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Specialized Inter-Particle Interaction Lbm For Patterned Superhydrophobic Surfaces, Amal Saeed Yagub

Wayne State University Dissertations

SPECIALIZED INTER-PARTICLE INTERACTION LBM FOR PATTERNED SUPERHYDROPHOBIC SURFACES

by

AMAL S. YAGUB

ABSTRACT:

Superhydrophobic surface characteristics are important in many industrial applications, ranging from the textile to the military. It was observed that surfaces fabricated with nano/micro roughness can manipulate the droplet contact angle, thus providing an opportunity to control the droplet wetting characteristics. The Shan and Chen (SC) lattice Boltzmann model (LBM) is a good numerical tool, which holds strong potentials to qualify for simulating droplets wettability. This is due to its realistic nature of droplet contact angle (CA) prediction on flat smooth surfaces. But SC-LBM was not able …

Structure-Thermal Coupling In Viscoelastic Material In Rubber Bushing Of Vehicle System, Zhengui Zhang

Open Access Dissertations

The objective of this research is to utilize the frequency-dependent viscoelastic material model and characterize the dynamic response of rubber bushing under external excitation. Furthermore, with appropriate modeling, two heat generation mechanisms of rubber bushing are explored and their thermal fields are investigated. Due to the nonlinear force-deflection relationship of the viscoelastic material, finding satisfactory mechanical properties of rubber components still poses a great challenge. However, industry nowadays is in urgent demand for precise finite element analysis (FEA) modeling of rubber components. For example, a proper constitutive relationship of rubber components is critical to providing a reliable and trustable simulation …

Surface Analytical Investigation On Organometal Triiodide Perovskite, Chengong Wang, Xiaoliang Liu, Congcong Wang, Zhengguo Xiao, Cheng Bi, Yuchuan Shao, Jinsong Huang, Yongli Gao

Department of Mechanical and Materials Engineering: Faculty Publications

In a little over a year, there has been an unexpected breakthrough and rapid evolution of highly efficient solid-state hybrid solar cells based on organometal trihalide perovskite materials. This technology has the potential to produce solar cells with the very highest efficiencies while retaining the very lowest cost. The authors have measured the electronic density of states of CH₃NH₃PbI₃ using ultraviolet photoemission spectroscopy (UPS), inverse photoemission spectroscopy (IPES), and x-ray photoemission spectroscopy (XPS). The valence band maximum and conduction band minimum positions are obtained from the UPS and IPES spectra, respectively, by linear extrapolation of …

Erratum: “The Operation Mechanism Of Poly (9,9-Dioctylfluorenyl-2,7-Diyl) Dots In High Efficiency Polymer Solar Cells” [Appl. Phys. Lett. 106, 193904 (2015)], Chunyu Liu, Yeyuan He, Xinyuan Zhang, Zhiqi Li, Jinfeng Li, Liang Shen, Zhihui Zhang, Wenbin Guo, Shengping Ruan

Department of Mechanical and Materials Engineering: Faculty Publications

We have noticed an error in Fig. 7 of the original article. Figs. 7(a) and 7(b) should be exchanged and the revised figure is shown below. We apologize for this error.¹

Electronic Structure Evolution Of Fullerene On Ch3Nh3Pbi3, Chenggong Wang, Congcong Wang, Xiaoliang Liu, John Kauppi, Yuchuan Shao, Zhengguo Xiao, Cheng Bi, Jinsong Huang, Yongli Gao

Department of Mechanical and Materials Engineering: Faculty Publications

The thickness dependence of fullerene on CH₃NH₃PbI₃ perovskite film surface has been investigated by using ultraviolet photoemission spectroscopy (UPS), X-ray photoemission spectroscopy (XPS), and inverse photoemission spectroscopy (IPES). The lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) can be observed directly with IPES and UPS. It is observed that the HOMO level in fullerene shifts to lower binding energy. The XPS results show a strong initial shift of core levels to lower binding energy in the perovskite, which indicates that electrons transfer from the perovskite film to fullerene molecules. Further deposition of fullerene …

Improving The Sensitivity Of A Near-Infrared Nanocomposite Photodetector By Enhancing Trap Induced Hole Injection, Liang Shen, Yanjun Fang, Qingfeng Dong, Zhengguo Xiao, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

