Polymer and Organic Materials Commons^™

Characterization Of The Fatigue Threshold Behavior Of Uhmwpe, Bethany B. Smith, Anurag Roy, Robert O. Ritchie, Lisa A. Pruitt

Faculty Journal Articles

Ultra-high-molecular-weight-polyethylene (UHMWPE) has been the material of choice for bearings in total joint replacements (TJRs) for decades as a result of its excellent wear resistance, chemical inertness, energetic toughness, low friction, and biocompatibility. Utilization of this polymer in orthopedic devices requires oxidation, wear, and fatigue resistance. Balancing these important properties by tailoring processing techniques and modulating microstructural features has been an ongoing endeavor in the field. Research into the clinical applications of UHMWPE has primarily focused on the challenges of wear and oxidation while studies into the realm of fatigue have been more limited. Literature gaps exist in fully understanding …

Effect Of Manufacturing Process On Mechanical Properties Of Polyetheretherketone (Peek) Cranial Implants Produced By Single-Point Incremental Forming (Spif), Elizabeth M. Mamros, Ihab Ragai, Brian Young

Faculty Conference Papers and Presentations

Polyetheretherketone (PEEK) is one of the most commonly used materials for cranioplasty due to its biocompatibility, relatively high strength, and light weight. Cranial implants manufactured from PEEK sheets using the same manufacturing process, e.g., single point incremental forming (SPIF), will have differing part properties based on the selected polymer forming process. Three fabrication methods for PEEK sheets were investigated: extrusion, modified hot pressing, and injection molding. Material characterization specimens were extracted for tensile, impact, and differential scanning calorimetry (DSC) experiments. The PEEK sheets were also subjected to formability tests at room temperature using SPIF. Slight differences in ultimate tensile strength …

Investigation Of Distributed Additive Manufacturing For 3d Printed Headband Component During Global Supply Chain Disruptions, Elizabeth M. Mamros, Saketh Kantipudi, Matthew C. Eaton, Jinjin Ha, Brad L. Kinsey

Faculty Conference Papers and Presentations

During the COVID-19 global pandemic, a shortage of personal protective equipment (PPE) occurred. Manufacturers of these critical products were unable to keep up with the growing demands as the situation evolved. Most face shields, a common type of PPE, include a headband component to provide the appropriate fit for the user and curvature for the clear face shield attachment. To mitigate this shortage in the local region, the Portsmouth Naval Shipyard (PNSY) generated a computeraided design (CAD) file for the headband component and asked the University of New Hampshire (UNH) to manufacture it with all available 3D printers, including printers …

Solid-State Shear Pulverization: A Comprehensive Study On Polymer Processing Technology From A Systematic Innovation Perspective, Tyler A. Will

Master’s Theses

Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been shown to impart beneficial properties onto homopolymers or create copolymers and composites through continuous fragmentation and fusion. The unique technology employs cold temperature to keep the polymer in the solid state. This thesis investigates industrial polymer processing in the context of real-world applications. This thesis analyzes SSSP using an organized methodology called systematic innovation (SI). SI facilitates problem solving by assisting engineers in conducting root cause analysis around a material and studying the physical setup of the equipment.

This …

Temperature-Dependent Diffusion In Block Copolymer Organogels, Ridwana Bashar

Master’s Theses

Organogels are often considered for transport-based applications such as transdermal drug delivery vehicles and gel actuators due to their unique properties. Recent consideration of styrenic block copolymer based organogels’ application in transdermal drug delivery requires an extensive investigation of drug diffusion behavior through these gels to assess their applicability. Temperature is a major influencing parameter on diffusion. The goal of this research is to better understand the impact of temperature on diffusion in styrenic triblock copolymer organogels. To accomplish this goal, we focused on three specific objectives: (i) accurately measure the diffusivities of a solute – AOT reverse micelles – …

Determination Of Hydrogel Degradation By Passive Mechanical Testing, Avery Rosh-Gorsky

Honors Theses

This paper details a new technique to measure the mechanical properties of ETTMP PEGDA hydrogels using Hertz Contact Theory and simultaneously analyze both the model drug release and gel erosion in situ. This method involves curing a drug loaded hydrogel in a standard cuvette and placing a glass bead and phosphate buffer solution (PBS). Over time, the cross-linked network of the hydrogel breaks down, and, as a result, the ball sinks into the hydrogel. This method provides a macroscopic and inexpensive way to continuously and passively measure properties of the hydrogel as the hydrogel degrades. By plotting both the …

Establishing Independent Tunability Of The Mechanical And Transport Properties Of Polymer Gels, Lucas Rankin

Master’s Theses

Polymer gels can be used in the fabrication of materials for filtering liquid and gaseous media, solid-state electrolytes, and transdermal medical patches. This diverse range of applications primarily relies on the transport and mechanical properties of polymer gels. Both sets of properties have shown excellent tunability, but typically in a coupled fashion. Establishing the independent tunability of the transport and mechanical properties of polymer gels (using simple, cost-effective methods) is paramount if polymer gels are to be used to their full potential. Specifically, block copolymer gels self-assemble into organized nanoscale networks within the gel solvent, which allows for facile control …