Other Mechanical Engineering Commons^™

Electrochemical Capture Of Co2 From Natural Gas Using A High-Temperature Ceramic-Carbonate Membrane, Jingjing Tong, Lingling Zhan, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

This study reports the first investigation of using a ceramic-carbonate dual-phase membrane to electrochemically separate CO₂ from a simulated natural gas. The CO₂ permeation flux density was systematically studied as a function of temperature, CO₂ partial pressure and time. As expected, the flux density was observed to increase with temperature and CO₂ partial pressure. Long-term stability test showed that flux density experienced an initial performance-improving “break-in” period followed by a slow decay. Post-test microstructural analysis suggested that a gradual loss of carbonate during the test could be the cause of the flux-time behavior observed.

Nanoindentation Of A Zinc Metal Soap Mixture For Use In A Laser Printer, George A. Nimick

Theses and Dissertations--Chemical and Materials Engineering

At the start of this project, the possible choices of metal soaps had already been narrowed to include some of the zinc soaps used in this project. These zinc soaps are mixtures of zinc stearate and zinc palmitate of varying ratios purchased from a supplier. Zinc soap was chosen as result of its common use in various industries as a lubricant and mold release, which implied potential benefits in an electrophotographic printing system. These potential benefits include, but are not limited to, a more efficient transfer from a photoconductive drum and protection of the drum from mechanical and chemical degradation. …

Influence Of Spatial Variations Of Railroad Track Stiffness And Material Inclusions On Fatigue Life, Celestin Nkundineza

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Railroad transportation is very important for economic growth and effective maintenance is one critical factor for its economic sustainability. The high repetitive forces from a moving railcar induce cyclic stresses that lead to rail bending and potential deterioration due to fatigue crack initiation and propagation. Previous research for prediction of fatigue life has been done under the assumptions of a uniform track bed and a homogeneous rail. However the spatial variation of the track stiffness is expected to increase the maximum stresses in the rail and, therefore, accelerate the fatigue process. The research described in this dissertation is focused on …

A Study To Evaluate Non-Uniform Phase Maps In Shape Memory Alloys Using Finite Element Method, Naren Motte

Theses and Dissertations

The unique thermo-mechanical behavior of Shape Memory Alloys (SMAs), such as their ability to recover the original shape upon heating or being able to tolerate large deformations without undergoing plastic transformations, makes them a good choice for actuators.

This work studies their application in the aerospace and defense industries where SMA components can serve as release mechanisms for gates of enclosures that have to be deployed remotely. This work provides a novel approach in evaluating the stress and heat induced change of phase in a SMA, in terms of the transformation strain tensor. In particular, the FEA tool

ANSYS has …

A Sinteractive Ni-Bazr0.8Y0.2O3-Δ Composite Membrane For Hydrogen Separation, Shumin Fang, Siwei Wang, Kyle S. Brinkman, Fanglin Chen

Faculty Publications

BaZr_0.8Y_0.2O_3−δ (BZY) is an excellent candidate material for hydrogen permeation membranes due to its high bulk proton conductivity, mechanical robustness, and chemical stability in H₂O- and CO₂-containing environments. Unfortunately, the use of BZY as a separation membrane has been greatly restrained by its highly refractory nature, poor grain boundary proton conductivity, high number of grain boundaries resulting from limited grain growth during sintering, as well as low electronic conductivity. These problems can be resolved by the fabrication of a Ni–BZY composite membrane with large BZY grains, which requires the development …

Shape Memory Behavior Of Single And Polycrystalline Nickel Rich Nickel Titanium Alloys, Irfan Kaya

Theses and Dissertations--Mechanical and Aerospace Engineering

NiTi is the most commonly used shape memory alloy (SMA) and has been widely used for bio-medical, electrical and mechanical applications. Nickel rich NiTi shape memory alloys are coming into prominence due to their distinct superelasticity and shape memory properties as compared to near equi-atomic NiTi shape memory alloys. Besides, their lower density and higher work output than steels makes these alloys an excellent candidate for aerospace and automotive industry. Shape memory properties and phase transformation behavior of high Ni-rich Ni₅₄Ti₄₆ (at.%) polycrystals and Ni-rich Ni₅₁Ti₄₉ (at.%) single-crystals are determined. Their properties are sensitive …

