Metallurgy Commons^™

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …

Mechanical Alloying Of Nitrogen Into Iron Powders, J. Rawers, D. Govier, D. C. Cook

Physics Faculty Publications

Mechanical alloying of nitrogen into bcc-fe powder is a very effective and efficient means of obtaining very high concentration of nitrogen in micron-size iron particles. Mechanical alloying increases the concentration of nitrogen in the iron powder far in excess of the bcc-Fe lattice low nitrogen solubility, however most of the infused nitrogen resides on the nano-size grain boundaries and in nano-size bct-fe that forms during mechanical alloying.

Identification And Characterization Of The Iron-Zinc Intermetallics Formed In Galvanneal Steel, Richard Frederick George Grant

Physics Theses & Dissertations

The demand to improve the corrosion resistance of steel sheet, particularly for use within the automotive industry, has led to a dramatic increase in the use of coated steels in place of cold-rolled sheet steel. Galvanneal steel results from the post annealing of the zinc-coated steel sheet, in which iron and zinc are interdiffused to form an iron-zinc alloy coating. Within this alloy coating, four main iron-zinc phases, Zeta, Delta, Gamma-1, and Gamma may be present. Manufacture of the most suitable coating requires identifying which phases form during the galvannealing process, an understanding of the properties of each phase and …

Calculated Point Defect Properties Of The Intermetallic Compounds Nickel Titanium (Niti) And Iron Titanium (Feti), Russell T. Lutton

Theses and Dissertations

Atomistic simulation with a modified version of the DYNAMO code was used to calculate the point defect properties of the intermetallic compounds nickel titanium and iron titanium. The calculated energies are believed to be experimentally accurate to within +/- 0.1 eV. Vacant Ni or Fe lattice sites were preferred and had energies of 6.356 eV for NiTi and 5.899 eV for FeTi. Removing a Ti atom resulted in a neighboring antisite defect caused by migration of a Ni or Fe atom into the vacant Ti site. These configurations had energies of 7.024 eV for NiTi and 6.336 eV for FeTi. …

Effects Of Sample Orientation On The Corrosion Of Zinc In Ammonium Sulfate And Sodium Hydroxide Solutions, D. Abayarathna, Edward Boyd Hale, Thomas J. O'Keefe, Y. M. Wang, D. Radovic

Physics Faculty Research & Creative Works

The corrosion and electrochemical properties of three zinc single crystal surfaces with different orientations have been investigated. In near-neutral 1 M (NH₄)₂SO₄, the corrosion rates on all three surfaces were found to be similar. However, the SEM morphologies of the corresponding corroded surfaces were markedly different from each other, but consistent with preferential attack of {1120} surfaces. In alkaline 0.5 N NaOH solution, the three sample orientations showed significantly different reactivities, with the (1120) surface exhibiting the highest reactivity and corrosion rate. Here, passivation ultimately occurred and the difference in the corrosion performance of …

Premartensitic Anelasticity In Indium-Thallium Alloys., Manfred Wuttig, C. Y. Lei, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

The linear and nonlinear low frequency internal friction of In-24 at. pct Tl displays a Curie-Weiss type behavior in the temperature range above the transformation temperature. The critical temperature equals the martensite start temperature. It is proposed that the origin of the observed internal friction is the diffusion-controlled interaction of substitutional atoms with the premartensitic strain modulation, tweed.

Non-Linear Oscillation, Automodulation And Anelasticity, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

The auto modulation observed in the course of internal friction is discussed as a special example of the universal nature of non-linear oscillations. Universal features of non-linear oscillations are the requirement of energy supply or negative damping and the period doubling route to chaos. The negative damping responsible for the auto modulation is described in terms of the soliton model for twinning deformation. © 1984 The Japan Society of Applied Physics.

Nonlinear Anelasticity Of Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

An approximate solution of the equation of motion of a nonlinear anelastic reed at or near resonance is presented. The steady state solution reproduces the well-known nonlinear resonances. The solution also predicts the existence of auto modulations, i.e., self-excited modulations of the amplitude and phase at constant power of excitation of the reed. Numerical examples of such auto modulations are presented for an antisymmetric deformation potential. Experimental studies of finite amplitude oscillations of a magnesium reed vibrating at 72 and 431 Hz at room temperature confirm the existence of auto modulations. The experimental results can be semi quantitatively described in …

Phaseautomodulation In Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

No abstract provided.

Autooscillations In Zinc, Manfred Wuttig, Alex Aning, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Autooscillations And Nonlinear Anelasticity, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

In conclusion it can be stated that a novel phenomenon, a mechanical auto oscillation, has been described theoretically and shown to exist experimentally. These auto oscillations occur when a nonlinear anelastic solid is forced into large amplitude oscillations in the vicinity of a martensitic transformation. They manifest themselves as a low frequency auto modulation of the a martensitic transformation. They manifest themselves as low frequency auto modulation of the forced vibration of such a solid. © 1980.

Nonlinear Anelasticity And The Martensitic Transformation, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

Zener's model of a standard linear solid is extended to include nonlinearities characteristic of metals and alloys in the vicinity of a martensitic transformation. The equation of motion of a nonlinear anelastic solid is derived and solved using van der Pol's method. The characteristics of the solutions indicate that auto-oscillations of finite amplitude can be excited externally. It is proposed that the streaming oscillations represent the beat between the external excitation and the auto-oscillation. © 1979.

The Martensite Transformation, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Analogy Between Spinodal Decomposition And Martensitic Transformation, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

The translation of the theory developed for the spinodal decomposition of a supercooled alloy to the language appropriate for the martensitic transformation is carried out. In the spinodal theory, the stability of the alloy with respect to the composition fluctuation is examined, while in the present theory the stability of the crystal with respect to the shear displacement fluctuation, the transverse phonon, is studied. The analogy to the spinodal theory requires the revival of the strain gradient energy term or the couple stress term, the presence of which has been a subject of controversies for a long time since Laval. …

On The Interaction Of Aluminium And Iron Calcium Borate Glasses And Its Effect On The Properties Of Their Composites, Sherif K. Arif

Archived Theses and Dissertations

No abstract provided.

Investigation Of The Platinum-Rich Portion Of The Platinum-Tantalum Phase Diagram, Bob Dean Browning

Theses and Dissertations

The Pt-Ta binary system was investigated at two isotherms;1000°C and 1500°C, and at eleven alloy compositions in the range of 50 to 100 atomic percent platinum. The alloys were examined by x-ray diffraction and metallography. Three intermetallic compounds, Pt₂Ta, Pt₃Ta, and Pt₄Ta were found to exist in this composition range. The Pt₄Ta intermetallic appeared only at the 1500°C isotherm. Platinum dissolved tantalum substitutionally to 90 atomic percent at 1500 °C and to approximately 80 atomic percent at 1000 °C.