Metallurgy Commons^™

Magnetic Properties Study Of The Mn-Al System With Additions Of B Or C And Mechanical Milling Techniques, Timothy E. Prost

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Recently a shift in the focus of permanent magnetic research has moved from Rare Earth (RE)-based alloys to those made from more readily available elements. Because of their relatively large magnetocrystalline anisotropy, L1₀ compounds have the potential for use as permanent magnet materials. One particular alloy that is readily available and inexpensive is near equi-atomic manganese and aluminum (Mn₅₀-Al₅₀). First characterized in 1958, it did not receive much attention until more recently when RE supply chain issues made the alloy more attractive for commercial and research applications. The ferromagnetic (FM) τ-phase (L1₀) is …

Analyzing The Corrosion Resistance Of Ni-Shield 200 Coatings At Different Temperatures When Exposed To Sulphuric Acid, Alex Hussinger

Materials Engineering

Six steel samples each were twin wire arc sprayed with Hastelloy C-276 or Nickel-Shield 200 coatings approximately 0.020″ thick. These samples were then cut into 3″ by 3″ squares. A 2″ diamond grit hole saw was used to abrade and polish to a smooth surface a ring in the middle in order to get an O-ring mechanical seal. The samples were then weighed and loaded into a jig that started from the bottom up with a stainless steel plate, then the sample, then a Viton O-ring, a ¾″ thick glass plate with a 1 3/4″ hole cut in it, another …

Design, Fabrication, And Characterization Of A Thin-Film Nickel-Titanium Shape Memory Alloy Diaphragm For Use In Micro-Electro-Mechanical Systems, Brian Joel Alvarez

Master's Theses

Previous work done at Cal Poly has shown that thin-film nickel-titanium (NiTi) can be easily sputtered onto silicon wafers and annealed to create a crystallized shape memory alloy (SMA) film. Initial work on creating devices yielded cantilevers that were highly warped due to thin-film stress created during the sputtering process. The objective of this work was to create a thin-film NiTi SMA device that could be better characterized. A membrane was selected due to the simplicity of fabrication and testing which would also oppose the thin-film stress due to the increase in attachment points to the substrate.

Silicon wafers were …

The Effects Of Heat Treatment On Area Percent Porosity And Corrosion Behavior Of High-Nickel Thermal Spray Coatings, Travis Crowe, Alec Guraydin

Materials Engineering

Samples of two Thermal Spray Coating (TSC) alloys on a low carbon steel substrate were obtained: alloy C276 and Nicko-Shield 200. Specimens of each alloy were subjected to heat treatments at temperatures at 1100° for 60 minutes and 1200° for 10 minutes, with some specimens left in the as-sprayed condition. Three replicates were prepared for each condition. Thin 1” strips were cut using a diamond wafering blade for porosity measurements and 2” x 1” specimens were cut for corrosion testing using a SiC abrasive saw. The porosity specimens were mounted in acrylic resin, polished, and examined using SEM. From these …

Review Of The Maxus 8 Sounding Rocket Experiment To Investigate Solidification In A Ti-Al-Nb Alloy, Robin Mooney, David Browne, Olga Budenkova, Yves R. Fautrelle, Ludo Froyen, Andrey Kartavykh, Stephan Rex, Burkhard Schmitz, Daniella Voss, Shaun Mcfadden

Conference Papers

A review of the MAXUS 8 sounding rocket microgravity experiment to investigate solidification structures in a Ti-Al-Nb intermetallic alloy is presented. The experiment was part of the Intermetallic Materials Processing in Relation to Earth and Space Solidification (IMPRESS) EU FP6 project. Key objectives were to investigate columnar and equiaxed solidification, and to achieve Columnar-to-Equiaxed Transition (CET) in the alloy. A microgravity experiment was designed to achieve this using a controlled power-down method. Two alloys were tested: one inoculated with a grain refiner and the other without grain refinement. Unrefined samples displayed axial and radial columnar growth. Boride inoculated samples displayed …

The Effects Of Applied Strain And Heat Treatment On The Properties Of Niti Wire During Shape Setting, Frank Zapoticla

