Physical Sciences and Mathematics Commons^™

Lean, Green, And Lifetime Maximizing Sensor Deployment On A Barrier, Peter Michael Terlecky

Dissertations, Theses, and Capstone Projects

Mobile sensors are located on a barrier represented by a line segment, and each sensor has a single energy source that can be used for both moving and sensing. Sensors may move once to their desired destinations and then coverage/communication is commenced. The sensors are collectively required to cover the barrier or in the communication scenario set up a chain of communication from endpoint to endpoint. A sensor consumes energy in movement in proportion to distance traveled, and it expends energy per time unit for sensing in direct proportion to its radius raised to a constant exponent.

The first focus …

Chemistry Of 6-Monobrominated Indigo, Mbi, Hiroko Ajiki

Dissertations, Theses, and Capstone Projects

6-monobrominated indigo, MBI, is a component of a historically important and the most expensive colorant, Tyrian Purple.

The colorant is remarkably stable under the sun, in the air and after extensive washing with water. The color is still vivid after thousands of years. Even though it has such a high stability, MBI and Tyrian Purple have color changes from purple to blue upon temperature changes. This color change has been known for long to certain people, but the mechanism of the color change was unknown.

Tyrian Purple also has recently attracted interests for applications towards semiconducting material due to its …

Scheduling And Resource Allocation In Wireless Sensor Networks, Yosef Alayev

Dissertations, Theses, and Capstone Projects

In computer science and telecommunications, wireless sensor networks are an active research area. Each sensor in a wireless sensor network has some pre-defined or on demand tasks such as collecting or disseminating data. Network resources, such as broadcast channels, number of sensors, power, battery life, etc., are limited. Hence, a schedule is required to optimally allocate network resources so as to maximize some profit or minimize some cost. This thesis focuses on scheduling problems in the wireless sensor networks environment. In particular, we study three scheduling problems in the wireless sensor networks: broadcast scheduling, sensor scheduling for area monitoring, and …

Nickel-Catalyzed Cross-Coupling Reactions Involving Secondary And Tertiary Alkyl Nucleophiles, Amruta Ajit Joshi

Dissertations, Theses, and Capstone Projects

In the first chapter, introduction of transition metal-catalyzed cross-coupling reactions has been given. These transition metal-catalyzed C-C bond forming reactions have been used extensively in organic synthesis. Among them, C(sp2)-C(sp2) bond forming reactions have been widely studied over decades. More recently, some reports have demonstrated the use of C(sp3) nucleophiles and electrophiles in cross-coupling reactions. However, use of secondary and tertiary alkyl nucleophiles has remained a challenge due to competitive β-hydride elimination and slow transmetallation of bulky secondary and tertiary alkyl organometallic nucleophiles.

In the second chapter, the first general nickel-catalyzed Negishi reaction for the cross-coupling of unactivated, acyclic secondary …

Conformational Features Of The Human U2-U6 Snrna Complex, Ravichandra Bachu

Dissertations, Theses, and Capstone Projects

The splicing of precursor messenger (pre-m) RNA, during which noncoding intervening sequences are excised and flanking coding regions ligated, is an integral reaction of gene expression. In eukaryotes, it is carried out by a dynamic RNA-protein complex called the spliceosome, in which five small nuclear (sn) RNA components are actively involved in recognition and chemical aspects of the process. A complex formed between U2 and U6 snRNAs is implicated in the chemistry of pre-mRNA splicing. The catalytic activity of the U2-U6 snRNA complex is dependent on the presence of Mg2+ ions, and the complex has been shown to have several …

Discovering Regularity In Point Clouds Of Urban Scenes, Sam Friedman

Dissertations, Theses, and Capstone Projects

Despite the apparent chaos of the urban environment, cities are actually replete with regularity. From the grid of streets laid out over the earth, to the lattice of windows thrown up into the sky, periodic regularity abounds in the urban scene. Just as salient, though less uniform, are the self-similar branching patterns of trees and vegetation that line streets and fill parks. We propose novel methods for discovering these regularities in 3D range scans acquired by a time-of-flight laser sensor. The applications of this regularity information are broad, and we present two original algorithms. The first exploits the efficiency of …

Planar Waveguide Structures For Post-Edfa Broadband Near Infrared Optical Amplifiers, Islam Hoxha

Dissertations, Theses, and Capstone Projects

This thesis reports on optical gain of up to 5.7 dB from a planar waveguide with core made of tetravalent chromium-doped calcium germanate single crystal.

