Materials Science and Engineering Commons^™

Applied Evanescent Wave On Zinc Oxide Nanorods Coated Glass Surface For Sensing Applications, Mohd Hafiz Jali

Student Works (2020-2029)

A simple and workable optical fiber sensor was successfully proposed and demonstrated by integrating the microfiber and the glass surface coated with Zinc Oxide (ZnO) nanorods. It exploited the distinctive features of the large evanescent wave of the microfiber and surface absorption capability of the ZnO nanomaterials coated glass surface to couple with the surrounding analyte. An experimental validation was performed to optimize and verify the sensing performance of the proposed structure. ZnO nanorod growth time of 12-hours and microfiber waist diameter of 6 µm provide optimum sensing results towards the changes of humidity concentration level. The diameter of silica …

Influence Of Parameters Of Non-Standard Modes Of Heat Treatment On Increasing The Wear Resistance Of Steel Products, Dorob Murotovich Berdiyev Dsn, Abdulaziz Abdullajanovich Yusupov Head Teacher, Ravshan Kobilovich Tashmatov Doctoral Student, Tuychi Nemat Ogli Ibodullayev Assistant, Kabira Erkinovna Qurbonova Head Teacher

Scientific-technical journal

The use of non-standard modes of heat treatment increases the density of dislocations in the crystal structure of the α-phase and increases the wear resistance of carbon, low-alloy steels under various friction conditions, which is comparable to the results when heated to a standard temperature (Ac₃+30÷50 °C). The preliminary extreme heating temperature is determined. After re-quenching at standard temperature and low tempering, the wear resistance of steels under various types of friction increases by up to 40 % compared to standard quenching.

Influence Of Parameters Of Non-Standard Modes Of Heat Treatment On Increasing The Wear Resistance Of Steel Products, Dorob Murotovich Berdiyev Dsn, Abdulaziz Abdullajanovich Yusupov Head Teacher, Ravshan Kobilovich Tashmatov Doctoral Student, Tuychi Nemat Ogli Ibodullayev Assistant, Kabira Erkinovna Qurbonova Head Teacher

Scientific-technical journal

The use of non-standard modes of heat treatment increases the density of dislocations in the crystal structure of the α-phase and increases the wear resistance of carbon, low-alloy steels under various friction conditions, which is comparable to the results when heated to a standard temperature (Ac₃+30÷50 °C). The preliminary extreme heating temperature is determined. After re-quenching at standard temperature and low tempering, the wear resistance of steels under various types of friction increases by up to 40 % compared to standard quenching.

Solid State Synthesis And Characterization Of Apatite Based Ceramic Waste Form For The Immobilization Of Radioactive Iodine, Md Imdadul Islam

LSU Doctoral Dissertations

The growing demand for nuclear power in the United States and worldwide is accountable for addressing the major concern of radioactive waste, involving the technical challenges of maintaining the nuclear fuel cycle and immobilizing high-level wastes for safe disposal in geological storage. The appropriate selection of waste forms for spent nuclear fuel such as fission products and radionuclides can be effective means for a feasible and sustainable nuclear fuel cycle. But highly volatile radionuclides such as iodine (129) are of specific concern due to its extraordinary long half-life (15.7 million years). Due to its poor solubility and high volatility at …

Fabrication And Characterization Of Electrospun Poly(Acrylonitrile-Co-Methyl Acrylate)/Lignin Nanofibers: Effects Of Lignin Type And Total Polymer Concentration, Suchitha Devadas, Saja M. Nabat Al-Ajrash, Donald A. Klosterman, Kenya A. Crosson, Garry S. Crosson, Erick S. Vasquez

Chemical and Materials Engineering Faculty Publications

Lignin macromolecules are potential precursor materials for producing electrospun nanofibers for composite applications. However, little is known about the effect of lignin type and blend ratios with synthetic polymers. This study analyzed blends of poly(acrylonitrile-co-methyl acrylate) (PAN-MA) with two types of commercially available lignin, low sulfonate (LSL) and alkali, kraft lignin (AL), in DMF solvent. The electrospinning and polymer blend solution conditions were optimized to produce thermally stable, smooth lignin-based nanofibers with total polymer content of up to 20 wt % in solution and a 50/50 blend weight ratio. Microscopy studies revealed that AL blends possess good solubility, miscibility, and …