Electrospinning Applications Air Filtration And Superhydrophobic Materials, Negar Ghochaghi, Adetoun Taiwo

Graduate Research Posters

Electrospinning is a widely applicable technique that generates non-woven fibers in the micro and nano range. In this project two of its applications are highlighted namely filtration media and enhancement of wettability. The first project demonstrates that electrospinning can be used to produce new fiber filtration media with controlled microstructure. The bimodal and unimodal orthogonal and random filters were made and characterized against their filtration efficiency and pressure drop. Figure of Merit (FOM) was also calculated and discussed. It is shown that the FOM increases when the electrospun fibers are arranged into alternating layers of aligned course and fine fibers. …

The Effect Of Surface Corrosion Damage On The Fatigue Life Of Extruded Aluminum Alloy 6061-T6, Matthew Weber

UNF Graduate Theses and Dissertations

Aluminum alloy 6061-T6 is a common engineering material used in aerospace, automotive, structural applications. Despite its wide use, little has been published about the effects of damage from surface corrosion on its fatigue life. An investigation was performed where 6061-T6 extrusions were exposed to a 3.5% NaCl solution at pH 2 for 2 days and 24 days. The length of time and pH were chosen in order to create distinct surface flaws. The effect of these flaws on the fatigue life was then investigated and analyzed using scanning electron microscopy (SEM) and Weibull statistics. It was determined that samples corroded …

Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates, Josh E. Smith

Master's Theses

Mode I interlaminar fracture of 3k 8-Harness-Satin Carbon cloth, with identical fill and weft yarns, pre-impregnated with Newport 307 resin was investigated through the DCB test (ASTM D5528). Crack propagations along both the fill and weft yarns were considered for both post-bonded (co-bonded) and co-cured laminates. A patent-pending delamination insertion method was compared to the standard Teflon film option to assess its applicability to mode I fracture testing. The Modified Beam Theory, Compliance Calibration method, and Modified Compliance Calibration method were used for comparative purposes for these investigations and to evaluate the validity of the proposed Equivalent Stiffness (EQS) method. …

Investigation Of Thermal Cycle And Hardness Distribution In The Laser Cladding Of Aisi H13 Tool Steel Produced By A High Power Direct Diode Laser, Parisa Farahmand, Prabu Balu, Fanrong Kong, Radovan Kovacevic

Mechanical Engineering Research

Laser cladding (LC) of tool steel has significant application in rapid tooling, and surface coating for worn-out components in different industries. During the LC process, several phase transformations influence the microstructural and mechanical properties of the deposited layer. In order to successfully implement the LC process, it is essential to understand the relationship between the thermal cycle (heating and cooling), phase transformations, and the output quantities of the deposited layer. In this study a direct diode laser with a power of up to 8 kW was used to deposit AISI H13 tool steel on mild steel grade A36 substrate to …

Enhanced Reducibility And Conductivity Of Na/K-Doped Srti0.8Nb0.2O3, Guoliang Xiao, Sirikanda Nuansaeng, Lei Zhang, Suwit Suthirakun, Andreas Heyden, Hans-Conrad Zur Loye, Fanglin Chen

Faculty Publications

Donor and acceptor co-doped SrTiO₃ materials have shown interesting features in their conductivity and reducibility. In this work, 10 mol% Na⁺ or K⁺ as acceptor dopants have been introduced into the A-site of donor-doped strontium titanate, SrTi_0.8Nb_0.2O₃, and the doping impact on their properties has been studied. By doping with Na or K, the sinterability of SrTi_0.8Nb_0.2O₃ in reducing atmospheres has been improved. Na_0.1Sr_0.9Ti_0.8Nb_0.2O₃ and K_0.1Sr_0.9Ti_0.8Nb_0.2O₃ show metallic …

Vulnerability Of Progressive Collapse In Reinforced Concrete Flat-Plate Buildings, Jinrong Liu

College of Engineering: Graduate Celebration Programs

• Progressive collapse is the spread of initial local failure, causing partial or
  even total collapse of a building.
• Flat plate structure is widely used for office and residential buildings.
• There is a large inventory of older flat plate building without continuous slab bottom reinforcement through columns.
• Limited knowledge exists regarding the risk of disproportionate collapse in
  older flat-plates under sudden column removal during abnormal events.
• Reliable mechanical model is needed for structural evaluation.

