Other Materials Science and Engineering Commons^™

Solvent-Free Coating Using Maco Bio-Based Reactive Diluent, Ryder James

Williams Honors College, Honors Research Projects

The project performed utilizes methacrylated cardanol (MACO) and a linseed oil resin to test how different weight percentages of MACO affect coating performance. MACO is synthesized from a phenolic lipid extracted from cashew nut shells, which are a cashew industry waste product. Not only does it utilize a waste product, but being a bio-based reactive diluent means it can replace the use of volatile organic solvents that are harmful to both humans and the environment. Weight percentage samples of 0%, 10%, 20%, 30%, and 40% were used. Coatings were applied using a 6-mil drawn down bar, with samples being prepared …

Effect Of Incorporating Pottery And Bottom Ash As Partial Replacement Of Cement, Bassam A. Tayeh, Doha M. Alsaffar, Lawend K. Askar, Asmahan Issa Jubeh

Karbala International Journal of Modern Science

This study addressed the environmental constraints in cement produc­tion. Ordinary Portland cement (OPC) was replaced with pottery powder (PP, produced by grinding locally available pottery) and bottom ash (BA) at 10%, 20% and 30% of cement mass. Moreover, 4% calcium chloride solution (CaCl₂.2H₂O) was used as mixing water. Material properties, such as standard consistency, setting time and compressive strength, were measured with different percentages of OPC replacement with PP and BA. Results indicated that the replacement with PP and BA increased the water demand to achieve the standard consistency. These results revealed that the strength evolution …

An Investigation Of High-Speed Consolidation And Repair Of Carbon Fiber - Epoxy Composites Through Ultrasonic Welding, David A. Hoskins

LSU Master's Theses

Adhesive repair of carbon fiber composite structures is commonly done on damaged structures to extend the service life. This method requires careful preparation of the damaged surface with intricate steps to ensure good bonding between the repair patch and the parent structure by means of an adhesive film. As with many forms of composite manufacturing, it is required to perform vacuum bagging, debulking, and a heated cure depending on the resin. All these steps make the repair process costly and time consuming.

In this present work, an alternative method of repair is investigated which explores the experimental feasibility of using …

Biopolymer-Stabilized Earth Materials For Resilient And Adaptable Infrastructures, Sherif Abdelaziz, Dilip Gersappe, Dilip Rafailovich

Department of Civil Engineering Faculty Publications

Earth dams and levees are constructed and retrofitted nowadays using the same materials that were used in the past, clays and sands. Despite the current advances in engineering, designing and constructing these critical infrastructure, earthen dams and levees continue to suffer from the same challenges over the years. These challenges include internal and surface erosions, loss of stability due to moisture migration, and inabilities to self-heal potential failure points. This project focuses on the use of biopolymers as additives to strengthen earthen dams and levees targeting an overall increase in their resilience.

Explicitly, the report for Milestone 3 presented the …

Development Of Experimental And Finite Element Models To Show Size Effects In The Forming Of Thin Sheet Metals, Jeffrey D. Morris

University of New Orleans Theses and Dissertations

Abstract

An experimental method was developed that demonstrated the size effects in forming thin sheet metals, and a finite element model was developed to predict the effects demonstrated by the experiment. A universal testing machine (UTM) was used to form aluminum and copper of varying thicknesses (less than 1mm) into a hemispherical dome. A stereolithography additive manufacturing technology was used to fabricate the punch and die from a UV curing resin. There was agreement between the experimental and numerical models. The results showed that geometric size effects were significant for both materials, and these effects increased as the thickness of …

Development Of A Sonically Powered Biodegradable Nanogenerator For Bone Regeneration, Avi S. Patel

University Scholar Projects

Background: Reconstruction of bone fractures and defects remains a big challenge in orthopedic surgery. While regenerative engineering has advanced the field greatly using a combination of biomaterial scaffolds and stem cells, one matter of difficulty is inducing osteogenesis in these cells. Recent works have shown electricity’s ability to promote osteogenesis in stem cell lines when seeded in bone scaffolds; however, typical electrical stimulators are either (a) externally housed and require overcomplex percutaneous wires be connected to the implanted scaffold or (b) implanted non-degradable devices which contain toxic batteries and require invasive removal surgeries.

