Polymer and Organic Materials Commons^™

Effect Of Sorbitol Plasticizer On Bioplastics Properties Based On Oil Palm Empty Fruit Bunches (Opefb) And Jackfruit Seed Starch, Nia Sasria, Vita Nur Afifah, Gusti Umindya Nur Tajalla

Makara Journal of Science

In bioplastics, natural materials that are easily decomposed are used to minimize plastic waste. In this research, the compositions used were cellulose from oil palm empty fruit bunches (OPEFB), jackfruit seed starch, and carboxymethyl cellulose (CMC) as a filler with sorbitol as a plasticizer. This study aimed to analyze the effect of a sorbitol plasticizer on bioplastic properties. The study began by extracting jackfruit seed starch and OPEFB cellulose. Subsequently, bioplastics were prepared by varying sorbitol, namely 0 (S – 0), 0.5 mL (S – 0.5), 1 mL (S – 1), and 1.5 ml (S – 1.5), with CMC 20%. …

Degumming Of Hemp Fibers Using Combined Microwave Energy And Deep Eutectic Solvent, Bulbul Ahmed

LSU Master's Theses

Hemp is considered as one of the sustainable agricultural fiber materials. Degumming or surface modification of hemp bast is needed to produce single fibers for ensuing textile and industrial applications. The traditional degumming process necessitates a high amount of alkali, which causes detrimental environmental pollution. This study offers a new method to degum hemp fibers with reduced use of harmful alkali and precious water resources. In this work, hemp bast fibers were degummed by using combined microwave energy and deep eutectic solvent (DES). The properties of hemp fibers manufactured by this method were investigated and compared with the traditional alkali …

Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore

Graduate Theses and Dissertations

Cellulose nanomaterials (CNMs) are derived from plant matter and are comprised of nanoscopic cellulose crystals and fibers. They have a diverse set of applications, from cosmetics to oil recovery. This study focuses on the properties of Oxone® mediated TEMPO-oxidized cellulose nanomaterials (OTO-CNMs) and their use in controlling the transport properties of polymeric substrates. Synthesis and characterization of cellulosic nanoparticles have resulted in the creation of OTO-CNMs with properties that increase hydrophilicity. With added hydrophilicity, OTO-CNMs possess lower fouling propensity, making them ideal membrane additive for transport limited separations such as hemodialysis.

To utilize the material and unique properties thereof, this …

Development Of An Injectable Methylcellulose Hydrogel System For Nucleus Pulposus Repair And Regeneration, Nada A. Haq-Siddiqi

Dissertations and Theses

Low back pain is the most common cause of disability in the world and is often caused by degeneration or injury of the intervertebral disc (IVD). The IVD is a complex, fibrocartilaginous tissue that allows for the wide range of spinal mobility. Disc degeneration is a progressive condition believed to begin in the central, gelatinous nucleus pulposus (NP) region of the tissue, for which there are few preventative therapies. Current therapeutic strategies include pain management and exercise, or surgical intervention such as spinal fusion, none of which address the underlying cause of degeneration. With an increasingly aging population, the socioeconomic …

Poly(Vinyl Alcohol)/Α-Chitin/Nanocellulose Composites Developed From Oil Palm Empty Fruit Bunch (Opefb) For Removal Of Cationic Dyes, Chun Fah Mok

Student Works (2020-2029)

In search of an eco-friendly polymeric adsorbent for dye effluent treatment application, poly(vinyl alcohol) (PVA)/chitin/nanocellulose composites were synthesized. The composites were reinforced by oil palm empty fruit bunch fibers (OPEFB)-derived nanocrystalline cellulose (NCC). With addition of 1 wt.% NCC, a maximum improvement of 57.64% and 50.66% in tensile strength and Young’s Modulus were achieved, respectively. However, the PVA-based composites exhibited low resistance in aqueous medium. Hence, maleic acid (MA) was incorporated, in view of modifying PVA-based composites through cross-linking reactions. The effect of varying chitin content (10 wt.%-30 wt.%) and MA content (10%-50% based on total solid content of composite) …

Evaluation Of Biodegradability Characteristics Of Cellulose-Based Film As Per Is/Iso 14855-1, Narayan C. Saha Dr, Gaurav Madhu Dr, Diksha B. Kadu Ms

Journal of Applied Packaging Research

Biodegradable polymers (especially those derived from plant sources) begin their lifecycle as renewable resources, usually in the form of starch or cellulose. In this paper, the evaluation of biodegradability of cellulose-based polymer film under controlled composting conditions as per the guidelines of IS/ISO 14855 (Part-1) standard has been described. Microcrystalline cellulose (MCC) powder was taken as positive-control polymer. The apparatus used to analyse the degree and rate of biodegradation was developed indigenously. The validation of the biodegradability testing apparatus was also performed as per the prescribed test method given in IS/ISO 14855-1.

