Physical Sciences and Mathematics Commons^™

Low Pressure Gas Flow Analysis Through An Effusive Inlet Using Mass Spectrometry, David Robert Brown

Chemistry & Biochemistry Theses & Dissertations

A mass spectrometric method for analyzing flow past and through an effusive inlet designed for use on the tethered satellite and other entering vehicles is discussed. Source stream concentrations of species in a gaseous mixture are determined using a calibration of measured mass spectral intensities versus source stream pressure for standard gas mixtures and pure gases. Concentrations are shown to be accurate within experimental error. Theoretical explanations for observed mass discrimination effects as they relate to the various flow situations in the effusive inlet and the experimental apparatus are discussed.

Self Consistent Model Of The Glow Discharge, Hao Chen

Electrical & Computer Engineering Theses & Dissertations

The strong spatial variation of the electric field intensity in the vicinity of the cathode of a gas discharge requires the use of microscopic methods to describe the nonequilibrium behavior of the electron dynamics in this region. A one-dimensional Monte Carlo code was developed. It allows one to obtain the distribution of the electron drift velocity and rate coefficients for a given electric field intensity in the cathode fall. The results of this calculation are used to find the density distribution of charged particles in this region and consequently, by means of Poisson's equation, a corrected electric field intensity. In …

Reactions Of Aqueous Chlorine In The Gastric Fluid Of The Rat, Michael Gary Nickelsen

Chemistry & Biochemistry Theses & Dissertations

Gastric fluid was recovered from Sprague-Dawley rats that had been fasted for 24 hr or 48 hr and administered 4 mL deionized water. The protein, carbohydrate and chloride ion content of the gastric fluid was determined.

When gastric fluid is chlorinated with radiolabeled chlorine to concentrations between 323 and 375 mg/L, analyzed by high performance chromatography followed by liquid scintillation counting, as much as 59% of the radiolabeled chlorine was associated with organic components of the gastric fluid.

Model studies with the aromatic amino acids and the protein pepsin showed the formation of chlorinated analogs. Two chlorinated amino acid derivatives …

Uniform L1 Behavior In Classes Of Integrodifferential Equations With Convex Kernels, Richard Noren

Mathematics & Statistics Faculty Publications

No abstract provided.

The Energy-Dependence Of Polarization Observables In The ²H(D,Γ)⁴He Reaction, H. R. Weller, R. M. Whitton, J. Langenbrunner, Evans Hayward, W. R. Dodge, S. Kuhn, D. R. Tilley

Physics Faculty Publications

Measurements of the tensor and vector analyzing powers, A_yy(130°) and A_y(130°), have been obtained for the ²H(d,γ )⁴He reaction for energies ranging from E_d(lab) = 0.3 MeV to E_d(lab) = _{50 MeV}. The A_yy(130°) data are sensitive to the D-state present in the ground state of ⁴He and are observed to have their maximum value near E_d = 30 MeV. The vector analyzing power data show a maximum near E_d = 3 MeV. The data are compared to the results of a microscopic …

No Antitwins In Minimal Imperfect Graphs, Stephan Olariu

Computer Science Faculty Publications

It is customary to call vertices x and y twins if every vertex distinct from x and y is adjacent either to both of them or to neither of them. By analogy, we shall call vertices x and yantitwins if every vertex distinct from x and y is adjacent to precisely one of them. Lovász proved that no minimal imperfect graph has twins. The purpose of this note is to prove the analogous statement for antitwins.

The Effects Of Siltation On Recruitment Of Spiny Lobsters, Panulirus Argus, William F. Herrnkind, Mark J. Butler, Richard A. Tankersley

Biological Sciences Faculty Publications

Fewer juvenile pinry lobsters were found in areas of the Florida Keys where their primary habitat was heavily silted as compared with similar, less silted habitat. Several hypotheses explaining this relationship were tested, and the time-to-metamorphosis was compared for settling pueruli within silted and nonsilted algae stands. Limited postlarval settlement and avoidance of silted algal habitats by juveniles, probably accounts for the paucity of young lobsters in heavily silted sites. In addition, although juvenile lobsters are nonselective predators, lower prey availability in silted algae probably promotes transciency which, in turn, causes increased mortality by predation while juveniles are exposed.

