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Articles 1 - 8 of 8
Full-Text Articles in Polymer and Organic Materials
Effect Of Oxidation Of Graphene On Agglomeration And The Mechanical Properties Of Thermosetting Resins, Matthew A. Reil
Effect Of Oxidation Of Graphene On Agglomeration And The Mechanical Properties Of Thermosetting Resins, Matthew A. Reil
Electronic Theses and Dissertations
Thermosetting resins are used extensively worldwide in applications ranging from adhesives to structural components. However, these resins generally fail in a brittle fracture mode which is undesirable in most situations. Graphene (G) and its derivatives have been considered as additives to epoxy for material property enhancement and varied results have been reported in the literature. In this work, the effects of the oxidation of G to graphene oxide (GO) on polymer interactions and plate agglomeration were studied by classical molecular dynamics (MD). Results from those simulations concluded that agglomerates were likely present in all G-based nanocomposites. The effect of these …
Polyethersulfone Thin-Film Nanocomposite Membrane Embedded With Amine-Functionalized Graphene Oxide For Desalination Applications, Ahmed Bahaeldin
Polyethersulfone Thin-Film Nanocomposite Membrane Embedded With Amine-Functionalized Graphene Oxide For Desalination Applications, Ahmed Bahaeldin
Theses and Dissertations
Thin-film nanocomposite (TFN) desalination membranes were prepared based on a polyethersulfone (PES) support, where the polyamide (PA) layer was embedded with amine-functionalized graphene oxide (GO). The effect of adding various concentrations of functionalized and un-functionalized GO on the desalination performance, hydrophilicity, and morphology of the membranes was additionally assessed throughout this work. Scanning electron microscopy (SEM) measurements were used to assess the morphology of the membranes in combination with Brunauer-Emmett-Teller (BET) analysis. Contact angle measurements were used to gauge the hydrophilicity of the synthesized membranes. The membrane with the best desalination performance contained 1x10-3 wt/vol% of functionalized GO in …
Constructing A Fine Dispersion And Chemical Interface Based On An Electrostatic Self-Assembly And Aqueous Phase Compound In Go/Sio2/Sbr Composites To Achieve High-Wear Resistance In Eco-Friendly Green Tires, Rui Zhang, Jiaye Li, Stephen Jerrams, Shui Hu, Shipeng Wen, Ligun Zhang
Constructing A Fine Dispersion And Chemical Interface Based On An Electrostatic Self-Assembly And Aqueous Phase Compound In Go/Sio2/Sbr Composites To Achieve High-Wear Resistance In Eco-Friendly Green Tires, Rui Zhang, Jiaye Li, Stephen Jerrams, Shui Hu, Shipeng Wen, Ligun Zhang
Articles
The hazard to the ecosystem caused by rubber microparticles generated from tire abrasion has been a constant concern. Therefore, to protect this ecosystem, the development of a tire tread with high abrasion resistance is especially significant. Herein, γ-aminopropyltriethoxysilane (APTES) was used to modify graphene oxide (GO) and silica (SiO2) to obtain GO and SiO2 with positive charges (NG and NS). Furthermore, NG and NS were electrostatically self-assembled by using maleic anhydride (MAH) hydrolysis, thereby obtaining composite particles (NG-NS) with “bridged structures”. Also, the NG-NS/styrene butadiene rubber (SBR) compounds possessing fine dispersion of NG-NS were prepared by the aqueous compounding method. …
Enhanced Gas Barrier Properties Of Graphene Oxide/Rubber Composites With Strong Interfaces Constructed By Graphene Oxide And Sulfur, Long Zheng, Stephen Jerrams, Zongchao Xu, Liqun Zhang, Li Liu, Shipeng Wen
Enhanced Gas Barrier Properties Of Graphene Oxide/Rubber Composites With Strong Interfaces Constructed By Graphene Oxide And Sulfur, Long Zheng, Stephen Jerrams, Zongchao Xu, Liqun Zhang, Li Liu, Shipeng Wen
Articles
