Materials Science and Engineering Commons^™

Interplay Between Phase Instability And Deformation Mechanisms In Beta Titanium Alloys In Aggressive Environments, Benjamin Elbrecht

All Dissertations

Modern designs, such as commercial jet turbines, are reliant on the high temperature performance of their constituent materials. Improvements to the strength-at-temperature of materials are critical to the continued advancement of efficiency and payload capacity in these advanced applications. This dissertation presents studies that progress towards this goal through the construction of a new experimental setup for complex temperature and force profiles that also accurately captures deformation behavior through non-contact measurements. Using this setup, studies into two specialty titanium alloys were executed: discovering the microscopic mechanisms responsible for the macroscale behavior and testing in conditions closely replicating aircraft turbine operating …

Moon Adaptive Technology For Extraterrestrial Architectural Robotics (Matear), Candela Noemi Solis Zampini

Theses and Dissertations

The Moon Adaptive Technology for Extraterrestrial Architectural Robotics (MATEAR) focuses on the development of an autonomous robotic system capable of providing structural building blocks directly from lunar regolith. As a sustained human presence on the Moon becomes a necessity, the costly and limited payload capacity associated with transporting construction goods from Earth creates a critical challenge. MATEAR addresses this problem through in-situ resource utilization (ISRU), integrating a regolith processing system onto a remote operated vehicle. The proposed system is designed to collect lunar dust, mechanically compact the material, and apply thermal treatment to enhance cohesion through sintering. These regolith-made bricks …

Enameling Coating Of Pipes: Thermal Proprieties And Corrosion Tests, Signo Reis, Genda Chen, Mike Koenigstein, Liang Fan

Materials Science and Engineering Faculty Research & Creative Works

Enamel coating on pipelines can be done in several ways such as the wet process, plasma spray, and electrostatic process. Wet process requires little capital expenses and provides an acceptable finish for industrial applications particularly when the part to be coated is small. Electrostatic process of enamel powder is most promising to coating large pipelines in field conditions. The enamel coating applied by the electrostatic process is very consistent and smooth since each particle is glass only. However, the powder is very fragile until fired and the charge retention is lowered in high humidity conditions. Coupons cut from a full-size …

Evaluation Of Iron-Phosphate Glass–Ceramic Waste Form For Electrorefiner Salt Waste Simulant Dechlorinated With Phosphoric Acid, Harmony Werth, Paige Murray, Lucas Greiner, Jade Beland, Charmayne Lonergan, Brian Riley, Krista Carlson

Materials Science and Engineering Faculty Research & Creative Works

The importance of glass and glass–ceramic nuclear waste forms has been reaffirmed in recent years by the growing interest in nuclear power as a reliable energy source. Determination of processing methods for the disposal of halide-containing wastes will be essential for the advancement of nuclear technologies such as non-aqueous fuel reprocessing. Phosphate-based dechlorination and subsequent vitrification of radioactive salt waste into an iron-phosphate waste form have been identified as a potential processing scheme for electrochemical processing waste. The impact of H₃PO₄-based dechlorination of complex salt mixtures on the vitrification process and structure of the final iron-phosphate …

Effect Of Composition On Grain-Boundary Chemistry And Fracture Behavior In High-Entropy Carbides, Caleb Schenck, Marium Mostafiz Mou, Elizabeth Pritchett, Fu Yun Tsai, Josephine Hartmann, Michael Lastovich, Sam Daigle, Kayla Yano, Matthew J. Olszta, Sanjit Bhowick, Elizabeth Kautz, Gregory E. Hilmas, William G. Fahrenholtz, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

