Materials Science and Engineering Commons^™

Studies On Glass Fiber-Reinforced Poly(Ethylene-Grafted-Styrene)-Based Cation Exchange Membrane Composite, Di Huang, Zhichao Chen, Jiann-Yang Hwang

Michigan Tech Publications, Part 1

To improve interfacial adhesion between glass fiber (GF) and poly(ethylene-grafted-styrene)-based cation exchange membranes (CEM), GF was modified by four coupling agents: [3-(Methacryloxy)propyl] trimethoxy silane (3-MPS), 1,6-bis (trimethoxysilyl) hexane (1,6 bis), Poly(propylene-graft-maleic anhydride) (PP-g-MA) and Triethoxyvinylsilane (TES). The results indicated the addition of modified GF increased tensile strength, tensile modulus, storage modulus and interfacial adhesion of GF/CEM composite but degraded the strains. The composite with 3-MPS modified GF obtained superior mechanical properties and interfacial adhesion, whereas the modified effect of TES was inconspicuous. The addition of unmodified GF even had negative effects on GF/CEM mechanical properties. The field emission scanning electron …

Optimization Of Electron Beam-Deposited Silver Nanoparticles On Zinc Oxide For Maximally Surface Enhanced Raman Spectroscopy, Andrew L. Cook, Christopher P. Haycook, Andrea K. Locke, Richard R. Mu, Todd D. Giorgio

TIGER Institute Faculty Research

Surface enhanced Raman spectroscopy enables robust, rapid analysis on highly dilute samples. To be useful, the technique needs sensing substrates that will enhance intrinsically weak Raman signals of trace analytes. In particular, three-dimensional substrates such as zinc oxide nanowires decorated with electron-beam deposited silver nanoparticles are easily fabricated and serve the dual need of structural stability and detection sensitivity. However, little has been done to optimize electron beam-deposited silver nanoparticles for maximal surface enhancement in the unique dielectric environment of the zinc oxide substrate. Herein, fabrication and anneal parameters of electron beam-deposited silver nanoparticles were examined for the purpose of …

A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin

Faculty Publications

High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …

Bio-Binder—Innovative Asphalt Technology, Amir Tabakovic

Articles

The global road network spans 16.3 million km [1], of which 5 million km is in the EU. These road networks fulfil major economic and social goals by facilitating the movement of goods and people throughout the EU, and are therefore of the utmost importance to the economic and social life of the EU [2]. National governments invest heavily in their road networks, e.g., in 2014, EUR 53.33 billion was invested in the development and maintenance of the EU road network [3]. Each year, the world produces 1.6 trillion tonnes of asphalt [4], of which 218 million tonnes is produced …

Mechanical Alloying-Assisted Coating Of Fe–Al Powders On Steel Substrate, Alfian Noviyanto, Sri Harjanto, Wahyu Bambang Widayatno, Agus Sukarto Wismogroho, Muhamad Ikhlasul Amal, Nurul Taufiqu Rochman

Makara Journal of Technology

The coating layer of Fe–Al powders on the steel substrate was prepared by mechanical alloying at room temperature. Fe, Al, and the steel substrates were milled with high-energy ball milling for 32 h with a ball-to-powder ratio of 8 in an argon atmosphere to prevent oxidation during milling. Although mechanical alloying was performed for 32 h, no new phases were observed after mechanical alloying, as analyzed by X-ray diffraction. However, the crystallite size of the milled powders for 32 h decreased by factor two compared with the initial powders. Scanning electron micrographs showed that the coating layers formed >8 h …

Performance Of Free-Space Optical Communication Systems Using Optical Amplifiers Under Amplify-Forward And Amplify-Received Configurations, Ucuk Darusalam, Arockia Bazil Raj, Fitri Yuli Zulkifli, Purnomo Sidi Priambodo, Eko Tjipto Rahardjo

Makara Journal of Technology

With the growth of digital technology in the stage of industrial revolution 4.0, the demand for broadcasting large amounts of information to last mile users has increased. Free-space optical (FSO) communication is one of the telecommunication platforms that has shown immense potential in meeting the demand for information broadcasting. In this work, the performance of FSO communication based on wavelength division multiplexing with a data rate of 80 Gbps is investigated through simulations. The configuration of optical amplifiers in the FSO system is set up on the basis of the amplify-forward and amplify-received configurations to expand the network. The investigation …

Iso 9001:2015 Risk-Based Thinking: A Framework Using Fuzzy-Support Vector Machine, Ralph Sherwin A. Corpuz

