Polymer and Organic Materials Commons^™

Recycling 3d Printing Waste In The Binghamton University Makerlab, Kevin Tejera

Library Research Scholars Program Spring 2026

3D printing is an important part of many university makerspaces. However, it comes with negative environmental consequences, including polylactic acid (PLA) filament waste. Currently, the MakerLab at Binghamton University has no closed-loop recycling system, leading to large quantities of used filament being sent to landfills, where it contributes to greenhouse gases and microplastic production.

This research project looks at the feasibility of an in-house PLA filament recycling program by examining the mechanical recycling process, cost/equipment needs, contamination issues, available space, and the effect of repeated recycling on the filament. An economic analysis will be completed through a break-even analysis and …

Predicting Long-Term Creep Behavior Using Short-Term Stress Relaxation Data In Expanded Polyethylene Foam, Andrew M. Seelig

All Theses

Closed cell expanded polyethylene (EPE) foams are widely used for protective packaging due to their high energy absorption properties and recyclability. However, these foams can be subjected to sustained compressive stresses (13.78 - 36.20 kPa), depending on density and application, leading to time-dependent deformation (creep). Creep reduces cushioning performance, making its understanding critical for effective protective packaging. Two standards, ASTM D3575 and ASTM D2221, define methods for conducting compressive creep tests on foam materials, with test durations extending up to 1000 hours. Accelerated methods such as Time Temperature Superposition (TTS) and the Stepped Isostress Method (SSM) have been explored for …

Mechanistic Insights Into Polymer-Assisted Graphene Exfoliation: The Roles Of Velocity, Adhesion, Cohesion, Temperature, Peeling Mode, And Edge Defect Via Coarse-Grained Molecular Dynamics, Linjiale Dai

All Theses

Graphene exfoliation is a critical step in the fabrication of high-quality graphene

layers. However, the underlying fracture mechanisms remain poorly understood. In this

work, I employed coarse-grained (CG) molecular dynamics (MD) simulations to

investigate how factors such as interfacial binding energy, substrate cohesion, temperature,

peeling mode, and edge defects influence the outcome of the exfoliation process. To model

polymer-assisted mechanical exfoliation, I used a finite-size system in which multilayer

graphene (MLG) is sandwiched between two thin polymer films. Leveraging the

spatiotemporal efficiency of the CG model, I performed fifty simulation iterations per

parameter set and analyzed the results from a …

Analysis Of Ptfe Radial Lip Seals For Wheel Bearing Applications, Madison Vogt

Theses and Dissertations--Mechanical and Aerospace Engineering

A numerical analysis was conducted to investigate the viscoelastic effects of nonlinear materials on the sealing zone and contact pressure distribution of radial lip seals in a conventional geometric topology. The use of nonlinear materials in radial lip seal applications is desirable to improve operation and reliability of rotating machinery due to their high operating temperatures, chemical compatibility, and low friction coefficients. Examples include, but are not limited to, seals within industrial air compressors, turbine engines, aircraft landing systems, chemical processing equipment, and Freon pumps. This work focuses on analyzing the nonlinear viscoelastic response of pure Polytetrafluoroethylene (PTFE) and PTFE …

Growth Kinetics And Stability Of Metal Halide Perovskite Nanocrystals: Influence Of Stirring Speed And Water Exposure, You-Lin Huang

Theses and Dissertations--Mechanical and Aerospace Engineering

Cesium lead bromide (CsPbBr₃) perovskite nanocrystals (NCs) have garnered significant interest due to their exceptional optoelectronic properties, including high photoluminescence quantum yield, tunable bandgap, and excellent carrier dynamics. These attributes make them promising candidates for applications in light-emitting diodes, photovoltaics, and sensing technologies. However, optimizing their synthesis and improving their environmental stability remain critical challenges. This dissertation explores the growth kinetics of CsPbBr₃ NCs, focusing on the effects of stirring speed and water exposure on their structural and optical properties.