Magnetically Induced Demulsification Of Water And Castor Oil Dispersions Stabilized By Fe3o4-Coated Cellulose Nanocrystals, Mohammad J. Hasan, Frankie A. Petrie, Ashley E. Johnson, Joshua Peltan, Meredith Gannon, Robert T. Busch, Serhiy O. Leontsev, Erick S. Vasquez, Esteban E. Ureña-Benavides

Chemical and Materials Engineering Faculty Publications

Superparamagnetic iron oxide (Fe3O4) nanoparticle (NP) coated cellulose nanocrystals (CNCs) were synthesized and used to prepare emulsions with magnetically controlled stability. Magnetite NPs were deposited onto the surface of wood pulp CNCs (WCNCs) and bacterial CNCs (BCNCs) by a one-step coprecipitation method. The effect of the CNC to Fe3O4 mass ratio (1:1, 1:2, and 1:4) was varied to optimize the colloidal, magnetic and emulsifying properties of the hybrid NPs. TEM images showed that the 1:4 ratios lead to greater coverage of Fe3O4 than lower Fe3O4 loadings (1:1, and 1:2). The CNCs and Fe3O4 appeared to interact via hydrogen bonding between …

Highly Efficient Visible-Light Photocatalytic Ethane Oxidation Into Ethyl Hydroperoxide As A Radical Reservoir, Yao Zhu, Siyuan Fang, Shaoqin Chen, Youjie Tong, Chunling Wang, Yun Hang Hu

Michigan Tech Publications, Part 1

Photocatalytic ethane conversion into value-added chemicals is a great challenge especially under visible light irradiation. The production of ethyl hydroperoxide (CH CH OOH), which is a promising radical reservoir for regulating the oxidative stress in cells, is even more challenging due to its facile decomposition. Here, we demonstrated a design of a highly efficient visible-light-responsive photocatalyst, Au/WO , for ethane oxidation into CH CH OOH, achieving an impressive yield of 1887 μmol g in two hours under visible light irradiation at room temperature for the first time. Furthermore, thermal energy was introduced into the photocatalytic system to increase the driving …

Fabrication And Characterization Methods Of Self-Cleaning Coatings For Solar Panels Application, Mohammed Khaleel M Alhussain

USF Tampa Graduate Theses and Dissertations

Transparent self-cleaning coatings with superhydrophobic and superhydrophilic behavior are of great interest in a wide range of industrial applications such as automotive, solar panels, windows, and optical devices. Each has its uses, properties, and characteristics. For the use of these coatings on solar panels, certain features are important in maintaining the efficiency of the panels in different weather conditions and reducing the operation and maintenance cost, such as self-cleaning, high transparency, antifouling, anti-fogging, and anti-icing. Herein, we have investigated the fabrication of self-cleaning coatings using two simple methods and ways to improve their characteristics. In the first method, a hydrophobic …

Spent Tea Leaves As An Adsorbent For Micro Solid Phase Extraction Of Polycyclic Aromatic Hydrocarbons In Different Matrices, Nazzatul Atirah Mohd Nazir

Student Works (2020-2029)

Food and water may be contaminated by hazardous pollutants, one of is a polycyclic aromatic hydrocarbon (PAHs), where 16 of pollutant in this group listed as a priority pollutant by Environmental Protection Agency (EPA). Thus, analysis of food contaminations is crucial for consumer safety. Therefore, a simple, sensitive, and miniaturize sample preparations are needed. In this study, spent tea leaves (STL), a waste from brewed tea, Camellia sinensis was utilized as novel micro-solid phase extraction (μ-SPE) sorbent for the determination of polycyclic aromatic hydrocarbon (PAHs) for the first time. It was of interest that spent tea leaves (STL) might serve …

