Physical Sciences and Mathematics Commons^™

The Apparent Dissociation Constants Of Carbonic Acid In Low Salinity Waters, Ching-Hui Hsu

OES Theses and Dissertations

The first and second apparent dissociation constants of carbonic acid in artificial seawater and diluted artificial seawater, K₁ ' and K₂ 1 were determined at selected combinations of temperatures and salinities between 2 to 30° C and 0 to 35 o/oo with special attentions to waters with salinities below 20 o/oo at atmospheric pressure by measuring K₁ ' and the product of K₁ ' and K₂.

The results can be expressed as functions of temperature and salinity by the following equations, pK₁ '=3360.206T^-1 +0. 033331 T-14.8303-0.09633x (Cl^1/2) pK₂ '=14911.671 …

Algebraic Grid Generation Using Tensor Product B-Splines, Bonita Valerie Saunders

Mathematics & Statistics Theses & Dissertations

In general, finite difference methods are more successful if the accompanying grid has lines which are smooth and nearly orthogonal. This thesis discusses the development of an algorithm which produces such a grid when given the boundary description.

Topological considerations in structuring the grid generation mapping are discussed. In particular, this thesis examines the concept of the degree of a mapping and how it can be used to determine what requirements are necessary if a mapping is to produce a suitable grid.

The grid generation algorithm uses a mapping composed of bicubic B-splines. Boundary coefficients are chosen so that the …

Analog Computer Simulation With Automatic Scaling By Digital Computer, Mark Anthony Motter

Electrical & Computer Engineering Theses & Dissertations

A computer-aided design approach for the simplification of analog computer simulation is presented. The simulation configuration consists of an EAI 2000 analog computer with serial communications link to a PDP — 11/24 digital computer. Under control of the PDP-11, the analog simulations are realized with appropriate time and magnitude scaling which adjusts the range of the simulation coefficients and prevents overloads of the analog components. The analog computer hardware configuration accommodates both stable plants up to eighth order and closed-loop systems up to tenth order. Cascade compensation is provided for the closed-loop systems.

The plant may be described by either …

Mossbauer Study Of Gadolinium Iron Garnet, Jun Li

Physics Theses & Dissertations

The Mossbauer spectroscopic study of Gadolinium Iron Garnet R₃Fe5^O12 (GdIG) has been performed over the temperature range of 7K to 715K. Both high temperature and low temperature properties of GdIG have been studied. The magnetization is along (111) direction over this temperature range. The internal magnetic fields at Fe⁵⁷ sites in GdIG gave two values for the octahedral(a), site which differ by 4-6 KOe and one value for the tetrahedral (d), site at each temperature. Measurements of the total isomer shift in the spectra show that the shift of the center of the spectra consists …

Feasibility Studies Of Conversion Electron Mossbauer Spectroscopy (Cems) Of Iron-Doped Inp, Edward Agyekum

Physics Theses & Dissertations

An electron detector for conversion electron Mossbauer spectroscopy (CEMS) has been designed and built. Tests have been performed to study the effects on the electron detector resolution with respect to high anode voltage, He/CH₄ gas flow rate, and counting rate. These parameters have been optimized to detect the 7.3 keV conversion electrons emitted following resonant absorption of the 14.4 keV source gamma-rays associated with the Mossbauer effect using ⁵⁷Fe nuclei. CEMS spectra have been obtained using standard ⁵⁷Fe enriched and natural iron samples. CEMS spectra and Mossbauer transmission spectra have also been obtained for iron-compensated InP (InP:Fe) …

Statistical Calibration Theory, James John Mckeon

Mathematics & Statistics Theses & Dissertations

A calibration method substitutes for measurements, X(,i), that are accurate but impractical or costly, a set of measurements, Y(,i), that are less accurate but simpler or less costly. There are two general types of calibration methods. The classical approach in which once the calibration sample is drawn, the estimates of the X values for a given unit is found without any consideration of the distribution of X values for the other units to be measured. This corresponds best to the literal meaning of the word "calibration". Maximum likelihood estimation is the statistical formulation of the classical approach.