We report the enhancement of the photoconductive gain of nanocomposite near-infrared photodetectors by a zinc oxide nanoparticles (ZnO NPs) rich surface at the nanocomposite/cathode interface. An argon plasma etching process was used to remove polymer at the surface of nanocomposite films, which resulted in a ZnO NPs rich surface. The other way is to spin-coat a thin layer of ZnO NPs onto the nanocomposite layer. The ZnO NPs rich surface, which acts as electron traps to induce secondary hole injection under reverse bias, increased hole injection, and thus the external quantum efficiency by 2–3 times. The darkcurrent declined one order …

Color And Texture Morphing With Colloids On Multilayered Surfaces, Ziguang Chen, Shumin Li, Andrew Arkebauer, George Gogos, Li Tan

Department of Mechanical and Materials Engineering: Faculty Publications

Dynamic morphing of marine species to match with environment changes in color and texture is an advanced means for surviving, self-defense, and reproduction. Here we use colloids that are placed inside a multilayered structure to demonstrate color and texture morphing. The multilayer is composed of a thermal insulating base layer, a light absorbing mid layer, and a liquid top layer. When external light of moderate intensity (∼0.2 W cm−2) strikes the structure, colloids inside the liquid layer will be assembled to locations with an optimal absorption. When this system is exposed to continuous laser pulses, more than 18 000 times …

Quantification Of Plaque Stiffness By Brillouin Microscopy In Experimental Thin Cap Fibroatheroma, Giuseppe Antonacci, Ryan M. Pedrigi, Avinash Kondiboyina, Vikram V. Mehta, Ranil De Silva, Carl Paterson, Rob Krams, Peter Torok

Department of Mechanical and Materials Engineering: Faculty Publications

Plaques vulnerable to rupture are characterized by a thin and stiff fibrous cap overlaying a soft lipid-rich necrotic core. The ability to measure local plaque stiffness directly to quantify plaque stress and predict rupture potential would be very attractive, but no current technology does so. This study seeks to validate the use of Brillouin microscopy to measure the Brillouin frequency shift, which is related to stiffness, within vulnerable plaques. The left carotid artery of an ApoE^-/- mouse was instrumented with a cuff that induced vulnerable plaque development in nine weeks. Adjacent histological sections from the instrumented and control arteries …

Mammalian Synthetic Biology: Emerging Medical Applications, Zoltan Kis, Hugo Sant'ann Pereira, Takayuki Homma, Ryan M. Pedrigi, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

In this review, we discuss new emerging medical applications of the rapidly evolving field of mammalian synthetic biology.We start with simple mammalian synthetic biological components and move towards more complex and therapy-oriented gene circuits. A comprehensive list of ON–OFF switches, categorized into transcriptional, post-transcriptional, translational and posttranslational, is presented in the first sections. Subsequently, Boolean logic gates, synthetic mammalian oscillators and toggle switches will be described. Several synthetic gene networks are further reviewed in the medical applications section, including cancer therapy gene circuits, immuno-regulatory networks, among others. The final sections focus on the applicability of synthetic gene networks to drug …

Ink-Jet Printing: A Method For Affordable Additive Manufacturing Of Dye-Sensitized Solar Cells, Ryan Longchamps

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Intelligent Supervisory Switching Control Of An Unmanned Surface Vehicle, Ivan Rodrigues Bertaska

Link Foundation Ocean Engineering and Instrumentation Fellowship Reports

The project originally proposed for this fellowship focused on developing a framework for multimodal control of an unmanned surface vehicle (USV) – transitioning it from an underactuated system to an overactuated one. This would assist in two main functions USVs are typically tasked with: transiting and station-keeping. This project has since expanded to encompass novel territory in control theory, robotics, and computer science. The author is hopeful that the work reported here will assist in the transition of USVs from an academic pursuit into a valuable, pervasive tool for the oceanic sciences and the ocean industry. For the continued expansion …

A Novel In Situ Microscope For Studying Benthic Organisms, Andrew Mullen

Link Foundation Ocean Engineering and Instrumentation Fellowship Reports

Coastal marine ecosystems such as coral reefs, kelp forests, sea grass beds and mangroves have significant societal value. As economic resources they support tourism, fisheries and storm protection while ecologically they host high biological diversity and productivity. Many basic biological, chemical, and physical processes taking place in these marine ecosystems occur at ‘micro-­‐scales’ less than a millimeter in size. Examples of significant micro-­‐scale activities include: coral bleaching of their single-­‐ celled symbiotic algae, larval settlement and attachment, competition between sessile organisms along thin interfaces, and fluxes of particles to and from the seafloor. It is also important to consider that …