High-entropy carbides (HECs) are often treated as a single material class defined by configurational entropy; however, their properties are governed by composition-specific defects and grain-boundary chemistry. This study demonstrates that substituting a single element can qualitatively change grain-boundary structure and fracture behavior in HEC ceramics. Two HECs, (Cr,Hf,Ta,Ti,Zr)C (HEC-Cr) and (Hf,Ta,Ti,W,Zr)C (HEC-W), were examined via electron microscopy, atom probe tomography, and molecular dynamics simulations. Simulations predict preferential segregation of Cr, W, and Zr to grain boundaries. Experiments confirmed Cr enrichment at grain boundaries and the formation of W-rich nanograins along boundary networks. Mechanical testing revealed that these compositional differences translated …

Evaluating The Integration Of Bio-Based Waste Into Cement Production: A Pathway To Sustainable Building, Anja Terzić, Suzana Filipović, Adriana Peleš Tadić, Jelena Živojinović, Ivana N. Jelić, Nina Obradović, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

Rapid urbanization has increased the demand for building materials, depleting natural resources used in cement production and prompting the use of alternative and waste materials. This research verifies that eggshell powder waste can fully replace limestone in clinker synthesis. Five clinkers were produced using eggshell powder, aluminum sources (bentonite, zeolite, fly ash, and kaolinitic–illitic clay), Fe-slag, and quartz sand, with mechanical preprocessing (10–30 min) before sintering at 1300 °C. Experimental tests assessed the effects of mix design and mechanical activation on clinkerization, phase formation, temperature, and mechanical properties. XRD, FTIR, and SEM/EDS confirmed consistent phase compositions and primary cement minerals. …

In-Operando Imaging For Mechanistic Insights And Process Optimization In The Biofuel-Driven Combustion Synthesis Of Cement And Precursor Phases, Shubham Agrawal, Jeffrey J. Long, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Biofuel-based combustion synthesis (BCS) is a promising low-carbon pathway for decarbonizing cement production, providing an alternative to the fossil-fuel-driven clinkering process typically conducted at ∼1450 °C. Understanding microscale combustion mechanisms is essential to efficiently transfer biofuel-generated heat to cement precursors for targeted phase formation. Unlike previous studies focusing on macro-scale parameters such as fuel content/type, porosity, and holding temperature, this work provides mechanistic insights into microscale combustion behavior, linking microstructural phenomena with macro-scale processing conditions to guide parameter optimization. In-operando microscale imaging was employed to examine combustion wave propagation, spatio-temporal temperature evolution, and microstructural transformations within reactive pellets. Two combustion …

Strong And Ductile Additively Manufactured Ti-6al-4v Through Yttrium Inoculation, Saeid Alipour, Ji Young Kim, Min Seok Kim, Arezoo Emdadi, Ju Li

Materials Science and Engineering Faculty Research & Creative Works

The unique microstructural features and thermal cycles in alloys produced by additive manufacturing (AM) techniques have led to the emergence of a new paradigm in the design and development of alloys for performance-critical applications. Despite the inherent microstructural features of AMed parts, optimizing the porosity-microstructure while acquiring desired mechanical performance has been crucial yet challenging. Hence, in many legacy alloys, achieving a strength-ductility synergy in the as-built condition without applying post-heat treatment or hybrid processes is considered an arduous task. In this research, we aimed to tailor the microstructure of the legacy Ti-6Al-4V alloy in the as-built condition by implementing …

Atom Probe Tomography Investigation Of Gas And Solid Fission Product Superlattice In Neutron Irradiated U-10 Wt.% Mo Fuel, Maalavan Arivu, Andrew Hoffman, Anish Ranjan, Assel Aitkaliyeva, Yaqiao Wu, Brandon Miller, Mukesh Bachhav, Dennis Keiser, Jian Gan, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Body-centered cubic structured γ U-Mo fuels have been developed for high performance research reactors. The formation of Xe gas bubble superlattice (GBS) in irradiated U-Mo fuels reduces the volumetric swelling of the fuels. In this study, atom probe tomography (APT) was used to measure the characteristics of the Xe GBS, including chemical composition, number density, and volume fraction of the gas bubbles, as well as the characteristics of the solid fission products, in neutron irradiated U-10 wt.% Mo fuel. It was found that in the bubbles (∼2 nm in diameter) that form the GBS are enriched with Xe with depletion …

