Physical Sciences and Mathematics Commons^™

Preparation And Electrochemical Properties Of Flake-Like Liv3O8 By Soft Template Assisted Sol-Gel Method As Anode Material For Aqueous Li-Ion Battery, Shuai Tan, Dan Sun, Hai-Yan Wang, Tian-Li Hou, Zhong-Xing Xiao, You-Gen Tang

Journal of Electrochemistry

Anode material has become the key issue for restricting the development of aqueous lithium ion battery (ALIB). Flake-like LiV3O8 materials were synthesized by sol-gel method using sodium dodecyl benzene sulfonate (SDBS) as a template. The XRD and SEM results showed that as-prepared flake-like LiV₃O₈ was of high purity with monoclinic system and P21/m space group. LiMn₂O₄//Li₂SO₄//LiV₃O₈ ALIB was assembled and tested. As observed, the flake-like LiV3O8 here exhibited good high-rate performance and cycling stability. A high discharge capacity of 154 mAh.g^-1 (based on the mass …

Synthesis And Electrochemical Performance Of Nano Licopo4 By Polyol Method, Fei Wang, Yang Jun

Journal of Electrochemistry

High potential LiCoPO₄ cathode material was synthesized by polyol method. Carbon layer of ca. 3 nm thick was coated on the LiCoPO4 surfaces by chemical vapor deposition from methylbenzene. Crystalline structure, morphology and electrochemical performance of the sample were studied by XRD, SEM, TEM, CV and galvanostatic charge/discharge curve. The synthesized material via polyol method showed a pure phase of LiCoPO₄. The LiCoPO₄/C electrode delivered a high discharge capacity of 132 mAh·g^-1 and maintained 78% of the initial capacity after 50 cycles at 0.1C rate. The two-step extraction/insertion behavior of Li⁺ in LiCoPO4/C …

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO₄/C are, respectively, 162 mAh·g^-1, 142 mAh·g^-1 and 92 mAh·g^-1 at 0.1C rate. The nano-sized LiFePO₄-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g^-1 even at 30C, while the macroscopic LiFePO₄-c/C (1 μm) exhibits a much poorer discharge …

Amino Acid Region 1000–1008 Of Factor V Is A Dynamic Regulator For The Emergence Of Procoagulant Activity, Joesph R. Wiencek, Mahesheema Na, Jamila Hirbawi, Michael Kalafatis

Chemistry Faculty Publications

Single chain factor V (fV) circulates as an Mr 330,000 quiescent pro-cofactor. Removal of the B domain and generation of factor Va (fVa) are vital for procoagulant activity. We investigated the role of the basic amino acid region 1000-1008 within the B domain of fV by constructing a recombinant mutant fV molecule with all activation cleavage sites (Arg(709)/Arg(1018)/Arg(1545)) mutated to glutamine (fV(Q3)), a mutant fV molecule with region 1000-1008 deleted (fV(ΔB9)), and a mutant fV molecule containing the same deletion with activation cleavage sites changed to glutamine (fV(ΔB9/Q3)). The recombinant molecules along with wild type fV (fV(WT)) were transiently expressed …

Primary Care-Based Educational Interventions To Decrease Risk Factors For Metabolic Syndrome For Adults With Major Psychotic And/Or Affective Disorders: A Systematic Review, Cynthia Nover, Sarah S. Jackson

Epidemiology Faculty Publications

Background

Individuals with major psychotic and/or affective disorders are at increased risk for developing metabolic syndrome due to lifestyle- and treatment-related factors. Numerous pharmacological and non-pharmacological interventions have been tested in inpatient and outpatient mental health settings to decrease these risk factors. This review focuses on primary care-based non-pharmacological (educational or behavioral) interventions to decrease metabolic syndrome risk factors in adults with major psychotic and/or affective disorders.

Methods

The authors conducted database searches of PsychINFO, MEDLINE and the Cochrane Database of Systematic Reviews, as well as manual searches and gray literature searches to identify included studies.