An Ethnobotanical, Ecological And Lc-Ms-Based Chemometric Investigation Of Phaleria Nisidai, A Traditional Adaptogen Containing Diterpene Esters From Palau, Micronesia, Daniel Kulakowski

Dissertations, Theses, and Capstone Projects

An ethnobotanical, ecological and LC-MS-based chemometric investigation of Phaleria nisidai, a traditional adaptogen containing diterpene esters from Palau, Micronesia

Palau is a country with a rich heritage of traditional medicine still being practiced. One of the most popular and respected remedies in Palau is a tea made from fresh leaves of Phaleria nisidai Kaneh. (Thymelaeaceae). Interviews conducted to determine the use of this plant revealed that it is employed non-specifically to treat a variety of general health concerns. Its use as a prophylactic to keep away sickness, as a 'system cleaner', as well as for strength and energy indicate …

Roundup Ready Nation: The Political Ecology Of Genetically Modified Soy In Argentina, Amalia Leguizamon

Dissertations, Theses, and Capstone Projects

This dissertation is a case study of agrarian transformation in an agro-export society, Argentina. I study the process of adoption of the technological package of genetically modified (GM) soy in the Argentine countryside, its socio-ecological consequences, and Argentines' responses to it. In particular, this research addresses Argentina's unique situation of being a developing country that has positively embraced the biotechnology of GM seeds as a key accumulation strategy without the emergence of major contestation against GM soy monocropping. In order to answer the puzzle of quiescence, I look at how power relations structure access to social and environmental goods and …

Analysis Of Dna Motifs In The Human Genome, Yupu Liang

Dissertations, Theses, and Capstone Projects

DNA motifs include repeat elements, promoter elements and gene regulator elements, and play a critical role in the human genome. This thesis describes a genome-wide computational study on two groups of motifs: tandem repeats and core promoter elements.

Tandem repeats in DNA sequences are extremely relevant in biological phenomena and diagnostic tools. Computational programs that discover tandem repeats generate a huge volume of data, which can be difficult to decipher without further organization. A new method is presented here to organize and rank detected tandem repeats through clustering and classification. Our work presents multiple ways of expressing tandem repeats using …

Reliability-Based Progressive Collapse And Redundancy Analysis Of Bridge Systems, Feng Miao

Dissertations, Theses, and Capstone Projects

Highway bridges like most structural systems are usually designed on a member by member basis and little consideration is provided to the effect of a local failure on system safety. There are concerns that some systems optimized to meet code-specified member design criteria may not provide sufficient levels of structural redundancy to withstand a possible local failure. In fact, a local failure of one structural element may result in the failure of another element creating a chain reaction that might progress throughout the whole structure or a major portion of it leading to a catastrophic collapse. Several recent catastrophic structural …

Strategies For Discriminating And Comparing Unknown Unitary Transformations, Guy F. Okoko

Dissertations, Theses, and Capstone Projects

How to discriminate or compare two unitary transformations that are completely unknown?

We first examine the unambiguous discrimination of two unknown unitary transformations; we show that the results are the same as those found for the programmable discrimination of two unknown quantum states.

Next we consider the minimum-error comparison of two unknown unitary transformations; the results are obtained in the general case where the prior probabilities are different.

Last we study the unambiguous discrimination of two unknown unitary transformations in the case where multiple copies of data are available.

Long-Term Warming And The Size And Phenology Of Long Island Sound Plankton, Edward Rice

Dissertations, Theses, and Capstone Projects

In coastal ecosystems with decades of eutrophication and other anthropogenic stressors, the impact of climate change on planktonic communities can be difficult to detect. A time-series of monthly surface water temperatures in the Central Basin of Long Island Sound (LIS) from the late 1940s until 2012 indicates a warming rate of 0.03°C per year, with recent summer temperatures increasing most consistently. During this warming trend, the proportion of chlorophyll produced by smaller phytoplankton and flagellates appears to be higher during warmer summer and fall months, enabling an increase in annual chlorophyll despite static nutrient levels. The phenology of phytoplankton and …

Measuring The Transmission Matrix For Microwave Radiation Propagating Through Random Waveguides: Fundamentals And Applications, Zhou Shi

Dissertations, Theses, and Capstone Projects

This thesis describes the measurement and analysis of the transmission matrix (TM) for microwave radiation propagating through multichannel random waveguides in the crossover to Anderson localization. Eigenvalues of the transmission matrix and the associated eigenchannels are obtained via a singular value decomposition of the TM. The sum of the transmission eigenvalues yields the transmittance T, which is the classical analog of the dimensionless conductance g. The dimensionless conductance g is the electronic conductance in units of the quantum conductance, G/(e^2/h).

