Physical Sciences and Mathematics Commons^™

A Numerical Investigation Of Sediment Dynamics In The Northern Gulf Of Mexico In Connection With Hurricanes, Fluid Mud, Climate Change, And Biogeochemical Cycling, Zhengchen Zang

LSU Doctoral Dissertations

Sediment transport and deposition in marginal seas is jointly controlled by many factors including hydrodynamics, fluvial inputs, and the characteristics of sediment particles. This dissertation study employs the coupled ocean-atmosphere-wave-and-sediment transport modeling system (COAWST) to investigate the mechanism of sediment transport in the northern Gulf of Mexico (nGoM) on different temporal scales, as well as its interaction with biogeochemical processes.

First of all, a three-way coupled (atmosphere-wave-ocean) hurricane model reproduced the hydro- and sediment dynamics during hurricane Gustav (2008). Intensive alongshore and offshore currents were simulated on the eastern/western sectors of hurricane track, respectively. High suspended sediment concentration (SSC) was …

Silica And Siloxane Model Systems, Bruno Jakobi

LSU Doctoral Dissertations

This dissertation focuses on the development and synthesis of model system for the investigation of the morphology, interactions, and dynamics in linear and branched polymers and polymer nanocomposites. The materials are designed to reduce the number of uncontrolled parameters and to be ideally suitable for neutron scattering studies. Hereby, two main objectives are defined:

The first project is to develop model nanocomposites based on the grafting of poly(dimethylsiloxane) (PDMS) to primary particles and well-defined aggregates. For that purpose, the functionalization of silica nanoparticles with a chlorosilane and the influence of moisture on the reaction was studied. Higher grafting densities than …

Pyrenylpyridines: Sky-Blue Emitters For Organic Light-Emitting Diodes, Thenahandi Prasanthi Deepthika De Silva, Sang Gill Youm, Isiah M. Warner

Faculty Publications

A novel sky-blue-emitting tripyrenylpyridine derivative, 2,4,6-tri(1-pyrenyl)-pyridine (2,4,6-TPP), has been synthesized using a Suzuki coupling reaction and compared with three previously reported isomeric dipyrenylpyridine (DPP) analogues (2,4-di(1 pyrenyl)pyridine (2,4-DPP), 2,6-di(1-pyrenyl)pyridine (2,6-DPP), and 3,5-di(1-pyrenyl)-pyridine (3,5-DPP)). 0 revealed by single-crystal X-ray analysis and computational simulations, all compounds possess highly twisted conformations in the solid state with interpyrene torsional angles of 42.3 degrees-57.2 degrees. These solid-state conformations and packing variations of pyrenylpyridines could be correlated to observed variations in physical characteristics such as photo/thermal stability and spectral properties, but showed only marginal influence on electrochemical properties. The novel derivative, 2,4,6-TPP, exhibited the lowest degree …

Short- And Intermediate-Range Structure And Dynamics Of Fe-Ni-C Liquid Under Compression, Jianwei Wang

Faculty Publications

Properties of liquid Fe alloys under high-pressure conditions are crucial for understanding the composition, thermal state, and dynamics of Earth's core. Experiments on such liquids, however, are often performed under pressures far below those of the outer core, necessitating long extrapolations of experimental results to core conditions. Such estimates can be complicated by light elements possibly forming pressure-dependent molecular clusters that can significantly affect the physical properties of liquids as core conditions are approached. First-principles molecular dynamics simulations were employed to compute the properties of an Fe-Ni-C liquid with a composition of Fe3.7Ni0.37C at 1673 K and pressures from 0 …

Short- And Intermediate-Range Structure And Dynamics Of Fe-Ni-C Liquid Under Compression, Jianwei Wang

Faculty Publications

Properties of liquid Fe alloys under high-pressure conditions are crucial for understanding the composition, thermal state, and dynamics of Earth's core. Experiments on such liquids, however, are often performed under pressures far below those of the outer core, necessitating long extrapolations of experimental results to core conditions. Such estimates can be complicated by light elements possibly forming pressure-dependent molecular clusters that can significantly affect the physical properties of liquids as core conditions are approached. First-principles molecular dynamics simulations were employed to compute the properties of an Fe-Ni-C liquid with a composition of Fe3.7Ni0.37C at 1673 K and pressures from 0 …

Turn-On Near-Infrared Fluorescent Sensors For Selective Monitoring Of Kinase Activity, Gerard Thomas Ducharme