Nanocellulose Sheets From Oil Palm Empty Fruit Bunches Treated With Naoh Solution, Farah Fahma, Faiza Ayu Lestari, Ika Amalia Kartika, Nurmalisa Lisdayana, Evi Savitri Iriani

Karbala International Journal of Modern Science

The objective of this study is to produce nanocellulose sheets from oil palm empty fruit bunches (OPEFBs). Nanocellulose sheets from OPEFBs were prepared through the dewatering process using vacuum filtration. Subsequently, the produced sheets were treated with NaOH solution to improve the mechanical stability of their structure, causing them to be firm in water. The water absorption of nanocellulose sheet increased with increasing NaOH concentrations up to 20 wt%, increasing tensile strength, and Young’s modulus, but decreased when they were treated with 30 wt%. The diameter shrinkage of nanocellulose sheets was directly proportional to the NaOH concentration and soaking time. …

Progress In Proton-Conducting Oxides As Electrolytes For Low-Temperature Solid Oxide Fuel Cells: From Materials To Devices, Wei Zhang, Yun Hang Hu

Michigan Tech Publications, Part 1

Among various types of alternative energy devices, solid oxide fuel cells (SOFCs) operating at low temperatures (300-600°C) show the advantages for both stationary and mobile electricity production. Proton-conducting oxides as electrolyte materials play a critical role in the low-temperature SOFCs (LT-SOFCs). This review summarizes progress in proton-conducting solid oxide electrolytes for LT-SOFCs from materials to devices, with emphases on (1) strategies that have been proposed to tune the structures and properties of proton-conducting oxides and ceramics, (2) techniques that have been employed for improving the performance of the protonic ceramic-based SOFCs (known as PCFCs), and (3) challenges and opportunities in …

Universal Image Segmentation For Optical Identification Of 2d Materials, Joshua Island, Randy M. Sterbentz, Kristine L. Haley

Physics & Astronomy Faculty Research

Machine learning methods are changing the way data is analyzed. One of the most powerful and widespread applications of these techniques is in image segmentation wherein disparate objects of a digital image are partitioned and classified. Here we present an image segmentation program incorporating a series of unsupervised clustering algorithms for the automatic thickness identification of two-dimensional materials from digital optical microscopy images. The program identifies mono- and few-layer flakes of a variety of materials on both opaque and transparent substrates with a pixel accuracy of roughly 95%. Contrasting with previous attempts, application generality is achieved through preservation and analysis …

The Effect Of Cement And Blast Furnace Slag Characteristics On Expansion Of Heat-Cured Mortar Specimens, Jair G. Burgos

USF Tampa Graduate Theses and Dissertations

Delayed ettringite formation (DEF) is a durability issue that typically occurs in concrete exposed to high temperatures at an early age such as precast elements and massive concrete structural elements. There are many advantages to precast concrete such as its quality control, better safety control, and reusable forms, which make them cheaper than casting on site [1]. Heat curing of precast concrete is conducted to obtain high early-strength. However, in doing so, durability issues can arise in the form of internal sulfate attack also known as DEF, if the internal temperature of concrete exceeds 70°C. Past this threshold, ettringite decomposes …

Temperature-Immune Self-Referencing Fabry–Pérot Cavity Sensors, Hengky Chandrahalim, Jonathan W. Smith

AFIT Patents

A passive microscopic Fabry-Pérot Interferometer (FPI) sensor an optical fiber a three-dimensional microscopic optical structure formed on a cleaved tip of an optical fighter that reflects a light signal back through the optical fiber. The reflected light is altered by refractive index changes in the three-dimensional structure that is subject to at least one of: (i) thermal radiation; and (ii) volatile organic compounds.

