Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Environmental Sciences (696)
- Computer Sciences (538)
- Earth Sciences (361)
- Chemistry (282)
- Life Sciences (270)
-
- Engineering (263)
- Environmental Indicators and Impact Assessment (253)
- Sustainability (223)
- Oil, Gas, and Energy (216)
- Mathematics (212)
- Environmental Monitoring (208)
- Mechanical Engineering (200)
- Materials Science and Engineering (196)
- Energy Systems (194)
- Mining Engineering (193)
- Structural Materials (193)
- Physics (182)
- Geology (176)
- Oceanography and Atmospheric Sciences and Meteorology (109)
- Entomology (107)
- Environmental Chemistry (76)
- Plant Sciences (70)
- Agricultural Science (62)
- Astrophysics and Astronomy (60)
- Social and Behavioral Sciences (60)
- Medicine and Health Sciences (57)
- Natural Resources Management and Policy (51)
- Atmospheric Sciences (49)
- Applied Mathematics (44)
- Institution
-
- University of Texas at Arlington (716)
- International Centre of Insect Physiology and Ecology (287)
- University of Kentucky (213)
- Utah State University (183)
- University of Alabama at Birmingham (124)
-
- University of Denver (79)
- Zayed University (76)
- University of South Florida (61)
- Nova Southeastern University (50)
- City University of New York (CUNY) (48)
- Ministry of Higher and Secondary Specialized Education of the Republic of Uzbekistan (40)
- Illinois Math and Science Academy (34)
- GALILEO, University System of Georgia (33)
- Michigan Technological University (25)
- Virginia Commonwealth University (25)
- Dartmouth College (23)
- University of New Mexico (23)
- University of North Dakota (23)
- Stony Brook University (22)
- Illinois State University (21)
- Smith College (17)
- Technological University Dublin (14)
- University of Nevada, Las Vegas (14)
- Brigham Young University (13)
- Butler University (13)
- Vocational Training Council (12)
- University of Miami (10)
- Edith Cowan University (9)
- Rose-Hulman Institute of Technology (9)
- Cleveland State University (8)
- Keyword
-
- Gas (194)
- And Energy; Structural Materials; Sustainability (193)
- Energy Systems; Environmental Indicators and Impact Assessment; Environmental Monitoring; Mining Engineering; Oil (193)
- Geology (120)
- 3d model (116)
-
- Rock (116)
- Sediments (44)
- Water quality (44)
- Chlorophyll (42)
- Nitrogen (42)
- Regulation (42)
- Environment (41)
- Seagrass (41)
- Areal photo (40)
- Caulerpa prolifera (40)
- Florida (40)
- Hillsborough Bay (40)
- Hooker's Point (40)
- Igneous (40)
- Monitoring sites (40)
- Mud (40)
- Nutrient (40)
- Seabed (40)
- Sedimentary (40)
- Sewage (40)
- Sewage treatment (40)
- Tampa Bay (40)
- Tampa Bay Area Study Group (40)
- Wastewater management (40)
- Calculus (38)
- Publication Year
- Publication
-
- All Peer-Reviewed Publications (287)
- Computer Science and Engineering Theses - Archive (200)
- World of Coal Ash Proceedings (193)
- Computer Science and Engineering Dissertations - Archive (117)
- All 3D Rock Models (116)
-
- Browse all Datasets (92)
- All Works (76)
- Earth & Environmental Sciences Theses - Archive (74)
- Chemistry & Biochemistry Dissertations - Archive (73)
- Mathematics Dissertations - Archive (66)
- Physics Theses - Archive (49)
- Physics Dissertations - Archive (47)
- Chemistry & Biochemistry Theses - Archive (35)
- Mathematica Notebooks for Pre-Calculus and Calculus (34)
- Central Asian Problems of Modern Science and Education (32)
- Open Educational Resources (29)
- PERC Post-Release Swordfish Survival sPAT Data (28)
- Datasets (26)
- Earth & Environmental Sciences Dissertations - Archive (24)
- Biology and Medicine Through Mathematics Conference (22)
- Data Sets (22)
- Images (20)
- Publications and Research (19)
- SoMAS Research Data (19)
- Canyonlands Research Bibliography (18)
- USF Tampa Graduate Theses and Dissertations (18)
- Annual Symposium on Biomathematics and Ecology Education and Research (17)
- USU Uintah Basin Faculty Publications (17)
- DEEPEND Datasets (15)
- Michigan Tech Research Data (15)
Articles 2221 - 2250 of 2429
Full-Text Articles in Physical Sciences and Mathematics
Projects That Assist With Content In A Traditional Organic Chemistry Course, John J. Esteb, John R. Magers, Luanne Mcnulty, Anne M. Wilson
Projects That Assist With Content In A Traditional Organic Chemistry Course, John J. Esteb, John R. Magers, Luanne Mcnulty, Anne M. Wilson
Scholarship and Professional Work - LAS
Projects that engage undergraduate students in content-based courses, such as organic chemistry, must relate to the material and provide useful tools for the divergent needs of the students. There are few examples of these types of projects in the literature. Herein, we describe two projects, the reaction notebook and the end-of-semester synthesis activity. Each project is designed to stimulate student ownership of the material and leads to engagement with the content of the course.