Computer Vision And Machine Learning Approaches For Defect Detection In 3d-Printed Cementitious Materials: A Systematic Review, Muhammad Ali Musarat, Ruben Paul Borg, Jingjie Wei, Carl James Debono, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

3D printing is evolving at a fast pace in both the manufacturing and construction sectors. These advancements can greatly benefit these industries. However, the 3D printing of concrete structures presents some challenges due to defects in the 3D concrete printed elements. Hence, this study systematically reviews Artificial Intelligence (AI)-driven techniques, such as Computer Vision and Machine Learning, to identify surface defects that can occur in 3D-printed cementitious material structures. The adopted methodology was the PRISMA statement with the aim of reporting the systematic review and meta-analysis. Two well-known databases, Web of Science and Scopus, were utilised for data extraction of …

Study On The Effects Of Molecular Layer Deposition Coating And Mechanical Pressure On Lithium Metal Anodes, Cameron Mondl

Graduate Theses and Dissertations

Lithium (Li) metal is a highly promising anode material for next-generation energy storage systems due to its outstanding theoretical capacity and low electrochemical potential. However, its commercialization implementation has been hindered due to interfacial instability and uncontrollable dendrite formation, leading to poor cycling efficiency and thermal runaway. Among the most promising stabilization strategies, protective interfacial coatings have emerged as an effective solution to promote more uniform Li deposition and suppress erratic morphological inconsistencies. In particular, molecular layer deposition (MLD) enables uniform film thickness through layer-by-layer deposits, offering a highly versatile approach to protective interfacial layers. In addition to interfacial engineering, …

Recovery And Evaluation Of A Germanium Infrared Camera, Michael Paszek

Graduate Theses and Dissertations

Short-wave infrared imagers made of germanium are a promising way to extend silicon-compatible imaging beyond the visible spectrum. They also use mature CMOS fabrication and readout electronics. This thesis details the recovery, initialization, and evaluation of a germanium focal plane array (FPA) infrared camera system using both a sealed TriWave camera and a modular prototype platform. Functionality was restored to this legacy hardware, and repeatable testing workflows were established for evaluating packaged infrared imagers under controlled indoor and outdoor conditions. The prototype used a custom software interface named Merlott for evaluation, and it followed a standard sequence that included checking …

Adsorption Of Pfas On Bridged Functionalized Organosilica Materials, Elisha Lawerh Kabutey

Electronic Theses and Dissertations

PFAS are hazardous contaminants that have a devastating impact on human health and the environment. Their hazardous nature has led to the development of various adsorption methods for removing these contaminants from water sources. In this study, functionalized organosilica materials were synthesized from bis[3-(trimethoxysilyl)propyl] amine using the sol-gel method. The surface amino groups of the organosilica were converted into amine hydrochloride groups. Their adsorption properties were evaluated using salts of perfluorooctanoic acid, perfluorooctanesulfonic acid, and perfluorobutanesulfonic acid. Results showed excellent adsorption capacity of the materials. Adsorption of PFAS leads to particle agglomeration and flotation of the spent material. A column …

The Influence Of Composition On Porosity And Strength In Planetary Analog Saline Ices, Tara C. Tomlinson

Dartmouth College Ph.D Dissertations

This thesis investigates how composition influences the physical structure and mechanical behavior of saline ice, with implications for both terrestrial sea ice and the ice shells of ocean worlds such as Europa and Enceladus. This is done through a multi-pronged approach of both numerical modeling and laboratory experiments. Modeling results re- veal that small-scale parameter variations in porosity, permeability, and permeability fac- tor may produce large discrepancies when extrapolated to planetary scales, underscoring the need for improved experimental constraints on pore connectivity and thermochemical conditions. Laboratory analyses show that while total porosity is relatively uniform with depth, it varies strongly …

The Impact Of People Interests In Evaluating The Open Public Spaces' Quality In The City Centre, Hasan Hadi, Adil Al-Saidi, Haitham Alshamari

