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Full-Text Articles in Physical Sciences and Mathematics

Teaming With Technology: Adaptive Automation In Joint Cognitive Systems For Industry 5.0, Jessica Johnson Jan 2025

Teaming With Technology: Adaptive Automation In Joint Cognitive Systems For Industry 5.0, Jessica Johnson

Virginia Digital Maritime Center (VDMC) Faculty Publications

Adaptive automation enables dynamic reallocation of functions between people and autonomous agents to improve performance in complex work. This paper presents a meta-analysis of experimental and quasi-experimental studies (2000-2025) on joint cognitive systems in industrially relevant contexts, quantifying effects on task performance, safety/failure management, workload, trust, and learning. Across studies, adaptive automation reliably reduces operator workload and shows moderate gains in task performance and safety, with healthier trust dynamics when adaptations are triggered by human-state or event cues, made transparent to the user, and remain rapidly overridable. Risks emerge when performance-triggered switching is opaque or poorly timed, which can erode …


Computer Science For Middle School (Cs4ms), Melani Loney, Lisa Steffian, Tancy J. Vandecar-Burdin Jan 2025

Computer Science For Middle School (Cs4ms), Melani Loney, Lisa Steffian, Tancy J. Vandecar-Burdin

Center for Educational Partnerships Publications

This session will discuss the project Computer Science for Middle School and the associated findings. This Virginia Department of Education funded project provides computer science Professional Development opportunities for in-service teachers, located in Southeastern Virginia, who instruct students in middle school grades 6- 8. Participating teachers learn to integrate computer science standards into core and elective content through online, asynchronous microcredentials and in-person Summer Workshops. The presentation will include project findings and next steps including teacher efficacy for implementing the computer science standards before and after completing the microcredentials and their students’ attitudes about computer science.


Transformative Impact Of Ai And Digital Technologies On The Fintech Industry: A Comprehensive Review, Soudeh Pazouki, Behdad Jamshidi, Armia Jalali, Arya Tafreshi Jan 2025

Transformative Impact Of Ai And Digital Technologies On The Fintech Industry: A Comprehensive Review, Soudeh Pazouki, Behdad Jamshidi, Armia Jalali, Arya Tafreshi

Finance Faculty Publications

This paper examines the impact of artificial intelligence (AI) and digital technologies on the financial technology (FinTech) industry and demonstrates how AI- enabled strategies are increasing the ability of businesses not only to grow, but also to better serve their customers through operational efficiencies. But as immersive as the technological advancements may be, they present challenges in connection with increasingly complicated licensing regulations and a constantly evolving technological landscape. We examine the way AI and algorithms are streamlining workflows, enhancing productivity and expanding access to financial resources for traditionally under – served populations. The paper also discusses the macroeconomic implications …


Extending A Pretrained Language Model (Bert) Using An Ontological Perspective To Classify Students' Scientific Expertise Level From Written Responses, Heqiao Wang, Kevin C. Haudek, Amanda D. Manzanares, Chelsie L. Romulo, Emily A. Royse, Caterina B. Azzarello Jan 2025

Extending A Pretrained Language Model (Bert) Using An Ontological Perspective To Classify Students' Scientific Expertise Level From Written Responses, Heqiao Wang, Kevin C. Haudek, Amanda D. Manzanares, Chelsie L. Romulo, Emily A. Royse, Caterina B. Azzarello

Human Movement Studies & Special Education Faculty Publications

The complex and interdisciplinary nature of scientific concepts presents formidable challenges for students in developing their knowledge-in-use skills. The utilization of computerized analysis for evaluating students' contextualized constructed responses offers a potential avenue for educators to develop personalized and scalable interventions, thus supporting the current teaching and learning of science. While prior research in artificial intelligence has demonstrated the effectiveness of algorithms, including Bidirectional Encoder Representations from Transformers (BERT), in tasks like automated classifications of constructed responses, these efforts have predominantly leaned towards text-level features, often overlooking the exploration of conceptual ideas embedded in students' responses from a cognitive perspective. …