An Improved Sin-Hyperbolic Constitutive Model For Creep Deformation And Damage, Mohammad Shafinul Haque

Open Access Theses & Dissertations

Inspection and maintenance of industrial gas turbines (IGTs) cost millions of dollars. Growing demand of obtaining higher IGT efficiency leads to higher temperature and pressure operating conditions. Long exposure of turbine components at elevated temperature and pressure

makes creep damage critically important to consider during planning, designing and operating conditions. Effective and economic maintenance requires accurate creep deformation, damage

evolution and rupture life prediction information. Creep prediction models are used to determine the state of the turbine components and to schedule the inspection, maintenance and replacement time periods. The more accurate the prediction model, the less is the overall cost …

Design Of A High Intensity Turbulent Combustion System, Mohammad Arif Hossain

Open Access Theses & Dissertations

In order to design next generation gas turbine combustor and rocket engines, a systematic study of flame structure at high intensity turbulent flow is necessary. The fundamental study of turbulent premixed combustion has been a major research concern for decades. The work is focused on the design and development of a high intensity turbulent combustion system which can be operated at compressible (0.3 < M < 0.5), preheated (T0=500K) and premixed conditions in order to investigate the 'Thickened Flame' regime. An air-methane mixture has been used as the fuel for this study. An optically accessible backward-facing step stabilized combustor has been designed for a maximum operating pressure of 6 bar. A grid has been introduced with different blockage ratios (BR = 54%, 61% & 67%) in order to generate turbulence inside the combustor for the experiment. Optical access is provided via quartz windows on three sides of the combustion chamber. Finite Element Analysis (FEA) is done in order to verify the structural integrity of the combustor at rated conditions. In order to increase the inlet temperature of the air, a heating section was designed to use commercially available in-line heaters. Separate cooling subsystems have been designed for chamber cooling and exhaust cooling. The LabVIEW software interface has been selected as the control mechanism for the experimental setup. A 10 kHz Time Resolved Particle Image Velocimetry (TR-PIV) system and a 3 kHz Planer Laser Induced Fluorescence (PLIF) system have been integrated with the system in order to diagnose the flow field and the flame respectively. The primary understanding of the flow field inside the combustor was achieved through the use of Detached Eddy Simulation (DES) by using commercially available software package ANSYS FLUENT. Preliminary validation is done by 10 kHz TR-PIV technique. Both qualitative and quantitative analysis have been done for CFD and experiment. Major flow parameters such as average velocity, fluctuation of velocity, kinetic energy, and turbulent intensity have been calculated for two distinct Reynolds number (Re = 815 & 3500). PIV results are compared with CFD results which show significant agreement with each other.

Thermal Shock Studies On Carbon-Carbon Composites: Experimentation And Analysis, Alma Lucia Leanos

Open Access Theses & Dissertations

The oxidation behavior of C/C composites under thermal shock conditions in air is understood and predicted experimentally and by computational efforts. In Chapter. 1, both compressive properties and oxidation behavior of pristine and thermal shock exposed 2D C/C composite specimens were examined. Pristine test specimens were exposed to thermal shock conditions with temperatures ranging from 400°C to 1000°C in an oxidizing environment, followed by compression tests on pristine and thermal shock exposed specimens to obtain their compressive responses.

Similarly, in Chapter. 2, the influence of thermal shock conditions on both, the extent of carbon materials decomposition and the through-thickness compressive …

Fluid Flow Characterization Of High Turbulent Intensity Compressible Flow Using Particle Image Velocimetry, Marco Efrain Quiroz

