Nanoscience and Nanotechnology Commons^™

Methods , Systems , And Devices Relating To Surgical End Effectors, Shane M. Farritor, Tom Fredrick, Joe Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices, and more specifically including end effectors that can be incorporated into such devices. Certain end effector embodiments include various vessel cautery devices that have rotational movement as well as cautery and cutting functions while maintaining a relatively compact structure. Other end effector embodiments include various end effector devices that have more than one end effector.

System For Imaging And Measuring Rail Deflection, Shane M. Farritor

Department of Mechanical and Materials Engineering: Faculty Publications

Devices, systems, and methods for imaging and measuring deflections in structures such as railroad rail are disclosed. One exemplary embodiment relates to a vision system having a high-speed, visible-light imaging camera and an evaluation unit configured for analyzing images from the camera to detect geometric variations in the structure. In a second example, additional sensors are used to identify the wheel location(s) in the same reference frame as the mea Surement system. In analyzing structures Such as railroad track rail, the imaging camera can be coupled to a moving rail vehicle and configured for generating images of the rail as …

Effect Of Random Ethylene Comonomer On Relaxation Of Flow-Induced Precursors In Isotactic Polypropylene, Benjamin Schammé, Eric Dargent, Lucia Fernandez-Ballester

Department of Mechanical and Materials Engineering: Faculty Publications

The effect of comonomer on structure and relaxation of flow-induced precursors was investigated in a series of isotactic polypropylene and random propylene−ethylene copolymers. The polymers were subjected to flow by fiber pulling and allowed to relax above their nominal melting temperature for specific times. The type of morphology developed after cooling revealed whether flow-induced precursors were still present or the melt had fully reequilibrated. Precursors were long-lived and, at fixed temperature, decayed significantly faster with higher ethylene content. The critical time for precursor relaxation followed an Arrhenius-type dependence with temperature. The apparent energy of activation for precursor dissolution decreased with …

Rapidly Solidified Rare-Earth Permanent Magnets: Processing, Properties, And Applications, Shampa Aich, Dillip K. Satapathy, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Rapidly solidified rare-earth-based permanent magnets are considered to have better potential as permanent magnets compared to the conventional bulk materials, which can be attributed to their improved microstructure and better magnetic properties compared to rare-earth magnets synthesized by the conventional (powder metallurgy) routes. The performance (quality) of these magnets depends on the thermodynamics and kinetics of the different processing routes, such as atomization, melt spinning, and melt extraction. Here, we review the various processing routes of rapidly solidified rare-earth permanent magnets and the related properties and applications. In the review, some specific alloy systems, such as Sm–Co-based alloys, Nd–Fe–B, and …

Biodegradable Elastic Nanofibrous Platforms With Integrated Flexible Heaters For On-Demand Drug Delivery, Ali Tamayol, Alireza Hassani Najafabadi, Pooria Mostafalu, Ali K. Yetisen, Mattia Commotto, Musab Aldhahri, Mohamed Shaaban Abdel-Wahab, Zeynab Izadi Najafabadi, Shahrzad Latifi, Mohsen Akbari, Nasim Annabi, Seok Hyun Yun, Adnan Memic, Mehmet R. Dokmeci, Ali Khademhosseini

Department of Mechanical and Materials Engineering: Faculty Publications

Delivery of drugs with controlled temporal profiles is essential for wound treatment and regenerative medicine applications. For example, bacterial infection is a key challenge in the treatment of chronic and deep wounds. Current treatment strategies are based on systemic administration of high doses of antibiotics, which result in side effects and drug resistance. On-demand delivery of drugs with controlled temporal profile is highly desirable. Here, we have developed thermally controllable, antibiotic-releasing nanofibrous sheets. Poly(glycerol sebacate)- poly(caprolactone) (PGS-PCL) blends were electrospun to form elastic polymeric sheets with fiber diameters ranging from 350 to 1100 nm and substrates with a tensile modulus …

Nondestructive Testing System Design For Biological Product Based On Vibration Signal Analysis Of Acceleration Sensor, Xiaohao Li, Tao Shen

