Other Materials Science and Engineering Commons^™

Simulation And Fabrication Of All Oxide-Based Ito/Tio2/Cuo/Au Heterostructure For Solar Cell Applications, Sajal Islam

Graduate Theses/Dissertations

Oxide heterostructures have drawn great attention lately, due to their environment-friendly properties and potential applications in optoelectronic devices. In this work, a simulation study of a heterojunction solar cell was performed with SCAPS (a solar cell simulator) using TiO2 as an n-type and CuO as a p-type layer. The thickness and the dopant-dependent simulations have shown that the solar cell operates at a maximum efficiency of 19.2% when the thickness of the TiO2/CuO layers is chosen 1.4µm/1.2µm compared to the 11.5% efficiency when FTO is replaced with ITO. An indium-doped tin oxide (ITO) vs fluorine-doped tin oxide (FTO) comparison study …

Growth, Characterization, And Mechanical Testing Of Diamond-Like Carbon Films, Tailei Qi

LSU Master's Theses

The high residual stresses within diamond-like carbon (DLC) films limit its thickness and make the film tend to delaminate from the substrate and be defective on the surface. To address this problem, a new plasma enhanced chemical vapor deposition system (PECVD) was set up to investigate the effects of different film growth parameters on the DLC films, such as chromium doping, gas fluxes, depositing pressures, bias voltages, and depositing times. After the film growth parameters were optimized, this condition was transferred from silicon wafer to SS316 steel plate to deposition of DLC films with some adjustments. Scanning electron microscopy (SEM) …

Entrepreneurially Minded Learning In The Unit Operations Laboratory Through Community Engagement In A Blended Teaching Environment, Erick S. Vasquez, Kelly Bohrer, Abraham Noe-Hays, Arthur Davis, Matthew Dewitt, Michael J. Elsass

Chemical and Materials Engineering Faculty Publications

Online and blended learning opportunities in Chemical Engineering curriculum emerged due to COVID-19. After eight weeks of in-person Unit Operations Laboratory sessions, a remote-learning open-ended final project was assigned to student teams. The assignment involved aspects related to entrepreneurial-minded learning (EML) and community-based learning (CBL). Results show correlations between self-directed learning and the EML framework. Continuous support and involvement of a community partner correlate to students' m

Biodegradable Nanocomposite Multifunctional Packaging Film For Fruits, Kalpani Y. Perera, Shubham Sharma, Dileswar Pradhan, Amit Jaiswal, Swarna Jaiswal

Articles

Biopolymers have been used in food packaging in recent years due to high pollution rates and decreased biodegradation of synthetic polymers. Chitosan (CH) and Sodium alginate (SA) are both biodegradable biopolymers with excellent film forming capability. TiO2 nanoparticles have high mechanical strength, degradation ability and antimicrobial properties, which are beneficial in food packaging. The aim of the current work is to develop the biodegradable multifunctional nanocomposite film for fruit (i.e., Pear) packaging applications. Bionanocomposite film was prepared by solvent casting method using CH-SA and various concentrations of TiO2. The multifunctional properties such as UV barrier, thermal, water retention, mechanical, chemical, …

Atomistic Simulation Of Desalination, Ian David Durr

Symposium of Student Scholars

Atomistic Simulation of Desalination

Ian Durr, Matheus Prates, and Jungkyu Park

Kennesaw State University

In this research, we investigate the desalination capacity of three-dimensional (3D) carbon nanostructures using molecular dynamics simulations. 3D carbon nanostructures proposed here will filter seawater efficiently because of their multiple layers with holes of tunable sizes. The structure is designed to be flexible, allowing mechanical deformation during daily use. The 3D carbon nanostructure will still possess high thermal conductivity, enabling easy recycle through a simple heating process. Here, we employ LAMMPS, Large-scale Atomic/MolecularMassively Parallel Simulator distributed by Sandia National Laboratories to measure salt ion flux through …