Open Access Theses & Dissertations

A high turbulent intensity combustion chamber has been designed in order to operate with compressible (0.3 < M < 0.5) and preheated (T=500K) air-methane combustion. These conditions will allow the investigation of different flame regimes; most notably the proposed "Thickened Flame" regime. Initial design and flow validation has been completed in order to begin further experimentation. A 10 kHz Time Resolved Particle Image Velocimetry (TR-PIV) system and a 3 kHz Planer Laser Induced Fluorescence (PLIF) system have been integrated with the system in order to diagnose the flow field and the flame respectively. The exhaust and chamber cooling subsystems were designed to comply with safety regulations, and the control systems were set up in a way that allows automated (LabVIEW) and user controlled sequencing. This work's main purpose is to characterize and map the flow properties at maximum flow conditions (M > 0.3) in order to map the following; flow structures, kinetic energy at different length scales, velocity fluctuations and turbulent intensity. PIV measurements are carried out for three different volumetric flow rates (ð???Ì? = 25 scfm, 55 scfm, and 115 scfm) and three different grid geometries for each (BR= 67%, 61%, and 54%). Upon finding that the main flow structure consisted of jets caused by the grid at higher flowrates, experiments were done with a grid BR = 67% which was thinner (50% of original …

A Distributed Surrogate Methodology For Inverse Most Probable Point Searches In Reliability Based Design Optimization, James Davidson

Browse all Theses and Dissertations

Surrogate models are commonly used in place of prohibitively expensive computational models to drive iterative procedures necessary for engineering design and analysis such as global optimization. Additionally, surrogate modeling has been applied to reliability based design optimization which constrains designs to those which provide a satisfactory reliability against failure considering system parameter uncertainties. Through surrogate modeling the analysis time is significantly reduced when the total number of evaluated samples upon which the final model is built is less than the number which would have otherwise been required using the expensive model directly with the analysis algorithm. Too few samples will …

Ultrafine Particle Generation And Measurement, Qiaoling Liu

Theses and Dissertations

Ultrafine particles (UFPs) with diameters smaller than 100 nm are omnipresent in ambient air. They are important sources for fine particles produced through the agglomeration and/or vapor condensation. With their unique properties, UFPs have also been manufactured for industrial applications. But, from the toxicological and health perspective, ultrafine particles with high surface-to-volume ratios often have high bio-availability and toxicity. Many recent epidemiologic studies have evidence UFPs are highly relevant to human health and disease. In order to better investigate UFPs, better instrumentation and measurement techniques for UFPs are thus in need. The overall objective of this dissertation is to advance …

High Temperature Transient Creep Analysis Of Metals, Sara Mirmasoudi

Browse all Theses and Dissertations

The ability to design vehicles capable of reaching hypersonic speeds has become a necessity to satisfy industry requirements, hence requiring the need for better understanding of creep behavior of materials. Although the steady state creep of metals has been analyzed rigorously, there is little known about transient creep of many metals. Understanding transient creep behavior of metals is crucial in analysis and design of short term hypersonic flight applications. Hence, a transient creep analysis of 304SS, Al7075-T6, Al2024-T6, Inconel 625, Inconel 718, and Rene N4 is carried out focusing on the microstructural behavior of these metals undergoing high temperature operating …

Surface Treatments To Tailor The Wettability Of Carbon Nanotube Arrays, Lvmeng He

Browse all Theses and Dissertations

Carbon nanotubes (CNTs) have gained great attention due to their excellent mechanical, electrical, and thermal properties. Carbon nanotube (CNT) arrays attached to solid substrates resemble a nano-carpet and have potentials in a variety of devices. In this study, the focus is to investigate the surface modification approaches of CNT carpets on flat (compressed) graphite. Wettability, or permeation of a liquid such as water into the CNT strands, may play very significant roles in many applications where a CNT-coated device may be used in aqueous environment. Short-term microwave plasma treatments were used in this project to functionalize CNT carpets for wettability. …

Efficiency Enhancement In Polymer Solar Cells With A Polar Small Molecule Both At Interface And In The Bulk Heterojunction Layer, Zhengguo Xiao, Qingfeng Dong, Qi Wang, Wenjing Tian, Hui Huang, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

The polar molecules, including ferroelectric materials with large dipole moments, have been applied as interfacial layers to increase the efficiency of organic solar cells by increasing the bounded charge separation, tuning the energy levels, etc. Here, we report a small polar molecule 2-cyano-3- (4-(diphenylamino) phenyl)acrylic acid (TPACA) that can be either blended in the active layer or at the polymer/electrode interface to increase the efficiency of organic solar cell devices after poling. It is found that the built-in potential of the device is increased by 0.2 V after poling under negative bias. Blending TPACA into the active layer has shown …

