist et al., 1977 was employed to increase detection levels and simplify quantitation of PCBs. PCB levels were reported in dry weight and lipid weight of both adductor muscle and reproductive tissue. Findings indicated residual levels or PCB/lipid weight increased as lipid levels decreased in both tissue types. Levels detected in all adductor muscle …

Evaluating The Effects Of Alum With Polyelectrolyte Coagulant Aids In Treatment Of Low Turbidity Waters, Kenneth John Stockwell

Civil & Environmental Engineering Theses & Dissertations

Potable water sources usually require treatment for removal of suspended organic and inorganic particles. Conventional treatment processes incorporate chemical coagulants for removal of these suspended particles. Alum is a widely used coagulant that can provide adequate removals of turbidity. However, high alum dosages are required for treatment of low turbidity waters producing a voluminous sludge that is difficult to dewater.

Recent Federal regulations have limited disposal options for chemical sludges. This has prompted a reevaluation of coagulants and their dosages with the goal of reducing the amount of sludge produced and improving the sludge handling characteristics necessary for ultimate disposal. …

Variability Of Atmospheric Hydrocarbon Concentrations And Deposition Rates, Charles Thomas Farmer

OES Theses and Dissertations

The atmospheric hydrocarbon concentration was determined at various locations throughout Southeastern Virginia from July 1981 to February 1983. During this period the concentration ranged from 0.4 to 5.5 μg/m³ . From October 1982 to February 1983, WET and dry deposition samples were collected in conjunction with these air samples. Total hydrocarbon dry deposition rates ranged from deposition rates ranged from 4 to 189 μg/m² /day, while WET 22 to 670 μg/m² /day. Hydrocarbon concentrations found were within the ranges reported in the literature for wet, dry and atmospheric hydrocarbon concentrations.

Linear trend analysis revealed no correlation between …

Application Of The Method Of Lines For Solutions Of The Navier-Stokes Equations Using A Nonuniform Grid Distribution, Jamshid Samareh Abolhassani

Mechanical & Aerospace Engineering Theses & Dissertations

The feasibility of the method of lines is investigated for solutions of physical problems requiring nonuniform grid distributions. To attain this, it was also necessary to investigate the stiffness characteristics of the pertinent equations. For specific applications, the governing equations considered are those for viscous, incompressible, two-dimensional and axisymmetric flows. These equations are transform­ ed from the physical domain having a variable mesh to a computational domain with a uniform mesh. The two governing partial differential equations are the vorticity and stream function equations. The method of lines is used to solve the vorticity equation and the successive over relaxation …

Input And Distribution Of Sewage Derived Sedimentary Material Adjacent To Chesapeake-Elizabeth Sewage Outfall, Virginia Beach, Virginia, Robert Carroll Brown

OES Theses and Dissertations

The concentrations of coprostanol and hydrocarbons were measured in the effluent from the Chesapeake-Elizabeth sewage treatment plant and surface sediments from the area surrounding the effluent discharge site. Most of the coprostanol (>84%) and hydrocarbons (>91%) were associated with particulates in the effluent. Some of these particles were incorporated into the sedimentary column within the study area, while some may have escaped from the area.

The study area is found to be a dynamic area where changes in the percentage and distribution of fine-grained sediments occur over periods of months. The movement of fine-grained sediments is an important …