Engineering The Surface Of Fe3o4 Nanoparticles For Catalytic And Magnetic Applications, Natalia Da Silva Moura

LSU Doctoral Dissertations

With the rapid depletion of the U.S. energy resources coupled with population growth, heat management technologies must be improved to sustain our quality of life. Precisely, in catalysis, it is estimated that only ~50% of the energy supplied to the reactor is used for product conversion due to dissipation losses. Among the emerging technologies with a promising reduction in heat losses is induction heating, offering targeted heat delivery with magnetic nanoparticles. Under alternating magnetic fields (AMF), these nanoparticles can absorb the energy from Radio-Frequency (RF) fields and dissipate it as heat on the nanoparticle surface. This in situ heat generation …

Analytical Model For Electromagnetic Induction In Pulsating Ferrofluid Pipe Flows, Huiyu Wang, John G. Monroe, Swati Kumari, Serhiy O. Leontsev, Erick S. Vasquez, Scott M. Thompson, Matthew J. Berg, Dibbon Keith Walters, Keisha B. Walters

Chemical and Materials Engineering Faculty Publications

No abstract provided.

Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts, Md Ashraful Abedin

LSU Doctoral Dissertations

One of the most challenging aspects of modern-day catalysis is the conversion of methane. Direct conversion of methane via dehydroaromatization (MDHA) is a well-known process which can produce valuable hydrocarbons. Mo oxide supported on ZSM-5/MCM-22 has been studied extensively in recent years for MDHA. Mo carbides are responsible for activating methane by forming CHx species. These are dimerized into C2Hy and oligomerized on ZSM-5/MCM-22 Brønsted acid sites to form aromatics. Sulfated zirconia (SZ) supported Mo catalyst contains the acid sites necessary to produce benzene in MDHA. Here, sulfated hafnia (SH), a homologous oxide like SZ, has been proposed to provide …

Mixed Metal Oxide Nanowires Via Solid State Alloying., Veerendra Atla

Electronic Theses and Dissertations

Mixed metal oxide materials with composition control find applications in energy conversion and storage processes such as heterogenous catalysis, photoelectrochemical catalysis, electrocatalysis, thermal catalysis, and lithium-ion batteries. Mixed metal oxides and/or complex oxides with composition control and in one-dimensional form as nanowires could be interesting to various catalysis applications due to control on single crystal surfaces, active sites, acidity versus basicity site density, and oxygen vacancies. The major challenge is to synthesize mixed metal oxide nanowires beyond binary oxides with composition control. In this dissertation, solid state alloying of binary oxide nanowires with solid and liquid precursors is studied to …

Degumming Of Hemp Fibers Using Combined Microwave Energy And Deep Eutectic Solvent, Bulbul Ahmed

LSU Master's Theses

Hemp is considered as one of the sustainable agricultural fiber materials. Degumming or surface modification of hemp bast is needed to produce single fibers for ensuing textile and industrial applications. The traditional degumming process necessitates a high amount of alkali, which causes detrimental environmental pollution. This study offers a new method to degum hemp fibers with reduced use of harmful alkali and precious water resources. In this work, hemp bast fibers were degummed by using combined microwave energy and deep eutectic solvent (DES). The properties of hemp fibers manufactured by this method were investigated and compared with the traditional alkali …

Optimization Of 3d Printed Mold Performance For Injection Molding Via Hollow Infill Patterns, Alan Fong

University Honors Theses

The applicability of hollow infill patterns has been explored for its applications in making 3D printed polymer-based injection molds in the additive manufacturing industry. Hollow infill patterns offer a significant reduction in material costs as well as the opportunity for reducing the cooling times via pumping a coolant fluid through the hollow cavity in a similar fashion to traditional conformal cooling channels. A 3D Jacks Support Hollow mold model was determined to be the best performing design. FEA analysis was conducted to determine the maximum reduction in internal volume (percentage of material saved) that could be achieved without exceeding the …