You Should Run For Office (Video), Kevin O'Brien, Grace Drake
You Should Run For Office (Video), Kevin O'Brien, Grace Drake
All Maxine Goodman Levin School of Urban Affairs Publications
No abstract provided.
Structural Evolution And Vorticity Of Flow During Extrusion And Exhumation Of The Greater Himalayan Slab, Mount Everest Massif, Tibet/Nepal: Implications For Orogen-Scale Flow Partitioning, M. J. Jessup, R. D. Law, M. P. Searle, Mary S. Hubbard
Structural Evolution And Vorticity Of Flow During Extrusion And Exhumation Of The Greater Himalayan Slab, Mount Everest Massif, Tibet/Nepal: Implications For Orogen-Scale Flow Partitioning, M. J. Jessup, R. D. Law, M. P. Searle, Mary S. Hubbard
Geosciences Faculty Publications
The Greater Himalayan Slab (GHS) is composed of a north-dipping anatectic core, bounded above by the South Tibetan detachment system (STDS_ and below by the Main Central thrust zone (MCTZ). Assuming simultaneous movement on the MCTZ and STDS, the GHS can be modelled as a southward-extruding wedge or channel. New insights into extrusion-related flow with the GHS emerge from detailed kinematic and vorticity analyses in the Everest region. At the highest structural levels, mean kinematic vorticity number (Wm) estimates of 0.74-0.91 (c. 45-28% pure shear) were obtained from sheared Tethyan limestone and marble from the Yellow Band on Mount Everest. …
Use Of Bootable Linux Cds For The Delivery Of Educational Course Content, Craig Valli
Use Of Bootable Linux Cds For The Delivery Of Educational Course Content, Craig Valli
Research outputs pre 2011
This paper outlines the processes involved in creating and using bootable Linux/Knoppix compact discs (CDs) as a means of delivering course content to students. An outline of experiences in using these CDs to deliver courses in totally on-line mode is also given.
Interactive Animated Concept Map Generation - Using Dynamic Animations, Suneel Vana
Interactive Animated Concept Map Generation - Using Dynamic Animations, Suneel Vana
Computer Science and Engineering Theses - Archive
We present a visualization tool, which is useful for the illustration of educational concepts using interactive animated concept maps. This system serves as a presentation tool which provides a collection of multimedia elements (images, animations, audios clips and video clips), a collection of animated presentation templates and an interface by using which users can retrieve the multimedia elements from the multimedia database and generate the dynamic animations by placing the selected elements into the placeholders of the templates. The system generates the animated presentation by replacing embedded multimedia objects and their properties as desired by its users. A multimedia information …
On The Existence And Stability Of Carbon -Based Silicon Fullerenes -A Density Functional Theoretic Study, Aravind Srinivasan
On The Existence And Stability Of Carbon -Based Silicon Fullerenes -A Density Functional Theoretic Study, Aravind Srinivasan
Physics Theses - Archive
The electronic and geometric properties of silicon-carbon fullerene-like nanostructures with two, four, six, twenty and twenty four carbon atoms on the surface of the Si60 cages by substitution, as well as inside the cage at various symmetry orientations have been studied within the generalized gradient approximation to density functional theory (GGA-DFT). The Perdew-Wang 91 (PW91) functional has been used to treat exchange and correlation energies. Full geometry and spin optimizations have been performed using Gaussian 03 suite of programs and the LANL2DZ basis set. Thus for the silicon atom, the Hay-Wadt pseudopotential with the associated basis set are used for …
Monitoring Health By Detecting Drifts And Outliers In Patterns Of An Inhabitant In A Smart Home, Gaurav Jain
Monitoring Health By Detecting Drifts And Outliers In Patterns Of An Inhabitant In A Smart Home, Gaurav Jain
Computer Science and Engineering Theses - Archive
The elderly, along with people with disabilities or chronic illness, are most often dependent on some kind of formal or informal care. They are forced to move to a place where they can be cared for. Automatic health monitoring allows them to maintain their independence and continue living at home longer by continuously providing key health and activity information to caregivers. In this thesis, we present a novel technique, called the Health Monitoring System (HMS), which is a data-driven automated monitoring system for detecting changes in the patterns of activities/inactivity, health data and the living environment. HMS classifies these changes …
Infosearch: A System For Searching And Retrieving Documents Using Complex Queries, Nikhil Deshpande
Infosearch: A System For Searching And Retrieving Documents Using Complex Queries, Nikhil Deshpande
Computer Science and Engineering Theses - Archive
