Other Materials Science and Engineering Commons^™

Magnetic Refrigerator Device Based On La (Fexcoysi1-X-Y)13, Khushar Javed

Theses and Dissertations

Particles of Lanthanum-iron-silicide, La (Fe_xCo_ySi_1-x-y)₁₃exhibit different magnetic properties when stored in air compared to the same stored in water. The sample with a nominal composition of La(Fe0_.842Co_0.073Si_0.084)₁₃was prepared by arc-melting from elements under argon atmosphere. In recent years, there has been research conducted on different processes that could drastically reduce energy costs of cooling and replacing gas compressors with magnetocaloric materials. Magnetization measurements were carried out on this magnetocaloric material to characterize it in order to design magnetic refrigerator device based on it. The …

Displacement Damage Effects In Gesn Light Emitting Diodes, Kevin K. Choe

Theses and Dissertations

Potential future use on Earth-orbiting satellites calls for investigation into the suitability of GeSn based photonic devices in high energy proton environments. The electroluminescence (EL) intensity of Ge1-xSnx (x = 0, 0.02, 0.069, and 0.094) light emitting diodes was measured before and after irradiation by 2 MeV protons at relatively high fluence levels. The results showed that GeSn devices with higher Sn content were up to 10 times more resistant against proton displacement damage than the pure Ge (x = 0) devices. As Sn concentration increased, the band gap decreased, and V-P hole trap energy level moved further from the …

Improved Fabrication For Micromirror Arrays, Enoc Flores

Theses and Dissertations

Micromirror devices which consisted of one SU-8 2050 layer, two different exposures, and a series of metal depositions were constructed and evaluated. By varying the exposure, a micromirror structure was fabricated with different thicknesses, a ratio of 1.083 µm/(mJ/cm2) was found. The initial design consisted of four layers. The pillar was made of one SU-8 layer, and the top portion had three layers in the following order: gold, SU-8, and gold. This design could not be released and did not have characteristics of a flat and conformal reflective surface. Several variations of the initial design were explored and all of …

Characterization Of Metal Contacts On Hydrothermally Synthesized Uranium Dioxide For Novel Semiconductor Applications, Tory E. Robinson

Theses and Dissertations

This research is focused on determining which metals or combinations of metals form effective electrical contacts on hydrothermally synthesized UO2 substrates to allow for additional work in characterization of the material as well as the feasibility of its use in semiconductor devices such as solid-state neutron detectors. A methodology was established for selection of candidate metals. Target mixtures composed of Au, Ag, Pt, and Mg were chosen along with several single-metals. Thin metal films were deposited onto tungsten probe tips and hydrothermally synthesized UO2 samples to allow for analysis of mechanical and deposited contact to the substrates through I-V measurements.

Scaling Film Cooling Adiabatic Effectiveness With Mass Transfer And Thermal Experimental Techniques, Luke J. Mcnamara

Theses and Dissertations

With increasing engine temperatures, it is becoming more important to design effective film cooling schemes. Low temperature, large scale tests are often implemented in the design process to reduce cost and complexity. A nondimensional adiabatic effectiveness can be used as an indication of the performance of a film cooling scheme. However, the coolant flow rate must be properly scaled between the low temperature tests and engine temperatures to accurately predict film cooling effectiveness. This process is complicated by gas property variation with temperature. Tests are commonly conducted using thermal measurement techniques with infrared thermography (IR), but the use of pressure …

Analysis And Design Of Modular Overhead Protection System Utilizing Readily Available Materials, Zachary J. Spranger

Theses and Dissertations

This research investigated passive overhead protective measures for existing facilities in an urban environment that are vulnerable to enemy munitions fire. A new modular structural system was designed utilizing commercially available construction material consisting of structural tubing, scaffolding clamps, base plates, and simple roofing components. Structural analysis software was used to model nine modular structures to understand the relationship between the load bearing capacity of the structural members and overall dimensions of the system. Environmental variables for the models were set to the Parwan Province in Afghanistan; this region presents worst-case scenarios both for environmental factors and threat of enemy …

Material Thermal Property Estimation Of Fibrous Insulation: Heat Transfer Modeling And The Continuous Genetic Algorithm, Elora Frye

Theses and Dissertations

Material thermal properties are highly sought after to better understand the performance of a material under particular conditions. As new materials are created, their physical properties will determine their performance for various applications. These properties have been estimated using many techniques including experimental testing, numerical modeling, and a combination of both. Existing methods can be time consuming, thus, a time-efficient and precise method to estimate these thermal properties was desired. A one-dimensional finite difference numerical model was developed to replicate the heat transfer through an experimental apparatus. A combination of this numerical model and the Continuous Genetic Algorithm optimization technique …