Fares On Fairness: Using A Total Error Framework To Examine The Role Of Measurement And Representation In Training Data On Model Fairness And Bias, Patrick Oliver Schenk, Christoph Kern, Trent D. Buskirk Jan 2025

Fares On Fairness: Using A Total Error Framework To Examine The Role Of Measurement And Representation In Training Data On Model Fairness And Bias, Patrick Oliver Schenk, Christoph Kern, Trent D. Buskirk

Information Technology & Decision Sciences Faculty Publications

Data-driven decisions, often based on predictions from machine learning (ML) models are becoming ubiquitous. For these decisions to be just, the underlying ML models must be fair, i.e., work equally well for all parts of the population such as groups defined by gender or age. What are the logical next steps if, however, a trained model is accurate but not fair? How can we guide the whole data pipeline such that we avoid training unfair models based on inadequate data, recognizing possible sources of unfairness early on? How can the concepts of data-based sources of unfairness that exist in the …


Determining The Transient Electric Field And The Effect Of Pulse Repetition Frequency On The Field In A Repetitive 10-Ns Pulsed Discharge In A Quiescent Ch₄-Air Mixture, Chunqi Jiang Jan 2025

Determining The Transient Electric Field And The Effect Of Pulse Repetition Frequency On The Field In A Repetitive 10-Ns Pulsed Discharge In A Quiescent Ch₄-Air Mixture, Chunqi Jiang

Bioelectrics Publications

The goal of this research is to understand the underlying physics enabled by nanosecond pulsed power in a discharge initiation and the following physicochemical processes that favor lean-fuel plasma ignition for combustion. The hypothesis of this project is that pulsed power waveforms such as the pulse repetition frequency (PRF), voltage amplitude, and dielectric surface alter the reduced electric field during the initiation of the discharge, resulting in different plasma properties, which will vary the physicochemical processes for efficient and selective radical productions. This is especially important for lean-burn combustion and reducing emission.


Dynamics Of Water Mass Exchange Across The Central Ross Sea Slope, Yuanjie Chen, Zhaoru Zhang, Pasquale Castagno, Xianxian Han, Michael S. Dinniman, Zhiqiang Liu, Chuning Wang Jan 2025

Dynamics Of Water Mass Exchange Across The Central Ross Sea Slope, Yuanjie Chen, Zhaoru Zhang, Pasquale Castagno, Xianxian Han, Michael S. Dinniman, Zhiqiang Liu, Chuning Wang

OES Faculty Publications

The central Ross Sea slope (CRSS) is a critical region for water mass exchange, significantly influencing the physical and biological processes of the Ross Sea shelf and the global overturning circulation. This study utilizes a high-resolution ocean-ice shelf-sea ice coupled model to investigate the mechanisms driving this exchange, involving the onshore transport of circumpolar deep water (CDW) and the offshore transport of dense shelf water (DSW). Combining numerical simulations and mooring observations, this work reveals high-frequency oscillations with a periodicity of ∼32 hr in CDW transport induced by Topographic Rossby Waves and DSW transport induced by cyclonic eddies. These findings …


Fault Tree Analysis For Robust Design, Jonathan Degroff, Gene Jean-Win Hou Jan 2025

Fault Tree Analysis For Robust Design, Jonathan Degroff, Gene Jean-Win Hou

Mechanical & Aerospace Engineering Faculty Publications

The objective of this research is to incorporate system failure into a robust design formation and solution process. The system failure referred to here will be built using fault tree analysis (FTA), which will take all lower-level failure events into consideration. Two examples are investigated here. One will directly treat the probabilities of the basis events as design variables, The other will be formulated in five different models: deterministic design optimization, the reliability index-based, the “and” gate-based, the “or” gate-based and the “inhibit” gate-based robust design. Their corresponding optimization solutions will be compared with each other. The post-optimality analysis of …