High Quality Single-Crystalline Aluminum Nitride Grown Using Pulsed Atomic-Layer Epitaxy Technique By Mocvd On Sapphire Substrate, Mohd Nazri Abd Rahman

Student Works (2020-2029)

The unique structural properties and engineering characteristics of nitride-based materials have given them a special position in semiconductor applications. Alloys with a tuned energy bandgap from ultraviolet to infrared wavelengths are possible to be deposited in maintaining the wurtzite crystal structure. However, the aluminum nitride / aluminum gallium nitride (AlN/AlGaN) based hetero-structures for deep-ultraviolet (DUV) emitters as well as AlN-based actuators and piezoelectric sensors are highly inefficient owing to the excessive mismatch in thermal and lattice features between these epilayers with flat c-plane sapphire substrates, resulting in crack formation and high dislocation densities. This thesis mainly focuses on the development …

Study Of Laser Based Additive Manufacturing For Titanium And Copper Alloys, Congyuan Zeng

LSU Doctoral Dissertations

Material processing by laser is increasingly applied in industrial applications for its outstanding characteristics, such as localized heating, high efficiency, and high manufacturing precision. In this study, two kinds of laser material processing strategies were investigated, namely laser surface engineering and laser-powder-bed fusion additive manufacturing, with pure titanium and copper alloys as target materials, respectively.

For laser surface engineering related studies, the work includes the investigation of the dynamic interactions between titanium and pure nitrogen or ambient air under transient laser processing conditions. Thanks to the in-situ synchrotron X-ray diffraction tests, the high-temperature reaction steps between titanium and pure nitrogen/ambient …

Investigation On The Performance Of Tetraglyme Based Solid Copolymer Electrolytes For Solid State Electrical Double Layer Capacitors (Edlcs), Sinasamy Sharmilah

Student Works (2020-2029)

Solid polymer electrolytes (SPEs) have been the focus of intensive research due to their large demand in applications such as electrochemical capacitors, fuel cells, solar cells and batteries. They have shown many advantages such as wider electrochemical potential window, good thermal stability, low volatility and easy handling. Due to these advantages, SPEs have great potential in energy storage applications. Usually, SPEs suffer from poor conductivity, which hinders its performance for energy storage applications. In order to enhance the conductivity of the SPEs, the host polymer incorporated with salt to provide ions for conductivity, ionic liquid to enhance the conductivity and …

A Macro-Scale Ruck And Tuck Mechanism For Deformation In Ion-Irradiated Polycrystalline Graphite, Steve Johns, Karthik Chinnathambi

Materials Science and Engineering Faculty Publications and Presentations

A vein structure, which becomes more pronounced with increasing ion dose, was found on the surface of polycrystalline HOPG (highly oriented pyrolytic graphite) implanted by ex situ C⁺ (up to 1.8x10¹⁷ ions/cm²), and in situ Ar⁺ in a transmission electron microscope (TEM). These veins are found to be independent of the crystallographic orientations and are associated with the formation of pores. Underneath the veins, a triangular-shaped core was formed with the graphite platelet inside the core displaced up towards the surface. A macro-scale ‘ruck&tuck’ geometry was thus generated at these triangle structure boundaries. Progressive movement …

Open-Source Molecular Modeling Software In Chemical Engineering Focusing On The Molecular Simulation Design Framework, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

Molecular simulation has emerged as an important sub-field of chemical engineering, due in no small part to the leadership of Keith Gubbins. A characteristic of the chemical engineering molecular simulation community is the commitment to freely share simulation codes and other key software components required to perform a molecular simulation under open-source licenses and distribution on public repositories such as GitHub. Here we provide an overview of opensource molecular modeling software in Chemical Engineering, with focus on the Molecular Simulation Design Framework (MoSDeF). MoSDeF is an open-source Python software stack that enables facile use of multiple open-source molecular simulation engines, …

Blood Driven Biopower Cells: Acquiring Energy From Reverse Electrodialysis Using Sodium Concentrations From The Flow Of Human Blood, Efecan Pakkaner, Chase Smith, Christina Trexler, Jamie Hestekin, Christa Hestekin