Analysis Of Additively Manufactured Lattice Structures Using Finite Element Methods, Christopher A. Box

Theses and Dissertations

Additive Manufacturing (AM) processes are well known for their ability to fabricate parts with complex geometries. Lattice structures leverage this ability to create parts with high strength-to-weight ratio and other desirable structural qualities. This research presents a parameterized modeling tool using common Finite Element Analysis (FEA) and scripting software with which aggregated lattice structures can be analyzed, given different geometric properties and loading conditions. A full factorial Design of Experiments is run to explore the effects of various parameters on the strength of lattice structures. Experimental compressive strength results from three FDM-produced PLA lattices are discussed and compared to predictions …

Effects Of Antidepressants On Human Mesenchymal Stem Cell Differentiation On Clinically Relevant Titanium Surfaces, Nancy B. Ayad

Theses and Dissertations

Selective Serotonin Reuptake Inhibitors (SSRIs) are the most frequently prescribed class of drugs worldwide and are implemented in the treatment of depression and other psychiatric disorders. SSRIs relieve depressive symptoms by modulating levels of the neurotransmitter serotonin in the brain. SSRIs block the function of the serotonin transporter, thereby increasing concentrations of extracellular serotonin. However, serotonin levels in the neurons of the brain only account for 5% while the remaining 95% is present outside the brain. Serotonin receptors and transporter are located on bone resident cells (mesenchymal stem cells (MSCs)), osteoblasts and osteoclasts, and serotonergic activity is believed to affect …

Diagnostics And Degradation Investigations Of Li-Ion Battery Electrodes Using Single Nanowire Electrochemical Cells, Naveen Kumar Reddy Palapati, Naveen Kumar Reddy Palapati

Theses and Dissertations

Portable energy storage devices, which drive advanced technological devices, are improving the productivity and quality of our everyday lives. In order to meet the growing needs for energy storage in transportation applications, the current lithium-ion (Li-ion) battery technology requires new electrode materials with performance improvements in multiple aspects: (1) energy and power densities, (2) safety, and (3) performance lifetime. While a number of interesting nanomaterials have been synthesized in recent years with promising performance, accurate capabilities to probe the intrinsic performance of these high-performance materials within a battery environment are lacking. Most studies on electrode nanomaterials have so far used …

The Modification Of Silica Aerogel Materials For Contemporary Use, Lauren White

Theses and Dissertations

Aerogel materials have had limited utility due to their fragility, geometrical limitations, fabrication costs and protracted fabrication times. The objective of this project was to eliminate these limitations. Native, cross-linked and hybrid aerogel monoliths have been fabricated using a newly developed one-pot method without the need for solvent exchange. The key to this technique is the use of an ethanol–water azeotrope mixture, which contains 4.4% water by volume, as both a gelation and supercritical drying solvent. The small water content allows for drying at temperatures close to the supercritical temperature of the dry solvent, where reactions such as silica dissolution …

A Study To Evaluate Non-Uniform Phase Maps In Shape Memory Alloys Using Finite Element Method, Naren Motte

Theses and Dissertations

The unique thermo-mechanical behavior of Shape Memory Alloys (SMAs), such as their ability to recover the original shape upon heating or being able to tolerate large deformations without undergoing plastic transformations, makes them a good choice for actuators.

This work studies their application in the aerospace and defense industries where SMA components can serve as release mechanisms for gates of enclosures that have to be deployed remotely. This work provides a novel approach in evaluating the stress and heat induced change of phase in a SMA, in terms of the transformation strain tensor. In particular, the FEA tool

ANSYS has …

Metamaterial Structure Design Optimization: A Study Of The Cylindrical Cloak, Jason V. Paul

Theses and Dissertations

Previously, Transformational Optics (TO) has been used as a foundation for designing cylindrical cloaks. The TO method uses a coordinate transform to dictate an anisotropic material parameter gradient in a cylinder coating that guides waves around the cylinder to reduce the Radar Cross Section (RCS). The problem is that the material parameters required for the TO cloak are not physically realizable and thus must be approximated. This problem is compounded by the fact that any approximation deviates from the ideal design and will allow fields to penetrate the cloak layer and interact with the object to be cloaked. Since the …

Distributed Spacing Stochastic Feature Selection And Its Application To Textile Classification, Jeffrey D. Clark