Objective: Here, we establish a biodegradable, piezoelectric …

Development Of A Sonically Powered Biodegradable Nanogenerator For Bone Regeneration, Avi Patel

Honors Scholar Theses

Background: Reconstruction of bone fractures and defects remains a big challenge in orthopedic surgery. While regenerative engineering has advanced the field greatly using a combination of biomaterial scaffolds and stem cells, one matter of difficulty is inducing osteogenesis in these cells. Recent works have shown electricity’s ability to promote osteogenesis in stem cell lines when seeded in bone scaffolds; however, typical electrical stimulators are either (a) externally housed and require overcomplex percutaneous wires be connected to the implanted scaffold or (b) implanted non-degradable devices which contain toxic batteries and require invasive removal surgeries.

Objective: Here, we establish a biodegradable, piezoelectric …

Influence Of Mechanical Properties Of Paper Coating On The Crack At The Fold Problem, Seyyed Mohammad Hashemi Najafi

Electronic Theses and Dissertations

Paper coating layers are subject to various stresses and deformations in many converting processes such as calendering, printing, slitting, and folding of the paper. In some cases, products may crack during folding to generate a defect called cracking at the fold (CAF). The parameters that influence these defects are not well understood. The overall goal of this thesis is to better understand the CAF behavior as related to material properties of the coating layer.

A method was developed to produce free-standing pigmented coating layers thick enough to be tested in bending as well as tension. The mechanical properties of these …

Development Of Functional Biomaterials Using Protein Building Blocks, Li-Sheng Wang

Doctoral Dissertations

Proteins have intrinsic molecular properties that are highly useful for materials applications, especially for biomaterials. My research has focused on translating these molecular properties to materials surface behavior. In one approach, I developed a fluorous-based thermal treatment strategy to generate stable thin films from a variety of naturally abundant proteins. The different surface properties generated from the choice of protein were utilized to modulate cell-surface interactions, prevent bacterial adhesions, and control drug loading/release. I have used nanoimprint lithography to generate patterned protein films for cell alignment. Coupling with inkjet printing deposition, I have fabricated mixed protein films with spatial and …

Analysis Of The Low-Cycle Fatigue Behavior Of Silicone Rubber For Biomedical Balloons, Chase Cooper

Materials Engineering

The development of a medical drug delivery device that allows for the deployment drugs into the adventitial tissue of blood vessels requires the inflation of a silicone elastomer. The inflated silicone must be able to consistently endure multiple loading cycles without failing so that the device can operate reliably. There are multiple methods of processing the silicone for the device and the goal of this study is to examine the effect of the various processing methods on the characteristics of the silicone. The Dynamic Mechanical Analysis Machine (DMA) is used to model the conditions of the device’s application by performing …

Voltage-Controlled Deposition Of Nanoparticles For Next Generation Electronic Materials, Subhodip Maulik

LSU Doctoral Dissertations

This work presents both a feasibility study and an investigation into the voltage-controlled spray deposition of different nanoparticles, namely, carbon nanotubes (CNTs), as well as molybdenum disulfide (MoS₂) and tungsten disulfide (WS₂) from the transition metal dichalcogenides (TMDCs) family of materials. The study considers five different types of substrates as per their potential application to next-generation device electronics. The substrates selected for this research were: 1) aluminum as a conducting substrate, 2) silicon as a semiconducting substrate, 3) glass, silicon dioxide (SiO₂), and syndiotactic poly methyl methacrylate (syndiotactic PMMA) as insulating substrates.

Since the …

Waste Management By Waste: Removal Of Acid Dyes From Wastewaters Of Textile Coloration Using Fish Scales, S M Fijul Kabir

LSU Master's Theses

Removal of hazardous acid dyes by economical process using low-cost bio-sorbents from wool industry wastewaters is of a pressing need, since it causes skin and respiratory diseases and disrupts other environmental components. Fish scales (FS), a by-product of fish industry, a type of solid waste, are usually discarded carelessly resulting in pungent odor and environmental burden. In this research, the FS of black drum (Pogonias cromis) were used for the removal of acid dyes (acid red 1 (AR1), acid blue 45 (AB45) and acid yellow 127 (AY126)) from wool industry wastewaters by absorption process with a view to …

