Polymer and Organic Materials Commons^™

Solvent Analysis Of Phenolic Resin Glass Fiber Reinforced Prepreg During Out-Time, Sixin Zhai, Crystal Ipong

Materials Engineering

Phenolic resin glass fiber reinforced prepregs are highly suitable for airplane interior components due to their high fire resistance, high temperature performance, and low-density characteristics. Safran Cabin seeks to improve their storage of the phenolic resin prepreg during their manufacturing process. The issues the company faces are the occasional delamination of prepreg laminas or the loss of tackiness rendering the lamina unfit for use. The area of investigation was determining the weight loss of volatiles during out-time. The term “out-time” consists of the time the prepreg experiences in transit, on the shop floor, and in short-term temperature-controlled storage. Simulated storage …

Reducing The Fouling Of Microfiltration Membranes Through Uv-Initiated Surface Modifications Using Poly (Ethylene Glycol) Based Monomers, Christopher Lo, Matthew Truong

Materials Engineering

Meissner Filtration Product Inc. designs and manufactures membranes for food and beverage, microelectronics, ultrapure chemicals, and pharmaceutical industries. Membrane filters utilized in these industries have lifetimes greatly limited due to membrane fouling. Increasing membrane lifetime will reduce downtime, waste, and cost of operation. The proposed project is aimed to develop a methodology for synthesizing a fouling-resistant polymer coating layer on hydrophobic membrane surfaces for reducing membrane fouling and increasing membrane filterability (membrane lifetime) that are critical for effective membrane operations in the pharmaceutical industry. In this study, commercial membranes were coated with a solution containing a monomer, crosslinker, and photoinitiator …

Development Of A Marine Biodegradable Target Balloon, Blake Samuel Robinson, Arash Sam Akhavi, David Leonardo Albarran-Martinez

Materials Engineering

The US Navy utilizes PVC target balloons, known as Killer Tomatoes, that are inflated onboard a naval vessel then deployed into the ocean to calibrate a variety of weaponry. The Navy has requested the investigation of biodegradable polymers to replace the PVC in attempts to reduce ocean waste that is generated from the leftover PVC material. After communicating with American Pacific Plastic Fabricators (APPF), the current manufacturer of the Killer Tomatoes, we gained an understanding of the manufacturing process and the material requirements that would allow a new material to be integrated into their current process. Two proprietary, trial polymers …

Pressure Driven Desalination Membranes: Lyotropic Liquid Crystals Containing Single Walled Carbon, Matteo A. Del Giudice, Samantha Castillo Merigold

Materials Engineering

This project presents a potential alternative desalination technique that utilizes the ion rejection properties of single walled carbon nanotubes dispersed in a lyotropic liquid crystal (LLC) matrix. Previous research has pointed to the polymerizable surfactant methacryloxy ethyl hexadecyl dimethyl ammonium bromide (C16MA) having capabilities of filtering molecular components smaller than a nanometer, when oriented in cylindrical micelles. SWCNTs were dispersed in deionized water by probe sonication and addition of surfactant cetyltrimethylammonium bromide (CTAB) due to SWCNTs’ hydrophobic properties. Membranes were produced containing 55wt% C16MA, 37wt% DI water, 0.1wt% with respect to the monomer (WRM) SWCNTs, 1.9 wt% WRM 2,2-dimethoxy-2-phenylacetophenone (photointiator), …

Composition For Protecting Technological Equipment Against Salt Deposits And Internal Corrosion, Hasan Kadirov, Sadritdin Turabdjanov

CHEMISTRY AND CHEMICAL ENGINEERING

Aimed studies on the synthesis of metal complexonates have carried out. The reaction of obtaining zincate zincate oxyethylene diphosphonic acid OEDP has studied. On the basis of synthesized zincate-OEDP, compositions of corrosion inhibitors and deposits of mineral salts with the addition of a vacuum residue of monoethanolamine (RMEA) and polyaminocrotanol (PKI-3), which are able to effectively suppress corrosion processes in environments with different initial corrosive activity, have been compiled. It is proved that the high efficiency of the composition OEDP : zincate-OEDP : PKI-3 (maximum protective effect - 97.9%) is much more effective than the composition OEDP : zincate-OEDP : …

Rational Disposal Of Pet Containing Waste And Prospects For The Synthesis Of New Polymers, Asror Juraev, Muzaffar Alimukhamedov, Ravshan Adilov, Farhod Magrupov

CHEMISTRY AND CHEMICAL ENGINEERING

As a result of the research on the utilization of polyethylene terephthalate-containing household waste, a promising direction was identified in the production of a new type of secondary polyethylene terephthalate (SPET) - unsaturated polyesters.It was revealed that the final product, which formed when the alcoholization process is complete in any proportion of of glycol and secondary polyethylene terephthalate, is the bisalkylent terephthalate of terephthalic acid; the content of the alcoholysis product consists of bisalkylent terephthalate, different molecule mass, functionally hydroxyl-containing complex polyester polyol and free diols.