Chemical Engineering Faculty Publications and Presentations

With the growth of the healthcare industry, small scale power sources are needed to support advancements in medical implants, artificial organs, and sensors throughout the body. However, it remains a challenge to find safe, reliable, and stable power sources for these devices. In this study, a miniaturized reverse electrodialysis (RED) biopower cell design using physiological salinity concentration differences between renal bloodstreams is explored for its potential to be used as a power supply for implantable medical devices. Two small scale RED devices produced consistent power for up to three to ten days, depending on the device design. A two-fold decrease …

First-Principles Studies Of Mof Absorption On Hydroxylated And Non-Hydroxylated Metal Oxide Surfaces And Implications For Atomic Layer Deposition Of Mos2, Matthew Lawson, Elton Graugnard, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

Significant interest in two-dimensional transition metal dichalcogenides has led to numerous experimental studies of their synthesis using scalable vapor phase methods, such as chemical vapor deposition (CVD) and atomic layer deposition (ALD). ALD typically allows lower deposition temperatures, and nucleation of chemical precursors requires reactions with surface functional groups. A common first-principles method used to study ALD modeling is the calculation of activation energy for a proposed reaction pathway. In this work we calculated the partial charge densities, local density of states (LDoS), Bader charge analysis, adsorption energies, and charge density difference using density functional theory (DFT) to investigate the …

Interface Structure And Luminescence Properties Of Epitaxial Pbse Films On Inas(111)A, Kevin D. Vallejo, Paul J. Simmonds

Materials Science and Engineering Faculty Publications and Presentations

Epitaxial heterostructures of narrow-gap IV-VI and III-V semiconductors offer a platform for new electronics and mid-infrared photonics. Stark dissimilarities in the bonding and the crystal structure between the rocksalt IV–VIs and the zincblende III–Vs, however, mandate the development of nucleation and growth protocols to reliably prepare high-quality heterostructures. In this work, we demonstrate a route to single crystal (111)-oriented PbSe epitaxial films on nearly lattice-matched InAs (111)A templates. Without this technique, the high-energy heterovalent interface readily produces two populations of PbSe grains that are rotated 180° in-plane with respect to each other, separated by rotational twin boundaries. We find that …

On Road Coordinates For Autonomous Vehicle Guidance, Ricardo Jacome

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

A new roadmap framework is proposed to improve the guidance and trajectory prediction capabilities of connected and automated vehicles (CAVs). Independent of road shape determination through external sensors, the system serves as a backup for challenging conditions, such as low sensor visibility and adverse environmental effects (e.g., rain, fog, snow). Based on the fusion of vehicle dynamics principles, differential geometry, and road design standards, the roadmap framework provides a consolidated collection of critical reference points of roadway centerlines and information about the shape of the roadway in the vicinity of a vehicle, including curvature, optimal travel velocity, and road alignment …

Static Fatigue Of Hi-Nicalon™ S Ceramic Fiber Tows At 600°C In Air And Silicic Acid-Saturated Steam, Caleigh M. Nelson

Theses and Dissertations

Ceramic matrix composites (CMCs) have the potential to be utilized in applications such as hypersonic vehicles, aircraft leading edges, hot sections of engines, and rocket nozzles. Of particular interest are advanced SiC/SiC composites that can withstand the elevated temperatures and harsh oxidizing environments while maintaining their properties and structural integrity under an applied load. Steam, a major component of combustion environment, is one such aggressive oxidizing environment. As steam passes through the SiC/SiC composite, entering the composite interior through the cracks in the SiC matrix, it becomes saturated with silicic acid, Si(OH)₄. Before incorporating SiC/SiC composites in the …

The Corrosion Of Stainless Steel Made By Additive Manufacturing: A Review, Gyeongbin Ko, Wooseok Kim, Kyungjung Kwon, Tae-Kyu Lee

Mechanical and Materials Engineering Faculty Publications and Presentations

The advantages of additive manufacturing (AM) of metals over traditional manufacturing methods have triggered many relevant studies comparing the mechanical properties, corrosion behavior, and microstructure of metals produced by AM or traditional manufacturing methods. This review focuses exclusively on the corrosion property of AM-fabricated stainless steel by comprehensively analyzing the relevant literature. The principles of various AM processes, which have been adopted in the corrosion study of stainless steel, and the corrosion behaviors of stainless steel depending on the AM process, the stainless steel type, and the corrosion environment are summarized. In this comprehensive analysis of relevant literature, we extract …