Polarized Positrons At Ce⁺Baf, A. Ushakov, J. Benesch, M. Bruker, L. Cardman, J. Conway, S. Covrig Dusa, P. Degtiarenko, Y. Enomoto, S. Gessner, P. Ghoshal, S. Gopinath, J. Grames, C. Gulliford, S. Habet, G. Hays, C. Hernández-García, A. Hofler, R. Kazimi, M. Kostin, V. O. Kostroun, F. Lin, V. Lizárraga-Rubio, K. Mahler, Y. Morikawa, S. Nagaitsev, S. Ogur, G. Palacios-Serrano, N. Raut, B. Rimmer, Y. Roblin, A. Seryi, K. Smolenski, M. Stutzman, R. Suleiman, A. Sy, N. Taylor, D. Turner, A. Ushakov, C. Valerio-Lizarraga, E. Voutier, S. Wang, Y. Zhang Jan 2025

Polarized Positrons At Ce⁺Baf, A. Ushakov, J. Benesch, M. Bruker, L. Cardman, J. Conway, S. Covrig Dusa, P. Degtiarenko, Y. Enomoto, S. Gessner, P. Ghoshal, S. Gopinath, J. Grames, C. Gulliford, S. Habet, G. Hays, C. Hernández-García, A. Hofler, R. Kazimi, M. Kostin, V. O. Kostroun, F. Lin, V. Lizárraga-Rubio, K. Mahler, Y. Morikawa, S. Nagaitsev, S. Ogur, G. Palacios-Serrano, N. Raut, B. Rimmer, Y. Roblin, A. Seryi, K. Smolenski, M. Stutzman, R. Suleiman, A. Sy, N. Taylor, D. Turner, A. Ushakov, C. Valerio-Lizarraga, E. Voutier, S. Wang, Y. Zhang

Mechanical & Aerospace Engineering Faculty Publications

A baseline concept for a continuous wave (CW) polarized positron injector was developed for the Continuous Electron Beam Accelerator Facility (CEBAF) at Jefferson Lab [1]. This concept is based on positron beam generation by a high current polarized electron beam (1 mA, 120 MeV, >85% polarization) irradiating a rotating water-cooled tungsten target or liquid metal target. The update on the development of the Ce⁺BAF injector concept including the polarized electron source, the development of high power targets, simulations of positron capture, the design of the transport line from the positron injector to the CEBAF North Linac and the planned experiment …


Revealing Spatiotemporal Neural Activation Patterns In Electrocorticography Recordings Of Human Speech Production By Mutual Information, Julio Kovacs, Dean Krusienski, Minu Maninder, Willy Wriggers Jan 2025

Revealing Spatiotemporal Neural Activation Patterns In Electrocorticography Recordings Of Human Speech Production By Mutual Information, Julio Kovacs, Dean Krusienski, Minu Maninder, Willy Wriggers

Mechanical & Aerospace Engineering Faculty Publications

Background

Spatiotemporal mapping of neural activity during continuous speech production has been traditionally approached using correlation coefficient (CC) analysis between cortical signals and speech recordings. A prior study employed this approach using electrocorticography (ECoG) data from participants who underwent invasive intracranial monitoring for epilepsy. However, CC cannot detect nonlinear relationships and is dominated by the correspondence between periods of silence and of non-silence.

New Method

We introduce the mutual information (MI) measure, which can capture both linear and nonlinear dependencies. We validated CC and MI on the sub-second spatiotemporal brain activity recorded during continuous speech tasks. To refine the results, …


Mass-Adaptive Admittance Control For Robotic Manipulators, Hossein Gholampour, Jonathon E. Slightam, Logan E. Beaver Jan 2025

Mass-Adaptive Admittance Control For Robotic Manipulators, Hossein Gholampour, Jonathon E. Slightam, Logan E. Beaver

Mechanical & Aerospace Engineering Faculty Publications

Handling objects with unknown or changing masses is a common challenge in robotics, often leading to errors or instability if the control system cannot adapt in realtime. In this paper, we present a novel approach that enables a six-degrees-of-freedom robotic manipulator to reliably follow waypoints while automatically estimating and compensating for unknown payload weight. Our method integrates an admittance control framework with a mass estimator, allowing the robot to dynamically update an excitation force to compensate for the payload mass. This strategy mitigates end-effector sagging and preserves stability when handling objects of unknown weights. We experimentally validated our approach in …


Optimal Manipulation Motion Action Planner Enabled By Physics Informed Neural Networks, Jonathon E. Slightam, Logan E. Beaver Jan 2025