The colossal amount of information available online has resulted in overloading users who need to navigate this information for their routine requirements. Although search engines have been effective in reducing this information overload, they support only queries involving keywords and Boolean operators. There are certain application domains where more expressive ways of searching are necessary. Consider searching a full-text patent database for documents containing more than n occurrences of a pattern, or for documents that have a particular pattern followed by another pattern within a specified interval. Such complex patterns involving pattern frequency and sequence, as well as patterns involving …
Customization Of A Generic Search Engine By Adding User Categories, Ajay Mohandas Madkaiker
Customization Of A Generic Search Engine By Adding User Categories, Ajay Mohandas Madkaiker
Computer Science and Engineering Theses - Archive
The current search engines available on the Net are generic in nature. They do not consider user preferences and treat all users information needs in the same way. As a result they frequently return a large number of links, that do not meet the user's information need. This requires more searching to find what the user is looking for. For example if a user is interested in a particular game, e.g. cricket, and enters the query world cup, a generic search engine would return links of all the sports that hold a world cup. The user has to browse through …
Estream: An Integration Of Event And Stream Processing, Vihang Garg
Estream: An Integration Of Event And Stream Processing, Vihang Garg
Computer Science and Engineering Theses - Archive
Event and stream data processing models have been researched extensively and are utilized in diverse application domains. Advanced applications require both event and stream processing, which is currently not supported. Although there are number of similarities and differences between them, a synergistic integration of their strengths will be better than the sum of their parts. In this thesis, we present EStream, an integrated event and stream processing system for monitoring changes on stream computations and for expressing and processing complex events on continuous queries (CQs). We introduce attribute-based constraints for reducing uninteresting events that are generated from CQs. We discuss …
Testing Java Monitors By State Space Exploration, Monica Maria Hernandez
Testing Java Monitors By State Space Exploration, Monica Maria Hernandez
Computer Science and Engineering Theses - Archive
Java monitors are classes that are intended to be accessed by multiple threads at the same time. Detecting synchronization faults in Java Monitors is considerably more challenging than testing regular classes, due to the inherent non-determinism of concurrent programs. This thesis proposes a state based exploration approach to testing Java monitors. This approach consists of exploring the state space of a Java monitor in a depth-first manner, dynamically building test sequences, which are comprised by the states explored along each path. Moreover, threads are introduced on the fly during the exploration of each path, based on several rules for simulating …
Hdb-Subdue, A Relational Database Approach To Graph Mining And Hierarchical Reduction, Srihari Padmanabhan
Hdb-Subdue, A Relational Database Approach To Graph Mining And Hierarchical Reduction, Srihari Padmanabhan
Computer Science and Engineering Theses - Archive
Data mining aims at discovering interesting and previously unknown patterns from data sets. Transactional mining (association rules, decision trees etc.) can be effectively used to find non-trivial patterns in categorical and unstructured data. For applications that have an inherent structure (e.g., chemical compounds, proteins) graph mining is appropriate, because mapping the structured data into other representations would lead to loss of structure. The need for mining structured data has increased in the past few years. Graph mining uses graph theory principles to perform mining. Database mining of graphs aims at mining structured graph data stored in relational database tables using …
Graph-Based Learning Using A Naive Bayesian Classifier, Robert Hawes
Graph-Based Learning Using A Naive Bayesian Classifier, Robert Hawes
Computer Science and Engineering Theses - Archive
Graph-based data representation is becoming increasingly more commonplace, as graphs can represent some kinds of data more efficiently than relational tables. As such, interesting patterns in the form of subgraphs can be discovered by mining these graph-based datasets. Because the learned patterns can be used to predict future occurrences, it is necessary to learn graphical concepts that can optimally classify the data in the presence of uncertainty. This work explores the construction and learning of optimal naïve Bayesian graph classifiers to distinguish between positive and negative graphs given a set of graphs as examples. Whereas most previous work in graph-based …
Approaches For Validating Frequent Episodes Based On Periodicity In Time-Series Data, Dhawal Y. Bhatia
Approaches For Validating Frequent Episodes Based On Periodicity In Time-Series Data, Dhawal Y. Bhatia