Master's Theses

NiTi components are commonly subjected to thermo-mechanical heat treatments during production and fabrication. This study investigates the effects of applied strain of 0-10% and heat treatments of 300-600ºC for times of 2-30 minutes during shape-setting of Ti–50.8 at% Ni wire with a nominal diameter of 0.495 mm and an initial transition temperature, Af, of 12ºC. Strain was applied prior to heat treatments by coiling NiTi wire, essentially producing coiled springs, around different diameter steel mandrels to obtain different strain levels. The samples of NiTi wire under applied strain were heat treated in a salt bath, followed by a rapid quench. …

Structural And Magnetic Properties Of Neodymium–Iron–Boron Clusters, Jeremy J. Anderson

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Using inert gas condensation techniques the properties of sputtered neodymium-iron-born clusters were investigated. A D.C. magnetron sputtering source created vaporous Nd-Fe-B which was then condensed into clusters and deposited onto silicon substrates. A composite target of Nd-Fe-B discs on an iron plate and a composite target of Nd-(Fe-Co)-B were utilized to create clusters. The clusters were coated with a carbon layer through R.F. sputtering to prevent oxidation.

Samples were investigated in the TEM and showed a size distribution with an average particle diameter of 8.11 nm. The clusters, upon deposition, were amorphous as indicated by diffuse diffraction patterns obtained through …

Characterization Of Aluminum-Boron Carbide Particulate Metal Matrix Composites, Eric Blank

Materials Engineering

The analysis of die-cast 380 aluminum-boron carbide particulate metal matrix composites (MMC) was performed in order to see if the samples had the required tensile strength of 300 MPa. 10wt% B4C die-cast samples were produced and tested. Half were heat treated to the T6 condition and the others were left as cast. Using ASTM standard B 557M it was found that the average tensile strength for the as-cast samples was 130 MPa and the heat treated samples had a tensile strength of 93 MPa. These values were both lower than expected. The heat treated samples were not expected to have …

Effects Of Oxygen Content Of Admitted Gases In Sulfide Flotation, Brian J. Boyle

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Methods Of Studying The Effects Of Frothers, Frank L. Bazzanella

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Studies In Modulation Of Interfacial Reactions For Certain Sulphide Minerals, Robert Owen Beyaert

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Habit Modification Of Naclo3 With Nai, William A. Coghlan

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Production Of Standard-Grade Ferromanganese In An Electric Arc Furnace, Force F. Baney Jr.

Bachelors Theses and Reports, 1928 - 1970

The investigations conducted in this project were essentially concerned with the effects of various compositions of two different slag systems upon the increased recovery of manganese in a standard-grade ferromanganese.

Investigation Of The Ternary System Silver-Aluminum-Indium (Ag-Al-In), Elvin H. Beardslee

Bachelors Theses and Reports, 1928 - 1970

This thesis paper contains material pertaining to & preliminary investigation of the ternary system Ag-Al-In. Procedures in this preliminary investigation are discussed in detail.

Preliminary Examination Of The Aluminum Corner Of The Ternary System Aluminum-Silver-Indium (A1-Ag-In), Jerome J. Blake

Bachelors Theses and Reports, 1928 - 1970

In this paper the author attempts to lay the groundwork for future work on the Al-Ag-In system.

Increased Corrosion Of A 304 Stainless Steel Upon Bending, William C. Tiddy

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Identification Of Nonmetallic Inclusions In Armco Ingot Iron With Polarized Light, Frank E. Panisko

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

The Hydrometallurgy Of Uranium, John E. Cesarani

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Crystal Habit Modification Of Sodium Chlorate, Michael R. Keegan

Bachelors Theses and Reports, 1928 - 1970

All single crystals have a particular habit or morphology. The crystal habit refers to the relative degree of development of crystallographic planes into surfaces which make up the external appearance of the single crystal.

In this paper, NaClO3 is used as a parent crystal. Its simple cubic habit is modified to tetrahedral by the use of impurities of SO4=, S2O3=, Cr2O7=, and NO3-. The degree of habit change is studied as a function of impurity concentration and temperature. The problem and phenomena are explained in terms of surface chemistry and thermodynamics.