HBRC Journal

The quality of open public spaces in city centres significantly affects people's satisfaction and responses to their built environment. The significance of these areas allow people to assess their performance. this paper addresses the issue of People's interests that affect their evaluation of public urban spaces in city centres. The research applied an ontological methodology that is people's experiences determine the spatial quality of the public spaces in city centres. In order to discover and assess the seven value variables, it recommended diagnosing a random sample of users as a group (A) and (B). The urban space in the historic …

Optimized Bombax Ceiba/Jute Hybrid Epoxy Composites For Enhanced Thermal Insulation Performance, Shadman Ahmed Khan, Naeem Ahmmed, Md Tanvir Hossain, Abdullah Ibn Asheque, Md Ariful Islam, Md Abdul Kader, Md Sohel Rana, Sakib Masud

Michigan Tech Publications

The development of sustainable hybrid natural-fiber composites provides a practical way toward lightweight materials with tailored mechanical and thermal performance. In this study, Bombax ceiba (BC)/jute hybrid epoxy composites were fabricated using a stacked preform followed by compression molding, and the effect of fiber blending ratio on mechanical, thermal, and microstructural properties was systematically investigated. Three compositions-40/60, 50/50, and 60/40 BC/jute by weight-were evaluated. Mechanical testing showed that the J50 composite, with a balanced fiber ratio, exhibited superior flexural strength and impact resistance, indicating effective hybrid synergy and improved stress transfer between fibers and the matrix. Thermogravimetric analysis showed that …

Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li

Journal of Electrochemistry

Flow-cell architectures have emerged as a powerful platform for continuous and stable lithium-mediated nitrogen reduction (Li-NRR), enabling ambient-condition electrochemical ammonia synthesis and offering a promising alternative to Haber-Bosch processes. However, Li-NRR is exceptionally sensitive to trace water, and even minor variations in water content can profoundly alter interfacial chemistry. Here, we systematically investigate how initial water concentration affects Li-NRR performance in a continuous-flow cell. Excess water drives the formation of a thick solid electrolyte interphase (SEI) layer, which may impede nitrogen access to metallic lithium and hinder lithium-ion transport. As a result, the ammonia Faradaic efficiency collapses from ~61% to …

Insertion Of Noble Metal Free Cathodic Catalyst Layer With Fe-N-C Catalyst For Boosted Performance Of Pemfc, Shi Zhou, Muhammad Tariq, Asif Nadeem Tabish, Muhammad Salman, Fan-Di Ning, Muhammad Rayyan Tayyab, Ran-Ran Peng, Meng-Geng Hao, Wen-Mu Li, Xiao-Chun Zhou

Journal of Electrochemistry

Economical Fe-N-C catalysts are considered as promising alternatives to platinum group metal catalysts for proton exchange membrane fuel cells (PEMFCs). Despite exhibiting robust activity on rotating disk electrodes, their performance within membrane electrode assemblies often experiences limitations, such as decreased O₂ diffusion, high H₂O₂ formation, low proton conduction, and a lower electron transfer number. In this study, key factors, including proton transport, electron conduction, and gas diffusion within air-breathing PEMFCs, have been investigated by adjusting cathode catalyst layer (CCL) compositions. From the experimental results, the optimal peak power density was obtained when the loading of Fe-N-C …

Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Journal of Electrochemistry

Homogeneous electrocatalytic nitrogen reduction reaction (NRR) provides a powerful framework to interrogate molecular nitrogen-fixation pathways under mild conditions. By tuning the metal center, ligand architecture, and reaction medium, these systems enable capturing key intermediates and delivering mechanistic insight at the molecular-level resolution. Nevertheless, advances remain constrained by highly reduced operating potentials, intense competition from the hydrogen evolution reaction (HER), limited durability in turnover, and inadequate long-term stability.