Optimal Manipulation Motion Action Planner Enabled By Physics Informed Neural Networks, Jonathon E. Slightam, Logan E. Beaver

Mechanical & Aerospace Engineering Faculty Publications

Autonomous robotic manipulation in unstructured environments faces many challenges and is hindered by capabilities that bridge the gap between perception and acting on the world. Action plans that are centric to object motion rather than end-of-arm tooling behavior may aid this. This paper presents an autonomous action planner for a feedback linearizeable system comprised of three base motions that can be leveraged on their own or in combination to give custom motion plans. The optimization routine for the three different types of motion are presented, which are integrated into physics informed neural networks. A component of this is the autonomy …


Line List For The A²Π−X²Σ⁺ And The B²Σ⁺−X²Σ⁺ Band Systems Of Caf, Léo Lavy, Peter F. Bernath, Adam Pastorek Jan 2025

Line List For The A²Π−X²Σ⁺ And The B²Σ⁺−X²Σ⁺ Band Systems Of Caf, Léo Lavy, Peter F. Bernath, Adam Pastorek

Chemistry & Biochemistry Faculty Publications

The spectral analysis of molecule-rich asymptotic giant branch (AGB) stars is challenging. Although other calcium and fluorine bearing molecules are observed in the microwave and in the visible spectrum of AGB stars, CaF has never been detected, despite favorable chemical equilibrium predictions. Yet, measuring the CaF abundance could give more insight into the fluorine budget of AGB stars and allow better simulation of stellar spectra. In this work, we present an analysis of the visible spectrum of CaF obtained with a Fourier transform spectrometer. CaF A²Π−X²Σ⁺ and B²Σ⁺−X²Σ⁺ band systems were excited with a hollow cathode discharge. Using previous fluorescence …


Collision-Induced Absorption Spectra Of N₂ And Ch₄, Ryan M. Johnson, Peter F. Bernath, Brant Billinghurst, Jianbao Zhao Jan 2025

Collision-Induced Absorption Spectra Of N₂ And Ch₄, Ryan M. Johnson, Peter F. Bernath, Brant Billinghurst, Jianbao Zhao

Chemistry & Biochemistry Faculty Publications

Collision-induced spectra are essential for radiative transfer modeling of Titan's atmosphere. We present experimental spectra of nitrogen–methane mixtures with an accompanying fit of N₂-CH₄ collision-induced absorption in the 30–400 cm⁻¹ region at about 130 K. We found a peak absorption of 2.30 × 10⁻⁵ cm⁻¹ amagat⁻² at 75 cm⁻¹ and a secondary peak of 1.35 × 10⁻⁵ c⁻¹ amagat⁻² at 206.5 cm⁻¹, which agrees with previous studies. Our work does not support the suggestion that N₂-CH₄ CIA in the far-infrared should be increased by about 50%, as suggested by spectroscopic modeling of Titan using data from A. Borysow & C. …


Transient Transmembrane-Electrostatically Localized Protons And Transmembrane Potential In A Laser Flashed Bacteriorhodopsin Purple Membrane Open Flat Sheet - Summary, James Weifu Lee Jan 2025

Transient Transmembrane-Electrostatically Localized Protons And Transmembrane Potential In A Laser Flashed Bacteriorhodopsin Purple Membrane Open Flat Sheet - Summary, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

The transmembrane-electrostatically localized protons/cations charges (TELCs, also known as TELPs) model may serve as a unified framework to explain a wide range of bioenergetic phenomena. Transient transmembrane-electrostatically localized protons (TELPs) and transmembrane potential in a laser flash-energized bacteriorhodopsin (bR) purple membrane (PM) open flat sheet are now better analyzed. Under the Heberle et al. (1994) experimental conditions, the number of bR molecules is now calculated to be 8200 per PM open flat sheet with a diameter of 600 nm. With a single-turnover laser flash intensity of 3 mJ/cm² to photoexcite 10% of the bR molecules, the laser flash-induced peak TELCs …


Experimental Absorption Cross Sections For Zro, Léo Lavy, Peter F. Bernath, Manish Bhusal, Jacques Liévin Jan 2025