Electron-Hole Diffusion Lengths >175 Μm In Solution-Grown Ch3Nh3Pbi3 Single Crystals, Qingfeng Dong, Yanjun Fang, Yuchuan Shao, Padhraic Mulligan, Jie Qiu, Lei Cao, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Long, balanced electron and hole diffusion lengths greater than 100 nanometers in polycrystalline CH₃NH₃PbI₃ are critical for highly efficient perovskite solar cells. We report that the diffusion lengths in CH₃NH₃PbI₃ single crystals grown by a solution-growth method can exceed 175 μm under 1 sun illumination and exceed 3 mm under weak light for both electrons and holes. The internal quantum efficiencies approach 100% in 3 mm-thick single crystal perovskite solar cells under weak light. These long diffusion lengths result from greater carrier mobility, lifetime and dramatically smaller trap densities in …

Towards Tuning The Mechanical Properties Of Three-Dimensional Collagen Scaffolds Using A Coupled Fiber-Matrix Model, Shengmao Lin, Lauren A. Hapach, Cynthia Reinhart-King, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Scaffold mechanical properties are essential in regulating the microenvironment of three-dimensional cell culture. A coupled fiber-matrix numerical model was developed in this work for predicting the mechanical response of collagen scaffolds subjected to various levels of non-enzymatic glycation and collagen concentrations. The scaffold was simulated by a Voronoi network embedded in a matrix. The computational model was validated using published experimental data. Results indicate that both non-enzymatic glycation-induced matrix stiffening and fiber network density, as regulated by collagen concentration, influence scaffold behavior. The heterogeneous stress patterns of the scaffold were induced by the interfacial mechanics between the collagen fiber network …

Development And Preliminary Evaluation Of A Spray Deposition Sensing System For Improving Pesticide Application, Melissa A. Kesterson, Joe D. Luck, Michael P. Sama

Department of Mechanical and Materials Engineering: Faculty Publications

An electronic, resistance-based sensor array and data acquisition system was developed to measure spray deposition from hydraulic nozzles. The sensor surface consisted of several parallel tin plated copper traces of varying widths with varying gap widths. The system contained an embedded microprocessor to monitor output voltage corresponding to spray deposition every second. In addition, a wireless module was used to transmit the voltage values to a remote laptop. Tests were conducted in two stages to evaluate the performance of the sensor array in an attempt to quantify the spray deposition. Initial tests utilized manual droplet placement on the sensor surface …

Multiscale Modeling Of Skeletal Muscle Active Contraction In Relation To Mechanochemical Coupling Of Molecular Motors, Jiangcheng Chen, Xiaodong Zhang, Shengmao Lin, He Wang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, a mathematical model was developed to relate the mechanochemical characterizations of molecular motors with the macroscopic manifestation of muscle contraction. Non-equilibrium statistical mechanics were used to study the collective behavior of myosin molecular motors in terms of the complex conformation change and multiple chemical states in one working cycle. The stochastic evolution of molecular motor probability density distribution during the contraction of sarcomere was characterized by the Fokker-Planck Equation. Quick muscle contraction was demonstrated by the collective dynamic behavior of myosin motors, the muscle contraction force, and the muscle contraction velocity-force relation. Our results are validated against …

Inducing Persistent Flow Disturbances Accelerates Atherogenesis And Promotes Thin Cap Fibroatheroma Development In D374y-Pcsk9 Hypercholesterolemic Minipigs, Ryan M. Pedrigi, Christian Bo Poulsen, Vikram V. Mehta, Niels Ramsing Holm, Nilesh Pareek, Anouk L. Post, Ismail Dogu Kilic, Winston A.S. Banya, Gianni Dall'ara, Alessio Mattesini, Martin M. Bjorklund, Niels P. Andersen, Anna K. Grondal, Enrico Petretto, Nicolas Foin, Justin E. Davies, Carlo Di Mario, Jacob Fog Bentzon, Hans Erik Botker, Erling Falk, Rob Krams, Ranil De Silva

Department of Mechanical and Materials Engineering: Faculty Publications

Background—Although disturbed flow is thought to play a central role in the development of advanced coronary atherosclerotic plaques, no causal relationship has been established. We evaluated whether inducing disturbed flow would cause the development of advanced coronary plaques, including thin cap fibroatheroma (TCFA).