For diffusive waves g>1, approximately g transmission eigenchannels contribute appreciably to the transmittance T. In …

Special Representations, Nathanson's Lambda Sequences And Explicit Bounds, Satyanand Singh

Dissertations, Theses, and Capstone Projects

{Let $X$ be a group with identity $e$, we define $A$ as an infinite set of generators for $X$, and let $(X,d)$ be the metric space with word length $d_{A}$ induced by $A$. Nathanson showed that if $P$ is a nonempty finite set of prime numbers and $A$ is the set of positive integers whose prime factors all belong to $P$, then the metric space $({\bf{Z}},d_{A})$ has infinite diameter. Nathanson also studied the $\lambda_{A}(h)$ sequences, where $\lambda_{A}(h)$ is defined as the smallest positive integer $y$ with $d_{A}(e,y)=h$, and he posed the problem to compute $\lambda_{A}(h)$ and estimate its growth rate. …

Automated Learner Classification Through Interface Event Stream And Summary Statistics Analysis, Edgar E. Troudt

Dissertations, Theses, and Capstone Projects

Reading comprehension is predominately measured through multiple choice examinations. Yet, as we will discuss in this thesis, such exams are often criticized for their inaccuracies. With the advent of "big data" and the rise of ITS (Intelligent Tutoring Systems), increasing focus will be placed on finding dynamic, automated ways of measuring students' aptitude and progress.

This work takes the first step towards automated learner classification based on the application of graphic organizers. We address the following specific problem experimentally: How effectively can we measure task comprehension via human translation of written text into a visual representation on a computer? Can …

Phylogeny And Population Genetics Of The Endangered Dwarf Bear-Poppy, Arctomecon Humilis Coville (Papaveraceae) Using Microsatellite Markers, Joshua Simpson

Dissertations, Theses, and Capstone Projects

The genus Arctomecon (Papaveraceae) is comprised of three narrowly endemic rare species that are largely restricted to gypsum soils of the eastern Mojave Desert. The small, remaining populations of these species have become increasingly isolated by urban development and habitat fragmentation. Arctomecon humilis is federally listed as endangered due to its limited distribution within a ~15 km radius of an actively expanding city. Organizations involved with land management and conservation have called for greater insight into the genetic variation and population structure of the remaining subpopulations as they make important decisions regarding where to focus their efforts and resources.

The …

Organic Pi-Stacking Semiconducting Material: Design, Synthesis And The Analysis Of Structure And Properties, Bin Wang

Dissertations, Theses, and Capstone Projects

Organic semiconducting materials have been under intensive investigation in the recent decades for potential applications in various electronic or optoelectronic devices such as light emitting diodes, photovoltaic cells and field effect transistors. Compared to inorganic counterparts, organic charge transport materials are attractive for their abilities of forming thin-films, large area manufacturing, compatibility with flexible substrate, light weight and potential low fabrication cost. The charge transport property of the organic active layer is one of the key factors to the electronic or optoelectronic performance of devices. Research projects presented in this thesis focused on improving charge carrier mobility of organic charge …

An Experimental Investigation Into The Mechanisms Of Bacterial Evolution, Zhenmao Wan

Dissertations, Theses, and Capstone Projects

This thesis studies the two fundamental mechanisms of bacterial evolution — horizontal gene transfer and spontaneous mutation, in the bacterium Escherichia coli through novel experimental assays and mathematical simulations. First, I will develop a growth assay utilizing the quantitative polymerase chain reaction (qPCR) to provide real-time enumeration of genetic marker abundance within bacterial populations. Second, I will focus on horizontal gene transfer in E. coli occurring through a process called conjugation. By fitting the qPCR data to a resource limited, logistic growth model, I will obtain estimated values of several key parameters governing the dynamics of DNA transfer through conjugation …

A Parametrization-Based Surface Reconstruction System For Triangular Mesh Simplification With Application To Large Scale Scenes, Adriana Wise

Dissertations, Theses, and Capstone Projects

The laser scanner is nowadays widely used to capture the geometry of art, animation maquettes, or large architectural, industrial, and land form models. It thus poses specific problems depending on the model scale. This thesis provides a solution for simplification of triangulated data and for surface reconstruction of large data sets, where feature edges provide an obvious segmentation structure. It also explores a new method for model segmentation, with the goal of applying multiresolution techniques to data sets characterized by curvy areas and the lack of clear demarcation features. The preliminary stage of surface segmentation, which takes as input single …