Department of Mechanical and Materials Engineering: Faculty Publications

In order to reduce the disadvantages of current biological product quality testing methods, taking the quality testing in cocoon trade markets as an example, this paper has proposed a quality nondestructive testing method for biological products based on the analysis of vibration signal from acceleration sensors. According to the wavelet transformation analysis on the random vibration signal acquired from the acceleration sensor, the random vibration signal related to the silkworm chrysalis quality has been analyzed and reconstructed; then the characteristic values such as: mean value, variance, mean square root, waveform index, pulse factor, and so on of the quality signal …

Solution Nuclear Magnetic Resonance Spectroscopy On A Nanostructured Diamond Chip, P. Kehayias, A. Jarmola, N. Mosavian, I. Fescenko, F.M. Benito, A. Laraoui, J. Smits, L. Bougas, D. Budker, A. Neumann, S.R.J. Brueck, V.M. Acosta

Department of Mechanical and Materials Engineering: Faculty Publications

Sensors using nitrogen-vacancy centers in diamond are a promising tool for small-volume nuclear magnetic resonance (NMR) spectroscopy, but the limited sensitivity remains a challenge. Here we show nearly two orders of magnitude improvement in concentration sensitivity over previous nitrogen-vacancy and picoliter NMR studies. We demonstrate NMR spectroscopy of picoliter-volume solutions using a nanostructured diamond chip with dense, high-aspect-ratio nanogratings, enhancing the surface area by 15 times. The nanograting sidewalls are doped with nitrogen-vacancies located a few nanometers from the diamond surface to detect the NMR spectrum of roughly 1 pl of fluid lying within adjacent nanograting grooves. We perform 1H …

Micro/Nanostructures Formation By Femtosecond Laser Surface Processing On Amorphous And Polycrystalline Ni60nb40, Edwin Peng, Alfred Tsubaki, Craig A. Zuhlke, Meiyu Wang, Ryan Bell, Michael J. Lucis, Troy P. Anderson, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Femtosecond laser surface processing is a technology that can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophilicity/superhydrophobicity. In this study, two unique classes of surface structures, below surface growth (BSG) and above surface growth (ASG) mounds, were formed by femtosecond laser surface processing on amorphous and polycrystalline Ni₆₀Nb₄₀ with two different grain sizes. Cross sectional imaging of these mounds revealed thermal evidence of the unique formation processes for each class of surface structure. BSG mounds formed on all three substrates using the same laser parameters had similar surface …

Methods , Systems , And Devices Relating To Robotic Surgical Devices , End Effectors , And Controllers, Shane M. Farritor, Thomas Frederick, Joe Bartels, Eric Markvicka, Jack Mondry

Department of Mechanical and Materials Engineering: Faculty Publications

The various embodiments disclosed herein relate to improved robotic surgical systems, including robotic surgical devices having improved arm components and/or bio metric sensors, contact detection systems for robotic surgical devices, gross positioning systems and devices for use in robotic surgical systems, and improved external controllers and consoles.

Degradation Resistant Surface Enhanced Raman Spectroscopy Substrates, Ryan D. Scherzer

UNF Graduate Theses and Dissertations

Raman spectroscopy is employed by NASA, and many others, to detect trace amounts of substances. Unfortunately, the Raman signal is generally too weak to detect when very small, but non-trivial, amounts of molecules are present. One way around this weak signal is to use surface enhanced Raman spectroscopy (SERS).

When used as substrates for SERS, metallic nanorods grown using physical vapor deposition (PVD) provide a large enhancement factor to the Raman signal, as much as 10¹². However, Silver (Ag) nanorods that give high enhancement suffer from rapid degradation as a function of time and exposure to harsh environment. …

Shear Driven Micro-Fluidic Pump, Nihad E. Daidzic

Aviation Department Publications

United States Patent, Patent Number US 9,528,503 B2, Date of Patent December 27, 2016.

An example includes an apparatus to pump a fluid. The apparatus includes a housing extending along a length defining an elongate interior, an actuator in the housing, conforming to the elongate interior, the actuator including a plurality of lumens, each having a length extending substantially parallel to the elongate interior, each from around 10 to 200 micrometers across and an actuator configured to oscillate the actuator in the actuator houslng along the length of the elongate interior with a rate differential between movement in a first …

The Effect Of A Powered Ankle Foot Orthosis On Walking In A Stroke Subject: A Case Study, Ali Pourghasem, Ismail Ebrahimi Takamjani, Mohammad Taghi Karimi, Mohammad Kamali, Mohammad Jannesari, Iman Salafian

Department of Mechanical and Materials Engineering: Faculty Publications

[Purpose] Standing and walking are impaired in stroke patients. Therefore, assisted devices are required to restore their walking abilities. The ankle foot orthosis with an external powered source is a new type of orthosis. The aim of this study was to evaluate the performance of a powered ankle foot orthosis compared with unpowered orthoses in a stroke patient.

