Other Materials Science and Engineering Commons^™

Fabrication & Characterization Of Hybrid Piezoelectric/Triboelectric Nanocomposite Nanogenerators Via Fusion Deposition Modeling, Khaled El Toukhy

Theses and Dissertations

This thesis aims to discuss the potential of using piezoelectric and triboelectric nanogenerators (PTENGs) for energy harvesting, particularly in the sportswear industry. PTENG's main advantage is that it offers good flexibility making it suitable for high-strain applications. The piezoelectric effect is induced by embedding piezoelectric nanofillers into one of the two triboelectric layers. PTENGs can generate both piezoelectric and triboelectric signals when strained resulting in an enhanced output compared to regular piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs). TPU was adopted as the matrix for PTENGs advantageous due to their flexibility, low electrical resistivity, and compatibility with additive manufacturing techniques. …

Application Of Quantum Algorithms In The Synthesis Of Dynamic Objects, Noilakhon Yakubova

Chemical Technology, Control and Management

Around the world, the food industry is focusing on achieving energy and resource efficiency. One of the main challenges in the field of process automation is the creation of effective control systems using intelligent technologies to improve the quality of processes and achieve the production of high-quality products with less energy and resources. Therefore, it is necessary to work with a large amount of data. Particular attention is paid to the development of computational algorithms for automated high-speed computational analysis systems for processing this data at high speed. Therefore, the article discusses the use of quantum computing methods in controlling …

Thermally Rearranging Polyimide Networks For High-Temperature Applications, William Guzman

Dissertations

High-performance polymers can retain functional properties when exposed to long-term or short-term durations of harsh conditions, such as mechanical action, at elevated temperatures (>177 °C). A mixture of intramolecular and intermolecular forces of and between polymer chains provide excellent property retention at elevated temperatures. Specifically, the highly aromatic nature of high-performance polymer backbones provides outstanding thermal stability, which is typically attributed to π-π stacking. However, the interrelationship between thermal stability and high aromaticity creates a challenging structure-processing relationship paradigm, which causes poor polymer processability in most high-performance polymers. Herein, it was demonstrated that rationally designing a crosslinking phenylethynyl imide …

Evaluation Of The Long-Term Performance Of Ogfc In South Carolina, Rishiraj Brahmbhatt

All Theses

Since the 1970s, South Carolina has employed open graded friction courses (OGFC) on high-speed asphalt roadways to enhance wet weather safety. While these mixes have indeed enhanced safety, they still grapple with durability issues, particularly concerning raveling. This research aimed to assess the prolonged performance of OGFC pavements in South Carolina, with a specific emphasis on isolated raveling occurrences. In 2012, the South Carolina Department of Transportation (SCDOT), constructed the first Warm Mix OGFC test section in South Carolina on I-20 Eastbound in Kershaw County, spanning 3.9 miles, using the Evotherm additive and excluding fibers. Following the success of this …

Temperature Gradient Effect On Solid-Liqid Interface Properties Of Al-Cu Alloy: A Molecular Dynamics Study, Prashant Kumar Jha

All Theses

Aluminum-copper (Al-Cu) alloys are widely used in the aerospace industry due to their favorable strength-to-weight ratio, good fatigue resistance, and corrosion resistance. These properties make Al-Cu alloys an excellent choice for aircraft structural components that require high strength and low weight. Additive manufacturing (AM), also known as 3D printing, has emerged as a promising processing method for Al-Cu alloys in aerospace manufacturing. AM enables the production of lightweight optimized geometries difficult to manufacture through conventional subtractive methods. AM also reduces material waste by only depositing material where needed in the part geometry. The rapid solidification conditions in AM processes motivate …

Advancing Additive Manufacturing For Biomedical Applications: Antimicrobial And X-Ray Absorptive Composite Filaments For Fused Filament Fabrication, John M. Arnold Jr