Makara Journal of Technology

Risk-based thinking (RBT) is one of the distinct new features of the International Organization for Standardization 9001:2015. Interestingly, the standard does not prescribe any tools. Hence, organizations are puzzled as to the extent of conformance. Some organizations have adopted formal tools. However, these tools seem insufficient in linking the standard into an evidence-based decision support system. To resolve gaps in RBT implementation, this paper proposes a framework based on fuzzy inference system (FIS) and support vector machine (SVM) to automate risk analysis and evaluation, proposal and verification of action plans, and prediction of the feasibility of risks and opportunities according …

Influence Of The Shaping Process On The Tensile Properties Of Steel Reinforcement Bars Carbon Steel Grades Bjtp24 And Bjts40, Nuraziz Handika, Ridha Amalia Idhar, Jessica Sjah, Essy Arijoeni, Elly Tjahjono

Makara Journal of Technology

According to the current applicable national standard in Indonesia, i.e. SNI 07 2529 1991, in addition to the limitation on the loading rate, the steel bar must be reduced, formed, or lathed, as part of the shaping process of samples. This study determined and compared the effect of the shaping process on the yield strength, ultimate strength, and percent elongation by conducting tensile tests of steel bar grade BJTS40, i.e. deformed bar type of steel, and grade BJTP24, i.e., plain bar type of steel. Three diameters of the deformed bar (BJTS40) and one diameter of the plain bar (BJTP24) were …

Ionic Conductiviy Of Alginate-Nh4cl Polymer Electrolyte, Nurhasniza Mamajan Khan, Noor Saadiah Mohd Ali, Ahmad Faizrin Ahmad Fuzlin, Ahmad Salihin Samsudin

Makara Journal of Technology

This study aims to produce a solid biopolymer electrolyte (SBE) by doping ammonium chloride (NH4Cl) into alginate. Solution casting was used to prepare the alginate–NH4Cl SBE system. Electrical impedance spectroscopy was performed to analyze the electrical properties of the SBE under the applied frequency range of 50 Hz–1 MHz. The incorporation of 8 wt.% NH4Cl enhances the ionic conductivity of the SBE up to 3.18 × 10-7 S/cm at ambient room temperature. Fourier transform infrared spectroscopy shows that complexation occurs between the hydroxyl (-OH), carboxylate (COO-) and ether linkage (C-O-C) functional groups due to the formation of inter- and intra-molecular …

Enhancement Of Regeneration Ratio And Thermal Durability For Regenerated Fiber Bragg Grating Based On Pre-Annealing Treatment And Multimaterial Fibers, Nurul Asha Mohd Nazal

Student Works (2020-2029)

Regenerated fiber Bragg grating (RFBG) or also known as regenerated grating (RG) is the creation of the temperature resistant grating through thermal erasure of seed grating (SG) followed by a rebirth of new grating in a annealing process. RG has shown to be a promising fiber Bragg grating component for operation under very high ambient temperature condition. Nonetheless, further investigation and improvement are required to better understand its formation mechanism and to enhance its performance. This study aims to enhance the regeneration ratio and thermal durability of the RG based on pre-annealing treatment and multimaterial fiber. In this work, the …

A Density Functional Theory Study On Using Montmorillonite To Reduce Air Pollution, Triati Dewi Kencana Wungu, Meqorry Yusfi, Suprijadi Suprijadi

Makara Journal of Technology

In this study, density functional theory (DFT) method is used to investigate the possibility of using a smectite clay mineral called montmorillonite (MMT) in reducing heavy metals, such as Cd, through Cd adsorption. The mechanism of Cd adsorption in MMT is observed theoretically, and the tetrahedrally isomorphic substitution on the upper layer of MMT is considered to observe the role of Al and Fe in strengthening Cd adsorption. Two types of MMT are modeled in this study: Al-MMT and Fe-MMT. The Al-MMT means that Al substitutes one atom in the upper tetrahedral layer of MMT, while Fe-MMT means that Fe …

Influence Of Lithium Bromide On Electrical Properties In Bio-Based Polymer Electrolytes, Ahmad Faizrin Fuzlin, Bouchta Sahraoui, Ahmad Salihin Samsudin

Makara Journal of Technology

This research presents the influence of lithium bromide (LiBr) on the electrical properties of alginate in bio-based polymer electrolytes (BBPEs) system. Bio-based alginate was prepared using the solution casting technique with various LiBr compositions. The ionic conductivity and electrical properties of the prepared BBPEs samples were studied using electrical impedance spectroscopy over a frequency range of 50 Hz–1 MHz. A maximum ionic conductivity of 7.46 × 10−5 S cm-1 was obtained for a sample containing 15 wt. % lithium bromide-doped alginate BBPEs at ambient temperature (303 K). The electrical analysis revealed that the most conductive sample based on alginate-LiBr BBPEs …

