Polymer and Organic Materials Commons^™

A Systematic Study On Structural And Optical Properties In Conjugated Polymer Photovoltaic Devices, Sri Sabarinadh Sunkavalli

Electrical & Computer Engineering Theses & Dissertations

Conjugated polymer/fullerene based solar cells represent an exciting alternative to inorganic ones because of their low production costs, flexibility and low weight. At present, commercialization of organic photovoltaic (OPV) cells is limited due to their relatively low efficiency in comparison to silicon ones. In order to understand the operation of OPV cells and to increase their efficiency, more information about the structure of the absorber layer is needed. In particular, the connection between structure and properties of the absorber layer is of great importance. Performance of bulk heterojunction organic solar cells based on poly (3-hexylthiophene) as donor and a soluble …

Big Challenges In Designing Small Parts For Mass Production, Kevin Delaney, David Kennedy

Conference Papers

Micro manufacturing involves the production of parts or products with features on a micro scale. The technology is used to produce parts for several business sectors which have experienced dramatic growth in recent years and forecasts are that this growth will continue in the years ahead. With the loss of traditional manufacturing jobs to lower-cost locations many companies in Ireland see micro manufacturing as having significant potential to preserve and increase revenue. A move into micro manufacturing will present significant opportunities for those companies willing to take the risk of producing parts with micro dimensions. Such a transition is a …

Equi-Biaxial Fatigue Of Elastomers: The Effect Of Oil Swelling On Fatigue Life, Stephen Jerrams, John Hanley, Niall Murphy, Ali Hassan

Articles

The effect of oil swelling on the fatigue life of ethylene propylene diene monomer rubber (EPDM) has been studied under conditions of equi-biaxial cycling using dynamic bubble inflation. Specimens were subjected to varying degrees of swelling in reference mineral oils and fatigued at constant engineering stress amplitudes. The reference oils used for swelling the EPDM had known aniline points, allowing the rubber-oil compatibility to be determined. The inflation fluid for fatigue testing was selected with a solubility parameter that would produce a desired level of incompatibility with the test specimens, thereby limiting the amount of additional swelling during cycling. Wöhler …

Raman Studies Of 1,3,5,7 Cyclooctatetraene At High Pressure, Martin Galley, Ed Romano, Sergey Tkachev, Michael Pravica

Undergraduate Research Opportunities Program (UROP)

We performed Raman spectroscopic studies of 1,3,5,7-cyclooctatetraene at elevated pressures up to 10 GPa with the aim of examining possible planarization of the molecule and further studying two prior-discovered phases of the solid with pressure. The Raman excitation source was a Krypton-ion laser operating at 674.1 nm (give wavelength).

1,3,5,7 Cyclooctatetraene has an octagonal formation however it is not aromatic or anti-aromatic (not a subject to the 4n+2 Huckel’s rule) [1]. As a result, its adopts a somewhat reactive tub shape. Upon the addition or removal of one to two electrons under ambient conditions, the molecule planarizes and becomes aromatic …

The Effects Of Build Orientation, Diameter And Printhead Life On The Cylindricity Of Three-Dimensionally Printed Parts, Troy E. Ollison

All-Inclusive List of Electronic Theses and Dissertations

Rapid prototyping (RP) technologies have become more than just a fast and inexpensive way to produce prototypes. Today RP is widely used to produce functional prototypes, end-use parts and tooling as well as visual prototypes. When RP is used for end-use parts with interconnected moving assemblies or for producing metal casting molds which must have sufficient material for machining tolerances, accuracy is very critical. However, in general, accuracy of the finished RP parts is relatively low lll compared to parts produced by traditional manufacturing processes. The understanding of why some of these accuracy differences exist is either unknown or not …

Damping Of Magnetorheological Elastomers, Lin Chen

Articles

The damping property of magnetorheological (MR) elastomers is characterized by a modified dynamic mechanical-magnetic coupled analyzer. The influences of the external magnetic flux density, damping of the matrix, content of iron particles, dynamic strain and driving frequency on the damping properties of MR elastomers were investigated experimentally. The experimental results indicate that the damping properties of MR elastomers greatly depend on the interfacial slipping between the inner particles and the matrix. Different from general composite materials, the interfacial slipping in MR elastomers is affected by the external applied magnetic field.

Effect Of Carbon Nanofiber-Matrix Adhesion On Polymeric Nanocomposite Properties—Part Ii, Khalid Lafdi, William Fox, Matthew Matzek, Emel Yildiz

Chemical and Materials Engineering Faculty Publications

A successful integration of two independent phases with good adhesion is imperative for effective translation of superior carbon nanofiber filler properties into a physically superior carbon nanocomposite. Carbon nanofibers were subjected to electrochemical oxidation in 0.1 M nitric acid for varying times.

The strength of adhesion between the nanofiber and an epoxy matrix was characterized by flexural strength and modulus. The surface functional groups formed and their concentration of nanofibers showed a dependence on the degree of oxidation. The addition of chemical functional groups on the nanofiber surface allows them to physically and chemically adhere to the continuous resin matrix. …

Carbon Nanoadditives To Enhance Latent Energy Storage Of Phase Change Materials, Shadab Shaikh, Khalid Lafdi, Kevin P. Hallinan

Chemical and Materials Engineering Faculty Publications

Latent energy storage capacity was analyzed for a system consisting of carbon nanoparticlesdopedphase changematerials (PCMs). Three types of samples were prepared by doping shell wax with single wall carbon nanotubes(SWCNTs), multiwall CNTs, and carbon nanofibers. Differential scanning calorimetry was used to measure the latent heat of fusion. The measured values of latent heat for all the samples showed a good enhancement over the latent heat of pure wax. A maximum enhancement of approximately 13% was observed for the wax/SWCNT composite corresponding to 1% loading of SWCNT. The change in latent heat was modeled by using an approximation for the intermolecular …

Nitrogen And Hydrogen Plasma Treatments Of Multiwalled Carbon Nanotubes, John G. Jones, A. R. Waite, Christopher Muratore, Andrey A. Voevodin

Chemical and Materials Engineering Faculty Publications

This article investigates plasma treatment of vertically aligned multiwall carbon nanotube (CNT) films in different plasma environments for modification of surface chemistry and morphology. The surfaces of the CNTs were functionalized with a pulsed dc plasma treatment, where the power was directly applied to the nanotube film in low pressure argon/nitrogen and argon/hydrogen backgrounds. Optical emission spectroscopy was used to detect atomic and molecular excitations in the gas mixtures as well as in pure gases in the vicinity of the CNT films. In situx-ray photoelectron spectroscopy was performed on the treated samples to examine CNT surface chemistry after treatment. …

Effect Of Carbon Black On The Mechanical Performances Of Magnetorheological Elastomers, Lin Chen

Articles

Several magnetorheological elastomer (MRE) samples, with different weight percentages of carbon black, were fabricated under a constant magnetic field. Their microstructures were observed by using an environmental scanning electron microscope (SEM), and their mechanical performance including magnetorheological (MR) effect, damping ratio and tensile strength were measured with a dynamic mechanical analyzer (DMA) system and an electronic tensile machine. The experimental results demonstrate that carbon black plays a significant role in improving the mechanical performance of MR elastomers. Besides the merits of high MR effect and good tensile strength, the damping ratio of such materials is much reduced. This is expected …