Experimental Absorption Cross Sections For Zro, Léo Lavy, Peter F. Bernath, Manish Bhusal, Jacques Liévin

Chemistry & Biochemistry Faculty Publications

Absorption cross sections for ZrO are provided and can be used as a template to interpret spectra of S-type stars. The ZrO spectrum was measured in emission from a carbon furnace at 2700 K and calibrated using synthetic spectra of ⁹⁰Zr¹⁶O. A set of nearly isolated molecular lines has been used for the calibration. We also thoroughly review the literature on the spectroscopy of ZrO. Comparison of the experimental spectrum with currently available line lists revealed issues in ZrO spectral simulation. (a) Within band systems, the relative intensities are not always well reproduced. (b) We identify yet unreported band systems, …


Exploring Physics Teacher Identity: Pathways Toward Equitable Instruction Among Teachers, Clausell Mathis, Jomo Mutegi, Turhan Carroll, Maya Patel, Andrea Wooley Jan 2025

Exploring Physics Teacher Identity: Pathways Toward Equitable Instruction Among Teachers, Clausell Mathis, Jomo Mutegi, Turhan Carroll, Maya Patel, Andrea Wooley

Teaching & Learning Faculty Publications

Physics teacher identity encompasses teachers' beliefs and views toward being a physics teacher. Physics teacher identity is influenced by teachers' perspectives on physics teaching and learning. Previous studies on teacher identity in general suggest that the construct is complex and malleable. Studies further suggest that it influences instructional methods, student engagement, and classroom environment. However, within physics education, there has yet to be an examination of how physics teacher identity influences "equitable" teaching approaches. This qualitative study sought to identify various dimensions of physics teacher identity and its implications for physics education research. We interviewed secondary and postsecondary physics teachers …


Why Ai Monitoring Faces Resistance And What Healthcare Organizations Can Do About It: An Emotion-Based Perspective, Karl Werder, Lan Cao, Eun Hee Park, Balasubramaniam Ramesh Jan 2025

Why Ai Monitoring Faces Resistance And What Healthcare Organizations Can Do About It: An Emotion-Based Perspective, Karl Werder, Lan Cao, Eun Hee Park, Balasubramaniam Ramesh

Information Technology & Decision Sciences Faculty Publications

Continuous monitoring of patients' health facilitated by artificial intelligence (AI) has enhanced the quality of health care, that is, the ability to access effective care. However, AI monitoring often encounters resistance to adoption by decision makers. Healthcare organizations frequently assume that the resistance stems from patients' rational evaluation of the technology's costs and benefits. Recent research challenges this assumption and suggests that the resistance to AI monitoring is influenced by the emotional experiences of patients and their surrogate decision makers. We develop a framework from an emotional perspective, provide important implications for healthcare organizations, and offer recommendations to help reduce …


Building Cyber Resilience: Educational Programs In K-12 Education, Mildred Jones, Vukica Jovanovic, Petros Katsioloudis Jan 2025

Building Cyber Resilience: Educational Programs In K-12 Education, Mildred Jones, Vukica Jovanovic, Petros Katsioloudis

Engineering Technology Faculty Publications

The article discusses the challenges of teaching cybersecurity in K-12 education. Topics mentioned include the lack of access to resources and appropriate professional development, the career and technical education cybersecurity pathways, the fundamental pathways for cybersecurity and information technology and the results of program evaluation in several local community high schools from 2021 and 2022.


Nexus: Network Exploration For Exploiting Unsafe Sequences In Multi-Turn Llm Jailbreaks, Javad Rafiei Asl, Sidhant Narula, Mohammad Ghasemigol, Eduardo Blanco, Daniel Takabi Jan 2025

Nexus: Network Exploration For Exploiting Unsafe Sequences In Multi-Turn Llm Jailbreaks, Javad Rafiei Asl, Sidhant Narula, Mohammad Ghasemigol, Eduardo Blanco, Daniel Takabi