The second approach …

A Geophysical Model Of The Gravity-Magnetic High, Virginia Coastal Plan, Gordon Everett Davison

OES Theses and Dissertations

The coastal plain province of Virginia is characterized by a coincidental gravity and magnetic high separating Appalachian-trend geophysical signatures to the west from non-Appalachian signatures to the east. Two cross-trend gravity and magnetic profiles, one on the Northern Neck of Virginia and one along Interstate Highway 64, were used to interpret the anomalous high. The profile models suggests that the anomaly is characterized by high-density, variably magnetic, east-dipping (60°) crustal blocks. Further information from well-logs indicate that the anomaly is due to meta-mafic rocks of oceanic origin, flanked by low-density, lower susceptibility, granitic units. This suggests that the anomalous gravity-magnetic …

The Synthesis And Evaluation Of A New Analog Of Phencyclidine (Pcp), William H. Johnson Jr.

Chemistry & Biochemistry Theses & Dissertations

Based on an interpretation of the literature of phencyclidine (PCP) together with an examination of the relevant models or prototype structures, this research has attempted to design and synthesize a rigid analog of the phencyclidine structure. The parent ring systems suggested for this study were the 1-arnino and 2-arninornethyltetralins, 10 and, 12.

Several organic compounds, based on this design, have been prepared by classical examples of reductive alkylation reactions of the corresponding 2-hydroxyciethylene-1-tetralones, 11, and by the condensation and subsequent reductive alkylation of the 1-arninotetralin, 9. These arninomethyltetralones, 28, 29 and 30, together with an example of a substituted 1-arninotetralin, …

Fluvial Depositional Processes Of A Tropical River, Colombia, South America, Michael L. Babuin

OES Theses and Dissertations

Fluvial depositional processes along the Rio Magui in south-western Columbia are primarily controlled by localized uplift downstream of the mouth of the river, sediment sources that produce both coarse-and-fine-grained load, and numerous over-bank flows caused by torrential rainfall.

Test Derivation For Cmos Iterative Logic Arrays, Ravi Sharma

Electrical & Computer Engineering Theses & Dissertations

Testability criteria for stuck-open (s-op) faults in one-dimensional unilateral iterative logic arrays (ILA) of CMOS combinational cells are considered in this thesis. A functional fault model to represents-op faults i~ an ILA cell is given. The procedure to detect as-op fault needs a pair of test vectors. The first is used to set up the initial conditions required to test the fault and the second is the test which distinguishes between the good and the bad circuit. Based on this approach necessary and sufficient conditions are given for the testability of as-op fault in a CMOS ILA cell. These conditions …

Selecting Non-Point Source Pollution Treatment Practices Using Linear Optimization, John Gardy Garland Iii

Civil & Environmental Engineering Theses & Dissertations

This paper provides a case study application of a linear optimization program as a water quality management tool. The optimization program seeks to minimize the cost of nonpoint source pollution control by selecting the best combination of pollution control management practices for Hampton, Virginia. The management practice options are grass swale roadways, porous pavers, ponds, detention basins and fertilizer management education. Management practice selection is limited by constraints on land-use and water quality. Pollutants evaluated are total nitrogen, total phosphorus, suspended solids, fecal coliforms and biochemical oxygen demand (five-day). The value in the water quality constraints for pollution loading on …

Foraminiferal Paleoenvironments Of The Eastover Formation (Upper Miocene Virginia), Joann H. Goshorn

OES Theses and Dissertations

Sixty-two taxa representing 29 genera from 39 foraminiferal sample pairs have been documented and analyzed in a paleoenvironmental study of the Eastover Formation in southeastern Virginia. The Eastover Formation consists of a lower Claremont Manor Member, a silt fine-grained sand and an upper Cobham Bay Member, a shelly fine grained sand. Planktonic specimens were rare and indicated a late Miocene to early Pliocene age for the Eastover Formation. Benthics were used to interpret paleoenvironments by comparison with data from the distribution of Recent foraminifera, species diversity, planktonic to benthic ratios, and sediment analyses. The foraminifera indicate that the Eastover Formation …