The laws of alcoholization of secondary …

Rehology And Electrical Conductivity Of Particulate Composites In Additive Manufacturing, Bin Xia

Mechanical Engineering Research Theses and Dissertations

Extrusion-based multi-functional additive manufacturing (AM) has been a rapidly developing area in AM recently. Particulate composites are widely used in this area to provide different functionalities with different types of particulate additives. However, there is no systematic understanding of the behavior of particulate composites during extrusion (especially in small nozzles) or of their properties once deposited in the build. This work investigates the properties of the type of particulate composites usually used in additive manufacturing, composed of a polymer matrix material and particulate additives within the micrometer scale. The focus is on the material rheology in the nozzle/capillary (for the …

Atomic Oxygen Resistant Low Earth Orbit Stable Polymer Matrix Composites Employing Phenylphosphine Oxide Epoxy-Amines, Witold Fuchs

Dissertations

Atomic oxygen (AO) attacks polymer matrix composites (PMC’s) on the surfaces of spacecraft in low earth orbit (LEO) and threatens safe spacecraft operation and service life. Incorporating phenylphosphine oxide (PPO) groups into polymer chains offers a self-regenerating method of protection from AO but remains poorly understood. Herein, epoxies containing PPO groups were synthesized with increasing concentrations of phosphorus [P] from 0 to 8 wt % to investigate their AO resistance. Measurements confirmed the exposure of these materials to AO produces a passivation phosphate (POx) layer on the surface of the sample and the efficacy of the resultant layer was directly …

Development Of Biomaterials For Drug Delivery, Raquel De Castro

Graduate Theses and Dissertations

Drug delivery systems (DDS) have highly evolved in the last decades with the development of hydrogels and nanoparticles. However, high systemic uptake, side effects, low bioavailability, and encapsulation efficiency continue to be a major hurdle faced by such DDSs.

Nanoparticles and hydrogels can be specifically designed for targeted DDSs to mitigate some of the problems. This dissertation aimed to design two DDSs for ocular drug delivery and one for cancer treatment. The first project sought to develop chitosan nanoparticles (Cs-NP) using PEGDA as a copolymer to encapsulate gentamicin (GtS) for ocular drug delivery. Cs-NPs contain positive charges that can interact …

Effects Of Static Mixer Geometry On Polyurethane Properties, Christian R. Dixon

Honors Theses

The field of additive manufacturing has gained significant academic interest in the past few decades with a recently developed type of three-dimensional (3D) printing. Reactive extrusion additive manufacturing combines precursor materials within a static mixer (SM) head, where polymerization begins before deposition. Variable static mixer geometries currently exist, but the relationship between mixer geometry and post-polymerization mechanical properties is undefined. To elucidate this relationship, a series of experiments with identical chemistry was performed using a high shear SM, a low shear SM, and a comparative batch reaction. While higher shear mixing trends with faster polymerization for step-growth polymerizations, consistent precursor …

Characterization Of Gesn Semiconductors For Optoelectronic Devices, Hryhorii Stanchu

Graduate Theses and Dissertations

Germanium-tin alloys with Sn compositions higher than 8 at. % to 10 at. % have recently attracted significant interest as a group IV semiconductor that is ideal for active photonics on a Si substrate. The interest is due to the fact that while at a few percent of Sn, GeSn is an indirect bandgap semiconductor, at about 8 to 10 at. % Sn, GeSn transitions to a direct bandgap semiconductor. This is at first surprising since the solid solubility of Sn in Ge under equilibrium growth conditions is limited to only about 1 at. %. However, under non-equilibrium growth conditions, …

Peptoid-Based Microsphere Coatings For Biomaterial Applications, Jesse Leland Roberts