LSU New Orleans Theses and Dissertations

The objective of this research was to investigate the use of nano- and microparticle amendments for the creation of Poly-lactic Acid composite materials for use in biomedical applications using the Fused Filament Fabrication process of Additive Manufacturing. Composites were created with the goal of imparting the useful properties of antimicrobial activity and x-ray absorption to the material. In addition to testing the efficacy of the particle amendments in achieving the desired properties, the thermal and mechanical properties of the composite materials were tested to ensure that the composites would be compatible with the Fused Filament Fabrication process and would produce …

Design And Characterization Of A Novel Eef2k Degrader With Potent Therapeutic Efficacy Against Triple-Negative Breast Cancer, Changxin Zhong, Rongfeng Zhu, Ting Jiang, Sheng Tian, Xiaobao Zhao, Xiaoya Wan, Shilong Jiang, Zonglin Chen, Rong Gong, Linhao He, Jin-Ming Yang, Na Ye, Yan Cheng

Markey Cancer Center Faculty Publications

Dysregulated eEF2K expression is implicated in the pathogenesis of many human cancers, including triple-negative breast cancer (TNBC), making it a plausible therapeutic target. However, specific eEF2K inhibitors with potent anti-cancer activity have not been available so far. Targeted protein degradation has emerged as a new strategy for drug discovery. In this study, a novel small molecule chemical is designed and synthesized, named as compound C1, which shows potent activity in degrading eEF2K. C1 selectively binds to F8, L10, R144, C146, E229, and Y236 of the eEF2K protein and promotes its proteasomal degradation by increasing the interaction between eEF2K and the …

Material World, Nicole Weldy

All Theses

My thesis, Material World, delves into the use of the crochet unit as a construction technique for building forms. Through this, I aim to organize different materials in a way that responds to the challenges posed by the physical world. My artistic process is centered around honoring the inherent qualities of thread and uses these qualities to create form, lightness, and linearity. At the same time, I remain receptive to transformative processes such as combining three-dimensional (3D) printed lines and lace stiffener to push the boundaries of what thread can do. By combining manual craftsmanship with technology materialized as …

Thermo-Mechanical Instabilities In Next-Generation Friction Materials In High-Speed Sliding Systems, Kingsford Koranteng

Electronic Theses and Dissertations

For centuries, the manufacturing industry has incorporated metals like copper into friction materials to enhance thermal properties and minimize thermo-mechanical instabilities (TMI) in high-speed sliding systems. Unfortunately, these metals have adverse environmental effects due to the emission of hazardous particulate matter. As a result, there is a growing movement towards adopting next-generation friction materials as an alternative solution.

The study begins by conducting experimental and numerical investigations to examine the instabilities found in metal-based friction materials. The primary objective is to utilize the insights gained from the investigations to computationally explore effective strategies for mitigating various instabilities that may arise …

Molecular Dynamics Study Of Characterization In Metal-Free Friction Materials, Yizhan Zhang

Electronic Theses and Dissertations

Metallic friction materials currently used in industry may adversely impact the environment. Substitutions for metals in friction materials, on the other hand, can introduce operational safety issues and other unforeseeable issues such as thermal-mechanical instabilities and insufficient strength. In view of it, this dissertation focuses on developing different kinds of materials from simple structure to complex structure and evaluating the material properties with the assistance of molecular dynamics (MD) tools at the nano scale.

First, the concept of the contacted surfaces in friction at the atomic scale was introduced in order to get accurate understanding of the friction process compared …

Novel Castor Oil/Water/Ethanol Pickering Emulsions Stabilized By Magnetic Nanoparticles And Magnetically Controllable Demulsification, Mohammad J. Hasan, Peng Chen, Neithan Dominick, Erick S. Vasquez, Esteban E. Ureña-Benavides

Chemical and Materials Engineering Faculty Publications

A novel castor oil/water/ethanol Pickering emulsion, stabilized by magnetic nanoparticles (NPs), was developed to allow on-demand demulsification by an external magnetic field for the extraction of ethanol from aqueous solution using the castor oil. The emulsion was stabilized by Fe3O4-coated cellulose nanocrystals (CNC@Fe3O4) and lignin-coated Fe3O4 NPs (lignin@Fe3O4). The stability of the emulsions was investigated at various castor oil to ethanol-water ratios (50/50 and 70/30), various NP concentrations, and ethanol concentrations in the aqueous phase. The magnetically controlled demulsification ability of the emulsions was investigated by using a permanent magnet. The results showed that the 70/30 emulsions were more stable …

Corrosion Case Study On Pipeline, Kangze Ren

Corrosion Research

The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.