LSU Doctoral Dissertations

Reliable and selective detection of specific biopolymers is critical in a broad range of biomedical and technological areas, including availability of simple and efficient point-of-care-compatible systems for the detection of prognostic, pharmacodynamic and predictive biomarkers. Monitoring epidermal growth factor receptor (EGFR) tyrosine kinase is of major significance due to its link to many epithelial cancers. This task is complicated by the high rate of mutation occurring in patients treated with kinase inhibitors. This dissertation describes a conceptually novel design and synthesis of turn-on near-infrared fluorescent sensors for selective and sensitive detection of EGFR. The fluorescent signal generation mechanism is based …

Age And Growth Of Hardhead Catfish And Gafftopsail Catfish In Coastal Louisiana, Usa, Shane Flinn, Stephen Midway

Faculty Publications

The Hardhead Catfish Ariopsis felis and Gafftopsail Catfish Bagre marinus are marine catfishes that have low recreational and commercial landings in U.S. waters, although they are among the most abundant species in coastal waters of the Gulf of Mexico. Few biological studies exist on marine catfishes, with most studies focusing on their unique reproductive biology. This study evaluated weight-length relationships for Gafftopsail Catfish (n = 264) and Hardhead Catfish (n = 823) sampled from across coastal Louisiana, USA, during 2016-2018; subsamples (93 and 266, respectively) were aged using lapilli for age and growth analyses. Hardhead Catfish showed a small but …

Nature Of The Crust In The Northern Gulf Of California And Salton Trough, Patricia Persaud

Faculty Publications

In the southern Gulf of California, the generation of new oceanic crust has resulted in linear magnetic anomalies and seafloor bathymetry that are characteristic of active seafloor-spreading systems. In the northern Gulf of California and the onshore (southeastern California, USA) Salton Trough region, a thick sedimentary package overlies the crystalline crust, masking its nature, and linear magnetic anomalies are absent. We use potential-field data and a geotherm analysis to constrain the composition of the crust (oceanic or continental) and develop a conceptual model for rifting. Gravity anomalies in the northern Gulf of California and Salton Trough are best fit with …

Coupled Landscape And Channel Dynamics Across The Ganges-Brahmaputra Tidal-Fluvial Continuum, Southwest Bangladesh, Edwin Jefferson Bomer Iv

LSU Doctoral Dissertations

The Ganges-Brahmaputra (G-B) Delta of Bangladesh and India is widely considered to be one of the most vulnerable coastal systems in the world, owing to locally-accelerated sea level rise and landscape modification by human activities. Recent research efforts have identified pronounced elevation differences between natural and embanked areas in the G-B tidal delta plain, suggesting that natural landscapes are keeping pace with sea-level rise while anthropogenic locations are actively subsiding. However, this observation represents a singular point in time, and longitudinal trends of surface elevation in these regions are presently unknown. For communities residing in upstream regions of G-B delta …

Sequence-Defined Ionic Peptoid Block Copolymers: Synthesis And Solution Self-Assembly, Garrett Leigh Sternhagen

LSU Doctoral Dissertations

This work covers efforts to develop a peptoid-based model system for systematically studying the role of ionic functional groups in determining the structure of ionic block copolymer (BCP) self-assemblies in water. A key challenge in the study of polyelectrolytes is the lack of synthetic control over the location of ionic monomers along a polymer chain. We developed a model system based on sequence-defined ionic peptoid BCPs having discrete chain length and precisely positioned ionic monomers along the chain to specifically address this issue. In Chapter 1, synthetic strategies to access well-defined polypeptoids and their application in BCP synthesis are reviewed. …

Intelligent Identification For Rock-Mineral Microscopic Images Using Ensemble Machine Learning Algorithms, Jonathan Shi

Faculty Publications

It is significant to identify rock-mineral microscopic images in geological engineering. The task of microscopic mineral image identification, which is often conducted in the lab, is tedious and time-consuming. Deep learning and convolutional neural networks (CNNs) provide a method to analyze mineral microscopic images efficiently and smartly. In this research, the transfer learning model of mineral microscopic images is established based on Inception-v3 architecture. The four mineral image features, including K-feldspar (Kf), perthite (Pe), plagioclase (Pl), and quartz (Qz or Q), are extracted using Inception-v3. Based on the features, the machine learning methods, logistic regression (LR), support vector machine (SVM), …