Fiber Optic Sensor Embedded Smart Helmet For Real-Time Impact Sensing And Analysis Through Machine Learning, Yiyang Zhuang, Qingbo Yang, Taihao Han, Ryan O'Malley, Aditya Kumar, Rex E. Gerald Ii, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Background: Mild traumatic brain injury (mTBI) strongly associates with chronic neurodegenerative impairments such as post-traumatic stress disorder (PTSD) and mild cognitive impairment. Early detection of concussive events would significantly enhance the understanding of head injuries and provide better guidance for urgent diagnoses and the best clinical practices for achieving full recovery. New method: A smart helmet was developed with a single embedded fiber Bragg grating (FBG) sensor for real-time sensing of blunt-force impact events to helmets. The transient signals provide both magnitude and directional information about the impact event, and the data can be used for training machine learning (ML) …

Static Fatigue Of Hi-Nicalon S Fiber Tows At 500°C In Air And In Silicic Acid-Saturated Steam, Richard J. Reinink

Theses and Dissertations

Recent developments in aerospace propulsion systems, along with emerging interest in hypersonic air vehicles has emphasized the need for materials which can withstand extreme service environments. The leading candidates for the structural components expected to operate in these environments are SiC-based ceramic matrix composites (CMCs). When a CMC component is subjected to thermomechanical loads in an aggressive environment during service, surface cracks form. As steam penetrates cracks in the SiC matrix, it becomes saturated with silicic acid, (SI(OH)₄) and attacks the SiC fibers. The interaction between the Hi-Nicalon™ S SiC fibers and the (SI(OH)₄)-saturated steam is …

Fatigue Of Two Oxide/Oxide Ceramic Matrix Composites At 1200°C In Air And In Steam. Effect Of Diamond Drilled Effusion Holes, Anthony R. Cabri

Theses and Dissertations

The tension-tension fatigue behavior of two oxide-oxide ceramic matrix composites (CMCs) was investigated at 1200°C in laboratory air and steam. Both composites consist of a porous oxide matrix reinforced with laminated, woven mullite/alumina (NextelTM720) fibers. The first composite had an alumina matrix, while the second had an alumina-mullite matrix. First, we assessed the effects of incorporating mullite into the matrix material on fatigue performance by studying the tension-tension fatigue behavior of alumina-mullite matrix CMC. Second, we evaluated the effects of effusion holes on the alumina matrix CMC's fatigue performance. Specimens containing an array of 17 effusion holes of 0.5-mm diameter …

Comparing The Environmental Impacts Of Using Mass Timber And Structural Steel, Khang Hoang Nguyen, Steelee Knight Morgan

Construction Management

Although mass timber has seen a gradual rise in demand in the past, there has been a lack of extensive research on the environmental impacts of using mass timber as a primary structural framing material. This paper compares structural steel, and mass timber’s total embodied carbon emissions. Accurate estimates were made using plans and specs for different projects retrieved from semi-structured interviews. The estimates were input through the EC3 Calculator to provide extensive total carbon emissions measurements between each construction material. Using structural steel framing increased the project’s overall environmental impact by roughly 84% compared to using mass timber. The …

Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun

Journal of Electrochemistry

As a new energy conversion device, direct ethanol fuel cells (DEFCs) are widely concerned because of their remarkable advantages such as high theoretical energy density and wide fuel sources. However, the rapid development of DEFCs has been severely impeded due to the sluggish kinetic process and toxic intermediates especially in their anodic reactions. Palladium (Pd)-based materials are considered to be excellent anode catalysts for DEFCs, especially under alkaline conditions. And further improving their performance is an important direction to promote the development of DEFCs. Surface structure and composition are the key factors affecting the performance of catalysts which can be …