Materials Science and Engineering Commons^™

Dielectric Properties Of Polycrystalline And Single Crystal (100) Strontium Titanate From 4 To 295 K, Hung Trinh, Alan Devoe, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

The dielectric properties of single crystal and polycrystalline SrTiO₃ (ST) were investigated from 295 to 4 K. Relative permittivity (εr) and loss tangent (tan(δ)) were measured systematically as a function of direct current (DC) voltage (0 V/cm to 800 V/cm), frequency (100 Hz to 1 MHz), and temperature (295 K to 4 K) for type (100) single crystal SrTiO₃ (SC-ST) and for polycrystalline SrTiO₃ (PC-ST). Calculated equivalent series resistance (ESR) data are also reported. Overall, the permittivity of ST showed a dependence on temperature, DC voltage, and frequency. Dependences on voltage and frequency were only observed at …

Stability Of A Solid Oxide Cell Stack Under Direct Internal-Reforming Of Hydrogen-Blended Methane, Ya-Fei Tang, An-Qi Wu, Bei-Bei Han, Hua Liu, Shan-Jun Bao, Wang-Lin Lin, Ming Chen, Wan-Bing Guan, Subhash C. Singhal

Journal of Electrochemistry

In this work, the long-term stability and degradation mechanism of a direct internal-reforming solid oxide fuel cell stack (IR-SOFC stack) using hydrogen-blended methane steam reforming were investigated. An overall degradation rate of 2.3%·kh^–1 was found after the stack was operated for 3000 hours, indicating a good long-term stability. However, the voltages of the two cells in the stack were increased at the rates of 3.38 mV·kh^–1 and 3.78 mV·kh^–1, while the area specific resistances of the three metal interconnects in the stack were increased to 0.276 Ω·cm², 0.254 Ω·cm² and 0.249 Ω·cm^{2 …}

Rational Design Of Heterostructured Nanomaterials For Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics In Alkaline Media, Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma

Journal of Electrochemistry

Owing to the merits of high energy density, as well as clean and sustainable properties, hydrogen has been deemed to be a prominent alternative energy to traditional fossil fuels. Electrocatalytic hydrogen evolution reaction (HER) has been considered to be mostly promising for achieving green hydrogen production, and has been widely studied in acidic and alkaline solutions. In particular, HER in alkaline media has high potential to achieve large-scale hydrogen production because of the increased durability of electrode materials. However, for the currently most prominent catalyst Pt, its HER kinetics in an alkaline solution is generally 2–3 orders lower than that …

Surface Modification Of Poly(4,4'-Oxydiphenilene Pyromellitimide) With Low-Pressure Plasma Treatment, Cihan Aktas

USF Tampa Graduate Theses and Dissertations

This study explores the change of the wetting characteristics of commercially availablepolyimide (PI), Kapton® HN, films a type of poly(4,4′-oxydiphenylene-pyromellitimide), following treatment with low-pressure plasmas of carbon tetrafluoride (CF4), air, hydrogen (H2), carbon-dioxide (CO2) and oxygen (O2) gases as well as the surface texturing via laser-exposure procedure. The water contact angle (CA) and surface free energy (SFE) of untreated PI films were determined as 82.4°±0.8 and 45.0±0.3 mN/m, respectively. After CF4 plasma gas treatment, the CA value of PI films increased to 110.2°±1.0, while it decreased to 9.3°±2.3 after O2 plasma gas treatment. The surface free energy (SFE) of PI …

Synthesis And Characterization Of Cellulose Microfibril-Reinforced Polyvinyl Alcohol Biodegradable Composites, Fatemeh Mahdiyeh-Boroujeni, Gabriella Fioravanti, Ronald Kander

School of Design and Engineering Papers

The pursuit of an environmentally sustainable manufacturing process requires the substitution of less damaging and recyclable solutions for harmful reagents. This study aims to assess the effectiveness of using cellulose microfibrils synthesized via different hydrolysis reactions as reinforcing agents in polyvinyl alcohol (PVA) at varying concentrations. The investigation explores the morphology, thermal properties, and chemical behavior of the cellulose particles. The cellulose microfibrils (CMFs) produced using citric acid exhibited the highest yield and aspect ratio. Notably, particles from organic acids demonstrated greater thermal stability, with oxalic acid-derived particles displaying the maximum thermal degradation temperature. Subsequently, cast films of PVA reinforced …

Research On Orthogonal Test Of Mgo-Fiber Cement Soil′S Deformation Modulus, Hu Qizhi, Yu Yang, Ma Qiang, Zhuang Xinshan