The synthesis of CsPbBr₃ NCs was performed using both mechanochemical (MC) and antisolvent methods, enabling an …

Degradation Of Polymers And Polymer Composites In Extreme Environments, Ben T. Jewell

Dissertations, Master's Theses and Master's Reports

Polymeric materials are widely used in engineering applications due to their high strength-to-weight ratio, easy manufacturability, and cost-effectiveness. When incorporated into composites, they provide further performance enhancements, enabling use in demanding structural applications. However, long-term exposure to harsh environments including elevated temperatures, UV radiation, harsh chemicals, and radiation, can drive degradation processes that alter the material’s network structure, and in turn, degrade its mechanical performance. Exposure to thermo-oxidative conditions is one of the most common environments driving polymer degradation, leading to chain scission and crosslinking events, with the resulting oxidative products causing discoloration, reduced ductility, and changes in glass transition …

A Manufacturing-To-Response Pathway For Manufacturing Optimization Of Carbon Fiber Reinforced Polymer Composite Structures, Madhura Limaye

All Dissertations

Over the past decade, there has been an increased adoption of thermoplastic and thermoset based continuous carbon fiber reinforced polymer (CFRP) composites for structural applications in several industries. Among the different manufacturing methods, thermoforming process for thermoplastic based continuous CFRP’s offer a major advantage in reducing cycle times for large scale productions. Similarly, out-of-autoclave curing process for thermoset based continuous CFRP’s using heated tooling enables production of large composite structures. However, these manufacturing processes can have a significant impact on the structural performance of parts by inducing undesirable effects. These effects include inhomogeneous fiber orientations, thickness variations, and residual stresses …

Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams

All Dissertations

While Carbon Fiber Reinforced Polymers (CFRPs) have exceptional mechanical properties concerning their overall weight, their failure profile in demanding high-stress environments raises reliability concerns in structural applications. Two crucial limiting factors in CFRP reliability are low-strain material degradation and low fracture toughness. Due to CFRP’s low strain degradation characteristics, a wide variety of interlaminar damage can be sustained without any appreciable change to the physical structure itself. This damage suffered by the energy transfer from high- stress levels appears in the form of microporosity, crazes, microcracks, and delamination in the matrix material before any severe laminate damage is observed. This …

Characterization Of Mechanically Recycled Polylactic Acid (Pla) Filament For 3d-Printing By Evaluating Mechanical, Thermal, And Chemical Properties And Process Performance, Mahsa Shabani Samghabady

All Theses

Polylactic acid (PLA) is a biopolymer made from renewable resources such as sugar and corn. PLA filament is a popular material used in Fused Deposition Modeling (FDM) 3D-printing. While this material has many advantages, all the failed parts, support structures, rafts, nozzle tests, and the many prototype iterations during the 3D-printing process contribute to the plastic pollution and release of greenhouse gases. Although PLA is biodegradable, it can take years to degrade in landfills. Instead of throwing away PLA waste and buying new filaments, PLA can be recycled. Amongst the different recycling technologies, mechanical recycling is the most environmentally friendly. …

Molecular Dynamics Modeling Of Polymers For Aerospace Composites, Swapnil Sambhaji Bamane

Dissertations, Master's Theses and Master's Reports

Polymer matrix composite materials are widely used as structural materials in aerospace and aeronautical vehicles. Resin/reinforcement wetting and the effect of polymerization on the thermo-mechanical properties of the resin are key parameters in the manufacturing of aerospace composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. It is challenging to determine contact angle values experimentally of high-performance resins on CNT materials such as CNT, graphene, bundles or yarns, and BNNT surfaces. It is also experimentally difficult to determine the effect of polymerization reaction on material properties of a …

Phase-Field Modeling Of The Polymer Membrane Formation Process For Micro- And Ultra-Filtration, Michael Rosario Cervellere

Graduate Theses and Dissertations

Porous polymer membrane filters are widely used in separation and filtration process. Micro- and ultra-filtration membranes are commonly used in biopharmaceutical applications such as filtering viruses and separating proteins from a carrier solution. The formation of these membrane filters via phase inversion is a complex and interconnected process where varying casting conditions can have a wide variety of effects on the final membrane morphol- ogy. Tailoring membrane filters for specific performance characteristics is a tedious and time consuming process. The time and length scales of membrane formation make it extremely difficult to experimentally observe membrane formation. Modeling the membrane formation …