Evaluation Of Possible Reproductively Mediated Character Displacement In The Crayfishes, Orconectes Rusticus And O. Sanbornii, Mark J. Butler Iv

Biological Sciences Faculty Publications

Orconectes rusticus is replacing several species of crayfishes in north-central and northeastern North America, including O. sanbornii in Ohio. Recent evidence suggests that the species replacements may be driven by asymmetrical reproductive success favoring O. rusticus. Nonetheless, some sympatric associations appear locally persistent. Because crayfish demonstrate size assortative mating and there is a disparity in the sizes of the species, further divergence in the sizes of the species in sympatry could enhance reproductive isolation, ultimately providing a mechanism for character displacement. To test this hypothesis the size differentials between crayfish collected from allopatric and sympatric populations in east-central Ohio …

Variability Of Surface Pigment Concentrations In The South Atlantic Bight, Charles R. Mcclain, James A. Yoder, L. P. Atkinson, J. O. Blanton, T. N. Lee, J. J. Singer, Frank Muller-Karger

CCPO Publications

A 1‐year time sequence (November 1978 through October 1979) of surface pigment images from the South Atlantic Bight (SAB) was derived from the Nimbus 7 coastal zone color scanner. This data set is augmented with in situ observations of hydrographic parameters, freshwater discharge, sea level, coastal winds, and currents for the purpose of examining the coupling between physical processes and the spatial and temporal variability of the surface pigment fields. The SAB is divided into three regions: the east Florida shelf, the Georgia‐South Carolina shelf and the Carolina Capes. Six‐month "seasonal" mean pigment fields and time series of mean values …

A Mathematical Model Of Tumor Growth By Diffusion, John A. Adam

Mathematics & Statistics Faculty Publications

A diffusion model of the prevascular stage of tumor growth is presented. The basic feature of such a model is the diffusion of growth inhibitor, which is produced at a spatially non-uniform rate within the tissue. Regimes of limited and unlimited tissue growth are determined, and the consistency of this and simpler models is discussed in the light of observational results.

A Mathematical Model Of The Dynamics Of An Optically Pumped Four-Level Solid State Laser System, Lila Freeman Roberts

Mathematics & Statistics Theses & Dissertations

This is a study of a mathematical model of the dynamics of an optically pumped four-level solid state laser system. A general mathematical model that describes the spatial and temporal evolution of the electron populations in the laser rod as well as the development of the left and right traveling photon fluxes in the cavity is developed. The model consists of a coupled set of first order semilinear partial differential equations. While the model was developed for Titanium-doped sapphire lasers, it is applicable to three and four level lasers in general.

The analysis of the model is conducted in two …

Consequences Of Thymidine Catabolism For Estimates Of Bacterial Production: An Example From A Coastal Marine Sediment, Kevin R. Carman, Fred C. Dobbs, James B. Guckert

OES Faculty Publications

Radioactively labeled thymidine (TdR) has been used extensively to measure bacterial production in aquatic environments, but critical assumptions of the TdR technique often have gone untested. In this study of a coastal marine sediment, the metabolic fate of methyl [³H]TdR and methyl [¹⁴C]TdR was at variance with the assumptions necessary for determining bacterial production. Only 2% of incorporated radioactivity was recovered in the DNA fraction of TCA-insoluble material following time-course incubations of l-300 min. At least the methyl group of TdR was extensively catabolized, as shown by copious production of ¹⁴C0₂. The temporal …

An Optically Controlled Closing And Opening Semiconductor Switch, K. H. Schoenbach, V. K. Lakdawala, R. Germer, S. T. Ko

Electrical & Computer Engineering Faculty Publications

A concept for a bulk semiconductor switch is presented, where the conductivity is increased and reduced, respectively, through illumination with light of different wavelengths. The increase in conductivity is accomplished by electron ionization from deep centers and generation of bound holes. The reduction of conductivity is obtained by hole ionization from the excited centers and subsequent recombination of free electrons and holes. The transient behavior of electron and hole density in a high power semiconductor (GaAs:Cu) switch is computed by means of a rate equation model. Changes in conductivity by five orders of magnitude can be obtained.