Results

The authors were …

Volatization Of Extraterrestrial Materials As Determined By Zinc Isotopic Analysis, Randal Christopher Paniello

All Theses and Dissertations (ETDs)

None

Timing And Spectroscopy Requirements For A Plastic Scintillating Fiber Bundle Time-Of-Flight Neutron Spectrometer, Paul A. Clement

Theses and Dissertations

The design parameters of a Time-of-Flight (TOF) neutron spectrometer composed of BCF-12 plastic scintillating fibers were investigated. A GEANT4 transport model was developed for analyzing the interaction of 2.5 MeV neutrons with a 14 x 14 BCF-12 fiber bundle. The bundle simulation demonstrated that 0.359% of all neutrons incident on the bundle will double scatter. The timing and data collection e efficiencies of a Tektronix DPO7104 series digital oscilloscope were examined to determine the signal processing requirements for future fiber bundle measurements. The minimum detectable neutron energy was computed by taking into account the bundle scintillation e efficiency, light collection …

Efficient And Long-Time Accurate Second-Order Methods For The Stokes-Darcy System, Wenbin Chen, Max Gunzburger, Dong Sun, Xiaoming Wan

Mathematics and Statistics Faculty Research & Creative Works

We propose and study two second order in time implicit-explicit methods for the coupled Stokes-Darcy system that governs flows in karst aquifers and other subsurface flow systems. the first method is a combination of a second-order backward differentiation formula and the second order Gear's extrapolation approach. the second is a combination of the second-order Adams-Moulton and second-order Adams-Bashforth methods. Both algorithms only require the solution of decoupled Stokes and Darcy problems at each time-step. Hence, these schemes are very efficient and can be easily implemented using legacy codes. We establish the unconditional and uniform in time stability for both schemes. …

Understanding Human Learning Using A Multiagent Based Unified Learning Model Simulation, Vlad T. Chiriacescu

Department of Computer Science and Engineering: Dissertations, Theses, and Student Research

Within cognitive science, computational modeling based on cognitive architectures has been an important approach to addressing questions of human cognition and learning. Modeling issues such as limited expressivity in representing knowledge and lack of appropriate selection of model structure represent a challenge for existing architectures. Furthermore, latest research shows that the concepts of long-term memory, motivation and working memory are critical cognitive aspects but a unifying cognitive paradigm integrating those concepts hasn’t been previously achieved.

Derived from a synthesis of neuroscience, cognitive science, psychology, and education, the Unified Learning Model (ULM) provides this integration by merging a statistical learning mechanism …

Coordinated Utilisation Of Wind Farm Reactive Power Capability For System Loss Optimisation, Lasantha Meegahapola, S Durairaj, D Flynn, B Fox

Dr Lasantha G Meegahapola

Most wind farms currently being installed are based upon doubly fed induction generator (DFIG) or direct-drive synchronous generator (DDSG) technology. Given that one of the impacts of introducing distributed generation is an alteration of steady-state power flows and voltages, both technologies are capable of providing local voltage support. Wind farms may, therefore, be included in optimal power flow (OPF) calculations to minimise fuel cost and/or network losses. The IEEE 30-bus system is considered as a case study, comparing fixed-speed induction generator (FSIG) requirements with DFIG capability. Results are presented for a range of DFIG capability modes, at varying system load …

Rfid-Based Anti-Theft Auto Security System With An Immobilizer, Geeth Jayendra, Sisil Kumarawadu, Lasantha Meegahapola

Dr Lasantha G Meegahapola

This paper presents a novel radio frequency identification (RFID) based vehicle immobilizer system, which features low hacking probability while preserving the safety of the passengers of the hijacked vehicle. The immobilizer uses the active RFID technology where the tag is generated with comparatively large character sets. The receiving unit is intelligently integrated into three control circuits in the vehicle, namely, ignition circuit, power control unit, and automatic gear changing system, enabling it to bring the vehicle speed down to zero in a safe step by step manner. The anti-theft auto security system proposed here was tested under different weather conditions …

Spectroscopic And Physico-Chemical Characterization Of Ir(I) And Ru(Iii) Complexes Of 32-Membered Unsymmetrical Dinucleating Macrocyclic Ligand, Mohammad Mansoob Khan Dr

Dr. Mohammad Mansoob Khan

No abstract provided.