Journal of China & Foreign Highway

Appropriate amounts of MgO and fiber can improve the compressive strength of cement soil. In order to further study the mechanical properties of MGO-fiber cement soil, Minitab software was used to design an orthogonal test method, and sensitivity analysis and influence analysis were carried out. The change rules of deformation modulus of MgO content, fiber content, and fiber length were studied at three different levels. The regression equations of MgO content, fiber content, and fiber length with cement soil deformation modulus were obtained by using Matlab software to process the test data. The sample was tested by scanning electron microscope …

Experimental Study On Performance Of Cast Asphalt Mixture Basedon Dry Modification, Wang Ming, Li Bo, Bao Guangzhi, Hu Deyong

Journal of China & Foreign Highway

Cast asphalt mixture is the most widely used material for the pavement of long-span steel bridge decks, and the special asphalt binder cannot be produced and used in small batches. The wet modification process is obviously not suitable for the production of the cast asphalt mixture during the operation and maintenance period. In this paper, according to the requirements of cast asphalt mixture and its binder, combined with the requirements of the dry modification process, the developed direct injection modifier was employed to conduct the mix design of cast asphalt mixture and tests of the fluidity, penetration and increment, low-temperature …

Kinetic Applications Of Smart Materials In Architecture: A Descriptive Analysis, Youssef Elkhayat

Journal of Engineering Research

In recent years, many smart materials for architectural applications have been invented. Some smart materials can adapt and interact with the surrounding environment and its variants, whether temperature, humidity, daylight or electric current. Smart material changes its shape without any need for assistance, and it can return to its original state without any significant deformation in shape with the end of the external influence. The invention of smart materials stimulated several architects and facade designers to consider using them in various architectural applications such as sun shading, sun breakers, and windows, significantly impacting the concept and technology of movement in …

Hanford Low-Activity Waste Vitrification: A Review, José Marcial, Brian J. Riley, Albert A. Kruger, Charmayne E. Lonergan, John D. Vienna

Materials Science and Engineering Faculty Research & Creative Works

This Paper Summarizes the Vast Body of Literature (Over 200 Documents) Related to Vitrification of the Low-Activity Waste (LAW) Fraction of the Hanford Tank Wastes. Details Are Provided on the Origins of the Hanford Tank Wastes that Resulted from Nuclear Operations Conducted between 1944 and 1989 to Support Nuclear Weapons Production. Waste Treatment Processes Are Described, Including the Baseline Process to Separate the Tank Waste into LAW and High-Level Waste Fractions, and the LAW Vitrification Facility Being Started at Hanford. Significant Focus is Placed on the Glass Composition Development and the Property-Composition Relationships for Hanford LAW Glasses. Glass Disposal Plans …

The Growth Of Ge And Direct Bandgap Ge1−Xsnx On Gaas (001) By Molecular Beam Epitaxy, Calbi Gunder, Fernando Maia De Oliveira, Emmanuel Wangila, Hryhorii Stanchu, Mohammad Zamani-Alavijeh, Solomon Opeyemi Ojo, Sudip Acharya, Abdulla Said, Chen Li, Yuriy I. Mazur, Shui-Qing Yu, Gregory J. Salamo

Materials Science and Engineering Faculty Publications and Presentations

Germanium tin (GeSn) is a tuneable narrow bandgap material, which has shown remarkable promise for the industry of near- and mid-infrared technologies for high efficiency photodetectors and laser devices. Its synthesis is challenged by the lattice mismatch between the GeSn alloy and the substrate on which it is grown, sensitively affecting its crystalline and optical qualities. In this article, we investigate the growth of Ge and GeSn on GaAs (001) substrates using two different buffer layers consisting of Ge/GaAs and Ge/AlAs via molecular beam epitaxy. The quality of the Ge layers was compared using X-ray diffraction, atomic force microscopy, reflection …

Thermo-Photo Catalytic Anode Process For Carbonate-Superstructured Solid Fuel Cells, Hanrui Su, Yun Hang Hu

Michigan Tech Publications

Converting hydrocarbons and greenhouse gases (i.e., carbon dioxide, CO2) directly into electricity through fuel cells at intermediate temperatures (450 to 550 °C) remains a significant challenge, primarily due to the sluggish activation of C-H and C=O bonds. Here, we demonstrated a unique strategy to address this issue, in which light illumination was introduced into the thermal catalytic CO2reforming of ethane in the anode as a unique thermo-photo anode process for carbonate-superstructured solid fuel cells. The light-enhanced fuel activation led to excellent cell performance with a record-high peak power density of 168 mW cm-2at an intermediate temperature of 550 °C. Furthermore, …

Balsa Bridge, Caleb T. Lovett

All Undergraduate Projects

The problem presented throughout this report was to create a small-scale bridge made entirely out of balsa wood and glue, that could withstand substantial force, as well as perform a lifting/lowering cycle. Other requirements associated with the bridge were properties of weight, deflection, size, and shape. This problem presented a challenge that tested the mathematical side of engineering, being strongly reliant on statics, mechanics of materials, and mechanical design analyses.