Gas Permeation Measurements On Small Polymer Specimens, Karen S. Burns

Chemistry & Biochemistry Theses & Dissertations

Mass spectrometry was used to measure oxygen and nitrogen permeabilities while polarography was used to measure oxygen permeabilities for several contact lens materials. Applicable sample holders were designed and fabricated to accommodate curved and flat specimens with surface areas of 0.5 cm² and 1.0 cm² and thicknesses between 0.025 mm and 0.500 mm. A prepared standard was used to calibrate the mass spectrometric analyses.

The oxygen permeability values determined by mass spectrometry were significantly greater than those determined by polarography. This was attributed to the phase boundary phenomena and the limiting oxygen permeance of water inherent in the …

Model Of Hot-Film Sensor With Substrate Effects, David Mcalpine Judge

Electrical & Computer Engineering Theses & Dissertations

A detailed mathematical model is constructed to investigate the frequency response of a hot-film anemometer system. Since several diverse factors affect the frequency response, the analysis is broken down into three main parts. Each part is a detailed mathematical model. The first model consists of the ordinary differential equations which govern the electronics of the feedback system and heat transfer of the sensor. An important simplification in this model is that the rate of heat conduction from the sensor to its substrate is constant.

In the second model the unsteady state heat transfer properties of the substrate are examined by …

Phytoplankton Dynamics In The Very Low Salinity Region Of The James River Estuary, Virginia, U.S.A., Changho Moon

OES Theses and Dissertations

During summer and autumn discharge from the James River estuary, Virginia, was less than 120 _m³sec^-1. There was a peak phytoplankton biomass in the very low salinity region (defined as the location where surface salinity measured less than 0.5$ 0/00) and this peak represented five to ten times greater biomass than adjacent waters. The peak biomass occurred independent of the tidal state and the location of nutrient inputs. It disappeared during winter and spring, and nutrient limitation was not responsible for the low phytoplankton biomass, indicating there were physical, not chemical controlling factors.

The peak biomass …

A Study Of Flow Separation In Transonic Flow Using Inviscid And Viscous Cfd Schemes, James Andrew Rhodes

Mechanical & Aerospace Engineering Theses & Dissertations

A comparison of flow separation in transonic flows is made using various computational schemes which solve the Euler and the Navier-Stokes equations of fluid mechanics. The flows examined are computed using several simple two-dimensional configurations including a backward facing step and a bump in a channel. Comparison of the results obtained using shock fitting and flux vector splitting methods are presented and the results obtained using the Euler codes are compared to results on the same configurations using a code which solves the Navier-Stokes equations.

Molting In The Mature Female Blue Crab, Callinectes Sapidus, Rathbun, Kirk J. Havens

OES Theses and Dissertations

The present study examines the hypothesis that mature female blue crabs, Callinectes sapidus, do not have a terminal anecdysis. Induced molting via eyestalk ablation, size frequency distributions and gonad and limb regeneration indices from field collected animals are used as indicators of potential post maturity molts.

Eyestalk ablation of mature females resulted in ecdysis approximately 51 days after ablation, indicating a physiological ability if mature females to complete ecdysis. Analysis of size frequency distributions indicates two distinct shifts from smaller to larger females, one in early spring and a second in early fall. While migration of larger females into …

Discrimination Of Subparallel Beach Ridges Using Detrital Ilmenite Composition And Fourier Shape Analysis, Allen E. Evans Jr.