The Influence Of Organic Pigments On Coating Properties, Sarah Medeiros

Williams Honors College, Honors Research Projects

Abstract

The purpose of this project was to identify the qualities of two synthesized organic pigments added to a coating. These high-performance pigments were benzodipyrrolidone and benzodifuranone, which are π-conjugated monomers. These pigments were each formulated into two different pigment concentrations and compared with a control that had no pigment. This project is limited by time constraints and the number of variables that can be tested in that time. Performance testing was conducted to evaluate the qualities of these coatings. The results demonstrated that the coatings were reproducible and most tests had results that were equal to or exceeded the …

Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater

Honors Undergraduate Theses

Traditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure that provides a mechanically stable, light weight material for LIB anodes. Due to its structure, reduced graphene oxide (rGO) is efficiently conductive and resistive to environmental changes. On the other hand, silicon-based …

A Study In The Use Of Elastic Materials In Expandable Containment Units, Andrew J. Eisenman, Joby Anthony Iii, David Satagaj

Montview Journal of Research & Scholarship

The rigidity of materials in conjunction with the aspect of elasticity has been a concern of modern technologies and construction in recent centuries because of the advantages that expandable storage would bring to the fields of containment units with respect to population growth and space exploration. The world population is currently growing at an exponential rate, and as our population grows, the more important it will become to have containment units that can both contain large volumes of material as well as minuscule amounts of material without wasting space. In order accomplish this, we will need a new type of …

Effect Of Liquid Contamination On Hermeticity And Seal Strength Of Flexible Pouches With Lldpe, Francesca Delle Cese, Koushik Saha, S. Roy, Jay Singh

Journal of Applied Packaging Research

Flexible packaging is a growing successful market and the majority of flexible package applications are for the food industry. The demand for process optimization and reduced production costs, has led to an increase in flexible packaging. However, fast production lines can result in contamination in the seal area. For flexible food packaging, contamination is considered any food particle or substance trapped in the seal area. Current quality control processes can detect contamination in the seal area, but it is not determined if seal contamination affects seal quality. Oil-based and sodium based snack foods are two common categories that can be …

Nonlinear Dielectric Behavior Of Field-Induced Antiferroelectric/Paraelectric-To-Ferroelectric Phase Transition For High Energy Density Capacitor Application, Mingyang Li

Dissertations, Master's Theses and Master's Reports

Electric field-induced antiferroelectric(AFE)/paraelectric(PE)-to-ferroelectric(FE) phase transitions are investigated for the associated nonlinear dielectric behavior, which could offer high dielectric capacity. The phenomenon in monolithic materials has been computed for Kittel antiferroelectric and BaTiO₃ model systems using the Landau-Ginzburg-Devonshire theory. The general switching curves give values of the polarization as a function of external electric field. A similar computation is performed for particle-filled polymer-matrix composites where an internal depolarization field is considered. The polarization-electric field response changes with different depolarization factors, which demonstrate the shape and alignment of the dielectric particles embedded in polymer-matrix are key factors for the composite to …

Tightening The Loop On The Circular Economy: Distributed Plastic Recycling With An Open Source Recyclebot, Shan Zhong

Dissertations, Master's Theses and Master's Reports

Following the goals of a circular economy, the growth of both plastic consumption and prosumer 3-D printing are driving an interest in producing 3-D printer filament from waste plastic. However, traditional recycling can have a significant environmental impact as it demands the collection and transportation of relatively low-density waste plastics to collection centers and reclamation facilities for separation and reconstruction. Compared to the traditional recycling, distributed recycling (where consumers directly recycle their own waste) has the potential to reduce energy consumption because it can save the energy for transportation needed in conventional recycling. A promising method of such distributed plastic …

Strategies For Controlling Bulk Heterojunction Morphology, Zach Daniel Seibers

Doctoral Dissertations

Organic photovoltaic devices have been extensively studied as a means to produce sustainable energy. However, the performance of organic-photovoltaic (OPV) devices is dependent upon a number of factors including the morphology of the active layer, device architecture, and processing conditions. Recent research has indicated that fullerenes in the bulk heterojunction are entropically driven to the silicon and air interfaces upon crystallization of P3HT, which occurs during thermal annealing. The first chapter of this research focuses on investigating the structure and function of end-tethered poly(3-hexylthiophene) chains to a transparent electrode as an anode buffer layer. Neutron reactivity reveals that these P3HT …

Creation And Evaluation Of Polymer/Multiwall Carbon Nanotube Films For Structural Vibration Control And Strain Sensing Properties, Weiwei Lin

FIU Electronic Theses and Dissertations

Multifunctional materials both with damping properties and strain sensing properties are very important. They promise to be more weight-efficient, and provide volume-efficient performance, flexibility and potentially, less maintenance than traditional multi-component brass-board systems.