Numerical Study Of Canopy Flows In Complex Terrain, Xiyan Xu

Dissertations, Theses, and Capstone Projects

Canopy flow plays a substantial role in regulating atmosphere-biosphere exchanges of mass and energy. The worldwide FLUXNET has been developed to quantify the net ecosystem exchange of mass and energy through fluid dynamics in and above vegetation canopy using tower-based eddy covariance (EC) technique. However, EC measurements are subject to advection errors in complex terrain, particularly during nights when atmospheric stability is strong. Because EC measurements are one-dimensional (1D), three-dimensional (3D) air movement, CO2 transport, and temperature variation around the instrumented tower are unknown. We employ a Computational Fluid Dynamics (CFD) model to investigate the impact on CO2 transport of …

Cyclic Phosphonium Ionic Liquids, Sharon I. Lall-Ramnarine, Joshua A. Mukhlall, James F. Wishart, Robert R. Engel, Alicia R. Romeo, Masao Gohdo, Sharon Ramati, Marc B. Berman, Sophia N. Suarez

Publications and Research

Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these novel materials, we report on a comparison of their properties with their ammonium congeners. These exemplars are slightly less conductive and have slightly smaller self-diffusion coefficients than their cyclic ammonium congeners.

Impacts Of Aerosol Particle Size Distribution And Land Cover Land Use On Precipitation In A Coastal Urban Environment Using A Cloud-Resolving Mesoscale Model, Nathan Hosannah, Jorge Gonzalez

Publications and Research

Urban environments influence precipitation formation via response to dynamic effects, while aerosols are intrinsically necessary for rainfall formation; however, the partial contributions of each on urban coastal precipitation are not yet known.Here, the authors use aerosol particle size distributions derived from the NASA aerosol robotic network (AERONET) to estimate submicron cloud condensation nuclei (CCN) and supermicron CCN (GCCN) for ingestion in the regional atmospheric modeling system (RAMS). High resolution land data from the National Land Cover Database (NLCD) were assimilated into RAMS to provide modern land cover and land use (LCLU).Thefirst two of eight total simulationswere month long runs for …

Wave Function For Harmonically Confined Electrons In Time-Dependent Electric And Magnetostatic Fields, Hong-Ming Zhu, Jin-Wang Chen, Xiao-Yin Pan, Viraht Sahni

Publications and Research

We derive via the interaction “representation” the many-body wave function for harmonically confined electrons in the presence of a magnetostatic field and perturbed by a spatially homogeneous time-dependent electric field—the Generalized Kohn Theorem (GKT) wave function. In the absence of the harmonic confinement – the uniform electron gas – the GKT wave function reduces to the Kohn Theorem wave function. Without the magnetostatic field, the GKTwave function is the Harmonic Potential Theorem wave function. We further prove the validity of the connection between the GKT wave function derived and the system in an accelerated frame of reference. Finally, we provide …

Boosted Top Production: Factorization And Resummation For Single-Particle Inclusive Distributions, Andrea Ferroglia, Simone Marzani, Ben D. Pecjak, Li Lin Yang

Publications and Research

We study single-particle inclusive (1PI) distributions in top-quark pair production at hadron colliders, working in the highly boosted regime where the top-quarkpTis much larger than its mass. In particular, we derive a novel factorization formula validin the small-mass and soft limits of the differential partonic cross section. This providesa framework for the simultaneous resummation of soft gluon corrections and small-mass logarithms, and also an efficient means of obtaining higher-order corrections to the differential cross section in this limit. The result involves five distinct one-scale functions, three of which arise through the subfactorization of soft real radiation in the small-mass limit. …

Tr-2014001: Computer-Aided Reasoning About Knowledge And Justifications, Natalia Novak

Computer Science Technical Reports

No abstract provided.

Tr-2014002: Proof Complexity And Quantitative Epistemology, Natalia Novak

Computer Science Technical Reports

No abstract provided.

Tr-2014006: New Algorithms In The Frobenius Matrix Algebra For Polynomial Root-Finding, Victor Y. Pan, Ai-Long Zheng

Computer Science Technical Reports

No abstract provided.

Tr-2014008: Supporting Genp And Low-Rank Approximation With Random Multipliers, Victor Y. Pan, Guoliang Qian, Xiaodong Yan

Computer Science Technical Reports

No abstract provided.

Tr-2014007: Real Polynomial Root-Finding By Means Of Matrix And Polynomial Iterations, Victor Y. Pan

Computer Science Technical Reports

No abstract provided.