OES Theses and Dissertations

Elemental composition (Fe, Ti, Mn, Mg, V, Cu, Ni, Zn, and Cr) and Fourier shape analysis of magnetically separated detrital ilmenite from seven Pleistocene and modern beach sand deposits of the Southeastern Virginia Coastal Plain were used to distinguish each deposit. Geomorphic expression, crosscutting relationships and proximity to the present shoreline differentiates the relative age of the seven sampled beach deposits. Analysis of ilmenite elemental composition, independent of geomorphic expression, distinguished beach sands of

different age and was successful in determining that each beach contained ilmenite similar in composition. Of the seven beach ridges tested, subtle yet significant differences in …

Investigation Of Complex Formation By Oligomers Of Cytosine And Guanosine, Steven Roberts Davis

Chemistry & Biochemistry Theses & Dissertations

Duplex formation between oligo(C:G) _n where n=3 to 4 was shown not to occur under conditions favorable for duplex formation between poly G and poly C. Instead, a stable guano sine self-structure was found to form which a T_m of 50°C for (Gp)₃ and 80°C for (Gp)₄ at strand concentrations of 10^-5M in 1M NaCl. Neither a duplex nor a self-structure formed in the absence of salt.

Oligomers of guanosine and cytosine were obtained by basic hydrolysis and separated according to chain length using DEAE Sephadex column chromatography. Separation of cytosine oligomers with chain lengths …

An Application Of Global Optimization Algorithm For Modal Parameter Identification, Chung-Men Chen

Mechanical & Aerospace Engineering Theses & Dissertations

Single-mode projection filters for modal parameter identification for flexible structures are introduced. An effective two-dimensional global optimization method using interval analysis is combined with the projection filters to facilitate identification for modal frequency and damping. A numerical simulation of a ten-mode structure is presented to illustrate the feasibility of the new method. The projection filters are practical for parallel processing implementation.

Sediment Budgets And Shoreline Dynamics Cape Henry, Virginia, Marcia R. Berman

OES Theses and Dissertations

Analysis of 1183 beach profiles from Cape Henry, Virginia indicated that the recession-erosion ''rule" established by the Army Corps of Engineers underestimates the short-term response of the shoreline to changes in sediment volume.

Correlation between bi-weekly backshore volume change and the change in high water line (HWL) position was stronger (0.67 < r < 0.88) than correlation between bi-weekly total volume change and the change in mean low water (MLW) shoreline position (0.33 < r < 0.52). The short-term change in position of MLW is influenced by minor features such as bars. The position of the HWL is controlled by volume change at the backshore.

Correlation between change in HWL and MLW shoreline positions improved from r = 0.01 tor·= 0.67 for intervals of two weeks to two years, respectively. This suggests parallel-shore retreat only may be operable for greater than two-year periods.

Sulfide In Shelf/Slope Waters Of The Western Atlantic, Christian F. Krahforst

OES Theses and Dissertations

Sulfide in the surface ocean has been recently considered as a source of hydrogen sulfide gas in the marine boundary layer. This "oxic" sulfide may also be important as a ligand in trace metal complexation. In the absence of actual data, the existence of sulfide in the ocean mixed layer remains speculative. The purpose of this study was to develop a sensitive technique (having picomolar detection limits) for the determination of sulfide in seawater, and to investigate the distribution of sulfide in the surface ocean.

In order to assess the abundance and distribution of sulfide in surface waters, samples were …

The Geochemistry Of Selenium And Sulfur In A Coastal Salt Marsh, David Jay Velinsky

OES Theses and Dissertations

Investigation of the various chemical forms of selenium and sulfur in sediments and pore waters can provide information about various oxidation/reduction processes. Five cores were obtained from the Great Marsh, from April 1985 to June 1986. Sampling times coincided with the seasonal redox cycle known to occur within the marsh system. Sediments were analyzed for various selenium and sulfur phases.

Iron monosulfides and elemental sulfur both display large seasonal changes in concentration and distribution with depth, indicating a coupling with redox conditions. In contrast, the depth distribution of greigite did not show appreciable changes with season. Pyrite underwent large concentration …

Large Deviation Local Limit Theorems For Ratio Statistics, Sanjeev V. Sabnis

Mathematics & Statistics Theses & Dissertations

Let {T„, n > 1} be an arbitrary sequence of non-lattice random variables and {S_n, n > 1} be another sequence of positive non-lattice random variables. Let the two sequences be independent. Let Ø_1n and Ø_2n be the moment genereating functions of {Tn, n > 1} and { S_n,n > 1} respectively. Let {a_n} be a sequence of real numbers such that a_n —»• oo.