To approach this problem, the first step was to complete in depth calculations of the chosen design. With this done, manufacturing and assembly was able to be completed. With a …

Hempcrete Curtain Walls, Anh Bui

2024 Awards for Excellence in Student Research and Creative Activity - Documents

This research aims to scrutinize the performance, durability, and viability of hempcrete in curtain wall applications—an exploration critical to advancing sustainable construction practices. Comprising hemp hurds and lime binders, hempcrete stands as an emerging sustainable building material with promising ecological benefits. Despite its potential, there exists a notable research gap concerning its application in curtain walls, which demand rigorous structural and weatherproofing standards. The primary objective is to subject full-scale hempcrete curtain wall assemblies to ASTM standard test methods, comparing their performance with conventional materials like stone and glass. The research hypothesis posits that hempcrete will exhibit satisfactory strength, fire …

Electrochromic Polymers: From Electrodeposition To Hybrid Solid Devices, Haradou Sare, Dongmei Dong

College of Science & Mathematics Departmental Research

This paper reports on the linear colorimetric and electrochromic (EC) characteristics of electrodeposited polyaniline (PANI) films. This paper also investigates the infrared EC properties of acid-doped PANI films. The electrochemical polymerization method was employed to create a porous and thin PANI film layer onto PET-ITO substrates. This layer was capped with WO3 film to create a gel electrolyte sandwich structure that demonstrates the compatibility of PANI films with cathodic WO3 films in full devices. The electrodeposition of the film was fabricated by applying different voltages and time, with the optimal film quality achieved with the 1.7 V voltage and a …

Research Trends And Impact Report On Aggregation-Induced Emission (Aie), 2001-2021, Elsevier Analytical Services

Public Reports

Since the concept of AIE was first proposed in China in 2001, it has gradually grown to a field of science that attracts dedicated researchers from around the world. Elsevier's data analytics team used AIE experts' interpretation of current theoretical, technological, and industrial development trends in the field for reference to collect AIE-related global scientific publications (from the Scopus database) to serve as a publication set in the field of AIE. This was undertaken to present, accurately and objectively, the development of AIE research over the past two decades and the latest scientific advancements in the field; to facilitate the …

Predicting Compressive Strength Of Concrete Incorporating Fly Ash, Blast Furnace Slag, And Superplasticizer Using Machine Learning Techniques, Muhammad Faisal Yaqub

2024 REYES Proceedings

Concrete is the second most essential element in the construction industry, and its strength requirements vary based on the specific conditions of each project. However, determining the compressive strength of concrete involves laboratory tests, which wastes a lot of time and money. Researchers have developed machine learning models that predict the compressive strength of cement-based concrete having various mixes. In this research, the compressive strength of concrete incorporating fly ash, blast furnace slag, and superplasticizer is predicted using different machine learning models, namely, Linear Regression, Random Forest Regression, Decision Tree Regression, Extreme Gradient Boosting, Light Gradient Boosting, AdaBoost, and CatBoost …

Deep Learning Based Optical Flow Analysis Of High-Speed Flows, Daniel H. Zhang, Zifeng Yang

Mechanical and Materials Engineering Faculty Publications

Two-dimensional Rayleigh scattering imaging is utilized to quantify the high-speed flow velocity by employing deep learning based optical flow analysis, along with density fields from Rayleigh scattering intensity profiles.

Amplification-Free Rapid Detection Of Specific Oligonucleotides Through Formation Of Core-Satellite Nanostructures On Solid Substrates, Vineet Kumar Jayakrishnan

Material Science and Engineering Theses - Archive

A rapid, portable, and highly sensitive method for detecting specific pathogens like Covid-19 would be invaluable for public health and emergency responses. The current standards like PCR and RT-PCR, are incredibly sensitive but also time-consuming, require skilled personnel, and demand substantial lab space. Here, we propose an alternative method capable of detecting specific oligonucleotide sequences within just 3 minutes, using a portable silicon or glass substrate (6 mm x 9 mm). We demonstrated this using 67-mer oligonucleotides with a Covid-19 sequence as a model system, achieving a detection sensitivity down to 1 nM. Our approach involves sandwiching target COVID-19 oligonucleotides …

Investigation Of Bone Structure And Composition Differences In Osteofibrous Dysplasia And Neurofibromatosis Type 1, Farzaneh Fereidouni

Material Science and Engineering Dissertations - Archive

Abstract

Investigation of Bone Structure and Composition Differences in Osteofibrous Dysplasia and Neurofibromatosis Type 1

Farzaneh Fereidouni, Ph.D.

