Materials Science and Engineering Commons^™

Oxidation And Mechanical Properties Of In Situ Hybrid (Ticp+Tibw)/Ti6al4v Composites With Tailored Network Microstructure, L. J. Huang, X. P. Cui, Y. Jiao, T. B. Duan, X. T. Li, Y. N. Gao, L. Geng

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Mechanically Activated Combustion Synthesis Of Molybdenum Borosilicides For Ultrahigh-Temperature Structural Applications, Alan Alberto Esparza Hernandez

Open Access Theses & Dissertations

The desire to improve the efficiency of power generation gas-turbines has led to a relentless quest for new, ultrahigh-temperature structural materials to replace the current nickel-based superalloys. These materials have reached the maximum allowable operating temperature determined by the melting temperature of these alloys, which is about 1150 °C. These materials could be replaced by molybdenum silicides and borosilicides based on Mo5SiB 2 (T2) phase due to their high melting point and mechanical properties. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at elevated temperatures. One novel approach to improve these properties is …

Investigation Of Ti-6al-4v Alloy Response To Atmospheric Re-Entry Exposure, Jessica Lynn Buckner

Open Access Theses & Dissertations

Ti-6Al-4V is a widely used aerospace alloy for its high strength-to-weight ratio and high operating temperature properties. Despite widespread use, titanium and its alloys have been shown to ignite in oxygen and nitrogen rich test streams. The reactivity of titanium is attributed to the high solubility for oxygen that increases with temperature, accelerating the oxidation rate and resulting in a combustion reaction. When introduced to the monatomic oxygen rich and high enthalpy re-entry environment, Ti-6Al-4V X-link components from the space shuttle Columbia exhibited accelerated oxidation and combustion behavior. Ti-6Al-4V metal plates tested in the simulated re-entry environment of an arc-jet …

Oxidation Resistance Of Nanocrystalline 316l Stainless Steel Processed By High Pressure Torsion, Kevin J. Meisner

Williams Honors College, Honors Research Projects

High Pressure Torsion (HPT) is a materials processing method used to refine the grain size of metallic materials through the application of simultaneous axial and torsional strain. HPT is reported to result in nanocrystalline structure, which the current scientific literature suggests may improve the high temperature oxidation resistance by enhancing diffusion of solutes, particularly Cr, to the surface to form a protective external oxide scale. If oxidation resistance is improved, this possibly allows the use of 316L in oxidizing environments where more expensive alloys are typically used. However, the influence of grain refinement to nanoscale on various properties have been …

Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria

Theses and Dissertations

Ultra high temperature ceramics (UHTCs) are leading candidates for aerospace structural applications in high temperature environments, including the leading edges of hypersonic aircraft and thermal protection systems for atmospheric re-entry vehicles. Before UHTCs can be used in such applications, their structural integrity and environmental durability must be assured, which requires a thorough understanding and characterization of their creep and oxidation behavior at relevant service temperatures.

Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim

Makara Journal of Technology

Chemical Oxygen Demand (COD) reduction of wastewater from soybean tofu production was studied by conducting advanced oxidation process (AOP) using hydrogen peroxide with UV radiation catalysts in a closed cylindrical glass reactor. The hydroxyl radical (*OH) concentration from H2O2 decomposition was modeled, and exponential trends were found for the *OH concentration over radiation time and operation temperature. As a result, it was found that the maximal *OH concentration was 0.209 mol L-1 at 240 minutes and 50 °C. The *OH concentration exponentially increased following rise in operation temperature. The H2O2/UV AOP application reduced COD concentration to approximately 42.41% from 10,545 …

High Temperature Oxidation Kinetics Of Dysprosium Particles, Brian J. Jaques, Darryl P. Butt

Materials Science and Engineering Faculty Publications and Presentations

Rare earth elements have been recognized as critical materials for the advancement of many strategic and green technologies. Recently, the United States Department of Energy has invested many millions of dollars to enhance, protect, and forecast their production and management. The work presented here attempts to clarify the limited and contradictory literature on the oxidation behavior of the rare earth metal, dysprosium. Dysprosium particles were isothermally oxidized from 500 to 1000 °C in N₂–(2%, 20%, and 50%) O₂ and Ar–20% O₂ using simultaneous thermal analysis techniques. Two distinct oxidation regions were identified at each isothermal temperature …

Transmission Electron Microscopy Characterization Of High-Temperatur Oxidation Of Fe-20cr-5al Alloy Prepared By Focused Ion Beam Technique, Mohammad Dani, Pudji Untoro, Teguh Yulius Surya Panca Putra, Parikin Parikin, Joachim Mayer, Arbi Dimyati