Community Ecology, Robert K. Rose, Elmer C. Birney

Biological Sciences Faculty Publications

COMMUNITIES with Microtus tend to be structurally simple, usually grasslands or tundra, and to have no more than two species of Microtus and rarely more than six species of small mammals. Microtus often dominates both numerically and in total small mammal biomass, especially at higher latitudes. The small mammal community is most influenced by Microtus through its fluctuations in density, and thus also in biomass, by its relatively high level of diurnal activity, and by its year-round activity. Other species of small mammals may be adversely affected because Microtus usually is larger and behaviorally dominant and also because the mere …

Microbial Manganese Reduction By Enrichment Cultures From Coastal Marine Sediments, David J. Burdige, Kenneth H. Nealson

OES Faculty Publications

Manganese reduction was catalyzed by enrichment cultures of anaerobic bacteria obtained from coastal marine sediments. In the absence of oxygen, these enrichment cultures reduced manganates when grown on either lactate, succinate, or acetate in both sulfate-free and sulfate-containing artificial seawaters. Sodium azide as well as oxygen completely inhibited microbial manganese reduction by these enrichment cultures, whereas molybdate had no effect on them. The addition of nitrate to the medium slightly decreased the rate of Mn²⁺ production by these enrichment cultures. These findings are consistent with the hypothesis that the manganese-reducing organisms in these enrichment cultures use manganates as terminal …

Sedimentologic And Stratigraphic Significance Of Boulder Layers In The Outer Coastal Plain Of Southeastern Virginia, Robert C. Mcdaniel

OES Theses and Dissertations

In southeastern Virginia one to two discontinuous boulder layers occur at the base of the Pleistocene Norfolk Formation. The sediments, heavy minerals and microfossils within the boulder layers in addition to boulder lithologies, dimensions and orientations were studied to determine the origin of these layers. These data indicate the boulder layers were separated into two similar yet distinct layers.

The ancestral James River with sea-level 100 meters lower than today probably had the capacity to entrain 70-80 percent of the clasts in the boulder layers, but probably not the capacity to entrain the larger cobbles and boulders in the boulder …

The Use Of Ilmenite Element Composition For The Determination Of Provenance, Yu W. Tsang

OES Theses and Dissertations

Fifty three samples were taken from three major rivers and their tributaries in Virginia: the James, Roanoke. and Potomac-Shenandoah Rivers. Samples were obtained from the Valley and Ridge. Blue Ridge and Piedmont provinces. The possible source rock types for these samples were determined by comparison of tributary ilmenite composition with drainage basin rock types. Ilmenite element concentration varied with different rock types. Ti was usually high for the ilmenite derived from non-mafic igneous rocks. Mg and Cr were high for the ilmenite from mafic igneous rocks. Zn was low for metamorphic ilmenite. The ilmenite from sedimentary rocks tended to have …

Large Deviation Local Limit Theorems For Arbitrary Sequences Of Random Varibles, Narasinga Rao Chaganty, J Sethuraman

Mathematics & Statistics Faculty Publications

The results of W. Richter (Theory Prob. Appl. (1957) 2 206-219) on sums of independent, identically distributed random variables are generalized to arbitrary sequences of random variables T_n. Under simple conditions on the cumulant generating function of T_n, which imply that T_n/n converges to zero, it is shown, for arbitrary sequences {m_n}, that k_n (m_n), the probability density function of T_n/n at m_n, is asymptotic to an expression involving the large deviation rate of T_n/n. Analogous results for lattice …

Effects Of El Nino On Local Hydrography And Growth Of The Giant Kelp, Macrocystis Pyrifera, At Santa Catalina Island, California, Richard C. Zimmerman, Deborah L. Robertson

OES Faculty Publications

Deepened isotherms associated with El Niño resulted in severe nutrient limitation and very low kelp productivity during the last half of 1983. Frond growth rates were so low that terminal blades formed before reaching the surface, eliminating the canopy. Frond initiation rates were also extremely low, resulting in significant reductions in mean plant size. Plants growing above 10m were more severely affected than plants at 20m. Nutrient pulses associated with internal waves are thus critical for survival of Macrocystis pyrifera in nutritionally marginal habitats in Southern California.