The Tensile Root Strength Of Spartina Patens Varies With Soil Texture And Atrazine Concentration, Lauris O. Hollis, R. Eugene Turner

Faculty Publications

The widely used agricultural herbicide atrazine enters wetlands and may potentially affect wetland plants that provide critical reinforcement of soil strength and contribute to ecosystem stability in ways that may vary among soil types. We conducted greenhouse experiments using four levels of atrazine doses and three different soil textures to test for differences between control and experimental treatments and interactive effects of soil texture and atrazine exposure by using the tensile root strength of the coastal wetland emergent macrophyte Spartina patens as the response variable. The tensile root strength of S. patens was not affected after 50days of atrazine exposure …

Preface, Hui-Hsiung Kuo, George Yin

Communications on Stochastic Analysis

No abstract provided.

Non-Nested Monte Carlo Dual Bounds For Multi-Exercisable Options, Xiang Cheng, Zhuo Jin

Communications on Stochastic Analysis

No abstract provided.

Subdifferentials Of Value Functions In Nonconvex Dynamic Programming For Nonstationary Stochastic Processes, Boris S. Mordukhovich, Nobusumi Sagara

Communications on Stochastic Analysis

No abstract provided.

Euler-Maruyama Method For Regime Switching Stochastic Differential Equations With Hölder Coefficients, Dung T. Nguyen, Son L. Nguyen

Communications on Stochastic Analysis

No abstract provided.

Totalitarian Random Tug-Of-War Games In Graphs, Marcos Antón, Fernando Charro, Peiyong Wang

Communications on Stochastic Analysis

No abstract provided.

Anticipating Exponential Processes And Stochastic Differential Equations, Chii Ruey Hwang, Hui-Hsiung Kuo, Kimiaki Saitô

Communications on Stochastic Analysis

No abstract provided.

Action Functionals For Stochastic Differential Equations With Lévy Noise, Shenglan Yuan, Jinqiao Duan

Communications on Stochastic Analysis

No abstract provided.

Fisetin, A 3,7,3 ',4 '-Tetrahydroxyflavone Inhibits The Pi3k/Akt/Mtor And Mapk Pathways And Ameliorates Psoriasis Pathology In 2d And 3d Organotypic Human Inflammatory Skin Models, Konstantin G. Kousoulas

Faculty Publications

Psoriasis is a chronic immune-mediated skin disease that involves the interaction of immune and skin cells, and is characterized by cytokine-driven epidermal hyperplasia, deviant differentiation, inflammation, and angiogenesis. Because the available treatments for psoriasis have significant limitations, dietary products are potential natural sources of therapeutic molecules, which can repair the molecular defects associated with psoriasis and could possibly be developed for its management. Fisetin (3,7,3 ',4 '-tetrahydroxyflavone), a phytochemical naturally found in pigmented fruits and vegetables, has demonstrated proapoptotic and antioxidant effects in several malignancies. This study utilized biochemical, cellular, pharmacological, and tissue engineering tools to characterize the effects of …

Stochastic Process And Its Role In The Development Of The Financial Market: Celebrating Professor Chow's Long And Successful Career, Xisuo L. Liu

Communications on Stochastic Analysis

No abstract provided.

Hybrid Models And Switching Control With Constraints, Jose L. Menaldi, Maurice Robin

Communications on Stochastic Analysis

No abstract provided.

Stochastic Partial Differential Equation Sis Epidemic Models: Modeling And Analysis, Nhu N. Nguyen, George Yin

Communications on Stochastic Analysis

No abstract provided.

Joint Geodetic And Seismic Analysis Of Surface Crevassing Near A Seasonal Glacier-Dammed Lake At Gornergletscher, Switzerland, Louis Garcia, Karen M. Luttrell

Faculty Publications

Seasonal lake Gornersee forms at the confluence of Gornergletscher and Grenzgletscher, Switzerland, and experiences outburst floods annually in midsummer. To study the interplay between lake drainage, glacier movement and crevasse activity, high-frequency seismometers and GPS receivers were deployed in networks near Gornersee during the summer ablation seasons of 2004, 2006 and 2007. We use a Rayleigh wave coherence method to locate 3289, 7939 and 4087 icequakes, respectively, primarily along well-defined surface crevasses. We calculate two-dimensional strains from triads of GPS stations and find mean differential strain rates of similar to 300 x 10(-6) d(-1) with diurnal variations up to 800 …