Computer Science and Engineering Theses - Archive
There is ongoing research on sequence mining of time-series data. We study Hybrid Apriori, an interval-based approach to episode discovery that deals with different periodicities in time-series data. Our study identifies the anomaly in the Hybrid Apriori by confirming the false positives in the frequent episodes discovered. The anomaly is due to the folding phase of the algorithm, which combines periods in order to compress data. We propose a main memory based solution to distinguish the false positives from the true frequent episodes. Our algorithm to validate the frequent episodes has several alternatives such as the naïve approach, the partitioned …
Csegrid Portal: A Secure Web-Based Solution For Providing Ubiquitious Access To Grid Services (Design, Development And Implementation Of A Prototype), Srikant D. Rao
Computer Science and Engineering Theses - Archive
Grid computing is emerging as a revolutionary concept for performing high performance computations on the grid. The grid infrastructure comprises of a large set of distributed computing resources that are shared across geographical and organizational boundaries. There is a need within the scientific community for friendly interfaces that can be used to obtain ubiquitous access to the grid resources. In this work, we address these needs by designing and implementing a web-based grid portal system (CSEGrid) that provides the user with transparent access to grid services like job submission, job status and resource monitoring, data transfer between grid resources, etc. …
Solving The Rubik's Cube With Parallel Processing, Aslesha Pramod Nargolkar
Solving The Rubik's Cube With Parallel Processing, Aslesha Pramod Nargolkar
Computer Science and Engineering Theses - Archive
This thesis investigates parallel processing techniques for solving the 3 x 3 x 3 Rubik's Cube. We explore various state-space search based algorithmic approaches to optimally solve the Cube. The parallel processing approach is based on IDA* using a pattern database as the underlying heuristic because of its well established effectiveness. The parallel algorithm is an extension of the Michael Reid algorithm which is sequential. The parallel algorithm exhibits good speedup and scalability. Nearly 150 random as well as symmetrical cube configurations were tested for the experiments on sequential and parallel implementations. The proposed parallel algorithm using master-slave type of …
Evolving Modular Programs By Extracting Reusable Functions Using Significance Testing, Anthony Loeppert
Evolving Modular Programs By Extracting Reusable Functions Using Significance Testing, Anthony Loeppert
Computer Science and Engineering Theses - Archive
Genetic programming is an automatic programming method that uses biologically inspired methods to evolve programs. Genetic programming, and evolutionary methods in general, are useful for problem domains in which a method for \emph{constructing} solutions is either not known or infeasible, but a method for \emph{rating} solutions exists. In order to address more complex problem domains, techniques exist to extract functions (modules) automatically during a GP search. This work describes a method to identify useful automatically extracted functions from a GP search to assist subsequent GP searches within the same problem domain, using significance testing. Functions classified as beneficial augment the …
Oligomeric And Polymeric Bibenzimidazole Based Metal Complexes And Crosslinked Polyethylenimine Based Flame Retardants, Jun Yin
Chemistry & Biochemistry Dissertations - Archive
In Part I, a simple and mild condensation route for the synthesis of novel bibenzimidazole oligomers and polymers is described using methyl 2,2,2-trichloroacetimidate as a key starting material. The dimer, trimer, tetramer, and polymers of bibenzimidazole were synthesized as a new series of potential conjugated chelating ligands for the metallopolymer studies. The polymers show the maximum absorption at around 400 nm. The optical band gap of the polymer is estimated to be 2.68 eV. In Part II, a series of multinuclear Ru complexes containing di-, tetra-, and octa-RuII centers based on the oligomeric bibenzimidazoles were synthesized and characterized. The species …
Efficient Xquery Processing Of Streamed Xml Fragments, Seo Young Ahn
Efficient Xquery Processing Of Streamed Xml Fragments, Seo Young Ahn
Computer Science and Engineering Theses - Archive
XStreamCast is a push-based streamed XML query processing system that supports multiple servers and clients. The servers broadcast streamed XML data while the clients register to these servers for a specific service and process streamed XML fragments. This thesis presents methods for efficient XQuery processing of streamed XML fragments for the client. The XQuery parser parses the XQuery given by the user first. The client processes the fragments and stores only the needed data for the query. The query is then applied to stored XML fragments. This system can be valuable for managing the memory of the client because it …