In this review, we take electron delivery to the molecular active site as the guiding principle for organizing homogeneous electrochemical N₂ activation and transformation. We classify reported systems into direct electron transfer …

A Comparative Study Of Tin Electrorefining In Molten Licl–Kcl–Cacl₂: Experimental Two-Electrode Current Control And Theoretical Three-Electrode Potential Control, Bryant Johnson, George Ankrah, Ander Fuller, Devin Rappleye

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

Molten salt electrorefining is a mature technology for metal recovery, yet conventional current‑controlled, two‑electrode operation provides limited electrochemical selectivity and restricted insight into electrode‑specific behavior. In this work, a simplified model is developed to compare current‑controlled two‑electrode electrorefining data with a potential‑controlled three‑electrode electrorefining simulation using tin in molten LiCl–KCl–CaCl₂ as a surrogate for plutonium processing. The model examines anodic and cathodic limitations under fixed‑potential operation and evaluates implications for selectivity, efficiency, and runtime relative to experimentally demonstrated two‑electrode performance. Results indicate that independent potential control enables operation closer to thermodynamic selectivity limits, with the potential to suppress impurity oxidation …

Low-Velocity Impact Behavior Of Reinforced Commodity And High-Performance Thermoplastic Composites, Yubo Ma

Research & Creative Achievement Day

The low velocity impact behavior and compression after impact performance of glass fiber reinforced polyethylene terephthalate glycol (GF/PETG), glass fiber reinforced amorphous polyethylene terephthalate (GF/PETa), and carbon fiber reinforced polyether ether ketone (CF/PEEK) thermoplastic composites were investigated to compare impact resistance across different material properties and cost levels. Quasi-isotropic laminates were fabricated by compression molding and subjected to drop weight impact at energy levels of 10, 15, and 20 J/mm, followed by compression after impact testing in accordance with ASTM D7136M and D7137 standards. Impact force response, energy absorption characteristics, and damage development were evaluated to assess material behavior under …

Growing Large Single And Multi-Crystals From Alum Powder, Owen Paulson, Mayra G. Aguilar, Owen T. Maloney, Kole C. Koehler

Research & Creative Achievement Day

Crystal growth science is used to replicate the growth of crystals that form in nature. Channels of hot fluid with concentrations of minerals created the crystals found as gemstones. At low concentrations, no crystal grows. At high concentrations, a multitude of crystals grow. At the ideal concentration, a single, clear crystal grows. Four solution concentrations were used to create seed crystals. Those Alum seed crystals were attached to a string and suspended in various concentrations of Alum solution to find concentrations that create no crystal, a single crystal, and a multi-crystal.

Growing Alum Crystals, Todd Carroll, Daniela Gutierrez Rubio, Kevin Dang, Samuel J. Whempner

Research & Creative Achievement Day

One of the easiest crystal growth experiments uses Alum powder to dissolve in water. The dissolved material slowly forms with seed crystals to create larger crystals. As the dissolved material is depleted, more is added to continue the crystal growth. Four different concentrations were used for seed crystal growth. Those crystals were attached to a string and hung in a bath of Alum solution. Different strategies were used to grow crystals and in some cases dissolve crystals.

Growing Alum Crystals, Jackson A. Struhar, Alexis M. Freiboth, Ana N. Schneider

Research & Creative Achievement Day

Alum, also known as Potash, is used to can pickles. Alum powder was used to create seed crystals. The seed crystal was hung in a jar submerged in distilled water with alum powder dissolved to attempt to grow an Alum crystal over the Spring semester. Three different concentrations were used to determine changes associated with crystal growth and quality. Numerous strategies were employed throughout the semester as growth methods worked and did not work.

Growing Large Alum Crystals, Wyatt N. Laborde, Will Gunderson, Kyle R. Behrens

Research & Creative Achievement Day

Alum forms a colorless cubic crystal that can grow to the size of a small apple over the span of 2-3 months of growth in a concentrated solution. Many different seed crystal solutions were used to obtain large clear seed crystals. The best seed crystal was attached to a string and suspended in various concentrations of Alum solution to allow for the seed crystal to grow into a large crystal. By monitoring the weight of the crystal, the solution concentration was adjusted for optimum growth.