Computer Science Faculty Publications

Large Language Models (LLMs) have revolutionized natural language processing, yet remain vulnerable to jailbreak attacks—particularly multi-turn jailbreaks that distribute malicious intent across benign exchanges, thereby bypassing alignment mechanisms. Existing approaches often suffer from limited exploration of the adversarial space, rely on hand-crafted heuristics, or lack systematic query refinement. We propose NEXUS (Network Exploration for eXploiting Unsafe Sequences), a modular framework for constructing, refining, and executing optimized multi-turn attacks. NEXUS comprises: (1) ThoughtNet, which hierarchically expands a harmful intent into a structured semantic network of topics, entities, and query chains; (2) a feedback-driven Simulator that iteratively refines and prunes these chains …


Contextual Memory Recall: A Novel Metric For Class Incremental Learning, Balasubramanian S, Sai Subramaniam M., Sai Sriram Talasu, Yedu Krishna P., Pranav Phanindra Sai M., Darshan Gera, Ravi Mukkamala Jan 2025

Contextual Memory Recall: A Novel Metric For Class Incremental Learning, Balasubramanian S, Sai Subramaniam M., Sai Sriram Talasu, Yedu Krishna P., Pranav Phanindra Sai M., Darshan Gera, Ravi Mukkamala

Computer Science Faculty Publications

We propose a novel metric for class incremental learning (CIL) called Contextual Memory Recall (CMR), which evaluates how well a CIL model recalls previously learned classes when given relevant past cues. Inspired by human memory, CMR offers newer insights into continual aspects of a CIL model that were not addressed by previously proposed metrics for CIL. Specifically, the standard metric, average incremental accuracy (AIA), overlooks the quality of evolving feature representations, whereas our proposed CMR accounts for it. As a result, methods using feature distillation perform well under AIA but poorly under CMR, while those without feature distillation excel under …


The Relative Contribution Of Deep And Shallow Benthic Sources To Iron Supply In The Ross Sea, With Specific Emphasis On The Ross Bank, Blair J.W. Greenan, Michael S. Dinniman, Dennis J. Mcgillicuddy Jr., Peter N. Sedwick, Stefanie L. Mack, Walker O. Smith Jr. Jan 2025

The Relative Contribution Of Deep And Shallow Benthic Sources To Iron Supply In The Ross Sea, With Specific Emphasis On The Ross Bank, Blair J.W. Greenan, Michael S. Dinniman, Dennis J. Mcgillicuddy Jr., Peter N. Sedwick, Stefanie L. Mack, Walker O. Smith Jr.

OES Faculty Publications

Summer primary productivity in the Ross Sea is limited by the availability of dissolved iron (DFe) in the euphotic zone. Previous studies have suggested that benthic sources dominate the supply of DFe to the upper water column in the southern Ross Sea polynya. The purpose of this study is to investigate whether these benthic sources are derived from shallow banks or deeper areas of the continental shelf. Our study combines analysis of in situ observations near Ross Bank with a physical ocean model simulation in an overlapping summertime period to investigate the vertical supply of DFe. Two passive tracer dyes …


Seasonal Variability Of Surface Ocean Carbon Uptake And Chlorophyll-A Concentration In The West Antarctic Peninsula Over Two Decades, Jessica S. Turner, David R. Munro, Amanda Fay, Sharon Stammerjohn, Heather Kim, Oscar Schofield, Heidi Dierssen Jan 2025

Seasonal Variability Of Surface Ocean Carbon Uptake And Chlorophyll-A Concentration In The West Antarctic Peninsula Over Two Decades, Jessica S. Turner, David R. Munro, Amanda Fay, Sharon Stammerjohn, Heather Kim, Oscar Schofield, Heidi Dierssen

OES Faculty Publications

The Southern Ocean plays a vital role in global CO₂ uptake, but the magnitude and even the sign of the flux remain uncertain, and the influence of phytoplankton phenology is underexplored. This study focuses on the West Antarctic Peninsula, a region experiencing rapid climate change, to examine shifts in seasonal carbon uptake. Using 20 years of in situ air-sea CO₂ flux and satellite-derived Chlorophyll-a, we observe that the seasonal cycles of both air-sea CO₂ flux and Chlorophyll-a intensify poleward. The amplitude of the seasonal cycle of the non-thermal component of surface ocean pCO₂ increases with increasing latitude, while the amplitude …