Viscoelasticity Of Ptfe-Based Face Seals, Bo Tan

Theses and Dissertations--Mechanical and Aerospace Engineering

PTFE-based materials are widely used in areas of tribology, particularly in seal and bearing applications because of their outstanding self-lubricating properties. Often in dynamic seal applications there is a need for ultra-low mechanical friction loss between the sealing surfaces. Due to its extremely low friction coefficient, there is interest in employing Polytetrafluoroethylene (PTFE) materials in such applications. One challenging aspect of employing PTFE is that these materials are viscoelastic and plastic. This dissertation concentrates on the modeling of viscoelastic material response when used as mechanical face seals with a focus on PTFE-based materials. First, the viscoelastic characteristics are measured through …

Combined Puncture And Cutting Of Soft-Coated Fabrics By A Pointed Blade: Energy, Force, And Stress Failure Criteria, Ennouri Triki, Chantal Gauvin

Études primaires

Soft elastomer-coated fabrics are widely used in engineering and protective applications. Puncture cutting by sharp-tipped objects is one of the most common failure modes of protective gloves made of coated fabrics. In order to investigate the puncture-cutting process of soft elastomer-coated fabrics, we studied the mechanisms and mechanics of pointed-blade insertion into specimens cut out from four protective gloves. Experimental and analytical analyses showed that total energy and critical puncture-cutting force calculated analytically are both able to predict the puncture-cutting resistance of soft elastomer-coated fabrics measured experimentally. Total energy is obtained from the relationship between the puncture-cutting work and the …

Practical Adhesion Measurements In Organic Coatings; Advancing Understanding And Mechanical Methods Development, Diana Gottschalk

Dissertations

“Adhesion” can be considered either a mechanical or chemical phenomenon. The mechanical interpretation describes the difficulty of separating surfaces and is useful for quantifying performance within applications that depend on bulk and interfacial properties. Chemical adhesion describes interfacial resistance to chemical attack and does not depend on bulk properties. Predicting chemical failure through mechanical measurement is confounded by the influence of bulk properties. However, the prospect is attractive because of the robust tolerance for sample geometries, allowing experiments to resemble an end-use system. The present work's primary goal was to elevate mechanical methods to provide a detailed interfacial characterization of …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Sensitivity And Uncertainty Quantification Of Continuum And Stochastic Bond Dissociation Kinetics Based Cohesive Laws, Rishabh Awasthi

Dissertations, Master's Theses and Master's Reports

Polymeric adhesives are being extensively used to develop light weight and durable Composite Materials which are have been employed in automotive, aeronautical, medical industry. Polymeric adhesives undergo failure due to relative opening sliding of bonded interfaces which requires a need to characterize the fracture mechanism. Numerous experiments are conducted to predict the fracture response for Mode-I, II,III and numerical simulations are employed to inversely calibrate the material parameters governing the constitutive laws. Cohesive zone models are largely employed in fracture mechanics to predict failure of interfaces undergoing large plastic deformations. The objective of this report is to employ the cohesive …

Multiscale Modeling Of Carbon Fibers/Graphene Nanoplatelets/Epoxy Hybrid Composites For Aerospace Applications, Hashim Al Mahmud

Dissertations, Master's Theses and Master's Reports

Significant research effort has been dedicated for decades to improve the mechanical properties of aerospace polymer-based composite materials. Lightweight epoxy-based composite materials have increasingly replaced the comparatively heavy and expensive metal alloys used in aeronautical and aerospace structural components. In particular, carbon fibers (CF)/graphene nanoplatelets (GNP)/epoxy hybrid composites can be used for this purpose owing to their high specific stiffness and strength. Therefore, this work has been completed to design, predict, and optimize the effective mechanical properties of CF/GNP/epoxy composite materials at different length scales using a multiscale modeling approach. The work-flow of modeling involves a first step of using …

