Materials Science and Engineering Commons^™

Effect Of Salt Valency And Concentration On Shear And Extensional Rheology Of Aqueous Polyelectrolyte Solutions For Enhanced Oil Recovery, Anna V. Walter, Leidy N. Jimenez, Jelena Dinic, Vivek Sharma, Kendra Erk

School of Materials Engineering Faculty Publications

The injection of polymer solutions into an oil basin can lead to enhanced oil recovery (EOR) by increasing the microscopic sweep of the reservoir, improving the water-oil motility ratio, and thus leading to greater yield from oil fields. In this contribution, we characterize both shear and extensional rheological response of aqueous solutions of partially hydrolyzed polyacrylamide (HPAM), the most commonly used polymer for EOR, for velocity gradients in both the flow direction (extensional) and perpendicular to flow (shear) arise in EOR applications. As HPAM is a charged polymer, to better emulate the environment in oil basins, the rheological response was …

Coatings On Mammalian Cells: Interfacing Cells With Their Environment, Kara A. Davis, Pei-Jung Wu, Calvin F. Cahall, Cong Li, Anuhya Gottipati, Brad J. Berron

Chemical and Materials Engineering Faculty Publications

The research community is intent on harnessing increasingly complex biological building blocks. At present, cells represent a highly functional component for integration into higher order systems. In this review, we discuss the current application space for cellular coating technologies and emphasize the relationship between the target application and coating design. We also discuss how the cell and the coating interact in common analytical techniques, and where caution must be exercised in the interpretation of results. Finally, we look ahead at emerging application areas that are ideal for innovation in cellular coatings. In all, cellular coatings leverage the machinery unique to …

Open-Source Automated Chemical Vapor Deposition System For The Production Of Two-Dimensional Nanomaterials, Lizandra Williams-Godwin, Dale Brown, Richard Livingston, Tyler Webb, Lynn Karriem, Elton Graugnard, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

The study of two- dimensional (2D) materials is a rapidly growing area within nanomaterials research. However, the high equipment costs, which include the processing systems necessary for creating these materials, can be a barrier to entry for some researchers interested in studying these novel materials. Such process systems include those used for chemical vapor deposition, a preferred method for making these materials. To address this challenge, this article presents the first open-source design for an automated chemical vapor deposition system that can be built for less than a third of the cost for a comparable commercial system. The materials and …

The Effect Of Cryogenic Thermal Cycling On Aging, Rejuvenation, And Mechanical Properties Of Metallic Glasses, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The structural relaxation, potential energy states, and mechanical properties of a model glass subjected to thermal cycling are investigated using molecular dynamics simulations. We study a non-additive binary mixture which is annealed with different cooling rates from the liquid phase to a low temperature well below the glass transition. The thermal treatment is applied by repeatedly heating and cooling the system at constant pressure, thus temporarily inducing internal stresses upon thermal expansion. We find that poorly annealed glasses are relocated to progressively lower levels of potential energy over consecutive cycles, whereas well annealed glasses can be rejuvenated at sufficiently large …

Achieving Superelasticity In Additively Manufactured Niti In Compression Without Post-Process Heat Treatment, Narges Shayesteh Moghaddam, Soheil Saedi, Amirhesam Amerinatanzi, Alejandro Hinojos, Ali Ramazani, Julia Kundin, Michael J. Mills, Haluk E. Karaca, Mohammad Elahinia

Mechanical Engineering Faculty Publications

Shape memory alloys (SMAs), such as Nitinol (i.e., NiTi), are of great importance in biomedical and engineering applications due to their unique superelasticity and shape memory properties. In recent years, additive manufacturing (AM) processes have been used to produce complex NiTi components, which provide the ability to tailor microstructure and thus the critical properties of the alloys, such as the superelastic behavior and transformation temperatures (TTs), by selection of processing parameters. In biomedical applications, superelasticity in implants play a critical role since it gives the implants bone-like behavior. In this study, a methodology of improving superelasticity in Ni-rich NiTi components …

Effect Of Crystallization Modes In Tips-Pentacene/Insulating Polymer Blends On The Gas Sensing Properties Of Organic Field-Effect Transistors, Jung Hun Lee, Yena Seo, Yeong Don Park, John E. Anthony, Do Hun Kwak, Jung Ah Lim, Sunglim Ko, Ho Won Jang, Kilwon Cho, Wi Hyoung Lee