Analysis Of Phytoplankton And Particle Variability At A Warm Core Ring/Shelf Break Front Using Flow Cytometry, Kimberly G. Davis

OES Theses and Dissertations

Particle variability at a Gulf Stream warm core ring/ shelf break front on 09 Nay 1985 was analyzed. Single particle measurements of fluorescence, perpendicular light scatter, and volume were made using a FACS Analyzer flow cytometer. Advantages and disadvantages of at-sea use of the instrument are described. To evaluate the flow cytometry data, individual particle data were compared with bulk phytoplankton and particle measurements. Abundance and size distributions of fluorescent and non-fluorescent particles indicated a convergence zone at the front while upwelling was likely within the ring perimeter. Variability in fluorescence (approximating chlorophyll A) and cell biovolume exposed regions of …

Reactions Of Organic N-Chloramines In The Gastric Fluid Of The Rat, Kathryn E. Mazina

Chemistry & Biochemistry Theses & Dissertations

Using chlorine as a drinking water disinfectant may have potential health effects due to its reactivity with organic amino nitrogen compounds found in the stomach. Organic N-chloramines have been shown to form in the stomachs of laboratory rats. The possible reactions of N-chloramines in the stomach fluid were examined in this study using a model radiolabeled N-chloramine. ³⁶Cl-N-Chloropiperidine, was synthesized and purified to remove ³⁶Cl-chloride. Stomach fluid was obtained from Sprague-Dawley rats which had been first fasted for 24 or 48 hours and then administered 3 mL of deionized water. Different concentrations of radiolabeled chloramine were reacted with …

Software Tools For Performance Evaluation Of Concurrent Processing, Rodrogo A. Obando

Electrical & Computer Engineering Theses & Dissertations

The development and use of software tools for performance evaluation of concurrent processing is presented in this thesis. The particular concurrent processing architecture proposed by Stoughton and Mielke is investigated. The modelling of this architecture is based on Petri net theory and it can be studied making use of circuit theory. Computation of lower bounds for Time Between Outputs (TBO) and Time Between Input and Output (TBIO) can be accomplished by using principles of circuit theory, among others. This new modelling needs to be deeply evaluated and studied. This evaluation and study is accomplished with the tools developed and presented …

Cross-Shore Sediment Transport In Relation To Waves And Currents In A Groin Compartment, Hyo Jin Kang

OES Theses and Dissertations

In nearshore areas waves are generally irregular, and the irregular wave-induced currents have different peak velocities (magnitude asymmetry) and durations (duration asymmetry) between forward and backward motions. These asymmetries may produce a net cross-shore sediment transport in one direction. The sediment transport mostly occurs as bedload where the waves are non-breaking.

Sediment transport on a sloping bed is also affected by gravity, and accordingly the Shields parameter should be re-evaluated for a grain on a sloping bed. It was also found that the affect of a steady current that interacts nonlinearly with the waves was important for the cross-shore sediment …

Synthesis Of Potential Long Acting Calcium Channel Antagonists: A Study Of 1,4-Dihydropyridine Analogs, Thomas E. Christos

Chemistry & Biochemistry Theses & Dissertations

An investigation was undertaken to synthesize and evaluate longer acting analogs to the antihypertensive agent nifedipine. Analogs that are capable of covalent bonding to the nifedipine receptor were considered. These compounds may show increased activity as they will remain at the receptor for a longer period of time.

During the course of this study, previously unreported and unexpected products were encountered and lead to a more intense examination of the Hantzsch synthesis. Of particular interest was the oxazolidine 25 which was a major component of the Hantzsch synthesis when ethanolamine was used instead of ammonium hydroxide. Also isolated during this …