Use Of Viscoplastic Damper For Improving The Resistance Of Steel Frames To Blast Loading, Gholamreza Abdollahzadeh, Hadi Faghihmaleki, Hamed Hamidi Jamnani, Atefeh Ebrahimi Bardar

Makara Journal of Technology

In this paper, we evaluated the effect of viscoplastic dampers on the response of steel frames under blast loading. We used SAP2000 software and link elements to investigate the responses of nine-story steel frames with and without dampers. The proposed viscoplastic damper is a new type of viscous damper. The application of this damper is based on the availability of its constituent materials. The damper acts as a viscoelastic damper at low levels of vibration, but it acts as a combination of viscoelastic operator and metal-yielding device at extreme levels of vibration. With respect to the height of the structure, …

Practical Adhesion Measurements In Organic Coatings; Advancing Understanding And Mechanical Methods Development, Diana Gottschalk

Dissertations

“Adhesion” can be considered either a mechanical or chemical phenomenon. The mechanical interpretation describes the difficulty of separating surfaces and is useful for quantifying performance within applications that depend on bulk and interfacial properties. Chemical adhesion describes interfacial resistance to chemical attack and does not depend on bulk properties. Predicting chemical failure through mechanical measurement is confounded by the influence of bulk properties. However, the prospect is attractive because of the robust tolerance for sample geometries, allowing experiments to resemble an end-use system. The present work's primary goal was to elevate mechanical methods to provide a detailed interfacial characterization of …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

An Investigation Into The Effects Of Fly Ash On Freeze-Thaw Durability Prediction, Yancy Schrader

Graduate Theses and Dissertations

Air is purposefully entrained into concrete primarily to improve resistance to freeze-thaw deterioration while saturated with water. Air entraining admixtures (AEAs) are chemical admixtures designed to entrain air into the concrete to provide adequate resistance to the effects of freezing and thawing. One of the challenges associated with air entrainment in concrete is the interaction of an AEA with supplementary cementitious materials present in the concrete, particularly fly ash. Fly ash is a by-product of the coal fired electrical generation industry, and often contains residual unburned carbon and other components that can increase the AEA demand of a particular concrete …

Effect Of Citric Acid On Slump, Compressive Strength, And Setting Time Of Belitic Calcium Sulfoaluminate Concrete, Israel Aguilar Rosero

Graduate Theses and Dissertations

Belitic calcium sulfoaluminate (BCSA) cement has well established advantages related to fast setting time, fast strength gain, long-term strengths, shrinkage, and sustainability. Due to its fast setting and hardening, this type of cement has historically been used to repair concrete structures, highways, and runways. This work provides much needed guidance on establishing mix design criteria for BCSA cement. Guidance is also given on the effects of set retarders on strength, slump, and setting times. Citric acid and a phosphonic acid-based admixture were tested as retarders for different concrete mixtures. Three studies were performed. In the slump study five different water …

Leveraging Biomimicry And Additive Manufacturing To Improve Load Transfer In Brittle Materials, Ana Paula Bernardo

Graduate Theses and Dissertations

With the emergence of Additive Manufacturing (i.e., 3D printing) in construction, new strategically designed shapes can be created to improve load transfer through structural members and foundations. Cross-sections can be optimized to carry load using less material, or even using weaker constituent materials, like soils, which are cheap and abundant. The goal of this research is to investigate the benefits of using cellular patterns which leverage biomimicry in civil engineering applications, since nature has perfectly engineered materials and patterns which carry loads with the least amount of material possible. Most of the periodic cellular work to date has focused on …

Design, Fabrication, And Reliability Effects Of Additively Manufactured First Level Compliant Interconnects For Microelectronics Application, Tumininu David Olatunji

Graduate Theses and Dissertations

Semiconductor packaging and development is greatly dependent on the magnitude of interconnect and on-chip stress that ultimately limits the reliability of electronic components. Thermomechanical related strains occur because of the coefficient of thermal expansion mismatch from different conjoined materials being assembled to manufacture a device. To curb the effect of thermal expansion mismatch between conjoined parts, studies have been done in integrating compliant structures between dies, solder balls, and substrates. Initial studies have enabled the design and manufacturing of these structures using a photolithography approach which involves a high number of fabrication steps depending on the complexity of the structures …

Mechanical And Frictional Behavior Of Textured And Non-Textured Surfaces, Raghuram R. Santhapuram

Graduate Theses and Dissertations

Tribology is the study of surfaces where two objects are sliding against another. Significant energy is lost due to friction between the sliding surfaces. Therefore, developing or designing surfaces to minimize friction is critical for the durability and reliability of the mechanical components. Several researchers have identified that surface texturing at the nanoscale (nanotexture) would reduce the friction between the contacting surfaces. The nanotextured surfaces have several applications in microelectromechanical systems and nanoelectromechanical systems. This dissertation employs molecular dynamics simulations to investigate the frictional and mechanical response of nanotextured aluminum (Al) and Al/amorphous silicon (a-Si) composite surfaces.