Drivers And Impacts Of Water Level Fluctuations In The Mississippi River Delta: Implications For Delta Restoration, Matthew Hiatt, John W. Day, Robert V. Rohli, John Andrew Nyman

Faculty Publications

This review synthesizes the knowledge regarding the environmental forces affecting water level variability in the coastal waters of the Mississippi River delta and relates these fluctuations to planned river diversions. Water level fluctuations vary significantly across temporal and spatial scales, and are subject to influences from river flow, tides, vegetation, atmospheric forcing, climate change, and anthropogenic activities. Human impacts have strongly affected water level variability in the Mississippi River delta and other deltas worldwide. Collectively, the research reviewed in this article is important for enhancing environmental, economic, and social resilience and sustainability by assessing, mitigating, and adapting to geophysical changes …

Multicomponent Model Of Crustal Stress At Cajon Pass, Southern California With Implications For Stress Field Heterogeneity, Elliott Conley Helgans

LSU Master's Theses

Earthquake processes in plate boundary settings are chiefly controlled by the in situ crustal stress field. Knowledge of the relative importance of various active processes acting on a fault system is necessary to understand the mechanics of faulting. This is of extreme importance to the Cajon Pass region of southern California, which may function as an earthquake gate, imposing control on large multifault ruptures. We model the in situ stress field at seismogenic depth in Cajon Pass by balancing the orientation of the modern stress field inferred from earthquake focal mechanisms against the superposition of the far field tectonic driving …

Sub-Tidal Hydrodynamics Of The Multi-Inlet Lake Pontchartrain Estuary Influenced By Mississippi River Diversion And Wind Associated With Atmospheric Fronts, Wei Huang

LSU Doctoral Dissertations

In-situ observations and a Finite Volume Community Ocean Model (FVCOM) are used to investigate the cold front induced sub-tidal hydrodynamics of Lake Pontchartrain, a semi-enclosed low-salinity estuary with multiple inlets connecting to the open ocean. Observations show that the sub-tidal hydrodynamic responses are highly correlated with the meteorological parameters during cold front events. Model results indicate that, under barotropic conditions, the remote wind effect has the greatest contribution to the overall water level variation, while the local wind stress during cold front events determines the slope for the water level inside the estuary. An examination of a quasi-steady state force …

Modeling Chemical Reactivity In Aqueous And Organic Systems: From Electronic Structure Methods To Force Field Development, Caitlin Gibson Bresnahan

LSU Doctoral Dissertations

Modeling reactivity in chemical systems has evolved dramatically in line with the capabilities of modern computing. Despite the advances in computational ability, the level in which one can model a system depends on a number of factors including the region of reactivity, size of the system, level of sophistication required in the molecular description, and so on. Electronic structure methods allow for a detailed description of the potential energy surface and inherently include all essential physics required for reactivity to occur, however these methods are limited by their computational expense. On the other hand, force fields allow for an atomistic …

A Two-Step Classification Platform To Classify Construction Sounds To Enhance Real-Time Construction Zone Monitoring, Jayati Halder Jui

LSU Master's Theses

In recent years, sounds generated from equipment used at a construction site have been found to be useful in identifying construction activities and associated equipment usage providing insightful information regarding project status and hazard issues. This study proposes a Two-Step Neural Classifier (TSNC) for accurate classification of real world construction sounds. Experimental results from real world construction site audio data showed an average classification accuracy of 98% for TSNC compared to 91% average accuracy for an ordinary (one-step) Artificial Neural Network (ANN). The TSNC model is a hierarchical model that exploits the idea of creating disjoint subgroups of construction sounds …

Seasonal Variability Of Forces Controlling Sedimentation In The Sundarbans National Forest, Bangladesh, Carol A. Wilson, E. J. Bomer

Faculty Publications

Southwest Bangladesh, located on the Ganges-Brahmaputra-Meghna delta, is experiencing the impacts of sea level rise (SLR) due to processes at both the local and global scale. In particular, regional alterations of the hydrodynamic network, due to embankment construction, have drastically altered effective SLR, placing millions of inhabitants at risk of prolonged inundation, and threatening the world's largest continuous mangrove stand, the Sundarbans National Forest (SNF). In order to effectively employ landscape recovery solutions, an understanding of local sediment transport and deposition is critical. This field-based study investigates the sediment dynamics between the mangrove platform and tidal channels of the SNF …