Fault Movements And Tectonics Of Eastern Iran: Boundaries Of The Lut Plate, Ali A. Nowroozi, A. Mohajer-Ashjai

OES Faculty Publications

Summary. From 1977 March 21 to 1981 July 28, about 15 earthquakes with M_s ≥6.0 and many earthquakes with M_s≥4.5 have occurred in Iran. The upsurge of seismic activity started following the Khorqu earthquake of 1977 March 21, M,=7.0, south-east of the Fars folded series of Zagros. This shock had a thrust focal mechanism solution indicating the general northward movement of the Arabian plate with respect to the Iranian landmass. It was followed by six major damaging earthquakes in eastern Iran. The earthquakes are associated with extensive faulting which surrounds the Lut plate. (1) The Zarand earthquake …

Computer Aided Simulation Of A Heating, Ventilating, And Air Conditioning System In A Building, Sunil Shrikrishna Kulkarni

Mechanical & Aerospace Engineering Theses & Dissertations

The Godwin Life Science Building on the Old Dominion University campus presents an interesting problem in terms of energy conservation. The building is the maximum energy resource consumer on the campus, having a criterion value of 234 KBtu/sq.ft-year (2657 MJoules/sq. rneter-year). A Simplified Energy Analysis Method (ASEAM) loads and systems computer program was used to simulate the building and its heating, ventilating, and air conditioning (HVAC) plant in order to understand the building's high annual energy resource consumption rate, and to devise ways to overcome it. The main goal was to assess and propose energy conservation improvements to the existing …

Tectonic Implications Of Late Tertiary Strata Exposed Along The Piankatank River, Eastern Virginia, Daniel Stephen Lane

OES Theses and Dissertations

Biostratigraphic analysis of Late Miocene and Pliocene strata along the Piankatank River in eastern Virginia exposes a juxtaposition of the Eastover and Yorktown Formations. This structure is situated on a NE trending alignment of geological, geomorphic, and geophysical features which run from southern Virginia to northern Delaware. Tectonic jointing in isolated sandstone bodies and fracture controlled drainage patterns provide further evidence of post-middle Pliocene tectonism in the region. The lateral spacing of this structure from the Stafford and Brandywine fault zones and other linear features on the Coastal Plain strongly implies that a structural similarity exists between the Piankatank structure …

Stratigraphy And Textural Analyses Of A Beach Ridge Complex, Cape Henry, Virginia, Daniel Leland Oyler

OES Theses and Dissertations

Eight lithological units, documented from the analyses of 26 boreholes, comprise five laterally extensive horizons in the subsurface of Cape Henry, Virginia. Interpretations of the environments of deposition for those units are based upon textural and compositional features, fossils, thickness and distribution of strata, and previous reports about late Tertiary and Quaternary deposits in nearby areas. The incised, Pliocene Chowan River Formation (Unit H) underlies Pleistocene Units F and G which are concentrated in a buried river valley beneath Cape Henry. Estuarine Units D and E resulted from a marine transgression of the study area during the early Holocene. The …

Groundwater Management By Linear Programming, Seungho Song

Civil & Environmental Engineering Theses & Dissertations

Three hydraulic optimization models are developed. These models combine the finite difference equations of two-dimensional groundwater flow in composite aquifers with various linear programming techniques. The hydraulic submodel employed in these hydraulic optimization models is so versatile that it accounts for time varying pumpage, leaky artesian conditions, a variety of boundary conditions, induced infiltrations from streams or rivers, and conversion from artesian to water table conditions. The objective of submodel 1 is to maximize the total hydraulic head from pumping wells at the end of a study period. The objective of submodel 2 is the same as submodel 1, but …

Numerical Experiments With The Quasigeostrophic Potential-Vorticity Equation, Peter L. Spence

OES Theses and Dissertations

A method is developed to model the circulation of a barotropic, 8-plane ocean under an imposed steady wind stress. The model includes the effect of both horizontal and vertical friction along with nonlinear advection of vorticity. Implementing the method involves solving the unsteady quasigeostrophic potential-vorticity equation using a compact finite difference scheme (Gatski, Grosch, and Rose, 1982).