Supramolecular Chemistry Of Nitrogen Dioxide, Yanlong Kang
Supramolecular Chemistry Of Nitrogen Dioxide, Yanlong Kang
Chemistry & Biochemistry Dissertations - Archive
Supramolecular chemistry has been defined as "chemistry beyond molecules", and involves investigating molecular systems held together reversibly by inter-molecular forces, not by covalent bonds. This dissertation discusses a supramolecular approach towards sensing, entrapment and utilization of NO2/N2O4 gases. Chapter 1 briefly discusses supramolecular chemistry and supramolecular chemistry of gases. In chapter 2, the interaction of NOx with metalloporphyrins is described. Specifically, ruthenium nitrosyl derivatives hold a special place in mimicking bio-relevant NO-metal interactions. A previously unnoticed reaction between NO2/N2O4 and a Ru(II) porphyrin is described. It causes disproportionation of N2O4 and leads to a stable nitrosyl nitrato complex. Our findings …
A Novel Game Theoretic Framework For Security In Wireless Sensor Networks, Afrand Agah
A Novel Game Theoretic Framework For Security In Wireless Sensor Networks, Afrand Agah
Computer Science and Engineering Dissertations - Archive
Due to severe resource limitations and often lack of centralized infrastructure, providing security in wireless sensor networks is a great challenge. Misbehavior due to malicious or faulty nodes can significantly degrade the performance of such networks. Therefore, countermeasures against denial of service (DoS) attacks and node misbehavior are essential requirements. We argue that the conventional view of security based on cryptography techniques is not sufficient for securing wireless sensor networks. In this dissertation, we investigate a novel framework by proposing three approaches for security enforcement in such networks that range from prevention of DoS attacks to secure routing. Prevention of …
Querying Microarray Databases, Zoe Alexandra Raja
Querying Microarray Databases, Zoe Alexandra Raja
Computer Science and Engineering Theses - Archive
Microarray technology has rapidly taken a key position among bioinformatics research tools. After the completion of the Human Genome Project, microarray databases have become particularly important to the management and analysis of genomic data. These databases are ideal tools for many research areas involving gene expression patterns under different experimental conditions. This work attempts to assess the querying capabilities of current public microarray database implementations by evaluating their data management, query interfaces, and results presentation. We are not aware of any comparative study available to date that evaluates this important class of biological databases. We examine and evaluate how several …
Repclass: Cluster And Grid Enabled Automatic Classification Of Transposable Elements Identified De Novo In Genome Sequences, Nirmal Ranganathan
Repclass: Cluster And Grid Enabled Automatic Classification Of Transposable Elements Identified De Novo In Genome Sequences, Nirmal Ranganathan
Computer Science and Engineering Theses - Archive
In the last few years many computer and laboratory improvements in the production and analysis of DNA sequences have made possible the complete sequencing of whole genomes. This provides us with a wealth of raw genomes that needs to be processed and annotated. 5% to 80% of eukaryotic genomes contain repetitive DNA consisting of transposable elements and tandem repeats which needs to be identified, classified and annotated in order to sequence and annotate the entire genome accurately. Existing tools allow us to identify and annotate transposable elements (TE) but no tool exists for their classification. This thesis work introduces REPCLASS …
Application Of Graph-Based Data Mining To Biological Networks, Chang Hun You
Application Of Graph-Based Data Mining To Biological Networks, Chang Hun You
Computer Science and Engineering Theses - Archive
A huge amount of biological data has been generated by long-term research. It is time to start to focus on a system-level understanding of bio-systems. Biological networks are networks of biochemical reactions, containing various objects and their relationships. Understanding of biological networks is a starting point of systems biology. Multi-relational data mining finds the relational patterns in both the entity attributes and relations in the data. A widely used representation for relational data is a graph consisting of vertices and edges between these vertices. Graph-based data mining, as one approach of multi-relational data mining, finds relational patterns in a graph …
Enhancements To The Sam-Grid Infrastructure, Bimal Balan
Enhancements To The Sam-Grid Infrastructure, Bimal Balan
Computer Science and Engineering Theses - Archive