Center for Applied Energy Research Faculty and Staff Publications

Blending organic semiconductors with insulating polymers has been known to be an effective way to overcome the disadvantages of single-component organic semiconductors for high-performance organic field-effect transistors (OFETs). We show that when a solution processable organic semiconductor (6,13-bis(triisopropylsilylethynyl)pentacene, TIPS-pentacene) is blended with an insulating polymer (PS), morphological and structural characteristics of the blend films could be significantly influenced by the processing conditions like the spin coating time. Although vertical phase-separated structures (TIPS-pentacene-top/PS-bottom) were formed on the substrate regardless of the spin coating time, the spin time governed the growth mode of the TIPS-pentacene molecules that phase-separated and crystallized on the …

Structural Transformations During Periodic Deformation Of Low-Porosity Amorphous Materials, Nikolai V. Priezjev, Maxim A. Makeev

Mechanical and Materials Engineering Faculty Publications

Atomistic simulations are employed to study structural evolution of pore ensembles in binary glasses under periodic shear deformation with varied amplitude. The consideration is given to porous systems in the limit of low porosity. The initial ensembles of pores are comprised of multiple pores with small sizes, which are approximately normally distributed. As periodic loading proceeds, the ensembles evolve into configurations with a few large-scale pores and significantly reduced number of small pores. These structural changes are reflected in the skewed shapes of the pore-size distribution functions and the appearance of a distinct peak at large length scales after hundreds …

Damage Precursor Identification In Composite Laminates Using Data Driven Approach, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

Composite materials are rapidly being used in commercial aviation and other day to day applications. The individual damage modes in composites are very well understood but it is the interaction of these local damage modes that leads to global failure. In the current research we intend to identify the damage precursors and the initiation of failure events in off axis unidirectional composite laminates loaded in quasi static uniaxial tension by measuring the dielectric response of the material by an in-situ technique using Broadband Dielectric Spectroscopy (BbDS). Using the variation of permittivity with strain, we are able to classify the stages …

Feed Control: Composite Recycle, Rosy Perez

All Undergraduate Projects

The Boeing Company gave Central Washington University an opportunity for students to research and come up with an idea to reduce costs and landfill waste caused by the trimmings from the 777x composite wing pieces. The engineering and manufacturing for this project is about transporting composite material through to the delamination and chipper process. The delamination process uses a ram to press two claw shaped devices together that bends and deforms the material in opposite directions. The chipper process uses counter rotating saw blades spaced 1/8” apart to produce small shredded material. It is important for this newly designed feed …

Stair Climbing Hand Truck, James Mcpherson

All Undergraduate Projects

Abstract

Getting a heavy object up a flight of stairs usually requires a team of two or more people. Even with a team of people, the task is often still difficult, dangerous, and possibly insurmountable by one person. This problem is especially prevalent in for those who are moving into apartment complexes. Most apartment complexes have many buildings with two or more floors of living quarters, and elevators are often missing. This project sought to offer a solution to this problem. The solution in question; a motorized hand-truck with 2, trigonal planar pinwheels in place of the stock wheels. The …

Proximitized Materials, Igor Žutić, Alex Matos-Abiague, Benedikt Scharf, Hanan Dery, Kirill Belashchenko

Kirill Belashchenko Publications

Advances in scaling down heterostructures and having an improved interface quality together with atomically thin two-dimensional materials suggest a novel approach to systematically design materials. A given material can be transformed through proximity effects whereby it acquires properties of its neighbors, for example, becoming superconducting, magnetic, topologically nontrivial, or with an enhanced spin–orbit coupling. Such proximity effects not only complement the conventional methods of designing materials by doping or functionalization but also can overcome their various limitations. In proximitized materials, it is possible to realize properties that are not present in any constituent region of the considered heterostructure. While the …

Coupling Of Light's Orbital Angular Momentum To A Quantum Dot Ensemble, Alaa A. Bahamran