Graduate Theses and Dissertations

Peptoids are peptidomimetic oligomers that predominantly harness similarities to peptides for biomimetic functionality. The incorporation of chiral, aromatic side chains in the peptoid sequence allows for the formation of distinct secondary structures and self-assembly into supramolecular assemblies, including microspheres. Peptoid microspheres can be coated onto substrates for potential use in biosensor technologies, tissue engineering platforms, and drug-delivery systems. They have the potential for use in biomedical applications due to their resistance to proteolytic degradation and low immunogenicity. This dissertation focuses on the physical characteristics and robustness of the peptoid microsphere coatings in various physiological conditions, along with their ability to …

Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore

Graduate Theses and Dissertations

Cellulose nanomaterials (CNMs) are derived from plant matter and are comprised of nanoscopic cellulose crystals and fibers. They have a diverse set of applications, from cosmetics to oil recovery. This study focuses on the properties of Oxone® mediated TEMPO-oxidized cellulose nanomaterials (OTO-CNMs) and their use in controlling the transport properties of polymeric substrates. Synthesis and characterization of cellulosic nanoparticles have resulted in the creation of OTO-CNMs with properties that increase hydrophilicity. With added hydrophilicity, OTO-CNMs possess lower fouling propensity, making them ideal membrane additive for transport limited separations such as hemodialysis.

To utilize the material and unique properties thereof, this …

Biopolymeric Materials For Tissue Regeneration, Cell Manufacturing, And Drug Delivery, David Alfonso Castilla-Casadiego

Graduate Theses and Dissertations

The development of materials for tissue regeneration, cell manufacturing, and drug delivery is possible by the manipulation of polymer properties and the use of three different techniques including layer-by-layer, electrospinning, and molding technique.

By applying the layer-by-layer technique over biomaterials, it is possible to develop polymeric multilayers that promote a more favorable environment for cellular functionality, increasing the possibility of improving their acceptance in the area of implantation. IRVASE demonstrated being a powerful technique that allows for a reliable characterization of the physical-chemical and thermal properties of the fabricated surfaces. This opens the possibility to monitor the design of surfaces …

Utilizing The Oxygen-Barrier Properties Of Poly(Isobutylene) To Enhance Photon Upconversion In Thermoplastic Elastomers, Haley Carroll

Honors Theses

Upconversion (UC) is the conversion of low energy light to higher energy light. It is utilized for a broad range of applications such as solar energy harvesting, microscopy of cellular biology, and cancer therapy. Specifically, triplet-triplet annihilation UC (TTA-UC) involves two dye species, a sensitizer and an annihilator, which are capable of upconverting noncoherent light such as sunlight. Traditionally, TTA-UC is achieved in solution, rubbers, or glasses, however, this work probes the capabilities of a thermoplastic elastomer (TPE) matrix to examine the effect of phase-separated morphology on the energy transfers necessary for TTA-UC. The system herein consists of poly(styrene-isobutylene-styrene) (SIBstar) …

Synthesis Of Superabsorbing Hydrogels Based On Starch Copolymers, Baxodir Kholnazarov, Khayit Turaev, Abdulakhat Jalilov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to synthesize highly swellable superabsorbent hydrogels based on starch copolymers. To achieve this goal, mineral-containing superabsorbent hydrogels based on starch, acrylamide, binder and initiator were synthesized. The optimal synthesis conditions were determined and studies were carried out on the influence of the molar ratios of the starting substances on the composition and physicochemical properties of the synthesized superabsorbent hydrogel. In the course of research, the optimum copolymerization temperature was 60 ° C, and the reaction time was 3 hours.

As a result of the study, a superabsorbent hydrogel based on starch, acrylamide and bentonite …

Synthesis Of Thiocol Oligomer Based On Sodium Tetrasulphide, Epichlorhydrine And Ammonium Phosphate, Bakhtiyor Normurodov, Khayit Turaev, Abdulakhat Jalilov, Sherzod Kasimov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this study is the synthesis and study of thiokol oligomer NEP-12 brand based on sodium tetrasulfide, epichlorohydrin and ammonium phosphate, which is intended for use as a main component of Thiokol sealant. To achieve this goal, a thiokol oligomer based on sodium tetrasulfide, epichlorohydrin, and ammonium phosphate was synthesized and investigated, and the optimal conditions for the synthesis of a thiokol oligomer were determined. Research has been carried out on the influence of the molar ratios of the starting substances on the composition and physicochemical properties of the synthesized thiocol oligomer. The optimum polycondensation temperature was taken …