Facile Fabrication And Characterization Of Kraft Lignin@Fe3o4 Nanocomposites Using Ph Driven Precipitation: Effects On Increasing Lignin Content, Frankie A. Petrie, Justin M. Gorham, Robert T. Busch, Serhiy O. Leontsev, Esteban E. Ureña-Benavides, Erick S. Vasquez

Chemical and Materials Engineering Faculty Publications

This work offers a facile fabrication method for lignin nanocomposites through the assembly of kraft lignin onto magnetic nanoparticles (Fe3O4) based on pH-driven precipitation, without needing organic solvents or lignin functionalization. Kraft lignin@Fe3O4 multicore nanocomposites fabrication proceeded using a simple, pH-driven precipitation technique. An alkaline solution for kraft lignin (pH 12) was rapidly injected into an aqueous-based Fe3O4 nanoparticle colloidal suspension (pH 7) under constant mixing conditions, allowing the fabrication of lignin magnetic nanocomposites. The effects of increasing lignin to initial Fe3O4 mass content (g/g), increasing in ratio from 1:1 to 20:1, are discussed with a complete chemical, structural, and …

Atomistic Thermo-Mechanical Description Of The Deformation Behavior, Scaling Laws, And Constitutive Modeling Of Nanoporous Gold, Mohammed Hassan Yousef Saffarini

LSU Doctoral Dissertations

Metallic foams, or nanoporous (NP) metals as it is widely referred to in literature, with ligament sizes up to a few tens of nm show exceptional mechanical properties such as high strength and stiffness per weight ratio under different loading scenarios due to their high surface area to solid volume ratio. Therefore, they can be utilized in a wide range of applications making them of great interest to researchers. While their elasticity and yield strength have been the subject of several studies, very limited attention was given to the effect of size, strain rate, and temperature on the material plastic …

Experimental Investigation Of The Performance Of A Hybrid Self-Healing System In Porous Asphalt Under Fatigue Loadings, Shi Xu, Liu Xueyan, Amir Tabakovic, Erik Schlangen

Articles

Self-healing asphalt, which is designed to achieve autonomic damage repair in asphalt pavement, offers a great life-extension prospect and therefore not only reduces pavement maintenance costs but also saves energy and reduces CO2 emissions. The combined asphalt self-healing system, incorporating both encapsulated rejuvenator and induction heating, can heal cracks with melted binder and aged binder rejuvenation, and the synergistic effect of the two technologies shows significant advantages in healing efficiency over the single self-healing method. This study explores the fatigue life extension prospect of the combined healing system in porous asphalt. To this aim, porous asphalt (PA) test specimens with …

Novel And Fast Peridynamic Models For Material Degradation And Failure, Siavash Jafarzadeh

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Fracture is one of the main mechanisms of structural failure. Corroded surfaces with chemically-induced damage are, notably, potential sites for crack initiation and propagation in metals, which can lead to catastrophic failure of structures. Despite some progress in simulating fracture and damage using classical models, realistic prediction of complex damage progression and failure has been out of reach for many decades. Peridynamics (PD), a nonlocal theory introduced in 2000, opened up new avenues in modeling material degradation and failure. Existing numerical methods used to discretize PD equations, however, are quite expensive as the PD nonlocal interactions make them unaffordable for …

Life Cycle Assessment Of An Ifixit Pro Tech Toolkit, Camden N. Webb, Dylan A. Ell

Materials Engineering

A life cycle assessment of an iFixit Pro Tech Toolkit was performed to determine the environmental impacts of iFixit’s best-selling toolkit. SimaPro software was used to measure three impact categories: energy usage, water consumption, and global warming potential. This project provides quantitative data on the resources required for repairing devices through use of the toolkit to ultimately reduce the global e-waste stream by re-using electronics. Using the cut-off method, global warming potential of the kit was 4.1 kg of CO₂ equivalents, water consumption was 1.5 m³, and energy usage was 73.9 MJ. Major contributors to these impact …