[Subjects and Methods] A single stroke subject participated in this study. The subject was fitted with three types of ankle foot orthosis (powered, posterior leg spring, and carbon ankle foot orthoses). He was asked to walk with and without the three types …

Optical Sub-Diffraction Limited Focusing For Confined Heating And Lithography, Luis M. Traverso

Open Access Dissertations

Electronics and nanotechnology is constantly demanding a decrease in size of fabricated nanoscale features. This decrease in size has become much more difficult recently due to the limited resolution of optical systems that are fundamental to many nanofabrication methods. A lot of effort has been made to fabricate devices smaller than the diffraction limit of light. Creating devices that are capable of confining fields by means of interference patterns of propagating wave modes and surface plasmon, has proven successful to confine light into smaller spot sizes.

Zone plate diffraction lenses generate spots with dimensions very close to the diffraction limit. …

Liquid Metal Particle Popping: Nanoscale To Macroscale, Trevor R. Lear

Open Access Theses

Liquid metal nanoparticles can be used to produce stretchable electronic devices. Understanding the mechanical properties of liquid metal nanoparticles is crucial to optimizing their use in various applications, especially printing of flexible, stretchable electronics. Smaller nanoparticles are desired for high-resolution printing and compatibility with existing scalable manufacturing methods; however, they contain less liquid metal and are more difficult to rupture than larger particles, making them less desirable for post-processing functionality. This study investigates the mechanics of liquid metal particle rupture as a function of particle size. We employ compression of particle films to characterize the composition of the particle core …

Carbon Nanotube Thermal Interfaces And Related Applications, Stephen L. Hodson

Open Access Dissertations

The development of thermal interface materials (TIMs) is necessitated by the temperature drop across interfacing materials arising from macro and microscopic irregularities of their surfaces that constricts heat through small contact regions as well as mismatches in their thermal properties. Similar to other types of TIMs, CNT TIMs alleviate the thermal resistance across the interface by thermally bridging two materials together with cylindrical, high-aspect ratio, and nominally vertical conducting elements. Within the community of TIM engineers, the vision driving the development of CNT TIMs was born from measurements that revealed impressively high thermal conductivities of individual CNTs. This vision was …

Experimentally Validated 3d Md Model For Afm-Based Tip-Based Nanomanufacturing, Rapeepan Promyoo

Open Access Dissertations

In order to control AFM-based TBN to produce precise nano-geometry efficiently, there is a need to conduct a more focused study of the effects of different parameters, such as feed, speed, and depth of cut on the process performance and outcome. This is achieved by experimentally validating a MD simulation model of nanomachining, and using it to conduct parametric studies to guide AFM-based TBN. A 3D MD model with a larger domain size was developed and used to gain a unique insight into the nanoindentation and nanoscratching processes such as the effect of tip speed (e.g. effect of tip speed …

Self-Patterning Gd Nano-Fibers In Mg-Gd Alloys, Yangxin Li, Jian Wang, Kaiguo Chen, Meiyue Shao, Yao Shen, Li Jin, Guo-Zhen Zhu

Department of Mechanical and Materials Engineering: Faculty Publications

Manipulating the shape and distribution of strengthening units, e.g. particles, fibers, and precipitates, in a bulk metal, has been a widely applied strategy of tailoring their mechanical properties. Here, we report self-assembled patterns of Gd nano-fibers in Mg-Gd alloys for the purpose of improving their strength and deformability. 1-nm Gd nano-fibers, with a 〈c〉-rod shape, are formed and hexagonally patterned in association with Gd segregations along dislocations that nucleated during hot extrusion. Such Gd-fiber patterns are able to regulate the relative activities of slips and twinning, as a result, overcome the inherent limitations in strength and ductility of Mg alloys. …

Single Site Robotc Device And Related Systems And Methods, Jack Mondry, Shane M. Farritor, Eric Markvicka, Thomas Frederick, Joseph Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incor porated into robotic and/or in vivo medical devices. Certain embodiments include various medical devices for in vivo medical procedures.