This study determines …

Application Of Percentage Within Limits Concepts On A Balanced Mix Design Of Asphalt Mixtures, Elvis Alexander Castillo Camarena

Graduate Theses and Dissertations

Many agencies have incorporated rutting, and more recently cracking, laboratory test requirements in the design process of asphalt mixtures. The objective of each additional specification is to produce a balance between the stability and durability of the final product. Although a performance-engineered mixture design (PEMD), denoted here as a balanced mix design (BMD), offers compelling benefits, there is concern regarding the compatibility of the BMD with current construction practices. The objective of this work is to correlate a BMD method with realistic binder content construction tolerances by applying the concepts of a percent-within-limits (PWL) approach to field QC/QA. First, Chapter …

Synthesis And In Vivo Biomedical Applications Of Ultrasmall Metal Nanoparticles, Shahab Ranjbar Bahadori

Material Science and Engineering Dissertations - Archive

Over the past decade, metal-based nanoparticles (MNPs) have gained much popularity in the field of nanomedicine owing to their exceptional physiochemical properties. Easy surface functionalization and conjugation with therapeutic moieties, stability, inertness, and inherent anticancer activities make MNPs promising diagnostic and therapeutic agents. Among different sizes of MNPs, which greatly affect their biodistribution and clearance, ultrasmall metal nanoparticles with the size less than 5 nm demonstrate unique pharmacokinetic properties, making them suitable for nanomedicinal applications. Therefore, many efforts have been made to synthesize various kinds of ultrasmall metal nanoparticles. In this study, a revolutionary synthesis method, termed as liquid diffusion …

Development Of Functional Materials And Devices On Flexible Platforms Using Additive Print Manufacturing Processes For Biomedical And Environmental Applications, Dinesh Maddipatla

Dissertations

In recent years, considerable research has been vested into the development of printed electronics (PE) to explore the best ways of fabricating electronic devices on flexible platforms using additive print manufacturing processes. PE produces flexible devices that are compatible with complex geometries, foldable applications and conformal to curved surfaces, with a promising potential for large‐area device fabrication at relatively lower manufacturing costs. This dissertation focuses majorly on the design and fabrication of novel flexible functional materials and devices for biomedical and environmental applications using additive printing processes.

Initially, a simple paper-based low cost and rapid prototypable platform with oxygen sensors …

Principles, Design, Fabrication, And Characterization Of Subwavelength Periodic Resonant Metasurfaces, Hafez Hemmati

Material Science and Engineering Dissertations - Archive

Since the emergence of diffraction gratings containing periodic unit cells, innumerable advances in theoretical studies and practical applications have emerged. Recently, these classic structures have been categorized as subsets of “meta-surfaces” or “meta-materials” in which periodically aligned wavelength-scale features manipulate all key properties of the electromagnetic waves in a desired manner for a wide variety of applications. This includes manipulating of amplitude, phase, spectral distribution, polarization state, and local mode structure of light in the various available spectral expressions. Among the significant characteristic properties of metasurfaces is the coupling of incident light to laterally propagating leaky Bloch modes in the …

Modeling And Analysis For Unit Cell Size, Material Anisotropy And Material Imperfection Effects Of Cellular Structures Fabricated By Powder Bed Fusion Additive Manufacturing., Yan Wu

Electronic Theses and Dissertations

Cellular structures are networks of interconnected struts or walls with porosities and are widely found in many natural load-bearing structures such as plants and bones. Cellular structures offer unique functional characteristics such as high stiffness to weight ratio, tailorable heat transfer coefficient, and enhanced mechanical energy absorption, which makes them highly attractive in various engineering disciplines such as biomedical implants, electrodes, heat exchangers, and lightweight structures. There exists an abundance of literatures that have investigated various mechanical properties of various cellular structures such as Poisson’s ratio, elastic modulus, ultimate strength, yield strength, and failure characteristics. Based on the classic cellular …

Magnetic Sensors And Geometrical Magnetoresistance: Areview, Abdelfattah Mohammed Mansour