Synthesis And Structure Of The Coordination Complex Of Copper Ion With Collagen, Dildorа Sadikova, Adham Rafikov, Oybek Tursunqulov, Dilnoza Soyibova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to synthesize, determine the composition and microstructure of complexes of copper (II) sulfate with collagen for use as a dye for textile material. Coordination complexes of copper (II) sulfate with collagen synthesized at different ratios of the initial substances by the interaction of solutions of different concentrations of copper sulfate and collagen of raw skin. With an increase in the salt content, the yield of the reaction product increases. With an excess of collagen, some of it does not bind into a complex and precipitates. With an excess of salt, almost the weight of …

Funtionalization Of Morphologically Different Nanoclays For Enhanced Mechanical Properties, Malachi Kent

Honors College Theses

Nanoclays are microscopic clays that are comprised of layered nanoparticle aluminosilicates that are naturally arranged in several morphologies. Halloysite nanotubes (HNT) are hollow, double-layered tubes, bentonite (BNT) clays are trapezoidal platelets, and nanosilica or silica dioxide (SiO₂) are spherical. These nanoclays were chosen for sustainable purposes as they are naturally derived and for economical purposes because of their cheap commercial availability. In this study, the nanoclays are functionalized with an epoxy organosilane group through reflux conditions at 120 °C for 24 hours. The pristine and functionalized nanoclays were extensively characterized with infrared radiation (IR) spectroscopy, scanning electron microscope …

Growth And Characterization Of Molecular Ferroelectric Thin Films, Yifan Yuan

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Compared with inorganic ferroelectrics, organic ferroelectrics have advantages of low cost and low toxicity, are in increasing demand in capacitors, piezoelectric, and memory devices to reduce the environmental load. This work focuses on two types of organic molecular ferroelectric materials, croconic acid (CA) and 2-methylbenzimidazole (MBI). The work here introduces several origins of ferroelectricity in typical organics and their switching mechanism. We then investigated the nucleation, growth, and ferroelectric measurements of CA thin films. We explored the effect of substrate temperature and an external electric field on the nucleation and growth processes. The results can be used to improve the …

Experiment On Activated Carbon Manufactured From Waste Coffee Grounds On The Compressive Strength Of Cement Mortars, Sukjoon Na, Sanghoon Lee, Sungmin Youn

All Engineering Faculty Research

In this paper, we performed an experiment with activated carbon manufactured from waste coffee grounds on the compressive strength of normal cement mortars. The activated carbon reinforcement was manufactured from waste coffee grounds, and the collected coffee grounds were then transformed into activated carbon granules through the physical activation process. The activated carbon/cement composites were prepared by mixing cement with activated carbon granules with the weight fractions of 0.5%, 1%, 1.5%, 5%, and 10% cement. The experimental results show that adding activated carbon up to 1.5 wt% increased the early strength of cement mortars. Furthermore, we found that the composites …

Nanocellulose Sheets From Oil Palm Empty Fruit Bunches Treated With Naoh Solution, Farah Fahma, Faiza Ayu Lestari, Ika Amalia Kartika, Nurmalisa Lisdayana, Evi Savitri Iriani

Karbala International Journal of Modern Science

The objective of this study is to produce nanocellulose sheets from oil palm empty fruit bunches (OPEFBs). Nanocellulose sheets from OPEFBs were prepared through the dewatering process using vacuum filtration. Subsequently, the produced sheets were treated with NaOH solution to improve the mechanical stability of their structure, causing them to be firm in water. The water absorption of nanocellulose sheet increased with increasing NaOH concentrations up to 20 wt%, increasing tensile strength, and Young’s modulus, but decreased when they were treated with 30 wt%. The diameter shrinkage of nanocellulose sheets was directly proportional to the NaOH concentration and soaking time. …

Characterization, Immobilization, And Polymer Related Applications Of Watermelon Seed Powder, A Practical Source Of Urease Enzyme, Anthony Quan Quoc Mai

LSU Doctoral Dissertations

Urease enzyme was crystallized almost a century ago, and to this day its intrinsic stability is not ideal for everyday applications. This work introduces a new process by which a naturally encapsulated material, watermelon seed powder (WMSP), is characterized for its stability and activity. WMSP enzymatic activity has been measured for over a year at various storage conditions—exposed to ambient atmosphere for a year, WMSP retained above 90% activity. In aqueous conditions, the enzyme maintained above 60% activity after two months; with the addition of a preservative that number stays at about 90%. There is a pH shift of the …