Electronic Theses and Dissertations

We theoretically and experimentally investigate the transfer of orbital angular momentum from light to an ensemble of semiconductor-based nanostructures composed of lead sulfide quantum dots. Using an ensemble of quantum dots offers a higher cross-section and more absorption of twisted light fields compared to experimentally challenging single-nanostructure measurements. However, each quantum dot (except for on-center) sees a displaced light beam parallel to its own axis of symmetry. The transition matrix elements for the light-matter interaction are calculated by expressing the displaced light beam in terms of the appropriate light field centered on the nanoparticles. The resulting transition rate induced by …

Synergistic Environmental Aging Of Glass Reinforced Polymer Composites, Tianyi Lu

Electronic Theses and Dissertations

Synergistic effects involved in the environmental degradation of Glass Reinforced Polymer (GRP) composites were examined and a novel synergistic aging model was proposed in this study. Six GRPs based on glass fibers with four different polymer resins and six pure polymer thermoplastic resins were exposed either individually or in combination to ultraviolet (UV) radiation, water condensation and elevated temperature for approximately 1000 h. The composites and polymers were monitored for weight changes as a function of time and their surfaces were examined after the tests using optical and scanning electron microscopes (SEM). Photodegradation of the polymer matrices was analyzed by …

Process Sustainability Evaluation For Manufacturing Of A Component With The 6r Application, Ana E. Bonilla Hernández, Tao Lu, Tomas Beno, Claes Fredriksson, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

Sustainability in manufacturing can be evaluated at product, process and system levels. The 6R methodology for sustainability enhancement in manufacturing processes includes: reduced use of materials, energy, water and other resources; reusing of products/components; recovery and recycling of materials/components; remanufacturing of products; and redesigning of products to utilize recovered materials/resources. Although manufacturing processes can be evaluated by their productivity, quality and cost, process sustainability assessment makes it a complete evaluation. This paper presents a 6R-based evaluation method for sustainable manufacturing in terms of specific metrics within six major metrics clusters: environmental impact, energy consumption, waste management, cost, resource utilization and …

Autojack - Hydraulic Powertrain System, Tyce Vu

All Undergraduate Projects

A primary problem for mechanics and automotive enthusiasts is the risk associated with lifting and securing a vehicle with conventional jack stands. Often times, improper jack-stand installation results in the vehicle collapsing unexpectedly, causing injury and/or death. This problem can be minimized through the application of a newly re-designed vehicle lifting system. The conventional method for lifting cars is time consuming and can be unsafe in many circumstances. A better, safer, and more efficient lift design was needed; the AutoJack. The approach of the AutoJack design was entirely focused on the safety of lifting a vehicle. Safety was improved by …

The Performance Of Concrete Containing Recycled Plastic Aggregates, Jason T. Manning

Undergraduate Honors Theses

Currently, our planet faces an issue with plastic waste and even with current recycling methods, there is still a large amount of it found in landfills and bodies of water. The goal of this research is to find a practical solution for the use of recycled plastic. This will be done by adding various amounts of recycled plastic aggregates into concrete mixes. The aggregate will act as a replacement (by volume) for sand and will be added in amounts of 0, 10, 30, 50, and 70 percent. There will be a 28-day compressive strength test, using 3 samples for each …

Study Of Synthesis Of Biodegradable Plastics From Alkaline Fermented Excessive Activated Sludge, Yaohui Liu, Chua Hong

Faculty of Science & Technology (THEi)

The environmental problems associated with plastics have become increasingly severe in recent years. Technologically and economically feasible solutions are in urgent need in order to ensure sustainable development in the plastic industry. Polyhydroxyalkanoates (PHAs) are a family of specialized polyesters of hydroxyalkanoates (HAs) and can be completely degraded in natural environment. They can be synthesized naturally or under artificially controlled processes. The barrier of limiting the application of PHAs is the high production cost. From years of study, PHAs are proofed to be able to be accumulated within the bacterial cells in activated sludge and the production yield had been …

Compressible And Choked Flows In Rotating Passages, Nolan J. Dyck, Anthony G. Straatman

Mechanical and Materials Engineering Publications

No abstract provided.

A Numerical Approach For Determining The Resistance Of Fine Mesh Filters, Anthony Sherratt, Christopher T. Degroot, Anthony G. Straatman, Domenico Santoro

Mechanical and Materials Engineering Publications

No abstract provided.