Makara Journal of Technology

The Focused Ion Beam (FIB) technique was applied for cross section preparation of the oxidized alloy for Transmission Electron Microscopy (TEM) study. Prior to preparation, the specimens of Fe-20Cr-5Al alloy sheet were oxidized in air at 1200 oC for 2 minutes, 10 minutes, 2 hours, and 100 hours. The microstructure and elemental composition of the samples were characterized using TEM equipped with an Energy Dispersive X-Ray Spectroscopy (EDX). The Electron Energy Loss Spectroscopy (EELS) was used to determine of the light elements. The TEM investigation reveals remarkable microstructure evolution of the specimens during oxidation which generally exhibit a typical multi-layer …

Naio4 Oxidation Of Mussel Adhesive Protein Film And Its Corrosion Protection For Mg-1.0ca Alloy, Rui-Qing Hou, Ping-Li Jiang, Shi-Gang Dong, Chang-Jian Lin

Journal of Electrochemistry

The effect of oxidation of mussel adhesive protein (Mefp-1) film on the corrosive resistance for Mg-1.0Ca alloy was investigated by scanning electron microscopy (SEM), atom force microscopy (AFM), electron probe microanalysis (EPMA), Infrared reflection absorption spectroscopy (IRAS) and electrochemical methods. The results showed that the NaIO₄ induced oxidation of the pre-formed Mefp-1 film with porous morphology involved structural change of the DOPA group in the protein and resulted in a more uniform film with net-like morphology. The protein film without oxidation had an increasing resistance for the corrosion of Mg-1.0Ca alloy up to 7 days exposure. After oxidation, Epit …

High Temperature Oxidation Of Nb-Cr-Mo-Si-B Alloys, Kathryn S. Thomas

Open Access Theses & Dissertations

It has been the trend to use nickel based superalloys in high temperature applications, however higher temperatures are required in the effort to enhance the efficiency of such components as jet turbine engines. The melting temperature of the nickel based superalloy limits the extent to which temperature can be raised as these materials are typically used at temperatures within 200 degrees of their melting point. Refractory metal based systems are attractive due to their high melting points, low densities, and good high temperature strength. However, in such cases as niobium, poor oxidation resistance limits the widespread use of such alloys. …

Thermal Shock Studies On Carbon-Carbon Composites: Experimentation And Analysis, Alma Lucia Leanos

Open Access Theses & Dissertations

The oxidation behavior of C/C composites under thermal shock conditions in air is understood and predicted experimentally and by computational efforts. In Chapter. 1, both compressive properties and oxidation behavior of pristine and thermal shock exposed 2D C/C composite specimens were examined. Pristine test specimens were exposed to thermal shock conditions with temperatures ranging from 400°C to 1000°C in an oxidizing environment, followed by compression tests on pristine and thermal shock exposed specimens to obtain their compressive responses.

Similarly, in Chapter. 2, the influence of thermal shock conditions on both, the extent of carbon materials decomposition and the through-thickness compressive …

Electrochemical Fabrication Of Two-Dimensional Flower-Like Pt Nanostructures For Methanol Electrocatalytic Oxidation, Xia Wang, Jun Hu, Yong-Jun Li

Journal of Electrochemistry

Two-dimensional flower-like Pt nanostructures (2D FPNs) were fabricated on glassy carbon substrates by galvanostatical electrochemical technique. The electrolyte was the HAuCl₄ + HClO₄ aqueous solution without addition of any structure-directing organic reagent, which made as-prepared Pt nanostructures cleaner, exhibiting much higher reactivity. Scanning electron microscopic images revealed that 2D FPNs were spherical Pt nano-flowers constructed by the smallest building blocks, nano-leaves. The number density of spherical Pt nano-flowers can be tuned by controlling the electrodeposition time. High resolution transmission electron microscopic images indicated that each nano-leaf was formed by growing along Pt(111) direction. Electrocatalytic activities of as-prepared 2D …

Oxidation-Resistant, Solution-Processed Plasmonic Ni Nanochain-SioX (X < 2) Selective Solar Thermal Absorbers, Xiaobai Yu, Xiaoxin Wang, Qinglin Zhang, Juchuan Li, Jifeng Liu