The University of Texas at Arlington, 2024

Supervising Professor: Harry F. Tibbals

Bone genetic diseases such as Osteofibrous Dysplasia (OFD) and Neurofibromatosis type 1 (NF1) present significant challenges, particularly in children, due to their effects on skeletal homeostasis. This study aims to apply advanced material analysis to elucidate the biological disparities associated with OFD and NF1 bone dysplasia and contribute to developing diagnostic protocols and remediation approaches for these and similar bone disorders.

By employing various analytical methods, including analysis of mineral-to-matrix …

Sub-1k Cold Electron Transport At Room Temperature, Anthony Martinez

Material Science and Engineering Dissertations - Archive

Thermally excited electrons at the high-energy tail of the Fermi-Dirac distribution impose fundamental limitations on the performance of solid-state electronic and spintronic devices. For example, the thermally excited electrons obscure the Coulomb blockade essential for single-electron transport. The hot electrons can also overcome the energy barrier of Metal-Oxide-Semiconductor Field-Effect transistors (MOSFETs), causing unwanted leakage currents that lead to excessive power consumption in the integrated circuits. This study investigates an approach in which quantum states are used to manipulate electron tunneling, blocking the transport of thermally excited hot electrons, thereby enabling cold-electron transport at room temperature. Here two heterogeneous quantum wells …

Kissing Bond Assessment In Adhesive Bonded Carbon Fiber Reinforced Composites Using Dielectric Spectroscopy, Minhazur Rahman

Mechanical and Aerospace Engineering Dissertations - Archive

The widespread use of fiber-reinforced composites in industries such as space, aviation, automobiles, and construction necessitates the formation of robust composite joints between critical structural components. Although adhesive-bonded joints are superior with improved load distribution and reduced weight, they are often overlooked in favor of bolted joints and mechanical fasteners due to the lack of reliable Non-Destructive Evaluation (NDE) techniques for adhesive-bonded composites. The anisotropic nature of the substrate and the intricate interfacial interactions between the adherend and adhesive material present significant challenges for conventional NDE methods. Moreover, weak adhesive bonds can result from uncontrolled manufacturing parameters, such as accidental …

Experimental Investigations And Optimization Of 3d Printed Cellular Structures For Protection Against Traumatic Brain Injury, Aaron R. Jackson

Mechanical and Aerospace Engineering Dissertations - Archive

Traumatic Brain Injury (TBI) disrupts brain function due to head impacts, blast exposures, and ballistic penetrations. It is a significant cause of mental health issues and disability, particularly among military personnel. Historically, combat helmets were designed primarily to protect against fragments. However, recent data highlights the need for helmets that also protect against blast and blunt impacts. Effective TBI prevention requires helmets that address various energy threats while remaining lightweight. A critical metric in this effort is head acceleration, which is closely linked to injury across different scales of brain damage.

Four lattice structures were 3D printed using Digital ABS …

Synthesis Of Ni-Based Intermetallics By Electrolytic Plasma Processing Of Ti And Ti-Based Alloys, Chuzhong Zhang

Material Science and Engineering Dissertations - Archive

EPP is an innovative surface modification technique that enables the deposition of metal ions from the electrolyte and their integration with substrate atoms to form intermetallic compound surface layers. EPP offers advantages such as high deposition rates, environmental cleanliness, and operational simplicity. In this study, Ni-Ti intermetallic layers were successfully synthesized on a Ti-6Al-4V substrate using EPP. The properties of the resulting Ni-Ti intermetallic layers were characterized using SEM, EDS, XRD, TEM, nanoindentation, and tribology tests.