Fabrication Of Stoichiometric U3Si2 Fuel Pellets, Adrian R. Wagner, Jason M. Harp, Kip E. Archibald, Seth C. Ashby, Jennifer K. Watkins, Kevin R. Tolman

Materials Science and Engineering Faculty Publications and Presentations

Uranium silicide, U₃Si₂, is an accident tolerant fuel type which is gaining momentum as a replacement fuel for uranium dioxide (UO₂). Idaho National Laboratories has been fabricating phase pure U₃Si₂ fuel pellets for use in various irradiation and material characterization experiments. Stoichiometric U₃Si₂ fuel pellets were fabricated using a powder metallurgy and arcmelting technique. The use of the stoichiometric ratio to alloy uranium and silicon, and sintering in a vacuum environment allowed for the fabrication of high density (>94% theoretical density), phase pure pellets, greater than 94% …

Spatiotemporal Analysis Of Nonaffine Displacements In Disorderedsolids Sheared Across The Yielding Point, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The time evolution and spatial correlations of nonaffine displacements in deformed amorphous solids are investigated using molecular dynamics simulations. The three-dimensional model glass is represented via the binary mixture, which is slowly annealed well below the glass transition temperature and then sheared at a constant strain rate. It is shown that with increasing strain,the typical size of clusters of atoms with large nonaffine displacements increases, and these clusters remain spatially homogeneously distributed, until the yielding point when mobile atoms become localized within a system-spanning shear band. Furthermore, the yielding transition is associated with an abrupt change in the spatial correlation …

Femtosecond Photon-Mediated Plasma Enhances Photosynthesis Of Plasmonic Nanostructures And Their Sers Applications, Peng Ran, Lan Jiang, Xin Li, Bo Li, Pei Zuo, Yongfeng Lu

Department of Electrical and Computer Engineering: Faculty Publications

Laser ablation in liquid has proven to be a universal and green method to synthesize nanocrystals and fabricate functional nanostructures. This study demonstrates the superiority of femtosecond laser-mediated plasma in enhancing photoredox of metal cations for controllable fabrication of plasmonic nanostructures in liquid. Through employing upstream high energetic plasma during laser-induced microexplosions, single/three-electron photoreduction of metallic cations can readily occur without chemical reductants or capping agents. Experimental evidences demonstrate that this process exhibits higher photon utilization efficiency in yield of colloidal metal nanoparticles than direct irradiation of metallic precursors. Photogenerated hydrated electrons derived from strong ionization of silicon and water …

Atmospheric Pressure Plasma‐Induced Decolorisation Of Cotton Knitted Fabric Dyed With Reactive Dye, Yaohui Liu, Chester Kin-Man To, Mei‐Ki Ngai, Chi-Wai Kan, Chua Hong

Faculty of Science & Technology (THEi)

The aim of this study was to investigate the decolorisation effect of atmospheric pressure plasma treatment on knitted fabrics dyed with reactive dyes under different processing parameters, ie, air concentration, treatment duration and water content. The fabrics were dyed with reactive dye of a blue colour, and the colour depths were 0.5%, 1.5% and 3.0% on weight of fabric. The colour properties of untreated and plasma‐treated fabric samples were evaluated by means of reflectance, K/S and relative unlevelness index. The colour properties were evaluated instrumentally and quantitatively in order to study the decolorisation effect induced by atmospheric pressure plasma treatment. …

An Orthogonal Study Of Industrial Scale Colour Fading Process Of Cotton Fabric, Yaohui Liu, Chester Kin-Man To, Hiu-Yan Cheung, Chi-Wai Kan, Chua Hong

Faculty of Science & Technology (THEi)

Colour fading is now a popular process used for imparting a vintage look to textile and fashion products, which enhances market value because of the current fashion trends. This study examined a non-aqueous colour fading process with the use of oxygen plasma-induced ozone treatment. An industrial scale machine and commercially available red sulpur-dyed cotton fabric (with 0.5 %, 1.5 % and 2.5 % colour depths) were used in this study. Since the colour fading process factors are inter-related to each other, a specific experiment approach, i.e. orthogonal method, was used for obtaining the optimum conditions in an industrial scale colour …