Nano Fab Lab 63, Brian K. Deemer, Josh Clemons, Nick Brodine, Delaney Fitzsimmons

Mechanical Engineering

Lawrence Livermore National Laboratories (LLNL) has several steps in the production process for ceramic nanofiber tubes that they would like to improve - electrospinning, cutting, rolling, sealing and heat treating. We undertook the challenge to deliver LLNL with a semi-automated process that efficiently integrates the steps of cutting, rolling, and sealing to save time and improve control over end dimensions. In this document, we discuss the technical background of the manufacturing steps currently followed to create nanofiber tubes, identify which steps are incorporated in our prototype and explain how they will interface with one another, define the design requirements, present …

Silicone Tadpole: Research Into Soft Bodies, Danielle Fernandez

Mechanical Engineering Undergraduate Honors Theses

In this thesis, research is conducted in the area of soft robotics by building a soft tadpole that can deform with a specific air pressure. The goal is to mimic the motion of an organic tadpole in respect to its S-shaped tail movement. The angle of deformation, derived from material mechanic theories, ranges from 45 to 80 degrees for this type of movement. The design includes a head compartment which acts as a tank to transfer nitrogen pressure and a tail section that receives the said pressure and bends as a result. The tail section was designed with two rows …

Application Of Computational Tools To Spaghetti-Based Truss Bridge Design, Jin Xu, Jiliang Li, Nuri Zeytinoglu, Jinyuan Zhai

ASEE IL-IN Section Conference

Application of Computational Tools to Spaghetti-Based Truss Design

Statics and Strength of Materials are two foundational courses for Mechanical/Civil Engineering. In order to assist students in better understanding and applying concepts to a meaningful design task, SolidWorks and theoretical calculation were used for a spaghetti-bridge design contest with the constraints of given maximum weight and allowable support-material weight. As the first step of this iterative designing process, both extrude feature and structural member were introduced to model planar bridge trusses. Then SolidWorks’ Statics module was used to run FEA analysis of the structural performance in efforts to optimize the …

Microstructural Characterization Of Shear Transformation Zones And Modeling Indentation Size Effect In Amorphous Polymers, Leila Malekmotiei

LSU Doctoral Dissertations

The first aim of this work is developing a procedure for experimental and analytical characterization of nano-scale microstructures which mediate large scale deformation in amorphous polymers. Glassy polymers are extensively used as high impact resistant, low density, and clear materials in industries. Nevertheless, their response under severe loading conditions is yet to be appropriately unraveled. Due to the lack of long-range order in the microstructures of glassy solids, their plastic deformation is different from that in crystalline solids. Shear Transformation Zones (STZs) are believed to be the main plasticity carriers in amorphous solids and defined as the localized atomic or …

Phase Transitions In Monochalcogenide Monolayers, Mehrshad Mehboudi

Graduate Theses and Dissertations

Since discovery of graphene in 2004 as a truly one-atom-thick material with extraordinary mechanical and electronic properties, researchers successfully predicted and synthesized many other two-dimensional materials such as transition metal dichalcogenides (TMDCs) and monochalcogenide monolayers (MMs). Graphene has a non-degenerate structural ground state that is key to its stability at room temperature. However, group IV monochalcogenides such as monolayers of SnSe, and GeSe have a fourfold degenerate ground state. This degeneracy in ground state can lead to structural instability, disorder, and phase transition in finite temperature. The energy that is required to overcome from one degenerate ground state to another …

Design And Analysis Of A 3d-Printed, Thermoplastic Elastomer (Tpe) Spring Element For Use In Corrective Hand Orthotics, Kevin Thomas Richardson

Theses and Dissertations--Mechanical and Aerospace Engineering

This thesis proposes an algorithm that determine the geometry of 3D-printed, custom-designed spring element bands made of thermoplastic elastomer (TPE) for use in a wearable orthotic device to aid in the physical therapy of a human hand exhibiting spasticity after stroke. Each finger of the hand is modeled as a mechanical system consisting of a triple-rod pendulum with nonlinear stiffness at each joint and forces applied at the attachment point of each flexor muscle. The system is assumed quasi-static, which leads to a torque balance between the flexor tendons in the hand, joint stiffness and the design force applied to …