SAM-Grid is a grid computing infrastructure for high energy physics (HEP) experiments in Fermilab. It is composed of data handling, job management and information management components. There are several challenges when the number of sites participating in the experiment increases. This thesis presents the enhancements made on the SAM-Grid infrastructure. This includes scalability and performance related enhancements. The enhancements mainly affect the batch adapter, monitoring and security layers. As a scalability aspect, Monitoring and Information services required changes to make it easier for monitoring large number of jobs. SAM-Grid is integrated with Sun Grid Engine (SGE) batch system. The batch …
Adaptive Agent Communities For Providing Services In Dynamic Networks, Nayantara Mallesh
Adaptive Agent Communities For Providing Services In Dynamic Networks, Nayantara Mallesh
Computer Science and Engineering Theses - Archive
New network applications are being created everyday to accommodate diverse user needs. Delivering services to the user in a timely manner taking into account network conditions, resources allocated and network load is a challenge. Multiprotocol Label Switching attempts to overcome best-effort service by providing a method for routing traffic around network congestion, resource reservation and quality of service (QoS) capabilities. IntServ and DiffServ are two other QoS models in use today. IntServ provides per-flow guarantee of quality while DiffServ is based on aggregate service classes. Adaptive Network Service (ANS) is a community of adaptive, collaborating agents residing in the network …
Multi-Dimensional Indexing For Xml Data, Do Youn Kim
Multi-Dimensional Indexing For Xml Data, Do Youn Kim
Computer Science and Engineering Theses - Archive
The Extensible Markup Language (XML) is becoming a dominant standard for exchanging and retrieving data over the internet. As XML in data exchanging grows, various XML indexing techniques have been proposed for fast and efficient query processing. A survey of theses techniques [9] categorized them into sequence-based indexes, structural indexes, dimension-based indexes and keyword-based indexes based on their properties. In this thesis, we focus on the multi-dimensional XML indexing; more precisely, it can be categorized as a 2-dimension based indexing, which is used in this paper. We studied the properties of multi-dimensional XML indexing and created an implementation to evaluate …
Adaptive, Multimodal, Application Independent User Interfaces For People With Disabilites Using Computers, Padmapriya Sambath
Adaptive, Multimodal, Application Independent User Interfaces For People With Disabilites Using Computers, Padmapriya Sambath
Computer Science and Engineering Theses - Archive
The goal of this thesis is to create more adaptive and flexible user interfaces for people with disabilities and presenting information to everyone and on every device at any time. Delivering information at any time leads to situations such as a person walking with a mobile device having a small screen wanting to make a flight reservation. The intention of presenting information to everybody immediately raises the question of how much of the available information reach people with disabilities. We have suggested a content based user interface language that may be used by external services to interact with the user. …
Service Discovery By Automated Structural And Semantic Matching, Alan Walker
Service Discovery By Automated Structural And Semantic Matching, Alan Walker
Computer Science and Engineering Theses - Archive
Pervasive computing systems need to locate and use services dynamically. Current models of service location and interaction rely on a fixed contract, or service description, located by name and/or a combination of keywords. This implies a priori agreement on the service description, leading to fragility and the inability for systems to interoperate unless they were built to match an existing standard. This thesis implements a technique for relaxing the fixed contract assumption, so that the nearest match amongst a set of services can be located. The system takes into account structural, data type and naming differences. The naming differences are …
Supramolecular Nanostructures Based On Calixarenes, Heng Xu
Supramolecular Nanostructures Based On Calixarenes, Heng Xu
Chemistry & Biochemistry Dissertations - Archive
This dissertation describes a systematic approach towards the design, synthesis, characterization, and application of calixarene-based supramolecular nanostructures. Chapter 1 briefly overviews the field of supramolecular chemistry and highlights its horizons. Chapter 2 introduces a modular strategy towards synthesis of nanoscale receptor macromolecules--calix-peptide conjugates. This strategy combines the unique host-guest capabilities of calixarene chemistry with synthetically flexible peptide synthesis. A series of calixarene amino acids was prepared and further utilized to synthesize calixarene dipeptides. Through this approach, calixarene amino acids are now available to be incorporated into peptide networks and nanostructured biologically relevant materials. Chapter 3 demonstrates supramolecular applications of calixarene-peptide …