Chemical and Materials Engineering Faculty Publications

Metal oxidation at high temperatures has long been a challenge in cermet solar thermal absorbers, which impedes the development of atmospherically stable, high-temperature, high-performance concentrated solar power (CSP) systems. In this work, we demonstrate solution-processed Ni nanochain-SiO_x (x < 2) and Ni nanochain-SiO₂ selective solar thermal absorbers that exhibit a strong anti-oxidation behavior up to 600 °C in air. The thermal stability is far superior to previously reported Ni nanoparticle-Al₂O₃ selective solar thermal absorbers, which readily oxidize at 450 °C. The SiO_x (x < 2) and SiO₂ matrices are derived from hydrogen silsesquioxane and tetraethyl orthosilicate precursors, respectively, which comprise Si-O cage-like …

Pulse Electrodeposition Of Pd-Ni Alloy Nanoparticles For Electrocatalytic Oxidation Of Formic Acid, Fang-Zu Yang, Jun-Pei Yue, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The Pd-Ni alloy nanoparticles with nickel atomic contents of 12.0%, 16.4% and 22.6% were successfully electrodeposited from a Pd-Ni alloy electrolyte by square wave pulse plating. The alloy nanoparticles were in the spherical shape with a diameter of 50 ~ 80 nm. As the growth potential of the alloy was negatively shifted, the nickel content of the alloy was increased, and the size of the nanoparticles was almost the same, whereas the number, the degree of crosslinking and the real active area of the nanoparticles were increased. As the nickel content of the alloy nanoparticles increased, the peak current for …

Sio2-Included Cesium Polyoxotungstate Catalysts For Oxidation, W Trakarnpruk, W Kanjina

Journal of Metals, Materials and Minerals

SiO2-included cesium polyoxotungstate catalysts were synthesized by a sol-gel method and characterizied by FTIR, XRD and N2 adsorption isotherms. XRD patterns prove that the cesium polyoxotungstate is uniformly dispersed in the silica network. The catalysts were used in oxidation of cyclohexane with H2O2. The products are cyclohexanol and cyclohexanone. The catalysts prepared by using a copolymer surfactant show higher surface area and exhibit higher activity. These catalysts are truly heterogeneous and can be reused at least 3 times.

Preparation And Catalytic Property Of High Surface Area Mixed Oxides From Calcination Of Mgcucr- And Mgcual-Layered Double Hydroxides, W. Trakarnpruk

Journal of Metals, Materials and Minerals

In this research work layered double hydroxides (LDHs) containing Mg, Cu and Cr(or Al) were prepared with starting Mg:Cu:Cr (or Al) molar ratio of 2:1:1. They were calcined at 500 ºC for 5 h to convert into corresponding mixed oxides possessing high surface area. The catalysts were characterized by chemical analysis (ICP), infrared spectroscopy (FTIR), thermal analysis (TGA/DTA), powder X-ray diffraction (XRD), surface area measurements and H2 temperature programmed reduction (TPR). Catalytic property of these mixed oxides catalysts were tested in the oxidation of ethylbenzene using tertbutylhydroperoxide as an oxidant without added solvent. The experimental results show that high conversion …

Kinetics And Mechanisms Of Titanium Wire Oxidation, Tanmay P. Engineer

Boise State University Theses and Dissertations

The kinetics and mechanisms of oxidation of titanium wire were assessed using a large test matrix in Ar-20% O₂ at 800 to 1200°C, and N₂-20% O₂ at 1000°C, for 0.5 to 24 hours. The effects of geometry on oxidation were evaluated by investigating the behavior of six high purity Ti wires with diameters varying from 50 to 2000 μm, with an objective of producing hollow TiO₂ tubes.

Oxidation behavior was characterized by measuring oxide thicknesses and morphology by optical microscopy, and the phases were characterized using a combination of SEM and TEM. The kinetics was …

Extraction Of Tin From Hardhead By Oxidation And Fusion With Sodium Hydroxide, C Bunnakkha, C Jarupisitthorn

Journal of Metals, Materials and Minerals

In this research work, the extraction of tin from tin-iron alloy or hardhead which is the intermediate product obtained during tin smelting was investigated. The hardhead containing 32.40 wt% Sn and 45.81 wt% Fe was ground to different sizes and oxidized at 500 to 800 °C for 1 to 6 hours to form SnO2 and Fe2O3. The results indicated that an increase in oxidation temperature decreased the required oxidation time. However using too high oxidation temperature (800 °C) resulted in sintering of the oxide product.In sodium hydroxide fusion stage, effects of fusion temperature, fusion time, NaOH quantity and oxide product …

Morphology And Roughness Of Al2o3 On Ferritic Stainless Steel Foil For Diesel Catalytic Converter Applications, Megan Butala