Dental Cement Thickening Agents For Mudslide Prevention, Kristina Emiliya Babayev, Emily Elizabeth Johnson, Diana Evet Reihaneh

Materials Engineering

The purpose of this project is to develop a non-toxic mud thickening agent for the application of decreasing mudslide intensity where performance is measured by flow rate, viscosity, and toxicity tests. We hypothesized that dental cements could be a potential candidate due to their adhesive, hydrophilic, and biocompatible properties. Zinc phosphate, glass ionomer, and polycarboxylate cement were among the dental cements tested. These tests were performed at low and high concentrations of 25 grams and 125 grams, respectively, mixed into soil to produce 3500 gram samples. The dental cements produced noticeable thickening effects in the mud, as the average viscosity …

Effect Of Dissolved Oxygen On Corrosion Of Carbon And 13cr Steel In A Brine Environment, Kevin Peter Iu, Andy Zhou

Materials Engineering

Oxygen corrosion is a major threat to seawater injection systems that are part of offshore drilling operations. Seawater is typically deoxygenated to an industry standard of(DO) by injection through a deaeration column followed by treatment with oxygen scavenging chemicals. Commercial simulation software like OLI Studio: Corrosion Analyzer predicts high corrosion rates when injection seawater contains high DO levels, justifying deoxygenation. However, a notable lack of experimental data exists concerning the effect of varying levels of dissolved oxygen on corrosion rate. The goal of this project is to measure the effect of three dissolved oxygen levels (0, 62, and 620 ppb) …

Pressure Driven Desalination Membranes: Lyotropic Liquid Crystals Containing Single Walled Carbon, Matteo A. Del Giudice, Samantha Castillo Merigold

Materials Engineering

This project presents a potential alternative desalination technique that utilizes the ion rejection properties of single walled carbon nanotubes dispersed in a lyotropic liquid crystal (LLC) matrix. Previous research has pointed to the polymerizable surfactant methacryloxy ethyl hexadecyl dimethyl ammonium bromide (C16MA) having capabilities of filtering molecular components smaller than a nanometer, when oriented in cylindrical micelles. SWCNTs were dispersed in deionized water by probe sonication and addition of surfactant cetyltrimethylammonium bromide (CTAB) due to SWCNTs’ hydrophobic properties. Membranes were produced containing 55wt% C16MA, 37wt% DI water, 0.1wt% with respect to the monomer (WRM) SWCNTs, 1.9 wt% WRM 2,2-dimethoxy-2-phenylacetophenone (photointiator), …

Sound, Material And Strength Correlation, Ryan Mcbride

Symposium of Student Scholars

With a growing amount of manufacturing utilizing 3D printing, there is a correlation between strength and material which can affect sound produced by sirens. An air raid siren that has been downloaded from Thingiverse.com spins with a 49:1 gear ratio to produce 2 tone sounds and with that large number of revolutions comes friction, and in order to create a 3D printed air raid siren, the siren must be made out of a material that can withstand high temperatures without melting and quick rotations without delaminating. There are many materials that can be printed to withstand those forces, but it …

Computational Design Of Nonlinear Stress-Strain Of Isotropic Materials, Askhad M.Polatov, Akhmat M. Ikramov, Daniyarbek Razmukhamedov

Chemical Technology, Control and Management

The article deals with the problems of numerical modeling of nonlinear physical processes of the stress-strain state of structural elements. An elastoplastic medium of a homogeneous solid material is investigated. The results of computational experiments on the study of the process of physically nonlinear deformation of isotropic elements of three-dimensional structures with a system of one- and double-periodic spherical cavities under uniaxial compression are presented. The influence and mutual influence of stress concentrators in the form of spherical cavities, vertically located two cavities and a horizontally located system of two cavities on the deformation of the structure are investigated. Numerical …