The goal of this dissertation work was to design, synthesize, investigate and apply polyaniline/Multiwall carbon nanotube (PANI/MWCNT) and polyurethane (PU) /MWCNT composites films for structural vibration control and strain sensors using free layer damping methods and static and dynamic strain sensing test methods.

The PANI/MWCNT was made by in situ polymerization of PANI in the presence of MWCNT, then frit compression was used to make circular and …

Analysis Of Optimal Process Conditions And Mechanical Properties On Nanocomposites According To Structural Changes Of Halloysite Nanotubes, Yun-Hae Kim, Soo-Jeong Park, Antonio Norio Nakagaito

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Development Of Eco-Friendly Composite Foam Boards For Thermal Insulation And Packaging Purposes Using Cellulose Nanofibrils (Cnf), Nadir Yildirim

Electronic Theses and Dissertations

Reducing energy consumption is a high priority in the United States and throughout the world. Energy used to heat and cool occupied constructed facilities is of particular concern, and one of the most effective strategies is insulating the building envelope. Historically, builders used whatever material was available to fill the void between interior and exterior walls, including wool fibers, paper, and even corn cobs. Today, homes are built using foam insulation that harden when applied, blown-in loose insulation, fiberglass mats or rigid foam boards usually composed of polystyrene. Rigid foam boards are used in a variety of applications despite the …

Carbon Nanoadditives To Enhance Latent Energy Storage Of Phase Change Materials, Shadab Shaikh, Khalid Lafdi, Kevin P. Hallinan

Kevin Hallinan

Latent energy storage capacity was analyzed for a system consisting of carbon nanoparticlesdopedphase changematerials (PCMs). Three types of samples were prepared by doping shell wax with single wall carbon nanotubes(SWCNTs), multiwall CNTs, and carbon nanofibers. Differential scanning calorimetry was used to measure the latent heat of fusion. The measured values of latent heat for all the samples showed a good enhancement over the latent heat of pure wax. A maximum enhancement of approximately 13% was observed for the wax/SWCNT composite corresponding to 1% loading of SWCNT. The change in latent heat was modeled by using an approximation for the intermolecular …

Tribological Performance Of Hybrid Filtered Arc-Magnetron Coatings: Part I: Coating Deposition Process And Basic Coating Properties Characterization, Vladimir Gorokovsky, Chris Bowman, Paul Gannon, David Vanvorous, Andrey Voevodin, Adam Rutkowski, Christopher Muratore, Richard Smith, Asghar Kayani, David Gelles, Vaithiyalingam Shutthanandan, Boris Trusov

Christopher Muratore

Aircraft propulsion applications require low-friction and wear resistant surfaces that operate under high contact loads in severe environments. Recent research on supertough and low friction nanocomposite coatings produced with hybrid plasma deposition processes was demonstrated to have a high potential for such demanding applications. However, industrially scalable hybrid plasma technologies are needed for their commercial realization. The Large area Filtered Arc Deposition (LAFAD) process provides atomically smooth coatings at high deposition rates over large surface areas. The LAFAD technology allows functionally graded, multilayer, super-lattice and nanocomposite architectures of multi-elemental coatings via electro-magnetic mixing of two plasma flows composed of different …

Progress In The Development Of Adaptive Nitride-Based Coatings For High Temperature Tribological Applications, Samir Aouadi, Brandon Luster, Punit Kohli, Christopher Muratore, Andrey Voevodin

Christopher Muratore

Adaptive tribological coatings were recently developed as a new class of smart materials that were designed to adjust their surface chemical composition and structure as a function of changes in the working environment to minimize friction coefficient and wear between contact surfaces. This paper provides an overview of the current research developments in this field, including: (1) Chameleon nanocomposite coatings which are produced by depositing a multi-phase structure whereby some of the phases provide mechanical strength and others are lubricious; (2) Micro- and nano-textured coatings which consist of hard nitride films with highly ordered micropores and nanopores that are subsequently …