U.S. Drought Monitor, December 24, 2013, Matthew Rosencrans

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for December 24, 2013 (12/24/13) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Hay, Cattle, Winter wheat.

Table Of Contents, Michele Harmon

Journal of the South Carolina Academy of Science

No abstract provided.

Multi-State Models For Natural History Of Disease, Amy Laird, Rebecca A. Hubbard, Lurdes Y. T. Inoue

UW Biostatistics Working Paper Series

Longitudinal studies are a useful tool for investigating the course of chronic diseases. Many chronic diseases can be characterized by a set of health states. We can improve our understanding of the natural history of the disease by modeling the sequence of visited health states and the duration in each state. However, in most applications, subjects are observed only intermittently. This observation scheme creates a major modeling challenge: the transition times are not known exactly, and in some cases the path through the health states is not known.

In this manuscript we review existing approaches for modeling multi-state longitudinal data. …

Determining The 7li(N,Gamma) Cross Section Via Coulomb Dissociation Of 8li, R. Izsak, A. Horvath, A. Kiss, Z. Seres, A. Galonsky, C. A. Bertulani, Zs Fueloep, T. Baumann, D. Bazin, K. Ieki, C. Bordeanu, N. Carlin, M. Csanád, F. Deák, Paul A. Deyoung, N. Frank, T. Fukuchi, A. Gade, D. Galaviz, C. R. Hoffman, W. A. Peters, H. Schelin, M. Thoennessen, G. I. Veres

Faculty Publications

The applicability of Coulomb dissociation reactions to determine the cross section for the inverse neutron capture reaction was explored using the reaction Li-8(gamma,n)Li-7. A 69.5 MeV/nucleon Li-8 beam was incident on a Pb target, and the outgoing neutron and Li-7 nucleus were measured in coincidence. The deduced (n,gamma) excitation function is consistent with data for the direct capture reaction Li-7(n,gamma) Li-8 and with low-energy effective field theory calculations.

Students' Perceived Utility Of Precision Taught Calculus, Rebecca-Anne Dibbs, David Glassmeyer, Wafa Yacoub

Faculty and Research Publications

The last decade of calculus research has showed students learn best when lecture is supplemented with thoughtful use of technology and group work; however, educators are given little direction of how they are to balance the already full first semester calculus class. Precision teaching is an instructional model that employs formative assessment to provide information on what topics are understood by students as well as indicate troublesome concepts. With this information, the instructor can adjust class time accordingly by incorporating supplemental activities most beneficial to students. The purpose of this interview study was to explore the perceived utility of precision …

A Search For Enhanced Very High Energy Gamma-Ray Emission From The 2013 March Crab Nebula Flare, P. T. Reynolds, Et Al

Physical Sciences Publications

In 2013 March, a flaring episode from the Crab Nebula lasting ~2 weeks was detected by Fermi-LAT (Large Area Telescope on board the Fermi Gamma-ray Space Telescope). The Very Energetic Radiation Imaging Telescope Array System (VERITAS) provides simultaneous observations throughout this period. During the flare, Fermi-LAT detected a 20 fold increase in flux above the average synchrotron flux >100 MeV seen from the Crab Nebula. Simultaneous measurements with VERITAS are consistent with the non-variable long-term average Crab Nebula flux at TeV energies. Assuming a linear correlation between the very high energy flux change >1 TeV and the flux …

High Resolution X-Ray Diffraction Analysis Of Cb1 Receptor Antagonists As A Means To Explore Binding Affinity, Steven P. Fournet