Exploration Of The Sludge Biodiesel Pathway, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater sludge is an overlooked source of fat, oil, and grease (FOG) that could be converted into biodiesel. The United States produces about 8 million tons of sludge per year. The disposal cost for this amount of sludge is about 2 billion US dollars. The widespread availability and low cost of sludge compared to other biodiesel raw materials make it an economical choice for a renewable fuel. Using sludge as a raw material can produce 25 to 30 mg per gram of fatty acid methyl ester (FAME); the main component of biodiesel. Sludge biodiesel has the potential of transforming a …

Voltage-Controlled Magnetic Anisotropy In Antiferromagnetic Mgo-Capped Mnpt Films, P. H. Chang, Wuzhang Fang, T. Ozaki, Kirill Belashchenko

Kirill Belashchenko Publications

The magnetic anisotropy in MgO-capped MnPt films and its voltage control are studied using first-principles calculations. Sharp variation of the magnetic anisotropy with film thickness, especially in the Pt-terminated film, suggests that it may be widely tuned by adjusting the film thickness. In thick films the linear voltage control coefficient is as large as 1.5 and -0.6 pJ/Vm for Pt-terminated and Mn-terminated interfaces, respectively. The combination of a widely tunable magnetic anisotropy energy and a large voltage-control coefficient suggest that MgO-capped MnPt films can serve as a versatile platform for magnetic memory and antiferromagnonic applications.

Comparison Of Tensile Properties Of Triaxial Braided Carbon Fiber Composites Made From Vacuum Assisted Resin Transfer Molding (Vartm) And Autoclave Molding, Donald A. Klosterman, Charles Browning

Chemical and Materials Engineering Faculty Publications

Triaxially braided fiber composites are increasingly being used in aerospace, ballistic, and sporting good applications due to their inherent damage tolerance, torsional stability, and cost compared to woven fabrics and unidirectional preforms. There have been numerous publications over the past 15-20 years on the mechanical properties and failure mechanisms of triaxial braided composites. However, most of these have involved panels made with autoclave curing. In the present study, braided carbon fiber composites were made using autoclave curing and vacuum assisted resin transfer molding (VARTM). The goal of the study was to compare the physical and tensile properties of quasi-isotropic panels …

Husky Hand: A Low-Cost Electro-Mechanical Prosthetic Arm For The Underprivileged, Adam Robert

Thinking Matters Symposium

A continuation of a low-cost prosthetic upper limb prototype design which was investigated in EGN 301. The prosthetic is specifically designed for the needs and requirements of under privileged individuals in the Dominican Republic with upper limb amputations. The project focuses on the creation of an open-source computer aided prosthetic hand/arm model. The design allows consumer-grade fused filament fabrication (FFF) 3-D printers to be used. The improved design allows for the integration of the PQ-12 linear actuator for grasp and finger control. This simplifies the assembly, while, also reducing the size and mass of the whole unit. Producing a low-cost …

Detection And Aggregation Of Listeria Monocytogenes Using Polyclonal Antibody Gold-Coated Magnetic Nanoshells Surface-Enhanced Raman Spectroscopy Substrates, Robert T. Busch, Farzia Karim, Yvonne Sun, H. Christopher Fry, Yuzi Liu, Chenglong Zhao, Erick S. Vasquez

Chemical and Materials Engineering Faculty Publications

Magnetic nanoshells with tailored surface chemistry can enhance bacterial detection and separation technologies. This work demonstrated a simple technique to detect, capture, and aggregate bacteria with the aid of end-functionalized polyclonal antibody gold-coated magnetic nanoshells (pAb-Lis-AuMNs) as surface-enhanced Raman spectroscopy (SERS) probes. Listeria monocytogenes were used as the pathogenic bacteria and the pAb-Lis-AuMNs, 300 nm diameter, were used as probes allowing facile magnetic separation and aggregation. An optimized covalent bioconjugation procedure between the magnetic nanoshells and the polyclonal antibody was performed at pH six via a carbodiimide crosslinking reaction. Spectroscopic and morphological characterization techniques confirmed the fabrication of stable pAb-Lis-AuMNs. …