Molybdenum Disulfide-Conducting Polymer Composite Structures For Electrochemical Biosensor Applications, Hongxiang Jia

USF Tampa Graduate Theses and Dissertations

Lactic acid is widely existing in human bodies, animals and microorganisms. Recently, using biosensor to detect the concentration of lactic acid and diagnose disease have attracted great research and development interests. Nanocomposites is one of the best material used for biosensor because their wonderful conductivity, optical and electrochemical properties. In the study, MoS₂ and polypyrrole (PPY) are used for the composite material electrode. To determine whether lactate oxidase (LOD) was helpful for the biosensor’s detective properties, both PPY-MoS₂ film with LOD and PPY-MoS₂ film without LOD are being tested. The fourier transform infrared spectroscopy (FTIR) and Raman …

Video Capture And Post-Processing Technique For Approximating 3d Projectile Trajectory, Chase M. Pfeifer, Judith M. Burnfield, Guilherme M. Cesar, Max H. Twedt, Jeff A. Hawks

Department of Mechanical and Materials Engineering: Faculty Publications

In this paper we introduce a low-cost procedure and methodology for markerless projectile tracking in three-dimensional (3D) space. Understanding the 3D trajectory of an object in flight can often be essential in examining variables relating to launch and landing conditions. Many systems exist to track the 3D motion of projectiles but are often constrained by space or the type of object the system can recognize (Qualisys, Göteborg, Sweden; Vicon, Oxford, United Kingdom; Opti-Track, Corvallis, Oregon USA; Motion Analysis, Santa Rosa, California USA; Flight Scope, Orlando, Florida USA). These technologies can also be quite expensive, often costing hundreds of thousand dollars. …

Influence Of Imperfections On Carbon Nanotube Properties, Marino Brcic, Marko Canadija, Josip Brnic

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Thermal Analysis Of Continuous And Patterned Multilayer Films In The Presence Of A Nanoscale Hot Spot, Jia-Yang Juang, Jinglin Zheng

Department of Mechanical and Materials Engineering: Faculty Publications

Thermal responses of multilayer films play essential roles in state-of-the-art electronic systems, such as photo/micro-electronic devices, data storage systems, and silicon-on-insulator transistors. In this paper, we focus on the thermal aspects of multilayer films in the presence of a nanoscale hot spot induced by near field laser heating. The problem is set up in the scenario of heat assisted magnetic recording (HAMR), the next-generation technology to overcome the data storage density limit imposed by superparamagnetism. We characterized thermal responses of both continuous and patterned multilayer media films using transient thermal modeling. We observed that material configurations, in particular, the thermal …

An Examination Of The Indentation Size Effect In Fcc Metals And Alloys From A Kinetics Based Perspective Using Nanoindentation, David Earl Stegall

Mechanical & Aerospace Engineering Theses & Dissertations

The indentation size effect (ISE) in metals is described as the rise in hardness with decreasing depth of indentation and contradicts conventional plasticity behavior. The goal of this dissertation is to further examine the fundamental dislocation mechanisms that may be contributing to the so-called indentation size effect. In this work, we examined several metals and alloys including 99.999% Aluminum (SFE ~200 mJ/m²), 99.95% Nickel (SFE ~125 mJ/m²), 99.95% Silver (SFE ~22 mJ/m²⁾, and three alloys, alpha brass 70/30 (SFE >10 mJ/m²), 70/30 nickel copper (SFE ~100 mJ/ …

Case Study Of Quantifying Energy Loss Through Ceiling-Attic Recessed Lighting Fixtures Through 3d Numerical Simulation, Ri Na, Shengmao Lin, Zhigang Shen, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Abstract Air leakage through recessed lighting fixtures has been identified as a common issue that causes extra energy consumption in residential buildings. However, few quantitative studies in this area were found. As such, a preliminary assessment of the magnitude of this type of energy loss was conducted by using three-dimensional (3D) transient computational fluid dynamics (CFD) models. A hypothetical layout of recessed lighting fixtures was designed with boundary conditions of four different seasons, which were obtained from recorded roof/attic temperature data sets. The results of the study indicate that leakage of recessed lighting fixtures could be a significant channel of …

Compositionally Graded Bulk Heterojunction Devices And Methods Of Manufacturing The Same, Jinsong Huang, Zhengguo Xiao

Department of Mechanical and Materials Engineering: Faculty Publications

Systems and methods are described to form compositionally graded BHJ structures utilizing solvent-fluxing techniques. In implementations, the systems and methods described herein involve a high boiling point additive, a solution of a polymer donor and an acceptor, a substrate material, a working solvent, and a flux solvent for formation of compositionally graded BHJ structures.