Machine Learning Prediction Of Hea Properties, Nicholas J. Beaver, Nathaniel Melisso, Travis Murphy

College of Engineering Summer Undergraduate Research Program

High-entropy alloys (HEA) are a very new development in the field of metallurgical materials. They are made up of multiple principle atoms unlike traditional alloys, which contributes to their high configurational entropy. The microstructure and properties of HEAs are are not well predicted with the models developed for more common engineering alloys, and there is not enough data available on HEAs to fully represent the complex behavior of these alloys. To that end, we explore how the use of machine learning models can be used to model the complex, high dimensional behavior in the HEA composition space. Based on our …

Optimizing Mn-Al Permanent Magnet Performance Through Control Of The Phase Transformation, Ternary Element Addition, And Advanced Processing, Thomas R. Keller

Dartmouth College Ph.D Dissertations

The growing need for electrical power in machines and vehicles brings with it a growing need for critical materials. The current high-performance permanent magnets (PMs) based on rare-earth (RE) elements Nd and Sm cannot escape the problem of raw material cost, geographic scarcity in the earth’s crust, and lack of circular global supply chains. This poses a problem of industrial ecology: can PMs be made from inexpensive, more abundant materials while still meeting sufficient performance criteria? PMs based on the magnetic τ phase of Mn-Al offer a possible alternative to REPMs. However, years of innovation have not yet achieved real-world …

Preparation Of High Entropy Titanite Pyrochlore And Radiation Stability Study, Adam Gootgeld

All Theses

Pyrochlore has been studied as a host phase for safe storage of radionuclides and exists naturally with long-term stability with good long-range order [1]. High entropy oxides show promising tunable properties that could demonstrate favorable bulk deposit of radioactive materials such as spent nuclear fuel (Uranium and other actinides). It is proposed that using high entropy oxides (HEOs) as the cation in this framework will shift the gibbs free energy so that radioactive nuclear waste will be stabilized for safe, long-term, eco-friendly storage. We have established a consistent method to fabricate high entropy titanite pyrochlores. In this study, ion beam …

Carbon Fibers From Athabasca Oil-Sand Asphaltenes, Blake Reardon

All Theses

Carbon fibers possess ultra-high specific strength and modulus. Therefore, the material is popular in aerospace, automotive, and sports industries. Approximately 95% of all carbon fibers are spun from a high-cost precursor, polyacrylonitrile (PAN). There is a need for a cheaper grade of carbon fiber for low-cost applications because about half of carbon fiber cost is associated with precursor cost. A promising alternative to the high-cost PAN precursor is petroleum-based asphaltene. Asphaltenes are highly aromatic and have a high carbon content but lack the purity of the PAN precursor. Processes like the molten- sodium desulfurization upgrading have been used to harvest …

Optimization Of Alti Pld Coating By Increasing Ti Content, N2 And Annealing Which Used For Skd61 Pins In Aluminum Die Casting, Rusman Kosasih, Maria Margaretha Suliyanti Prof, Dedi Priadi, Wisnu Usni

Journal of Materials Exploration and Findings

The Alumunium Titanium Nitrogen (AlTiN) coating is known as one of the best coating materials for protective coating, while Pulsed Laser Deposition (PLD) is a laser coating process used for electric layer and superconductor applications, producing thin films up to 20 µm in thickness. The combination of these two matters has already been researched and is still in progress. One major challenge in the aluminium casting industry is to minimize the damage caused to tool steel pins made from SKD61, when aluminium material sticks to the pin, and halting production. Therefore, research on effective coatings for tool steels and testing …

