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Rheological, Interfacial, And Filtration Behavior Of Lignocellulosic Nanomaterials In Suspension And Emulsion Drilling Fluids, Meen Sung Koo Mar 2025

Rheological, Interfacial, And Filtration Behavior Of Lignocellulosic Nanomaterials In Suspension And Emulsion Drilling Fluids, Meen Sung Koo

LSU Doctoral Dissertations

In recent years, the rheological aspects of suspensions/emulsions applied by cellulose nanomaterials (CNMs) have been gained considerable interests due to high gel-forming properties ascribed by hydrophilicity, crystallinity, ease functionalization, and high aspect ratio. Introducing residual lignin in CNMs (LCNMs) seemed to be capable of achieving various advantages in the application of CNMs ascribed by hydrophobicity, binding effects, and abundant aromatic groups derived from complexity of lignin. This dissertation dedicates to the characterizations of (L)CNMs, and rheological properties of (L)CNMs applied fluids (i.e., suspension and emulsion). In the suspension system, the presence of lignin in LCNMs decreased gel strength, viscosity, and …


Bio-Based Polyurethane Foams Made From Microwave Liquefaction Of Biomass, Xingyan Huang Aug 2018

Bio-Based Polyurethane Foams Made From Microwave Liquefaction Of Biomass, Xingyan Huang

LSU Doctoral Dissertations

Polyurethane (PU) foam is one of the most versatile construction insulations due to its low density, low thermal conductivity, and high mechanical performance. However, it is still highly dependent on petro-based chemicals, i.e. polyol and isocyanate. In this work, biomass, such as rape straw, switchgrass, and yaupon holly (Ilex vomitoria) were liquefied using microwave energy to produce bio-based polyol in order to substitute petro-based polyol in the production of PU foam. Cellulose nanocrystals (CNCs) were also extracted from liquefaction solid residue. They were then applied to reinforce high bio-content PU foam. Moreover, lignin was fractionated from bio-polyol by …