Solid State Synthesis And Characterization Of Apatite Based Ceramic Waste Form For The Immobilization Of Radioactive Iodine, Md Imdadul Islam

LSU Doctoral Dissertations

The growing demand for nuclear power in the United States and worldwide is accountable for addressing the major concern of radioactive waste, involving the technical challenges of maintaining the nuclear fuel cycle and immobilizing high-level wastes for safe disposal in geological storage. The appropriate selection of waste forms for spent nuclear fuel such as fission products and radionuclides can be effective means for a feasible and sustainable nuclear fuel cycle. But highly volatile radionuclides such as iodine (129) are of specific concern due to its extraordinary long half-life (15.7 million years). Due to its poor solubility and high volatility at …

Fabrication And Characterization Of Electrospun Poly(Acrylonitrile-Co-Methyl Acrylate)/Lignin Nanofibers: Effects Of Lignin Type And Total Polymer Concentration, Suchitha Devadas, Saja M. Nabat Al-Ajrash, Donald A. Klosterman, Kenya A. Crosson, Garry S. Crosson, Erick S. Vasquez

Chemical and Materials Engineering Faculty Publications

Lignin macromolecules are potential precursor materials for producing electrospun nanofibers for composite applications. However, little is known about the effect of lignin type and blend ratios with synthetic polymers. This study analyzed blends of poly(acrylonitrile-co-methyl acrylate) (PAN-MA) with two types of commercially available lignin, low sulfonate (LSL) and alkali, kraft lignin (AL), in DMF solvent. The electrospinning and polymer blend solution conditions were optimized to produce thermally stable, smooth lignin-based nanofibers with total polymer content of up to 20 wt % in solution and a 50/50 blend weight ratio. Microscopy studies revealed that AL blends possess good solubility, miscibility, and …

Magnetically Induced Demulsification Of Water And Castor Oil Dispersions Stabilized By Fe3o4-Coated Cellulose Nanocrystals, Mohammad J. Hasan, Frankie A. Petrie, Ashley E. Johnson, Joshua Peltan, Meredith Gannon, Robert T. Busch, Serhiy O. Leontsev, Erick S. Vasquez, Esteban E. Ureña-Benavides

Chemical and Materials Engineering Faculty Publications

Superparamagnetic iron oxide (Fe3O4) nanoparticle (NP) coated cellulose nanocrystals (CNCs) were synthesized and used to prepare emulsions with magnetically controlled stability. Magnetite NPs were deposited onto the surface of wood pulp CNCs (WCNCs) and bacterial CNCs (BCNCs) by a one-step coprecipitation method. The effect of the CNC to Fe3O4 mass ratio (1:1, 1:2, and 1:4) was varied to optimize the colloidal, magnetic and emulsifying properties of the hybrid NPs. TEM images showed that the 1:4 ratios lead to greater coverage of Fe3O4 than lower Fe3O4 loadings (1:1, and 1:2). The CNCs and Fe3O4 appeared to interact via hydrogen bonding between …

Jcati Carbon Fiber Recycling Shredder, Benjamin Cooley

All Undergraduate Projects

Once carbon fibers are cast into a resin and used in a composite material, retrieving those fibers can be a difficult task. However, it is beneficial to recycle and reuse the fibers from old unneeded components rather than pay the cost of acquiring new ones. The Joint Center for Aerospace Technology Innovation (JCATI) carbon fiber recycling device condenses the multistep process of extracting the fibers by integrating all steps into one automated device. In the previous version of the device, the cutting blades turned the long composite strips into thin fingers but did not sever them across the width.

The …