Pygoscelis Penguins Prefer Different Oceanographic And Terrestrial Habitats During The Austral Summer, Katherine L. Gallagher, Rachel Herman, Katherine Walton, Michael S. Dinniman, Heather J. Lynch Jan 2025

Pygoscelis Penguins Prefer Different Oceanographic And Terrestrial Habitats During The Austral Summer, Katherine L. Gallagher, Rachel Herman, Katherine Walton, Michael S. Dinniman, Heather J. Lynch

OES Faculty Publications

Pygoscelis penguins interact with both terrestrial and marine environments, especially during the austral summer when they raise their chicks. Accessible ice-free ground spaces serve as locations for penguins to build colonies and successfully raise chicks while the surrounding marine environment serves as the foraging grounds for adult birds. Penguins must be able to navigate through the waters around their colonies to forage for Antarctic krill (Euphausia superba), their primary prey during the austral summer. Krill, whose distributions are driven partially by the surrounding physics and partially by their behaviors, must also be plentiful in the waters near the …


Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo Jan 2025

Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo

OES Faculty Publications

Mercury loads from Submarine Groundwater Discharge (SGD) may represent an overlooked source of methylmercury (MeHg) to the ocean, affecting human and ecosystem health. The SGD process involves the flow of fresh, saline, or mixed groundwater from coastal aquifers into the oceans classified in different components. Existing studies rarely report the fluxes supplied by the different SGD components; therefore, the relevance of SGD as a source of mercury remains unclear. We aimed to quantify SGD-driven mercury/methylmercury fluxes to the coast, focusing on the largest coastal lagoon in the western Mediterranean. We measured total dissolved mercury and MeHg in surficial and porewaters …


Multi-Centennial Spatial Coherency Among Atlantic Tropical Cyclones From Simulated And Reconstructed Storm Records, Richard M. Sullivan, Elizabeth Wallace, Sylvia Dee, Gabiel A. Vecchi, Wenchang Yang, Kerry Emanuel Jan 2025

Multi-Centennial Spatial Coherency Among Atlantic Tropical Cyclones From Simulated And Reconstructed Storm Records, Richard M. Sullivan, Elizabeth Wallace, Sylvia Dee, Gabiel A. Vecchi, Wenchang Yang, Kerry Emanuel

OES Faculty Publications

Proxy-based reconstructions of long-term Atlantic tropical cyclone (TC) variability reveal low-frequency oscillations in regional TC landfalls over the Common Era. However, the limited spatial coverage and increased uncertainty of the proxy records complicates assessments of this feature. Here we present a new multi-ensemble set of synthetic TCs downscaled from the Last Millennium Reanalysis project, which is based on sea surface temperatures that more accurately reflect past conditions. Throughout ensemble members, there are coherent multi-centennial shifts in landfalls with persistent intervals of increased (decreased) occurrence along the eastern US concurrent with inverse activity in the southwest Caribbean and Gulf of Mexico, …


Topographic Forcing Of Submesoscale Instability In The Antarctic Circumpolar Current, Laur Ferris, Donglai Gong, John Klinck Jan 2025

Topographic Forcing Of Submesoscale Instability In The Antarctic Circumpolar Current, Laur Ferris, Donglai Gong, John Klinck

CCPO Publications

Subpolar frontal zones are characterized by energetic storms, intense seasonal cycles, and close connectivity with surrounding continental shelf topography. At the same time, predicting the ocean state depends on appropriate partition of resolved and parameterized dynamics, the latter of which requires understanding the dynamical processes generating diffusivity throughout the water column. While submesoscale frontal instabilities are shown to produce turbulent kinetic energy (TKE) and mixing in the surface boundary layer (SBL) of the global ocean, their development in complex dynamical regimes (e.g., elevated preexisting turbulence, large ageostrophic shear, or in proximity to topographic boundaries) is less understood. This study investigates …


Determination Of Structural Factors Contributing To Protection Of Zinc Fingers In Estrogen Receptor Α Through Molecular Dynamic Simulations, Patricia B. Lutz, Wesley R. Coombs, Craig A. Bayse Jan 2025