Plasma Enhanced Surface Treatments Using Electron Beam-Generated Plasmas, Darrin Leonhardt, Christopher Muratore, Scott Walton, Robert Meger

Christopher Muratore

NRL has developed a ‘large area plasma processing system’ (LAPPS) utilizing a high energy (∼2 keV) modulated electron beam to drive the plasma ionization. This system has been shown to be (1) efficient at producing plasma in any gas composition, (2) capable of producing low temperature plasma electrons (9–10¹² cm⁻³) and (3) scalable to large area (square meters). In this work, the progress of a number of applications using LAPPS is discussed. Nitride growth in stainless steel was investigated, which demonstrated high rates (up to 20 μm/h^1/2) at low temperatures (≤462 °C). Complementary mass spectrometry …

Molybdenum Disulfide As A Lubricant And Catalyst In Adaptive Nanocomposite Coatings, Christopher Muratore, Andrey Voevodin

Christopher Muratore

Nanocomposite YSZ–Ag–Mo–MoS₂ coatings with different MoS₂ additions (0–100 at.%) were deposited with a hybrid pulsed laser/magnetron sputtering/filtered cathodic arc process. Wear testing was performed from 25 to 700 °C for each of the coatings. Electron microscopy and other characterization techniques were used to examine the surfaces and wear tracks of the coatings and to determine the mechanisms resulting in the measured tribological properties. Adaptive coatings containing 8 at.% MoS₂demonstrated a friction coefficient of 0.2 throughout the temperature range examined here, compared to 0.4 for YSZ–Ag–Mo with no MoS₂. Characterization of the YSZ–Ag–Mo–8% MoS_{2 …}

In Situ Studies Of Tic1−X N X Hard Coating Tribology, Marisa Rebelo De Figueiredo, Christopher Muratore, Robert Franz, Richard Chromik, Kathryn Wahl, Andrey Voevodin, Michel O'Sullivan, Markus Lechthaler, Christian Mitterer

Christopher Muratore

TiC1−x N x hard coatings present time-dependent tribological behavior with an initial running-in period (500–2000 cycles) marked by an elevated friction coefficient, followed by >10000 cycles with low-friction and wear at room temperature (RT) in ambient air. The mechanisms behind this behavior are not completely understood. Tribological tests performed at RT and at different relative humidity (RH) levels revealed that a minimum value between 15 and 25% RH is needed to trigger the low-friction regime at a sliding speed of 100 mm s−1. By in situ observations of transfer film growth, it could be observed that third body material …

Adaptive Nanocomposite Coatings With A Titanium Nitride Diffusion Barrier Mask For High-Temperature Tribological Applications, Christopher Muratore, Jianjun Hu, Andrey Voevodin

Christopher Muratore

Adaptive nanocomposite coatings that demonstrate low friction throughout broad ranges of temperature, wear, humidity and other environments are currently in development. One effective temperature adaptation mechanism at temperatures ≤ 500 °C is diffusion of noble metal to the coating surface, providing a low shear strength interface at the friction contact supported by a hard surface underneath. To prolong the wear lifetime of chameleon coatings relying upon this mechanism for low friction, a coating architecture incorporating a diffusion barrier mask to inhibit noble metal diffusion was employed. The diffusion barrier-capped coating provided lubrication at 500 °C over ten times longer than …

A Simultaneous Increase In The Thermal And Electrical Transport In Carbon Nanotube Yarns Induced By Inter-Tube Metallic Welding, Sabyasachi Ganguli, Amber Reed, Chaminda Jayasinghe, Joe Sprengard, Ajit Roy, Andrey Voevodin, Christopher Muratore

Christopher Muratore

Vertically aligned arrays of multiwall carbon nanotubes (MWCNT) were decorated with gold (Au) nanoparticles of different diameter and areal densities and spun into yarns. The melting point of Au nanoparticles determined by differential scanning calorimetry was approximately 260 °C, well below the oxidation temperature of carbon. A continuous yarn was formed while pulling out a bundle of CNTs from the metalized CNT array. Relatively low temperature (300 °C) thermal processing of the metalized yarn resulted in a 30% improvement in thermal conductivity, 40% increase in electrical conductivity and a 4× increase in elastic modulus. Cross-sections of the yarn were examined …