University of New Orleans Theses and Dissertations

Abstract

Charge density studies have been conducted on ten CB₁ cannabinoid receptor antagonists via high resolution x-ray crystallography. Bond critical point values and various other properties derived from these studies including the electrostatic potential were analyzed in correlation to the affinity of each compound with the CB₁ receptor. Correlation/anti-correlation was found between several properties and K_i. The data was also interpreted by principal component analysis with three principal components accounting for 85% of the data variation. Data mining was limit due to the low sample count and the requirements set for the inclusion of correlated/anti-correlated variables …

High Yield Solvothermal Synthesis Of Hexaniobate Based Nanocomposites Via The Capture Of Preformed Nanoparticles In Scrolled Nanosheets, Shivaprasad Reddy Adireddy

University of New Orleans Theses and Dissertations

The ability to encapsulate linear nanoparticle (NP) chains in scrolled nanosheets is an important advance in the formation of nanocomposites.These nanopeapods (NPPs) exhibit interesting properties that may not be achieved by individual entities. Consequently, to fully exploit the potential of NPPs, the fabrication of NPPs must focus on producing composites with unique combinations of morphologically uniform nanomaterials. Various methods can produce NPPs, but expanding these methods to a wide variety of material combinations can be difficult. Recent work in our group has resulted in the in situ formation of peapod-like structures based on chains of cobalt NPs. Building on this …

Analysis Of Windows 8 Registry Artifacts, Jeremy M. Stormo

University of New Orleans Theses and Dissertations

Microsoft’s series of Windows operating systems represents some of the most commonly encountered technologies in the field of digital forensics. It is then fair to say that Microsoft’s design decisions greatly affect forensic efforts. Because of this, it is exceptionally important for the forensics community to keep abreast of new developments in the Windows product line. With each new release, the Windows operating system may present investigators with significant new artifacts to explore. Described by some as the heart of the Windows operating system, the Windows registry has been proven to contain many of these forensically interesting artifacts. Given the …

Wave Transformation At A Saltmarsh Edge And Resulting Marsh Edge Erosion: Observations And Modeling, Kevin J. Trosclair

University of New Orleans Theses and Dissertations

This study examines wind generated waves during winter storms, their transformation/attenuation near the marsh edge, and the resulting saltmarsh edge erosion. A simple numerical model for wave generation, transmission and marsh edge erosion was developed and validated against observations from Lake Borgne, Louisiana. Results suggest that meteorological conditions modify the local water depth via wind or wave setup and atmospheric pressure, thus exerting a first order control on the location of wave attack, which in turn determines the type of wave forces (shear vs. impact) that dominate the erosion process. Scarp failure follows, at a location determined by water level, …

Categorization Of Large Corpora Of Malicious Software, Deekshit Kura

University of New Orleans Theses and Dissertations

Malware is computer software written by someone with mischievous or, more usually, malicious and/or criminal intent and specifically designed to damage data, hosts or networks. The variety of malware is increasing proportionally with the increase in computers and we are not aware of newly emerging malware. Tools are needed to categorize families of malware, so that analysts can compare new malware samples to ones that have been previously analyzed and determine steps to detect and prevent malware infections.

In this thesis, I developed a technique to catalog and characterize the behavior of malware, so that malware families, the level of …

Ultra-Low Temperature Measurements Of London Penetration Depth In Iron Selenide Telluride Superconductors, Andrei Diaconu

University of New Orleans Theses and Dissertations

The newly discovered iron based superconductors have captivated the attention of the scientific community due to the unusual mechanism behind their superconductivity and their promise as the next generation high temperature superconductors. After a century of superconductor research, the physical mechanism behind high temperature superconductivity is still not understood. These new materials bring renewed hope in elucidating the pairing mechanism responsible with high temperature superconductors and achieving the ultimate goal of the field, room temperature superconductivity. Consequently, a deeper understanding of the intriguing properties of iron based materials is essential.