Materials Engineering

The improved thermal properties of metal-substrate catalytic converters enable effective catalysis sooner after ignition than traditional ceramic monoliths, resulting in less harmful emissions. ACAT Global, a manufacturer of stainless steel catalytic converters, uses ferritic stainless steel substrates for low temperature catalytic converters for diesel automobiles. Production begins with an oxidizing heat treatment to increase surface roughness. The success of the second production step, the application of catalyst-containing ceramic slurry (washcoat), depends on the surface roughness that results from oxidation. Formation of the primary oxide of interest, alumina (Al₂O₃), is controlled by the stainless steel foil composition, …

Al2O3 Oxide Morphology For Two Fe-Cr-Al Stainless Steel Foils Used In Gasoline Engine Catalytic Converters, Jennifer Suiter

Materials Engineering

Corrugated 0.05 in thick strips of Fe-Cr-Al ferritic stainless steel samples with 4% and 6% aluminum were heat treated, and the resulting Al₂O₃ oxide was analyzed using SEM imaging. Three heat treatment cycles were carried out for each sample. The heat treatments were based on future metal-substrate catalytic converter processing prior to applying the washcoat Each heat treatment started with a 90 minute ramp from room temperature to 538°C and a 32.5 minute ramp from 538°C to 899°C. The three different dwell periods at 899°C were 4 hours, 6 hours, and taking a sample out every hour …

The Effects Of Uncommon Silicides On The Oxidation Of Alloys From The Nb-Cr-Si System, Daniel Brendan Voglewede

Open Access Theses & Dissertations

Niobium based alloys are being tapped as potential successors to current nickel base superalloys in high temperature applications. In the aerospace industry, high temperature materials are constantly being pushed to higher temperature regimes in order to improve engine efficiency however current superalloys cannot be pushed further due to melting temperature limitations. Niobium, being a refractory metal, can withstand much higher temperatures than nickel however its oxidation properties are woefully inadequate.

The purpose of this study is to ascertain whether increased silicon additions can improve niobium oxidation properties by: forming ternary silicides with better oxidation properties and by preventing the formation …

Oxidation Of Borides And Carbides With Y2o3 And Ta Additions, Salvador Manuel Rodriguez

Open Access Theses & Dissertations

The study presented here describes an investigation of an oxidation scale of a fully-sintered Y2O3-ZrB2-TiC composite exposed in air at 1173K. Upon oxidation of the boride/carbide, a ZrO2-TiO2 was expected to form similar to the ZrO2-SiO2 dual scale of an oxidized ZrB2-SiC. The 47wt% Y2O3-38wt%ZrB2-16wt%TiC composite formed a dual scale consisting primarily of an Y2O3-ZrO2-TiC inner scale with an outer scale of ZrO2-TiO2-Y2O3.

The samples oxidized with a parabolic layer growth allowing the calculation of the effective diffusion coefficient indicating that the oxidation was controlled by oxygen ingress through primarily the ZrO2-Y2O3 phase. The oxygen potential between the inner layer …

Characterization Of The Oxidation Kinetics Of Fecral Ferritic Stainless Steels At 900°C For Catalytic Converter Applications, Stacy Stamm

Materials Engineering

This study characterized the oxidation kinetics of two types of ferritic stainless steel foils used as substrates for catalytic converters. Catalytic converters rely on an alumina layer on the surface of the foils, which allows the catalyst to attach to the substrate. Because the alumina layer is so important, this study characterized the weight gain, thickness, and composition of the alumina as it grew at 900°C for up to 400 hours. The two foils characterized were an MK foil, used for gasoline engines, and an EMS foil, used for diesel engines. The MK foil showed a percent weight gain of …

Development And Characterization Of The Oxidation Behavior Of Various High Temperature Niobium Based Alloys, Benedict Isabel Portillo

Open Access Theses & Dissertations

The oxidation response of various niobium based refractory alloys from the Nb-Mo-Si-B-X alloy system has been examined at temperatures between 700 and 1400°C in air. The development of these alloys was part of an ongoing effort to develop and discover a new materials system capable of replacing nickel based super alloys. Additions of titanium were found to provide limited oxidation resistance. A discontinuous layer of TiO2 was observed to from at temperatures above 1100°C. Alloys containing titanium additions were observed to suffer from pest oxidation at low and intermediate temperatures due to the development of Nb2O5. Poor oxidation resistance at …

Oxidation Of Cyclohexane And Ethylbenzene By Hydrogen Peroxide Over Co-Substituted Heteropolytungstate Catalyst, W Kanjina, W Trakarnpruk

Journal of Metals, Materials and Minerals

The tetrabutylammonium salt of Co-substituted heteropolytungstate, [(n-C4H9)4N]4 HPW11Co(H2O)O39.3H2O was synthesized and characterized. It was shown to be an active catalyst for the oxidation of cyclohexane and ethylbenzene. The oxidation reactions were performed using green oxidant hydrogen peroxide and acetonitrile as solvent. The major products of the oxidation of cyclohexane were cyclohexanone (K) and cyclohexanol (A). High selectivity towards K-A oil was achieved. At longer time cyclohexanol was converted to cyclohexanone. Ethylbenzene was also selectively oxidized to acetophenone. These oxidation reactions appear to be radical processes since they were totally inhibited in the presence of radical scavenger.