Methods and Results—D374Y-PCSK9 hypercholesterolemic minipigs (N=5) were instrumented with an intracoronary shear-modifying stent (SMS). Frequency-domain optical coherence tomography was obtained at baseline, immediately post-stent, 19, and 34 weeks and used to compute shear stress metrics of disturbed flow. At 34 weeks, plaque type was assessed within serially-collected histological sections and co-registered to …

Self‑Propelled Droplets On Heated Surfaces With Angled Self‑Assembled Micro/Nanostructures, Cory Kruse, Isra Somanas, Troy Anderson, Chris Wilson, Craig Zuhlke, Dennis Alexander, George Gogos, Sidy Ndao

Department of Mechanical and Materials Engineering: Faculty Publications

Directional and ratchet-like functionalized surfaces can induce liquid transport without the use of an external force. In this paper, we investigate the motion of liquid droplets near the Leidenfrost temperature on functionalized self-assembled asymmetric microstructured surfaces. The surfaces, which have angled microstructures, display unidirectional properties. The surfaces are fabricated on stainless steel through the use of a femtosecond laser-assisted process. Through this process, mound-like microstructures are formed through a combination of material ablation, fluid flow, and material redeposition. In order to achieve the asymmetry of the microstructures, the femtosecond laser is directed at an angle with respect to the sample …

Quantification Of Ultraprecision Surface Morphology Using An Algebraic Graph Theoretic Approach, Prahalad Rao, Satish T. S. Bukkapatnam, Zhenyu (James) Kong, Omer F. Beyca, Kenneth Case, Ranga Komanduri

Department of Mechanical and Materials Engineering: Faculty Publications

Assessment of progressive, nano-scale variation of surface morphology during ultraprecision manufacturing processes, such as fine-abrasive polishing of semiconductor wafers, is a challenging proposition owing to limitations with traditional surface quantifiers. We present an algebraic graph theoretic approach that uses graph topological invariants for quantification of ultraprecision surface morphology. The graph theoretic approach captures heterogeneous multi-scaled aspects of surface morphology from optical micrographs, and is therefore valuable for in situ real-time assessment of surface quality. Extensive experimental investigations with specular finished (Sa ~ 5 nm) blanket copper wafers from a chemical mechanical planarization (CMP) process suggest that the proposed method was …

Acoustic Nonlinearity Parameters For Transversely Isotropic Polycrystalline Materials, Christopher M. Kube, Joseph A. Turner

Department of Mechanical and Materials Engineering: Faculty Publications

This article considers polycrystalline materials with macroscopic elastic anisotropy and the effect of the anisotropy on the quadratic nonlinearity parameter used to describe second harmonic generation in solids. The polycrystal is assumed to have transversely isotropic elastic symmetry, which leads to a directional dependence of the nonlinearity parameters. Additionally, the anisotropy leads to second harmonic generation from an input shear wave. Estimates of the longitudinal and shear wave nonlinearity parameters are given as a function of single-crystal elastic constants, macroscopic anisotropy constants, and propagation direction. An inverse model is presented that relates measured nonlinearity parameters to the macroscopic anisotropy constants. …

Interfacial Electronic Structure At The Ch3nh3pbi3/Moox Interface, Peng Liu, Xiaoliang Liu, Lu Lyu, Haipeng Xie, Hong Zhang, Dongmei Niu, Han Huang, Cheng Bi, Zhengguo Xiao, Jinsong Huang, Yongli Gao

Department of Mechanical and Materials Engineering: Faculty Publications

Interfacial electronic properties of the CH₃NH₃PbI₃ (MAPbI₃)/M_oOx interface are investigated using ultraviolet photoemission spectroscopy and X-ray photoemission spectroscopy. It is found that the pristine MAPbI₃ film coated onto the substrate of poly (3,4-ethylenedioxythiophene) poly(styrenesulfonate)/indium tin oxide by two-step method behaves as an n-type semiconductor, with a band gap of ~1.7 eV and a valence band edge of 1.40 eV below the Fermi energy (EF). With the MoOx deposition of 64A ° upon MAPbI3, the energy levels of MAPbI3 shift toward higher binding energy by 0.25 eV due to electron transfer …