A great deal about the pairing mechanism of Cooper electron …

Techniques For The Visualization Of Positional Geospatial Uncertainty, Brent A. Barré

University of New Orleans Theses and Dissertations

Geospatial data almost always contains some amount of uncertainty due to inaccuracies in its acquisition and transformation. While the data is commonly visualized (e.g. on digital maps), there are unanswered needs for visualizing uncertainty along with it. Most research on effectively doing this addresses uncertainty in data values at geospatial positions, e.g. water depth, human population, or land-cover classification. Uncertainty in the data’s geospatial positions themselves (positional uncertainty) has not been previously focused on in this regard. In this thesis, techniques were created for visualizing positional uncertainty using World Vector Shoreline as an example dataset. The techniques consist of a …

Variational Iteration Method For The Burgers' Flow With Fractional Derivatives—New Lagrange Multipliers, Guo-Cheng Wu, Dumitru Baleanu

G.C. Wu

The flow through porous media can be better described by fractional models than the classical ones since they include inherently memory effects caused by obstacles in the structures. The variational iteration method was extended to find approximate solutions of fractional differential equations with the Caputo derivatives, but the Lagrange multipliers of the method were not identified explicitly. In this paper, the Lagrange multiplier is determined in a more accurate way and some new variational iteration formulae are presented.

Social Aggregation In Pea Aphids: Experiment And Random Walk Modeling, Christa Nilsen, John Paige, Olivia Warner, Benjamin Mayhew, Ryan Sutley, Mathew Lam, Andrew J. Bernoff, Chad M. Topaz

Chad M. Topaz

No abstract provided.

Comment On “Synthesis, Characterization, And Structures Of Persistent Aniline Radical Cation”: It Is A Protonated Aniline And Not An Aniline Radical Cation, Marat R. Talipov, Jeewantha S. Hewage, Sergey V. Lindeman, James R. Gardinier, Rajendra Rathore

Chemistry Faculty Research and Publications

The same, but different: The reaction of tri-tert-butylaniline (TBA) with AgSbF₆ in CH₂Cl₂ produces a green-colored intermediate which undergoes decomposition to form a protonated aniline (TBAH⁺SbF₆⁻). Crystals of the protonated aniline salt (see picture) were analyzed by X-ray diffraction and found to have the same crystal characteristics as the crystals of the supposed cation radical first identified in 2012.

Synthesis Of Novel Azetidines, Amber Thaxton

University of New Orleans Theses and Dissertations

Azetidine is a four-membered nitrogen-containing heterocyclic ring that has recently received a great deal of attention as a molecular scaffold for the design and preparation of biologically active compounds. Structure-activity studies employing functionalized azetidines have led to the development of variety of drug molecules and clinical candidates encompassing a broad spectrum of biological activities.

Herein, the synthesis a novel series of 3-aryl-3-arylmethoxyazetidines is described. Selected 3-aryl-3-arylmethoxyazetidines were evaluated for their binding affinity to multiple monoaminergic transporters for the potential treatment of methamphetamine addiction. It was discovered that this scaffold exhibits high binding affinity (nM) for both the serotonin and dopamine …

4d Evolution Of Fluvial System And Channel-Fill Architecture Of The Cretaceous Blackhawk Formation, Wasatch Plateau, Utah: An Integrated Fluvial Rock Record Analysis, Hiranya Sahoo

University of New Orleans Theses and Dissertations

Using an integrated dataset comprising outcrop, core, GPR and LiDAR data, this study targets a high-quality outcrop "window" of the upper Cretaceous Blackhawk Formation in the eastern Wasatch Plateau in central Utah, spanning a fairly large spatial (~30 km² area comprising eight contiguous, and vertical cliff faces) and temporal (~4 my) range. This research provides field-validation and -calibration of a wider range of fluvial heterogeneity: 1) large-scale heterogeneity (10’s of m vertically and 100’s of m laterally), 2) intermediate-scale heterogeneity (1’s of m vertically and 10’s of m laterally), and 3) small-scale heterogeneity (10’s of cm vertically and 1’s …