Jcati Pyrolysis System, Jack Dutton

All Undergraduate Projects

The Joint Center for Aerospace Technology Innovation (JCATI) project is designed to recycle carbon fiber pieces for use in manufacturing. Part of the system requires the removal of resin from the carbon fibers to facilitate the recycling of carbon fiber. To accomplish this task the pyrolysis process is implemented using a commercial grade oven with a conveyor system. Argon gas is injected into the shroud and over the oven to purge the interior of oxygen. The conveyor system enables this to be a batch process. A ramp is used to allow simple addition of material to the conveyor system and …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

Combined Puncture And Cutting Of Soft-Coated Fabrics By A Pointed Blade: Energy, Force, And Stress Failure Criteria, Ennouri Triki, Chantal Gauvin

Études primaires

Soft elastomer-coated fabrics are widely used in engineering and protective applications. Puncture cutting by sharp-tipped objects is one of the most common failure modes of protective gloves made of coated fabrics. In order to investigate the puncture-cutting process of soft elastomer-coated fabrics, we studied the mechanisms and mechanics of pointed-blade insertion into specimens cut out from four protective gloves. Experimental and analytical analyses showed that total energy and critical puncture-cutting force calculated analytically are both able to predict the puncture-cutting resistance of soft elastomer-coated fabrics measured experimentally. Total energy is obtained from the relationship between the puncture-cutting work and the …

Viscoelasticity Of Ptfe-Based Face Seals, Bo Tan

Theses and Dissertations--Mechanical and Aerospace Engineering

PTFE-based materials are widely used in areas of tribology, particularly in seal and bearing applications because of their outstanding self-lubricating properties. Often in dynamic seal applications there is a need for ultra-low mechanical friction loss between the sealing surfaces. Due to its extremely low friction coefficient, there is interest in employing Polytetrafluoroethylene (PTFE) materials in such applications. One challenging aspect of employing PTFE is that these materials are viscoelastic and plastic. This dissertation concentrates on the modeling of viscoelastic material response when used as mechanical face seals with a focus on PTFE-based materials. First, the viscoelastic characteristics are measured through …

Establishing Independent Tunability Of The Mechanical And Transport Properties Of Polymer Gels, Lucas Rankin

Master’s Theses

Polymer gels can be used in the fabrication of materials for filtering liquid and gaseous media, solid-state electrolytes, and transdermal medical patches. This diverse range of applications primarily relies on the transport and mechanical properties of polymer gels. Both sets of properties have shown excellent tunability, but typically in a coupled fashion. Establishing the independent tunability of the transport and mechanical properties of polymer gels (using simple, cost-effective methods) is paramount if polymer gels are to be used to their full potential. Specifically, block copolymer gels self-assemble into organized nanoscale networks within the gel solvent, which allows for facile control …

Charge Transport, Conductivity And Seebeck Coefficient In Pristine And Tcnq Loaded Preferentially Grown Metal Organic Frameworks, Xin Chen, Kai Zhang, Zeinab Mohammed Hassan, Engelbert Redel, Helmut Baumgart

Electrical & Computer Engineering Faculty Publications

This investigation on Metal-Organic Framework (MOF) HUKUST-1 films focuses on comparing the undoped pristine state and with the case of doping by TCNQ infiltration of the MOF pore structure. We have determined the temperature dependent charge transport and p-type conductivity for HKUST-1 films. Furthermore, the electrical conductivity and the current-voltage characteristics have been characterized in detail. Because the most common forms of MOFs, bulk MOF powders, do not lend themselves easily to electrical characterization investigations, here in this study the electrical measurements were performed on dense, compact surface-anchored metal-organic framework (SURMOF) films. These monolithic, well-defined, and (001) preferentially oriented MOF …

Determination Of Hydrogel Degradation By Passive Mechanical Testing, Avery Rosh-Gorsky

Honors Theses

This paper details a new technique to measure the mechanical properties of ETTMP PEGDA hydrogels using Hertz Contact Theory and simultaneously analyze both the model drug release and gel erosion in situ. This method involves curing a drug loaded hydrogel in a standard cuvette and placing a glass bead and phosphate buffer solution (PBS). Over time, the cross-linked network of the hydrogel breaks down, and, as a result, the ball sinks into the hydrogel. This method provides a macroscopic and inexpensive way to continuously and passively measure properties of the hydrogel as the hydrogel degrades. By plotting both the …