Bioink Properties Before, During And After 3d Bioprinting, Katja Hölzl, Shengmao Lin, Liesbeth Tytgat, Sandra Van Vlierberghe, Linxia Gu, Aleksandr Ovsianikov

Department of Mechanical and Materials Engineering: Faculty Publications

Bioprinting is a process based on additive manufacturing from materials containing living cells. These materials, often referred to as bioink, are based on cytocompatible hydrogel precursor formulations, which gel in a manner compatible with different bioprinting approaches. The bioink properties before, during and after gelation are essential for its printability, comprising such features as achievable structural resolution, shape fidelity and cell survival. However, it is the final properties of the matured bioprinted tissue construct that are crucial for the end application. During tissue formation these properties are influenced by the amount of cells present in the construct, their proliferation, migration …

Optical Patterning Of Trapped Charge In Nitrogen-Doped Diamond, Harishankar Jayakumar, Jacob Henshaw, Siddharth Dhomkar, Daniela Pagliero, Abdelghani Laraoui, Neil B. Manson, Remus Albu, Marcus W. Doherty, Carlos A. Meriles

Department of Mechanical and Materials Engineering: Faculty Publications

The nitrogen-vacancy (NV) centre in diamond is emerging as a promising platform for solid-state quantum information processing and nanoscale metrology. Of interest in these applications is the manipulation of the NV charge, which can be attained by optical excitation. Here, we use two-colour optical microscopy to investigate the dynamics of NV photo-ionization, charge diffusion and trapping in type-1b diamond. We combine fixed-point laser excitation and scanning fluorescence imaging to locally alter the concentration of negatively charged NVs, and to subsequently probe the corresponding redistribution of charge. We uncover the formation of spatial patterns of trapped charge, which we qualitatively reproduce …

Modeling Of A Roll-To-Roll Plasma Cvd System For Graphene, Yudong Chen, Majed A. Alrefae, Anurag Kumar, Timothy S. Fisher

The Summer Undergraduate Research Fellowship (SURF) Symposium

Graphene is a 2D carbon material that has extraordinary physical properties relevant to many industrial applications such as electronics, oxidation barrier and biosensors. Roll-to-roll plasma chemical vapor deposition (CVD) has been developed to manufacture graphene at large scale. In a plasma CVD chamber, graphene is grown on a copper foil as it passes through a high-temperature plasma region. The temperatures of the gas and the copper foil play important roles in the growth of graphene. Consequently, there is a need to understand the temperature and gas velocity distributions in the system. The heat generated in the plasma creates a thermal …

Laser Direct Written Silicon Nanowires For Electronic And Sensing Applications, Woongsik Nam

Open Access Dissertations

Silicon nanowires are promising building blocks for high-performance electronics and chemical/biological sensing devices due to their ultra-small body and high surface-to-volume ratios. However, the lack of the ability to assemble and position nanowires in a highly controlled manner still remains an obstacle to fully exploiting the substantial potential of nanowires. Here we demonstrate a one-step method to synthesize intrinsic and doped silicon nanowires for device applications. Sub-diffraction limited nanowires as thin as 60 nm are synthesized using laser direct writing in combination with chemical vapor deposition, which has the advantages of in-situ doping, catalyst-free growth, and precise control of position, …

Contribution Of Fiber Undulation To Mechanics Of Three-Dimensional Collagen-I Gel, Shengmao Lin, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The collagen-I gel is extensively used as a scaffold material in tissue engineering due to its ability to mimic the extracellular matrix (ECM). In this study, the mechanics of collagen-I gel is investigated using a numerical model of three-dimensional collagen network. The resulted mechanical behavior was validated against the published experimental data. Results illustrated that fiber alignment was dominated in the low strain region, and its transition to stretching dominated phenomena at higher strain led to the strain stiffening of collagen gel. The collagen undulation at the microscopic level was found to delay the initiation of strain stiffening