Physico-Chemical Principles Of Sixteenth Century Metallurgy, Robert E. Johnson

Bachelors Theses and Reports, 1928 - 1970

Following a review of sixteenth century metallurgical literature and a discussion of Gibbs free energy, this thesis discusses thermodynamic considerations of galena (PbS) reduction by iron from a lead assay of this period. The importance of fluxes in this assay is emphasized. The discussion covers both equilibrium and non-equilibrium conditions at 1100 degrees Celsius. Possible substitutes for iron are also covered.

Information from twenty-one small controlled lead assays is correlated with the thermodynamic discussion to determine the purpose of each constituent in the assay.

The Beneficiation Of Titaniferous-Magnetite Sands, Ronald Lloyd Nordwick

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation of beneficiation methods is to develop and study possible economic methods for recovering an iron-titanium concentrate of sufficient purity to meet metallurgical requirements for subsequent direct reduction to pig iron and a high titanium slag.

Stress-Corrosion Cracking Of Brass, Paul A. Fossey

Bachelors Theses and Reports, 1928 - 1970

the mechanism of stress-corrosion cracking of brass has been sought for many years. Investigators have proposed many mechanisms, but each of these mechanisms has always had several drawbacks. This paper presents an account of experimental work done in the laboratory on this subject and compares it to the work of previous investigations. It evaluates the mechanisms presented by investigators and shows the failures of these mechanisms. A theory of Nitrogen Embrittlement is presented and an evaluation of this theory with experimental work follows.

Experimental Arc Furnace Smelting Of Titaniferous Iron Sands From The Northern Oregon Coast, Allan P. Herring

Bachelors Theses and Reports, 1928 - 1970

This investigation is an attempt to experimentally smelt titaniferous iron sands from the Northern Oregon Coast in a laboratory arc furnace.

The Effect Of Ph Upon Chelation Reactions In Montmorillonite Clays, Joseph Michael Keane

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to investigate several chelation reactions and determine the effect of variable pH upon these reactions.

An Investigation Of The Sintering Of Iron-Wire Compacts, George L. Vivian

Bachelors Theses and Reports, 1928 - 1970

A study of the sintering of iron has been made by observing the rate of bonding of iron wires wound on iron spools. The specimens were sintered at a constant temperature of 850c in vacuum furnaces capable of producing pressures of 10-5 to 10-4 mm of mercury, and the growth of the bond between wires was observed as a function of time.

It has been concluded that the volume-diffusion mechanism is strongly operating in the sintering of iron at 850c, but in an evacuated system, the evaporation-condensation mechanism also contributes to the sintering process.

The Identification Of Montana Clays By X-Ray Analysis, David Stephen Malyevac

Bachelors Theses and Reports, 1928 - 1970

The purpose of this study is to identify the various Montana clay minerals by means of X-ray diffraction. The ultimate aim of this investigation is to identify the different clay mixtures through an analysis of their respective diffraction patterns, and diffraction patterns obtained after various chemical and thermal treatments.

The Design And Construction Of An Electrolytic Cell For Aluminum Reduction, Thomas H. Melrose

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation was to design and construct a laboratory size electrolytic cell in which to reduce alumina, using the same basic materials that are used in a commercial size cell. The cell was designed to have a capacity of approxi­mately 100 grams of metallic aluminum produced every 8 hours. The cell was constructed so it could be operated continuously.

Investigation Of Inclusions In Armco Ingot Iron, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Various chemical and electrolytic separation methods were investigated in an attempt to separate the in­clusions in Armco ingot iron. Residues obtained were X-rayed for identification purposes. The microstruc­tures of this iron were studied with the object of de­termining the relative sizes, locations, and possible compositions of the inclusions.

Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline

Bachelors Theses and Reports, 1928 - 1970

When a cold-worked metal is annealed, it’s physical properties hange as a result of a new grain structure. The annealing treatment is divided into three stages according to the changes that occur in the distorted metal: (1) recovery, (2) recrystallization, and (3) grain growth.

Polarography Of Indium, John Jackson

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to study the various aspects of the polarography of indium. The eventual goal would be to develop a method of analyzing indium in unknowns. The investigation is approached by studying the indium ions in various electrolytes and in various concentrations.