Numerical Modeling And Characterization Of Vertically Aligned Carbon Nanotube Arrays, Johnson Joseph

Theses and Dissertations--Mechanical and Aerospace Engineering

Since their discoveries, carbon nanotubes have been widely studied, but mostly in the forms of 1D individual carbon nanotube (CNT). From practical application point of view, it is highly desirable to produce carbon nanotubes in large scales. This has resulted in a new class of carbon nanotube material, called the vertically aligned carbon nanotube arrays (VA-CNTs). To date, our ability to design and model this complex material is still limited. The classical molecular mechanics methods used to model individual CNTs are not applicable to the modeling of VA-CNT structures due to the significant computational efforts required. This research is to …

Analytical And Numerical Modeling Of Assembly Procedures Of Steel Fulcra Of Bascule Bridges, Sriharsha Garapati

USF Tampa Graduate Theses and Dissertations

To model shrink-fitting in metal components, an analytical model for two long compound cylinders with temperature dependent material properties and interference between them is developed for calculating transient temperatures and stresses. A finite element model is developed for the same geometry which incorporated the temperature dependent material properties. A convergence study is performed on the finite element and analytical model. The finite element model is validated by comparing the approximations of finite element model with the analytical solution.

In an assembly procedure of fulcrums for bascule bridges, called AP1, the trunnion is shrink-fitted into a hub, followed by shrink fitting …

High Performance Low Temperature Solid Oxide Fuel Cells With Novel Electrode Architecture, Yu Chen, Qian Liu, Zhibin Yang, Fanglin Chen, Minfang Han

Faculty Publications

In this study, we have fabricated high performance low temperature solid oxide fuel cells (LT-SOFCs) with both acicular anodes and cathodes with thin Gd-doped ceria (GDC) electrolyte film. The acicular Ni-Gd_0.1Ce_0.9O_2−δ (Ni-GDC) anode was prepared using freeze drying tape casting, while the hierarchically porous cathode with nano-size Sm_0.5Sr_0.5CoO₃ (SSC) particles covering an acicular GDC skeleton was prepared by a combination of freeze drying tape casting and self-rising approaches. The acicular electrodes with 5–200 μm pores/channels enhance mass transport, while SSC particles of about 50 nm in the cathode promote …

Strain Energy And Lateral Friction Force Distributions Of Carbon Nanotubes Manipulated Into Shapes By Atomic Force Microscopy, Mark C. Strus, Roya R. Lahiji, Pablo Ares, Vincente Lopez, Arvind Raman, Ron R. Reifenberger

Other Nanotechnology Publications

The interplay between local mechanical strain energy and lateral frictional forces determines the shape of carbon nanotubes on substrates. In turn, because of its nanometer-size diameter, the shape of a carbon nanotube strongly influences its local electronic, chemical, and mechanical properties. Few, if any, methods exist for resolving the strain energy and static frictional forces along the length of a deformed nanotube supported on a substrate. We present a method using nonlinear elastic rod theory in which we compute the flexural strain energy and static frictional forces along the length of single walled carbon nanotubes (SWCNTs) manipulated into various shapes …

Iii Finishing, Lapping, Honing And Polishing: Processes, Characterisation And Novel Techniques-Experimental Research On Ultra-Smooth Surface Polishing Based On Two-Dimensional Vibration Of Liquid, Zhong Ning Guo, X. Z. Huang, Z. G. Huang, Z. Q. Yu, T. M. Yue, Wing Bun Lee

Faculty Publications

No abstract provided.

Kinetics Of Laser Chemical Vapor Deposition Of Carbon And Refractory Metals, Feng Gao

Doctoral Dissertations

Three-dimensional laser chemical vapor deposition (3D-LCVD) has been used to grow rods of carbon, tungsten, titanium, and hafnium from a variety of hydrocarbons and metal halide-based precursors. A novel computerized 3D-LCVD system was designed and successfully used in the experiments. A focused Nd:Yag laser beam (λ = 1.06 μm) was utilized to locally heat up a substrate to deposition temperature. The rods, which grew along the axis of the laser beam, had a typical diameter of 30–80 μm and a length of about 1 mm. The precursors for carbon deposition were the alkynes: propyne, butyne, pentyne, hexyne, and octyne. Propyne …