Engineering Of Gold Nanoparticles For Drug Delivery, Fangchao Liu

Wayne State University Dissertations

Due to their ease of synthesis, versatile surface chemistry, ease of imaging, and biocompatibility, gold nanoparticles (AuNPs) are employed as drug delivery devices in the treatment of respiratory problems associated with spinal cord injury (SCI). We have developed a method for the synthesis of a tripartite nanoconjugate comprised of an AuNP drug carrier chemically conjugated to a transporter protein (wheat germ agglutinin coupled to horseradish peroxidase or WGA-HRP) and to potent SCI drugs. The therapeutic efficacy and biodistribution were studied in a validated animal model. Our results show that a single administration of the nanoconjugate improved diaphragmatic activity at a …

Shear Band Formation In Amorphous Materials Under Oscillatoryshear Deformation, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The effect of periodic shear on strain localization in disordered solids is investigated using molecular dynamics simulations. We consider a binary mixture of one million atoms annealed to a low temperature with different cooling rates and then subjected to oscillatory shear deformation with a strain amplitude slightly above the critical value. It is found that the yielding transition occurs during one cycle but the accumulation of irreversible displacements and initiation of the shear band proceed over larger number of cycles for more slowly annealed glasses. The spatial distribution and correlation function of nonaffine displacements reveal that their collective dynamics changes …

Structural Relaxation Of Porous Glasses Due To Internal Stresses And Deformation Under Tensile Loading At Constant Pressure, Nikolai V. Priezjev, Maxim A. Makeev

Mechanical and Materials Engineering Faculty Publications

The time evolution of the pore size distributions and mechanical properties of amorphous solids at constant pressure is studied using molecular dynamics simulations. The porous glasses were initially prepared at constant volume conditions via a rapid thermal quench from the liquid state to the glassy region and allowing for simultaneous phase separation and material solidification. We found that at constant pressure and low temperature, the porous network becomes more compact and the glassy systems relocate to progressively lower levels of the potential energy. Although the elastic modulus and the average glass density both increase with the waiting time, their dependence …

Rare-Earth-Activated Group Vi D0 Metal Oxides As Thermosensitive Phosphors, Samarage Sameera Perera

Wayne State University Dissertations

ABSTRACT

RARE-EARTH-ACTIVATED GROUP VI d0 METAL OXIDES AS

THERMOSENSITIVE PHOSPHORS

by

SAMARAGE SAMEERA PRASAD PERERA

AUGUST 2019

Advisor: Dr. Federico A. Rabuffetti

Major: Chemistry

Degree: Doctor of Philosophy

Thermosensitive phosphors are solid-state materials that demonstrate distinct dependence of luminescence emission on temperature. These materials enable optical temperature sensing in environments where conventional thermometry is not possible (e.g., gas turbines, combustion engines, surface temperature distributions). However, the design of thermosensitive phosphors that show adequate sensitivity and low thermal quenching in the intermediate temperature range (i.e., 500–1000 K) remains challenging. This challenge can be addressed by understanding how to rationally manipulate the …

Leaching Characteristics Of Rare Earth Elements From Bituminous Coal-Based Sources, Xinbo Yang

Theses and Dissertations--Mining Engineering

The demand for rare earth elements (REEs) has increased over the last decade due to applications in high technology devices including those in the defense industry. The recovery of REEs from primary sources such as rare earth minerals are viable using physical separations followed by chemical processing. However, weak market values and environmental concerns have limited the viability of such operations. On the other hand, REE recovery from secondary sources such as apatite ore, bauxite waste, and waste recycling, provides an opportunity to take advantage of a resource that does not require mining costs as well as other associated costs …

Atomistic Simulations Of Deformation In Metallic Nanolayered Composites, Sixie Huang

Doctoral Dissertations

"The mechanical behavior of Metallic Nanolayered Composites (MNCs) is governed by their underlying microstructure. In this dissertation, the roles of the interlayer spacing (grain size, d) and the intralayer biphase spacing (layer thickness, h) on mechanical response of Cu/Nb MNCs are examined by Molecular Dynamics (MD) simulations. The study of the strength of MNCs show that small changes in both d and h play a profound role in the relative plastic contributions from grain boundary sliding and dislocation glide. The interplay of d and h leads to a very broad transition region from grain boundary sliding dominated flow, where the …