Synthesis And Behavior Characterization Of Multi-Scale Hierarchical Structured Composites, Jacob M. Mayfield

College of Graduate Studies: Theses & Dissertations

The purpose of the synthesis of a multi-scale hierarchical composite material was to create a material with a high specific strength, a low mass, and high strength material. To achieve this the material categorization of the Formlabs Tough V2 resin was conducted. The resin was used in the construction of a bio-mimicry diamond lattice structure. The structure was subjected to compression testing to characterize the material properties. The Tough V2 resin structure combined with cellulose created a multi-scaled material on Macro and Micro levels to show the bio-inspired design to increase the material properties in a favorable manor. The Tough …

Selective Depolymerization Of Industrial Hemp And Its Effects On Thermal Resistivity, Tanner J. Jolly

Materials Engineering

There is a growing shift within the construction materials industry towards green and sustainable building products. Spending in this area has increased 5 fold since 2011 to a total revenue of $70 billion. An area of particular interest has been aimed at replacing fiberglass batt insulation with cellulose. Cellulose is the most abundant polymer on earth, and has potential to replace petroleum derived insulations. This project explores the potential of selectively isolating cellulose by depolymerizing the support structures found in lignocellulosic materials – specifically lignin and hemicellulose. The current focus is on isolating cellulose from Cannibas sativa, but more …

Solution Casting And Mechanical Testing Of Arabinan-Cellulose Nanocomposites, Kevin Su, Alina Lusebrink

Materials Engineering

The purpose of this work was to investigate methods to produce consistent, reliable, and testable thin films of arabinan-cellulose nanocomposites. Mechanical properties and composition of the Opuntia ficus-indica cactus spines served as motivation for this research. The high specific strength and stiffness, biodegradability, and sustainability of these spines inspired the creation of composites fabricated from the same materials found in cactus spines: arabinan and nanocrystalline cellulose (NCC). Arabinan serves as the matrix material and NCC as the reinforcement. To explore the feasibility of using a non-toxic solvent, different solution casting techniques with water as a solvent were investigated. Ultrasonication was …

Molecular Dynamics Investigation Of The Arabinan-Cellulose Interface For Cellulose Nanocomposite Applications, Luke Thornley

Materials Engineering

Atom level computer simulations of the arabinan and cellulose interface were performed to better understand the mechanisms that give arabinan-cellulose composites (ArCCs) their strength with the goal to improve man-made ArCCs. The molecular dynamics (MD) software LAMMPS was used in conjunction with the ReaxFF/c force field to model the bond between cellulose and arabinan. A cellulose nanocrystal with dimensions 51 x 32 x 8 Å was minimized with various weight percent of water, 0%, 3%, 5%, 8%, 10%, and 12%. After the system was equilibrated for at least 100,000 femtoseconds, an arabinan molecule composed of 8 arabinose rings was added …

Manufacture And Mechanical Testing Of Thin Film Composites Composed Of Poly-Lactic Acid And Nanocrystalline Cellulose, Catherine E. Mohan

Materials Engineering

Society’s overuse of petroleum-based plastic products has created a waste problem that is threatening environments around the world. New efforts have been made to find a suitable replacement derived from a renewable source. Poly-lactic acid has become one of the front-runners in this search. It is derived from starches found in potatoes, corn, and other grains. There are many factors that make Poly-lactic acid-based polymers a suitable replacement for petroleum-based ones, but it still suffers from low mechanical strength due to low crystallinity percentages. Doping the polymer with nanocrystalline cellulose provides more nucleation sites for the crystallization of the polymer …

Effects Of Sodium Hydroxide Pretreatment On Structural Components Of Biomass, Alicia A. Modenbach, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Pretreatment is a unit operation in the conversion of biomass to valuable products that utilizes various combinations of conditions, including chemicals, heat, pressure, and time, to reduce the recalcitrance of lignocellulose. Many such pretreatments have been developed over the years, as the operating conditions can be adapted so that lignocellulose is modified in ways unique to each pretreatment. By tailoring pretreatment conditions to achieve these modifications, the types of final products produced can be controlled. The purpose of this review is to provide a consolidated source of information for sodium hydroxide effects on lignocellulose. The structural characteristics of lignocellulose and …

Cellulose Nanocrystals As A Material For Microencapsulation, Lauren C. Kennedy, Congwang Ye, Colton Steiner, Carlos Martinez

The Summer Undergraduate Research Fellowship (SURF) Symposium

Cellulose is an abundant, biodegradable, and inexpensive renewable polymer that is light in weight with high mechanical strength (Habibi, Lucia, Rojas 2010). Full fibers of cellulose have been used in many products such as plastics and textiles for over a century and a half, but recently, modern extraction techniques have made it possible to investigate uses for minuscule cellulose fibers (Habibi, Lucia, Rojas 2010). Through acid hydrolysis, cellulose fibers become rod-like nanostructures with a high aspect ratio that are known as Cellulose Nanocrystals (CNCs) (Habibi, Lucia, Rojas 2010). Since CNCs are biodegradable and derive from a renewable resource, finding ways …

An Investigation Of Arabinan And Cellulose Based Nano-Composite Fabrication Methods, Marianne Smithfield, Carl Petterson, Robert Miller

Materials Engineering

Microcrystalline cellulose was converted into nanocrystalline cellulose via an acid hydrolysis procedure. Scanning electron microscopy (SEM) was employed to measure the particle size and thus the effectiveness of acid hydrolysis. The nanocrystalline cellulose was poured through a 0.2μm filter to isolate the particles of ideal size. The nanocrystalline cellulose samples were stored in dimethylformamide (DMF) to prevent mold growth and agglomeration upon drying. Numerous composite samples were created by dissolving the arabinan in a solvent, suspending cellulose in the arabinan solution, and then drying the sample. Casting was performed in a silicon mold to allow sample removal without damage. Initial …