Determination Of Structural Factors Contributing To Protection Of Zinc Fingers In Estrogen Receptor Α Through Molecular Dynamic Simulations, Patricia B. Lutz, Wesley R. Coombs, Craig A. Bayse

Chemistry & Biochemistry Faculty Publications

The ERα transcription factor that induces tumor growth is a potential target for breast cancer treatment. Each monomer of the ERα DNA-binding domain (ERαDBD) homodimer has two conserved (Cys)4-type zinc fingers, ZF1 (N-terminal) and ZF2 (C-terminal). Electrophilic agents release Zn2+ by oxidizing the coordinating Cys of the more labile ZF2 to inhibit dimerization and DNA binding. Microsecond-length molecular dynamics (MD) simulations show that greater flexibility of ZF2 in the ERαDBD monomer leaves its Cys more solvent accessible and less shielded from electrophilic attack by sulfur-centered hydrogen bonds than ZF1 which is buried in the protein. In the …


Unraveling Visible Spectra Of S-Type Stars: The F3Δ–A3Δ (Α System) And E3Π–A3Δ (Β System) Band Systems Of Zro, Manish Bhusal, Peter Bernath, Jacques Liévin Jan 2025

Unraveling Visible Spectra Of S-Type Stars: The F3Δ–A3Δ (Α System) And E3Π–A3Δ (Β System) Band Systems Of Zro, Manish Bhusal, Peter Bernath, Jacques Liévin

Chemistry & Biochemistry Faculty Publications

ZrO has many low-lying states, and its spectra are essential for the characterization of S-type stars. A high-resolution emission spectrum recorded with a Fourier transform spectrometer at the National Solar Observatory is used for the analysis. The 0–0 and 1–0 bands of the f³Δ-a³Δ system (α system) and the 0–0 band of the e³Π-a³Δ system (β system) have been rotationally analyzed using the modern spectral fitting program PGOPHER. New ab initio calculations of transition dipole moments have been performed to determine the band strengths. These band strengths are used to produce line lists that are suitable for the …


Phytochemical Analysis, Antioxidant, And Antibacterial Properties Of Partition Fractions Of Adansonia Digitata And Annona Muricata Extracts Using Chloroform, Ethyl Acetate, Ethanol, And Aqueous Solvent Systems, Fagbohun Oyenike Bushirat, Hassan Abdusalam Adewuyi, Sakariyau Adio Waheed, Maryam Nana Musa, Timothy God-Giveth Olusegun, Ayomide Babatunde Ishola, Agumage Idoko, Adeola Victor Kolawole, Adesanmi Adefunmilayo Oluwatuyi, Sarah Ngozi Agwasim Jan 2025

Phytochemical Analysis, Antioxidant, And Antibacterial Properties Of Partition Fractions Of Adansonia Digitata And Annona Muricata Extracts Using Chloroform, Ethyl Acetate, Ethanol, And Aqueous Solvent Systems, Fagbohun Oyenike Bushirat, Hassan Abdusalam Adewuyi, Sakariyau Adio Waheed, Maryam Nana Musa, Timothy God-Giveth Olusegun, Ayomide Babatunde Ishola, Agumage Idoko, Adeola Victor Kolawole, Adesanmi Adefunmilayo Oluwatuyi, Sarah Ngozi Agwasim

Chemistry & Biochemistry Faculty Publications

Adansonia digitata and Annona muricata are traditionally used medicinal plants with reported pharmacological properties. In this study, we aimed to elucidate the phytochemical composition, antioxidant activity, and antibacterial properties of partition fractions of Adansonia digitata and Annona muricata extracts obtained using chloroform, ethyl acetate, ethanol, and aqueous solvent systems. The plant extracts were successively partitioned using chloroform, ethyl acetate, ethanol, and aqueous solvent systems. Phytochemical analysis was performed using standard methods. Antioxidant activity was evaluated using FRAP and DPPH assays. Antibacterial activity was assessed using agar well diffusion and MIC determination. Phytochemical analysis revealed the presence of alkaloids (10.2-15.6%), flavonoids …