Theses and Dissertations

Many situations require the need to quickly and accurately locate dismounted individuals in a variety of environments. In conjunction with other dismount detection techniques, being able to detect and classify clothing (textiles) provides a more comprehensive and complete dismount characterization capability. Because textile classification depends on distinguishing between different material types, hyperspectral data, which consists of several hundred spectral channels sampled from a continuous electromagnetic spectrum, is used as a data source. However, a hyperspectral image generates vast amounts of information and can be computationally intractable to analyze. A primary means to reduce the computational complexity is to use feature …

Memristive Properties Of Thin Film Cuprous Oxide, Brett C. Castle

Theses and Dissertations

Memristive properties of thin film copper oxides with different grain sizes were characterized using tunneling atomic force microscopy (TUNA) and optical reflection measurements. The thin films containing copper ions of different chemical states were prepared by thermal oxidation of metallic copper thin films, deposited via magnetron sputtering onto silicon wafer substrates at an elevated temperature for various lengths of time. The TUNA measurements showed a memristive hysteresis in the I-V curves under an applied bias profile with an initial bias of -3.5V, a ramp up to 3.5V, and subsequent return to -3.5V. Histogram analysis of the barrier height distribution for …

Characterization And Measurement Of Passive And Active Metamaterial Devices, Christopher A. Lundell

Theses and Dissertations

This document addresses two major obstacles facing metamaterial development: uncertainty in the characterization of electromagnetic field behavior in metamaterial structures and the relatively small operational bandwidth of metamaterial structures. To address the first obstacle, a new method to characterize electromagnetic field behavior in a metamaterial is presented. This new method is a bistatic radar cross section (RCS) measurement technique. RCS measurements are well-suited to measuring bulk metamaterial samples because they show frequency dependence of scattering angles and offer common postprocessing techniques that can be useful for visualizing results. To address the second obstacle, this document characterizes the effectiveness of an …

Optical And Electrical Characterization Of Bulk Grown Indium-Gallium-Arsenide Alloys, Austin C. Bergstrom

Theses and Dissertations

Advances in crystal growth techniques have allowed increased quality in growth of bulk ternary In_xGa_1-xAs. Here, the optical and electrical properties of samples grown through the vertical Bridgman (or multi-component zone melting growth) method have been investigated through photoluminescence spectroscopy and Hall effect measurements. Indium mole fractions varied from 0.75 for 1. Hall effect measurements at temperatures ranging from 10 to 300 K revealed moderate n-type doping with carrier concentrations ranging from 1.5 to 9.6×10¹⁶ cm^-3 at 10 to 15 K. Carriers from deep donor levels became appreciable between 50 and 100 K. Hall …

Ceramic Matrix Composite Characterization Under A Combustion And Loading Environment, Andrew R. Nye

Theses and Dissertations

Lightweight materials that can withstand high temperatures and corrosive environments are constantly sought after in the aerospace industry, typically for Gas Turbine Engine (GTE) application. These materials need to retain their strength throughout the long service period they would see in the combustor and turbine components of a GTE. One material that is ideal for these types of applications is an oxide/oxide Ceramic Matrix Composite (CMC). The fatigue behavior of the oxide/oxide CMC Nextel^TM 720/Alumina (N720/A) was investigated in a unique high temperature environment. N720/A consisted of an 8-harness satin weave of Nextel^TM aluminum oxide/silicon oxide fibers bound …

Production And Characterization Of High Repetition Rate Terahertz Radiation In Femtosecond-Laser-Induced Air Plasma, Michael L. Dexter

Theses and Dissertations

The purpose of this research was to produce and characterize high repetition rate terahertz radiation in ionized air plasma. An 800 nanometer, 50 femtosecond, 0.35 Watt, 40 KHz, pulsed Ti:Sapphire laser system was used as the source infrared beam. This beam was focused onto a second harmonic generation crystal to produce a collinear, perpendicularly polarized secondary beam at 400 nm. After realigning the polarization of the fundamental to the second harmonic and compensating for group velocity dispersion introduced by the optics, both beams were recombined and focused by a 3.75 cm focal length mirror to form an air plasma. An …

Nondestructive Evaluation Of Aircraft Composites Using Terahertz Time Domain Spectroscopy, Christopher D. Stoik

Theses and Dissertations

Terahertz (THz) time domain spectroscopy (TDS) was assessed as a nondestructive evaluation technique for aircraft composites. Material properties of glass fiber composite were measured using both transmission and reflection configuration. The interaction of THz with a glass fiber composite was then analyzed, including the effects of scattering, absorption, and the index of refraction, as well as effective medium approximations. THz TDS, in both transmission and reflection configuration, was used to study composite damage, including voids, delaminations, mechanical damage, and heat damage. Measurement of the material properties on samples with localized heat damage showed that burning did not change the refractive …