Journal of Metals, Materials and Minerals

Magnetic sensing devices are of the extremely significant kind of detectors, that are used several important and useful applications. Geometrical extraordinary magnetoresistance (EMR) is thegeometrical kind of magnetoresistance associated with the non-magnetic semiconductor-metalhybrid structure and influenced by geometrical shape. As a result of Lorentz force, the current path change from metal (in absence of magnetic field) to semiconductor (under the subjection of themagnetic field) in semiconductor-metal hybrid structure is the key of EMR phenomena, i.e. once the metal is placed in a semiconductor, it works as a short circuit with the majority of applied current moving through metallic inhomogeneity and …

Quenched And Tempered High Strength Steel:A Review, Gadadhar Sahoo, Krishna Kumar Singh, Vinod Kumar

Journal of Metals, Materials and Minerals

Quenched and tempered steel are broadly classified as low alloy conventional grades with C contentof 0.15-0.40% and tool steels with C content as high as 2% alloyed with strong carbide forming elementssuch as Cr, V, Mo etc. in the range of 1-12%. In both the cases, steels are used in hardened/quenchedand tempered or auto tempered condition for improved toughness, strength and wear resistance. The C content and tempering temperature are optimized based on desired application. However, achieving high strength/hardness along with adequate toughness is a challenge. The chemistry designis one of the important parts of developing these grades. The judicious …

Characterization Of Tio2-Activated Carbon Onto Adsorption And Photocatalytic Propertiesand Its Application, Mark Chobchun, Pasakorn Jutakridsada, Puttiporn Thiamsinsangwon, Pornnapa Kasemsiri, Khanita Kamwilaisak, Prinya Chindaprasirt

Journal of Metals, Materials and Minerals

This study investigates the characterization of TiO2in conjunction with activated carbon(AC) on its adsorption and photocatalytic properties. TiO2in theabsence and presence of AC were preparedby the sol-gel method. TiCl4was used as a precursor to reduce using acidic solution during preparationprocess. The effects of the amount of AC on the characteristics of composites were investigated. TGA technique was used to evaluate the amount of TiO2and AC in TiO2/AC composite. The adsorptionproperties of TiO2/AC were characterized using XRD, TEM, N2adsorption/desorption, FTIR and UV - Visdiffuse reflectance spectroscopy techniques. The photocatalytic activitiesof the composites were investigated by measuring the removal of acid dye. …

Screen Printed Textile Electrodes Using Graphene And Carbon Nanotubes With Silver For Flexible Supercapacitor Applications, Norawich Keawploy, Radhakrishnan Venkatkarthick, Panyawat Wangyao, Jiaqian Qin

Journal of Metals, Materials and Minerals

The eco-friendly conductive cotton textile is promising alternatives for the flexible substrates in wearable devices since the cotton is as an inexpensive natural fabric material and compatible in modern portable electronics with adequate electrical conductivity. In this work, flexible conductive cotton-based electrodes areprepared via a screen-printing method using the carbonaceous nanomaterialssuch as carbon nanotubes (CNTs) and graphene with an additional component of conductive silver (Ag) powder and textile ink. The prepared conductive cotton electrodes exhibit lower sheet resistance (<10Ω) along with superior mass loading (20-30mgcm-2). On the basis of the performance of cottonelectrodes prepared, an all-solid-state flexible supercapacitor device was successfully fabricated whichexhibits a high specific areal capacitance of 677.12 mFcm-2at 0.0125 mAcm-2 for a suitable electrodecomposition (60% of Ag and 40% CNTs) using a PVA-KOH gel electrolyte. The flexible device endures a stable electrochemical performance under severe mechanical deformation using differentbending angles (0, 30, 45, 60and 90) of the device and possesses excellent cyclic stability with the capacitance retention of ~80% even after 3000 CV cycles.

The Usage Of Coal−Layered Double Oxide For Removal Of Toxic Dye Fromaqueous Solution, Pornnapa Tongchoo, Sonchai Intachai, Prakaidao Pankam, Chomponoot Suppaso, Nithima Khaorapapong

Journal of Metals, Materials and Minerals

CoAl−layered double oxide derived from calcination of CoAl−layered double hydroxide at400Cfor 120 min, delivered the change in microstructure with increasing surface area. Spinel Co3O4was the majority in the product as confirmed by X-ray diffraction, and Fourier transform infrared andUV-visible spectroscopies. The calcined product, CoAl−layered double oxide resulted in significantadsorption capacity on dye removal superior to that of CoAl−layered double hydroxide. The adsorbed amounts of the diverse dyes increased as follows: methylene blue phenolphthaleinmethyl orange orange II. The adsorption affinity between adsorbent and dyes relied on electrostatic interaction and physical adsorption.