Once developed, this model is used in four separate numerical experiments. In each experiment, a model ocean with an initial flow field is driven to a steady state solution. Vertical viscosity is held constant in the first three experiments while lateral viscosity is …

The Effects Of X-Irradiation On The Metamorphosis And Budding Of Aurelia Aurita, Michael John Prokopchak

OES Theses and Dissertations

With the aid of the Aurelia Metamorphosis Test System, the acute or subtle morphological and behavioral effects of irradiation on the Norfolk Aurelia aurita were described and the sensitivity to X-irradiation of those organisms receiving thyroxine and those not receiving thyroxine was compared. Levels of radiation were 0 (control), 5,000, 10,000, 15,000, 20,000 and 40,000 rads. Morphology of the ephyrae, statolith and rhopalia numbers were recorded using the light microscope, Developmental abnormalities of the scyphistomae and ephyrae were recorded with the scanning electron microscope and light microscope. Two major findings from this investigation were the absence of rhopalia and statoliths …

Design Of Infrasound-Detection System Via Adaptive Lmstde Algorithm, Camille S. Khalaf

Electrical & Computer Engineering Theses & Dissertations

A proposed solution to an aviation safety problem is based on passive detection of turbulent weather phenomena through their infrasonic emission. This thesis describes a system design that is adequate for detection and bearing evaluation of infrasounds. An array of four sensors, with the appropriate hardware, is used for the detection part. Bearing evaluation is based on estimates of time delays between sensor outputs. The generalized cross correlation (GCC), as the conventional time-delay estimation (TOE) method, is first reviewed. An adaptive TUt approach, using the least mean square (LMS) algorithm, is then discussed. A comparison between the two techniques is …

Triple Trigonometric Series And Their Application To Mixed Boundary Value Problems, Gordon Melrose

Mathematics & Statistics Theses & Dissertations

In this dissertation the author investigates some triple trigonometric series which occur in the solution of mixed boundary value problems in elasticity and potential theory. By choosing a suitable integral representation for the sequence of unknown constants, the problem is reduced to solving a singular integral equation of the first kind. Twenty four cases in which the integral equation can be solved in closed form are discussed in detail.

In later chapters, the application of triple trigonometric series to problems in physics and engineering is demonstrated and closed form solutions for the physical parameters of interest are obtained.

Estimating The Parameters Of Truncated Distributions, Mukul Mohan Mittal

Mathematics & Statistics Theses & Dissertations

The problem considered here is the estimation of the parameters of some special truncated distributions. If the sample observations are restricted to the interval {O, T} with T known, then it is well known in the literature that the method of maximum likelihood fails to provide a finite estimate, for the mean of an exponential distribution, whenever the sample mean is greater than T/2 (Deemer and Votaw, 1955, Ann. Math. Statist. 26, 498-504). Not so well known is the nonexistence of the maximum likelihood estimator (m.l.e.), under certain conditions, for the scale parameter of a gamma distribution from a truncated …

Block Encoding Of Speech Spectral Principal Components, James R. Holland Jr.

Electrical & Computer Engineering Theses & Dissertations

A Karhunen-Loeve series expansion was used to block encode speech spectral principal components as a function of time. Each of ten principal components was first obtained as a linear combination of 2© speech spectral band energies. Using a fixed block length of 10 frames (0.128 s), the K-L basis vectors were computed separately for various speakers for each principal component. In all cases the resulting basis vectors were essentially a set of discrete cosine basis vectors. Synthesis of speech from the block encoded parameters showed that very little information is lost with up to 70% data reduction. The block encoding …

Suboptimal Algorithms For Improvement Of Pipeline Through Insertion Of Delays, Sukhamoy Som

Electrical & Computer Engineering Theses & Dissertations

Pipelining is now widely used in the design of high speed processors in order to overcome the intrinsic speed limitations imposed by the technology. For a good performance and avoidance of internal conflicts, the concurrent operations within different subunits of a pipeline architecture should be properly scheduled This scheduling problem is known to be intrinsically difficult" and a member of the "NP complete class of problems. The aim of this thesis is to develop heuristic suboptimal algorithms whose execution time is a polynomial function of the number of items to be scheduled. Insertion of delay is used as a basic …