Ebc Development For Hot-Pressed Y2O3/Al2O3 Doped Silicon Nitride Ceramics, Sivakumar Ramasamy, Surendra N. Tewari, Kang N. Lee, Ramakrishna T. Bhatt, Dennis S. Fox

Chemical & Biomedical Engineering Faculty Publications

Multilayer EBCs of alcohol and sol-based slurries containing (a) 45% SiO₂-34% Y₂O₃-%Al₂O₃, (b) mullite/Gd₂SiO₅ (88/12wt.%) with and without B₂O₃ addition, (c) mullite/rare-earth silicates (94/6wt.%, (Gd₂SiO₅, Lu₂SiO₅, Er₂SiO₅, and HfSiO₄)), and (d) only mullite, were applied on hot pressed Y₂O₃/Al₂O₃ doped Si₃N₄ substrates. Of the four major EBC systems studied, only mullite/Gd₂SiO₅ (88/12wt.%) EBCs sintered in air at …

Effects Of Crystallographic Orientation On The Early Stages Of Oxidation In Nickel And Chromium, Louis P. Bonfrisco, Megan Frary

Materials Science and Engineering Faculty Publications and Presentations

Surface orientation plays an important role in the oxidation behavior of single crystals where studies have found the relative oxidation rates for surfaces with different orientations. However, most materials are polycrystalline and contain myriad orientations that contribute to the overall oxidation process. Here we determine the effects of orientation on the early stages of oxidation behavior as a function of surface orientation for polycrystalline nickel (face-centered cubic) and chromium (body-centered cubic). After high temperature oxidation, the oxide topography is characterized using optical profilometry and the underlying microstructure is characterized with electron backscatter diffraction (EBSD). By correlating results from EBSD and …

Enhanced [Ru(Bpy)3]2+-Mediated Oxidation Of Guanine Prompted By Dhp, Bao-Lian Zhang, Wei Hong, Bao-Yi Lu, Hong Li

Journal of Electrochemistry

The effects of dihexadecyl phosphate(DHP) and multi-walled carbon nanotubes(MWNTs) on the oxidation of guanine mediated by[Ru(bpy)₃]²⁺ on the ITO electrode have been investigated by cyclic voltammetry and differential pulse voltammetry.The results showed that [Ru(bpy)₃]²⁺ can mediate the oxidation.In the range from 0.01 to 0.15 mmol·L^-1,peak currents for guanine oxidation mediated by [Ru(bpy)₃]²⁺ increased with the rise of DHP concentrations.On the contrary,cationic surfactant HTAC has the ability to weaken the mediated oxidation of guanine.In addition,the oxidative mechanism of guanine mediated by [Ru(bpy)₃]²⁺ with the participation of DHP …

High Temperature Oxidation Characteristics Of Nb-10w-Xcr Alloys, Maria Del Pilar Moricca

Open Access Theses & Dissertations

The use of refractory metals in high temperature applications has been attractive for several years. Systems based on niobium represent a potential new generation of refractory materials systems because of their low density, high melting points, and strength at elevated temperatures. Despite these desirable characteristics, the widespread use of niobium-based alloys is limited because its oxidation resistance is still inadequate for structural applications. Understanding the oxidation kinetics of Nb-based alloys and the role of the different phases in the oxidation process is of crucial importance to improve the oxidation resistance of these materials.

The effect of Cr content on the …

Oxidation Modeling By Means Of Molecular Dynamics, Chaiyod Soontrapa

UNLV Theses, Dissertations, Professional Papers, and Capstones

Oxidation modeling is normally engineered to study systems at macroscopic scales, mostly in analytical forms based on diffusion theories. The associated time scale is usually in months, days, or minutes, and the length scale is in the order of microns. In this dissertation, oxidation modeling is performed at atomistic scale with the time and length scales in picoseconds and angstroms, respectively, using molecular dynamics. Molecular dynamics simulations generate trajectories of each atom or particle in a system according to the laws of physics. Studying oxidations under the atomistic point of view can offer new insights on atomic behaviors and influencing …