Design And Fabrication Of A Composite Torpedo Baseball Bat, Peyton A. Lee, Carter Mathison, Jaden J. Schwantz, Noah Misukanis, Cole V. Stalberger

Research & Creative Achievement Day

Observing current trends in Major League Baseball, there has been increasing interest in torpedo-style wood bats due to their unique weight distribution. Unlike traditional bat geometries, the torpedo design shifts more weight toward the hands, improving balance and allowing for greater control throughout the swing. This project applies the same concept using composite materials so that high school and college players can also have access to this design innovation. The proposed bat is constructed from carbon fiber reinforced polymer with an epoxy resin to create a lightweight and durable structure. The design aims to maintain the performance benefits of the …

Cast In Steel: Horseman's Axe, Sam A. Morris

Create@State

Cast in Steel is a competition between universities across North America started by the Steel Founders Society of America. The competition is centered around giving students the opportunity to learn about casting and the steel industry in general. A prompt of a weapon or tool with some level of historical significance is given to all the teams. The prompt for the 2026 Arkansas State University team, was a Horseman’s Axe. The team designed their rendition of a horseman’s axe, worked with Southern Cast Products as their local industry parter, and fabricated a finished axe to represent Arkansas State University as …

Development Of Cao-Based Heterogeneous Catalysts For The Production Of Palm Oil-Based N-Methyl Diethanolamine Esterquats, Haliza Abdul Aziz

Student Works (2020-2029)

Esterquats are cationic surfactants that are readily biodegradable and exhibit low aquatic toxicity. To produce esterquats via heterogeneous-catalyzed transesterification of methyl ester has become a preferred route to the conventional homogeneous catalysis as the approach can reduce the production cost through catalyst reuse and minimized water footprint through wastewater treatment. Many transesterification reactions catalyzed by pure calcium oxide (CaO) are attributed to its high basicity and it can be derived from a cheap, non-toxic, and environmentally friendly precursor. To enhance the performance and stability of CaO, a series of CaO-based catalysts were synthesized via a wet impregnation method. The catalytic …

Techno-Enviro-Economic Analysis Of Precipitated Calcium Carbonate Production From Carbon Dioxide In Cement Industry Flue Gas And Calcium Hydroxide, Natalia Debora Panggabean, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

CCUS is a technological solution to reduce emissions from the cement industry, which is the second largest CO2-intensive industry. This study aims to analyze technical, economic, and environmental performance of Precipitated Calcium Carbonate (PCC) synthesis in cement industry flue gas. The process simulation includes the CO2 capture system from cement plant, CO2 captured used as feedstock for PCC synthesis process through its reaction with calcium hydroxide. The simulation was carried out using ASPEN Plus software. Technical analysis was performed to determine the CO2 capture efficiency and PCC synthesis efficiency. Economic analysis was conducted to calculate CO2 capture cost and production …

Feasibility Analysis Of Thermal Oxidizer To Determine Remaining Life Using Fitness- For-Service Level 3 Method, Yudhi Yudistirawan, Donanta Dhaneswara, Wahyuaji Narottama Putra, Gama Widyaputra, Dewi Kurnia Suci, Agung Putra Mahardhika

Journal of Materials Exploration and Findings

An aged thermal oxidizer (TOX) in the oil and gas industry necessitates a comprehensive evaluation to ensure its continued safe operation. This study presents a Remaining Life Assessment (RLA) and a Fitness for Service (FFS) evaluation for the four main components of the TOX, in accordance with API 510, API 579/ASME FFS-1, and ASME BPVC Section VIII Div-1 standards. The investigation includes the determination of maximum stress and maximum temperature required to assess the operational viability of the reactor. The four components are radiant, convection, transition, and stack sections—were modeled using the finite element method (FEM). Following the geometric modeling, …