Usa Boccia Ball Ramp For Athletes With Quadriplegia, Alissa A. Koukourikos, Matthew Lee, Nathan Bernards

Mechanical Engineering

In this report, the design process in creating an assistive device for Boccia Classification 3 (BC3) players is outlined. The initial research steps, including research into the rules of the game, capabilities of the players, and existing products is documented to show where ideas for the product stemmed from. This transitions into requirements that the sponsor requested, and preliminary designs and ideas for the product. Finally, this report explains the details of the final design, which has been analyzed for safety, ease of use, and ability to function under different conditions. The processes of manufacturing and testing will also be …

A Study In The Use Of Elastic Materials In Expandable Containment Units, Andrew J. Eisenman, Joby Anthony Iii, David Satagaj

Montview Journal of Research & Scholarship

The rigidity of materials in conjunction with the aspect of elasticity has been a concern of modern technologies and construction in recent centuries because of the advantages that expandable storage would bring to the fields of containment units with respect to population growth and space exploration. The world population is currently growing at an exponential rate, and as our population grows, the more important it will become to have containment units that can both contain large volumes of material as well as minuscule amounts of material without wasting space. In order accomplish this, we will need a new type of …

Negahban Group Report: Saw-Tooth Shear Response Of Aged Poly(Methyl Methacrylate) (Pmma), Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

Results for isothermal saw-tooth shear loading experiments conducted on annealed and oven-cooled poly(methyl methacrylate) (PMMA) at temperatures between 50^oC and 140^oC. The experiments were conducted 1996.

The Limits & Effects Of Draw On Properties And Morphology Of Pan-Based Precursor And The Resultant Carbon Fibers, Sarah Edrington

Theses and Dissertations--Mechanical and Aerospace Engineering

The process, structure, and property relationship of PAN fiber as a precursor to carbon fiber was studied. The limitations of stable spinning and property improvement associated with hot draw in solution spinning were found and quantified. Conditions were varied to generated precursor fiber up to the limit of draw, from which actual samples were collected for thermal conversion to carbon fiber. Samples of PAN and subsequent carbon fiber were characterized using tensile testing and x-ray analysis. The effects of draw on modulus and break stress, as well as the orientation of the crystalline structure of both parent precursor and resultant …

Crack Growth Behavior Under Creep-Fatigue Conditions Using Compact And Double Edge Notch Tension-Compression Specimens, Santosh B. Narasimha Chary

Graduate Theses and Dissertations

The American Society for Testing and Materials (ASTM) has recently developed a new standard for creep-fatigue crack growth testing, E 2760-10, that supports testing compact specimens, C(T), under load controlled conditions. C(T) specimens are commonly used for fatigue and creep-fatigue crack growth testing under constant-load-amplitude conditions. The use of these specimens is limited to positive load ratios. They are also limited in the amount of crack growth data that can be developed at high stress intensity values due to accumulation of plastic and/or creep strains leading to ratcheting in the specimen. Testing under displacement control can potentially address these shortcomings …

Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason Gerald Vogeler

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …

Design And Fundamental Understanding Of Minimum Quantity Lubrication (Mql) Assisted Grinding Using Advanced Nanolubricants, Parash Kalita

Graduate Theses and Dissertations

Abrasive grinding is widely used across manufacturing industry for finishing parts and components requiring smooth superficial textures and precise dimensional tolerances and accuracy. Unlike any other machining operations, the complex thermo-mechanical processes during grinding produce excessive friction-induced energy consumption, heat, and intense contact seizures. Lubrication and cooling from grinding fluids is crucial in minimizing the deleterious effects of friction and heat to maximize the output part quality and process efficiency. The conventional flood grinding approach of an uneconomical application of large quantities of chemically active fluids has been found ineffective to provide sufficient lubrication and produces waste streams and pollutants …