This work aims to understand the fabrication mechanism and investigate the effects of various processing parameters on the EPP process. Key factors such as …

Generalizable Fugitive Carrier Method For 3d Printing Of Hydrogels, Hakan Arslan

Mechanical and Aerospace Engineering Dissertations - Archive

Hydrogels, with physical characteristics resembling biological soft tissues, hold great potential for bioinspired and biomedical applications. However, using them in additive manufacturing systems has challenges because of their poor mechanical and rheological properties. In response to these challenges, we introduce a fugitive carrier method, a novel and generalizable approach for materials incompatible with pneumatic-based extrusion three-dimensional (3D) printers. Our developed fugitive carrier method allows the 3D printing of a broad spectrum of hydrogel precursors with low viscosity while retaining their inherent properties. This technique has been successfully demonstrated by creating biomimetic structures with anisotropic and programmable systems utilizing temperature-sensitive hydrogel …

Quantitative Modeling Of Micro Discharge And Oxide Growth In Plasma Electrolytic Oxidation Of Titanium, Kingsley I. Ochiabuto

Material Science and Engineering Dissertations - Archive

Plasma electrolytic oxidation (PEO) has been extensively applied in the past to improve the tribological properties of titanium and its alloys allowing their widespread use in industrial applications. However, the complete PEO mechanism of action remains unclear. While there are several mathematical models providing useful insights into the PEO process, they do not fully incorporate the effect of applied potential on the outcomes of PEO. In this work, we develop an experimentally informed computational model by expanding on the dielectric breakdown model. We incorporate experimental data to extract key parameters, exploring the iterative dependency of the oxide thickness and ionic …

Spray-On Sensor Formulations That Enable Detection Of Physical And Chemical Stimuli, Priyanka Shiveshwarkar

Bioengineering Dissertations - Archive

Polydiacetylene based materials have been used for a variety of liquid phase sensing applications. There remains a need for low cost, easy-to-read gas phase sensors for continuous monitoring of physiological parameters and environmental hazards at work or at home. Such sensors could have applications in everyday life, for example as point-of-care or at home testing devices to enable early detection of disease to reduce healthcare costs. Making accessible and non-invasive technologies for monitoring of health and health risks provides individuals with the ability to be proactive in regard to their health and safety. In other examples, environmental monitoring systems could …

Generating Blood Analog For Laser Induced Fluorescent Particle Image Velocimetry, Chungyiu Ma, Jared Chong, Hang Yi, Zifeng Yang, Luke Bramlage, Bryan Ludwig

Mechanical and Materials Engineering Faculty Publications

To mimic blood non-Newtonian viscosity features under designated temperatures from 305 to 315 K, transparent blood analogs were generated by the mixture of xanthan gum and deionized water with fluorescent particles for laser induced fluorescent particle image velocimetry.

Enhancing Scanning Tunneling Microscopy With Automation And Machine Learning, Darian Smalley

Graduate Thesis and Dissertation 2023-2024

The scanning tunneling microscope (STM) is one of the most advanced surface science tools capable of atomic resolution imaging and atomic manipulation. Unfortunately, STM has many time-consuming bottlenecks, like probe conditioning, tip instability, and noise artificing, which causes the technique to have low experimental throughput. This dissertation describes my efforts to address these challenges through automation and machine learning. It consists of two main sections each describing four projects for a total of eight studies.

The first section details two studies on nanoscale sample fabrication and two studies on STM tip preparation. The first two studies describe the fabrication of …

Sustainable Additive Manufacturing Of Polysulfone Membranes For Liquid Separations, Brian Leonard, Harrison Loh, David Lu, Ebuka A. Ogbuoji, Isabel Escobar, Konstantinos Sierros, Oishi Sanyal

UK CARES Faculty Publications

Membranes serve as important components for modern manufacturing and purification processes but are conventionally associated with excessive solvent usage. Here, for the first time, a procedure for fabricating large area polysulfone membranes is demonstrated via the combination of direct ink writing (DIW) with non-solvent induced phase inversion (NIPS). The superior control and precision of this process allows for complete utilization of the polymer dope solution during membrane fabrication, thus enabling a significant reduction in material usage. Compared to doctor blade fabrication, a 63% reduction in dope solution volume was achieved using the DIW technique for fabricating similarly sized membranes. Cross …

Graphene Reinforced Polymer Composite For Small-Scale Vertical Axis Wind Turbine Rotors, Kunal A. Bachim

Mechanical and Aerospace Engineering Theses - Archive

Polymers have evolved as an indispensable asset in various sectors ranging from packaging and construction to energy and aerospace. However, the accumulation of polymer waste poses a necessity to shift toward sustainable waste management processes. Mechanical recycling is a primary method in establishing a circular economy approach for polymers. However, a fundamental challenge arises in this process: a decrease in the mechanical performance of the recycled product compared to that of its pristine counterpart.

This project addresses the challenge of enhancing the recyclability of polyethylene terephthalate (PET) from discarded polymer material by incorporating graphene nanoparticles into the polymer matrix during …