Mechanical And Durability Properties Of Fly Ash Geopolymer Concrete – A Review, Ali Shebli, Jamal Khatib, Adel Elkordi

BAU Journal - Science and Technology

Geopolymers have emerged as a promising alternative for Ordinary portland cement (OPC) in construction industry, due to their potential to minimize the emissions of carbon dioxide (CO₂) and improve the efficiency of waste recycling. This paper aims to study the fresh and hardened properties of fly ash geopolymer concrete (GPC), as well as to review the raw materials used in the production of geopolymers. Several factors impact the mechanical and durability properties of fly ash GPC, including the specific type of fly ash utilized, the curing temperature, the alkaline activator (AA) concentration, and the type of AA used. …

The Modernization Of Large Power Transformer Tanks, Babajide O. Williams

Electronic Theses and Dissertations

Due to the current demands placed on the power grid in terms of climate change, increasing urbanization, and terrorist attacks, the U.S. government in response to these demands, mandated that all the grid components be modernized in order to increase their reliability. As a critical component of the grid, Large Power Transformers (LPTs) play a key role in ensuring sustainable power generation and distribution. A literature search performed in this work and the analysis of data retrieved from the search showed that the tanks of these LPTs are critical to their durability, longevity, and reliability. Therefore, the reliability of LPTs …

Interlaminar Tensile Properties Of Unidirectional And Woven Carbon Fiber Reinforced Toughened Epoxy Laminates, Eric Timothy Casey, Sean Mckalip Thompson

Materials Engineering

This project aims to develop a dataset on interlaminar tensile strength comparing unidirectional and woven thermoset matrix carbon fiber composites keeping ply count, matrix material, and fiber diameter constant. The interlaminar tensile strength is an important property relating to the delamination failure mode. Interlaminar tensile strength is determined using the ASTM D6415 testing standard. This test is a modified four-point bend test using a 90° curved beam test specimen. Laminates were produced by laying up pre-impregnated carbon fiber sheets onto a curved beam tooling. The unidirectional laminate was produced with 20 plies in a [0,0,90,0,0]₄ layup pattern. The woven …

Exploring The Potential Of Pavegen’S Kinetic Energy Generating Floor For Sustainable Energy Solutions: A Proposal For Cal Poly Slo, Brandon J. Cuneo

Construction Management

This paper proposes the installation of Pavegen's kinetic energy generating floors at Cal Poly’s campus as a sustainable energy solution. Pavegen has developed a pioneering technology that converts footsteps into clean and renewable energy. The versatility of these floors is demonstrated through successful implementations in various settings, such as transportation hubs and public spaces, generating power from foot traffic. Collaborations with Schneider Electric, installation at Dupont Circle, and integration at Heathrow Airport showcase the potential for sustainable urban infrastructure. This paper outlines research conducted on Pavegen and similar solutions, including communication with company representatives and examining proposed installation locations at …

3d Printed Aircraft, Matthew Nagy, Charles D'Amico, Alexis Salgado Medina

Mechanical Engineering

This project is to design, build, and test a 3D-printable aircraft. The goal is to create a final design that will be able to fly for the longest duration possible, around 20 seconds. To determine the correct preliminary design and manufacturing process for a 3D printed RC aircraft, an analysis of multiple design options and manufacturing materials was performed. This allowed for a variety of choices for aircraft type, airfoil design, structure, among other topics to be narrowed down to the most promising option. It has been found that the aircraft will follow a design similar to industry motor-gliders, with …

Effective Nanomembranes From Chitosan/Pva Blend Decorated Graphene Oxide With Gum Rosin And Silver Nanoparticles For Removal Of Heavy Metals And Microbes From Water Resources, Mohamed Morsy

Nanotechnology Research Centre

No abstract provided.