Constructing strong interfacial interactions and complex filler networks is crucial to establishing high gas barrier properties in rubber composites. In this research, sulfur-graphene oxide (S-GO) hybrids were prepared by in situ growth of sulfur on the surfaces of GO sheets. The S-GO hybrids were also introduced into butadiene styrene rubber (SBR) using a green method of latex compounding. Results showed that sulfur could melt and spread on the surface of the GO during the crosslinking process at high temperatures. This process prevented the aggregation of GO and resulted in a fine dispersion of GO and complex filler networks in S-GO/SBR …
Enhanced Fatigue And Durability Of Carbon Black/Natural Rubber Composites Reinforced With Graphene Oxide And Carbon Nanotubes, Hao Guo, Stephen Jerrams, Zongchao Xu, Yanfen Shou, Liang Jiang, Liqun Zhang, Li Liu, Shipeng Wen
Enhanced Fatigue And Durability Of Carbon Black/Natural Rubber Composites Reinforced With Graphene Oxide And Carbon Nanotubes, Hao Guo, Stephen Jerrams, Zongchao Xu, Yanfen Shou, Liang Jiang, Liqun Zhang, Li Liu, Shipeng Wen
Articles
Graphene oxide (GO) sheets and carbon nanotubes (CNTs) are of nanometer size and offer large shape factors which are beneficial in reducing crack propagation rates of composites when used in carbon black (CB) reinforced natural rubber (NR), thereby prolonging the service lives of rubber composites. In this research, CNT-CB/NR and GO-CB/NR composites were prepared by partially replacing CB with one-dimensional CNTs and two-dimensional flaky graphene oxide GO, respectively. The results showed that the complex filler dispersion in NR matrices was improved due to the isolation effect between the different fillers. The strain-induced crystallization (SIC) ability of CB/NR was effectively enhanced …
Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater
Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater
Honors Undergraduate Theses
Traditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure that provides a mechanically stable, light weight material for LIB anodes. Due to its structure, reduced graphene oxide (rGO) is efficiently conductive and resistive to environmental changes. On the other hand, silicon-based …
Silk As A Biomaterial Paste For Biomimetic Composite, Sang Hyun Park
Silk As A Biomaterial Paste For Biomimetic Composite, Sang Hyun Park
McKelvey School of Engineering Graduate Student Theses & Dissertations
Silk is a highly promising biomaterial with unique bio-physicochemical properties, such as excellent mechanical and optical properties, biocompatibility and programmable biodegradability. Among many different types, silk from domesticated silkworm, bombyx mori has received wide attention owing to its availability in virtually unlimited quantities and ease of extraction. In this study, we investigated silkworm silk as a protein glue to realize nacre-like composites. We have employed spin assisted layer-by-layer technique to fabricate ultrathin free-standing biocomposite films. Two different composites have been studied: (i) graphene oxide (GO)/silk and (ii) chitin/silk. From our prior work, it is known that the adsorption of amphiphilic …
Friction And Wear Of Polytetrafluoroethylene/Graphene Oxide Composite Thin Films, Justin Kyle Carter
Friction And Wear Of Polytetrafluoroethylene/Graphene Oxide Composite Thin Films, Justin Kyle Carter
Graduate Theses and Dissertations
Polytetrafluoroethylene (PTFE) is a commonly used solid lubricant due to its low coefficient of friction and chemical inertness. As a polymer, PTFE suffers from high wear and low adhesion to substrates limiting its use as a thin film. Thin PTFE films are ideal candidates for solid lubrication in micro-machines and bearing applications. The main goal of this work is to enhance the durability of thin PTFE films through the addition of few layered graphene oxide (GO) as filler. In order to address adhesion issues, the addition of an adhesive layer of polydopamine (PDA) between stainless steel substrates and thin PTFE …