Synthesis And Characterization Of Sodium Cathode Materials, He Zhou

McKelvey School of Engineering Graduate Student Theses & Dissertations

As sodium batteries hold great promise as a next-generation energy storage device to replace lithium batteries, the development of sodium battery materials has become increasingly urgent. The current study aims to investigate two potential sodium-ion battery cathode materials, Sodium Vanadium Phosphate, and Sodium Manganese Hexacyanoferrate, optimize the experimental procedures, conduct a systematic analysis of material properties and characterization, and ultimately determine the ideal synthesis conditions for these materials.

In the first part of the study, we focused on optimizing the synthesis of Sodium Vanadium Phosphate. By investigating various synthesis conditions, such as annealing temperature, pressure, ascorbic acid content, and material …

Exploring Methods For Recycling Filament Waste In 3d Printing, Max Rios Carballo

Publications and Research

The goal of the current study is to investigate cutting-edge techniques for recycling filament waste from 3D printing procedures. Appropriate waste management techniques are required to reduce this trash's harmful environmental consequences. The goal of the project is to look at new methods for recycling filament waste in order to minimize disposal and encourage reuse. To acquire data from pertinent papers and research, a thorough literature review methodology was used. The findings show that this issue may be resolved utilizing a variety of recycling techniques, including shredding, melting, and re-extrusion. The type of filament waste and the intended goal will …

Utilization Of Machine Learning To Investigate Material State, Ana B. Abadie

Honors College Theses

The ability to predict material behavior that undergoes various loading conditions is critical to the development of reliable and safe components. Thermal and mechanical fatigue loading can cause significant damage to materials, leading to failure and potential safety hazards. Machine learning algorithms have emerged as a promising tool for improving accuracy and efficiency of predicting material behavior under such loading conditions. This research provides a comprehensive overview of a machine learning algorithm that is able to analyze and predict material state independently of the loading sequence. Unidirectional carbon fiber reinforced polymer (UD CFRP) composite which has undergone two different loading …

Development Of Dynamic Risk-Based Inspection Using Forward Difference Approach For Pipe Failure Due To Uniform Corrosion, Jaka Fajar Fatriansyah, Zahra Nadia Nurullia, Andreas Federico, Dedi Priadi

Journal of Materials Exploration and Findings

The oil and gas industry is one of the world's largest and most influential energy contributors. All aspects involved in the operation of this industry are fundamental to be reviewed and managed correctly, especially by preventing or minimizing the failures that could occur. Uniform corrosion is the most common component failure mechanism that can cause failure in the oil and gas industry. The company's actions in managing and preventing the risk of this type of failure have a major role in the sustainability of the company due to the possibility of more significant impacts if the risk cannot be handled …

Optimization Of Porosity In Cold Spray Produced Copper And Zinc Coatings, Cameron Hughes

Graduate Theses & Non-Theses

Since its invention in 1981, the cold spray (CS) additive manufacturing (AM) process has been studied and optimized to produce well-adhered, dense material coatings. CS can operate at a wide range of temperatures if the feed material remains in a solid state. Copper and zinc were studied to characterize and understand the effects of heating element voltage, travel speed, and standoff distance on deposit porosity, grain size, microhardness, and coating thickness. Samples were sprayed on 3.2 mm x 25 mm x 150 mm 6061 aluminum substrates. Sections were taken from the middle of the samples to represent steady-state conditions. Sample …

High-Pressure Slurry Ablation For Improving Separation Of Copper/Molybdenum And Flotation Of Gold Tailings, Mitchell Harvey

Graduate Theses & Non-Theses

Disa Technologies’ High-Pressure Slurry Ablation (HPSA) is a patented particle attrition technology for the comminution and selective liberation of minerals. Two slurry streams are pumped at high pressure through opposing nozzles and collisions between solid particles suspended in the slurry streams cause breakage of the feed material. HPSA was evaluated for improving the rougher flotation of molybdenite from Cu-Mo bulk concentrate and gold-bearing pyrite from gold tailings.

Copper/molybdenum samples were provided by Montana Resources in Butte, Montana. A two-factor factorial design of experiments was used to identify HPSA operating conditions which gave the highest increase in flotation performance. Variables were …

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …