Materials Science and Engineering Commons^™

Molecular Dynamics Modeling And Simulation Of Bitumen Chemical Aging, Farshad Fallah

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Chemical aging of asphalt binder leads to significant changes in its mechanical and rheological properties, resulting in poor pavement behavior and distress. Various laboratory methods have been used to simulate asphalt aging during the service life of the pavement. However, controversy exists regarding the capability of these methods to predict field aging, as various factors interact with the pavement during service and the mechanism behind aging is not fully understood. The two main outcomes of chemical aging are oxidation of asphalt molecules, and change in asphalt SARA (saturate, aromatic, resin, and asphaltene) fractions. Reaction of oxygen with asphalt components forms …

Optimum Conditions For Eor Using Nanofluids Subjected To Em Waves, Muhammad Kashif, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Today’s major challenge for oil industry is to improve the oil recovery from the reservoir. Various enhanced oil recovery (EOR) methods have been applied in the field and the steam injection is one of the most favourable methods. The deep reservoir will result in failure of this method due to excessive heat dissipation. In this situation, generating and injecting steam may be uneconomical due to the tremendous reduction of the recovery. Some methods using nanotechnology have been introduced and elaborated. However, we propose the electromagnetic (EM) method as an alternative due to its long range transmission of the transverse waves. …

Analysis Of Strength Of Glass Fibre Composite Leaf Spring Using Finite Element Method, Andoko Andoko, Poppy Puspitasari, Avita Ayu Permanasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Leaf spring, as one of the main components of the suspension system, serves the function of absorbing road shocks and any wheel vibrations, preventing them from being transmitted directly to the vehicle body. Moreover, it can increase the tire traction as well as support the weight of the vehicle and various kinds of external forces. Various studies on the use of composite materials for leaf springs have shown that the strength of composite leaf spring is similar to steel leaf spring with the same load carrying capacity. However, the composite leaf spring has the added advantage of being more lightweight. …

Factors Affecting The Surface Roughness In Sinking Edm Process, Ahmad Atif Fikri, Maftuchin Romlie, Aminnudin Aminnudin

Journal of Mechanical Engineering Science and Technology (JMEST)

The purpose of this study is to gain insights into the surface quality (smoothness) of sinking EDM machining products. Among other non-conventional machining processes, Electrical Discharge Machining (EDM) is the most commonly used process. EDM is a machining process that uses electric sparks created between a workpiece and a tool (electrode). As a manufacturing process, EDM is used for workpieces which have intricate contours and precise dimensions, and works by using electric discharges (sparks) applied in a rapid series of repetitive electrical discharges between the two electrodes, separated by a dielectric fluid, and subject to an electric voltage. Since the …

The Strength Of Moulding Sand Consisting Of A Mixture Of Bentonite, Tapioca Flour, And Sago Flour As A New Binder Formula To Improve The Quality Of Al-Si Cast Alloy, Andoko Andoko, Riana Nurmalasari, M. Alfian Mizar, Retno Wulandari, Poppy Puspitasari, Avita Ayu Permanasari

Journal of Mechanical Engineering Science and Technology (JMEST)

The major factors determining the quality of sand casting products are the base sand and the composition of the sand mould and the binding material. In the foundry industry, the most commonly used binder for creating sand moulds is bentonite. However, the price of bentonite is likely to keep rising. This study aimed at discovering a new binder formula associated with the effect of binder composition i.e. bentonite, tapioca flour, and sago flour on the basis of its mechanical and physical properties. The new formula was expected to be a better binder in the production of sand moulds, resulting in …

Analysis Of Biodegradation Of Bioplastics Made Of Cassava Starch, Nanang Eko Wahyuningtiyas, Heru Suryanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Environmental pollution due to plastic waste taking too long to decompose has become a global problem. There have been numerous solutions proposed, one of which is the use of bioplastics. The use of cassava starch as the main ingredient in the manufacture of bioplastics shows great potential, since Indonesia has a diverse range of starch-producing plants. The aim of the present study is to analyse the effect of glycerol on microbial degradation. This experimental research investigated the use of cassava flour mixed with glycerol plasticizer at various concentrations (0, 2, 2.5, 3%) in the synthesis of bioplastics. The aspects studied …

Effect Of Magnetic Field On Diesel Engine Power Fuelled With Jatropha-Diesel Oil, Sukarni Sukarni, Partono Partono, Deni Krisdianto, Retno Wulandari

Journal of Mechanical Engineering Science and Technology (JMEST)

Jatropha oil has characteristics very close to the diesel fuel, so it has good prospects as a substitute or as a mixture of diesel fuel. Previous research showed that jatropha oil usage in diesel engines caused power to decrease. It was probably owing to the higher viscosity of the Jatropha oil compared to that of diesel oil. Installing the magnetic field in the fuel line of a diesel engine fueled with jatropha-diesel oil is expected to reduce the viscosity of jatropha-diesel oil mixture, hence improve the combustion reaction process. This research aims to know the influence of the magnetic field …

Utilization Of Carbon Nanotubes In Electromagnetic Wave Detectors, Muhammad Hanis Zakariah, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Direct detection of hydrocarbon by an active source using electromagnetic (EM) energy termed seabed logging (SBL) has shown very promising results. However, currently available electromagnetic wave technology has a number of challenges include sensitivity and frequency matching. This paper presents development of the carbon nanotubes (CNTs) as electromagnetic wave detector due to outstanding properties of carbon nanotubes. They are currently one of the desired materials for advanced technologies. Two types of detectors were developed in this work, carbon nanotube-based (D1) and without nanotubebased (D2) detectors. Various configuration and arrangement for each type of detector were investigated to determine the one …

Glucose Recovery From Different Corn Stover Fractions Using Dilute Acid And Alkaline Pretreatment Techniques, D. Aboagye, N. Banadda, R. Kambugu, Jeffrey Seay, N. Kiggundu, A. Zziwa, I. Kabenge

Chemical and Materials Engineering Faculty Publications

Background: Limited availability of corn stover due to the competing uses (organic manure, animal feed, bio-materials, and bioenergy) presents a major concern for its future in the bio-economy. Furthermore, biomass research has exhibited different results due to the differences in the supply of enzymes and dissimilar analytical methods. The effect of the two leading pretreatment techniques (dilute acid and alkaline) on glucose yield from three corn stover fractions (cob, stalk, and leaf) sourced from a single harvest in Uganda were studied at temperatures 100, 120, 140, and 160 °C over reaction times of 5, 10, 30, and 60 min.

Results: …

Suppression Of Magnetism In Ba5Alir2O11: Interplay Of Hund's Coupling, Molecular Orbitals, And Spin-Orbit Interaction, Sergey V. Streltsov, Gang Cao, Daniel I. Khomskii

Center for Advanced Materials Faculty Publications

The electronic and magnetic properties of Ba₅AlIr₂O₁₁ containing Ir-Ir dimers are investigated using the generalized gradient approximation (GGA) and GGA + spin-orbit coupling (SOC) calculations. We found that the strong suppression of the magnetic moment in this compound recently found by Terzic et al. [Phys. Rev. B 91, 235147 (2015)] is not due to charge ordering but is related to the joint effect of the spin-orbit interaction and strong covalency, resulting in the formation of metal-metal bonds. They conspire and act against the intraatomic Hund's rule exchange interaction to reduce total magnetic moment of the …

An Evaluation Of The Efficiency Of Compartmented Alginate Fibres Encapsulating Rejuvenator As Asphalt Pavement Healing System, Amir Tabakovic, Luke Schuyffel, Aleksandar Karac, Erik Schlangen

Articles

This paper explores the potential methods for evaluating a healing system for asphalt pavements. The healing system under investigation involves compartmented calcium-alginate fibres encapsulating an asphalt binder healing agent (rejuvenator). This system presents a novel method of incorporating rejuvenators into asphalt pavement mixtures. The compartmented fibres are used to distribute the rejuvenator throughout the pavement mixture, thereby overcoming some of the problems associated with alternate asphalt pavement healing methods, i.e., spherical capsules and hollow fibres. The asphalt healing efficiency methods to be evaluated in this paper include: (i) standard test methods for asphalt pavements, such as the Indirect Tensile Strength …

Real-Time Sensing Of Single-Ligand Delivery With Nanoaperture-Integrated Microfluidic Devices, W. Elliott Martin, Ning Ge, Bernadeta R. Srijanto, Emily Furnish, C. Patrick Collier, Christine A. Trinkle, Christopher I. Richards

Chemistry Faculty Publications

The measurement of biological events on the surface of live cells at the single-molecule level is complicated by several factors including high protein densities that are incompatible with single-molecule imaging, cellular autofluorescence, and protein mobility on the cell surface. Here, we fabricated a device composed of an array of nanoscale apertures coupled with a microfluidic delivery system to quantify single-ligand interactions with proteins on the cell surface. We cultured live cells directly on the device and isolated individual epidermal growth factor receptors (EGFRs) in the apertures while delivering fluorescently labeled epidermal growth factor. We observed single ligands binding to EGFRs, …

Ismar / Rmcmr 2017 Abstract Book - Joint Conference Of The International Society Of Magnetic Resonance, The Rocky Mountain Conference On Epr, And The Rocky Mountain Conference On Magnetic Resonance

Rocky Mountain Conference on Magnetic Resonance

Abstracts from the 59th annual meeting of the Rocky Mountain Conference on Magnetic Resonance, hosted jointly with the International Society of Magnetic Resonance and the Rocky Mountain Conference on EPR. Held in Quebec City, Canada, July 23-28, 2017.

Estimating Index Of Refraction For Specular Reflectors Using Passive Polarimetric Hyperspectral Radiance Measurements, Jacob A. Martin, Kevin C. Gross

Faculty Publications

Results of a method of estimating index of refraction from passive, polarimetric hyperspectral imaging radiance measurements are presented. As off-nadir viewing hyperspectral imaging platforms gain prominence, estimating index of refraction, which is invariant to viewing angle, may prove advantageous to estimating the emissivity, which is not. Results show that index of refraction can be retrieved to within 8% rms error for fused silica and sapphire glass targets, while simultaneously estimating object temperature. The accuracy and self-consistency of this technique for estimating index of refraction are shown to compare favorably to the maximum smoothness temperature–emissivity separation algorithm. Additionally, the results show …

Fabricating Ordered 2-D Nano-Structured Arrays Using Nanosphere Lithography, Chenlong Zhang, Sandra Cvetanovic, Joshua M. Pearce

Department of Materials Science and Engineering Publications

Recent advances in the use of plasmonic metamaterials to improve absorption of light in thin-film solar photovoltaic devices has created a demand for a scalable method of patterning large areas with metal nanostructures deposited in an ordered array. This article describes two methods of fabricating ordered 2D nanosphere colloidal films: spin coating and interface coating. The two methods are compared and parameter optimization discussed. The study reveals that:

• For smaller nanosphere sizes, spin coating is more favorable, while for larger nanospheres, the angled interface coating provides more coverage and uniformity.

• A surfactant-free approach for interface coating is developed …

Comparison Between Single Loading–Unloading Indentation And Continuous Stiffness Indentation, Yun-Fei Jia, Yuan-Yuan Cui, Fu-Zhen Xuan, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Experiments are performed on fused silica, Si, and duplex stainless steel to examine whether the CSM (continuous stiffness indentation) method will provide approximately the “same” results of contact modulus and indentation hardness as those measured from the quasi-static single loading–unloading indentation. The experimental results show that the elastic modulus measured by the CSM method is compatible with that by the quasi-static loading–unloading method for hard materials, while there exists a percentage difference of ∼21.3% between the smallest value and the largest vale of the measured indentation hardnesses from the CSM method for fused silica and a percentage difference of ∼15.3% …

Graphite And Graphene-Oxide Based Pgm-Free Model Catalysts For The Oxygen Reduction Reaction, Joseph Henry Dumont

Nanoscience and Microsystems ETDs

The world currently relies heavily on fossil fuels such as coal, oil, and natural gas for its energy. Fossil fuels are non-renewable, that is, they draw on finite resources that will eventually dwindle, becoming too expensive or too environmentally damaging to retrieve. One alternative source of energy are fuel cells, electrochemical devices that convert chemical energy to cleanly and efficiently produce electricity. They can be used in a wide range of applications, including transportation, stationary, portable and emergency power sources. Their development has been slowed by the high cost of PGM electrocatalysts needed at both electrodes as well as sluggish …

Novel Durable Antimicrobial Ceramic With Embedded Copper Sub-Microparticles For A Steady-State Release Of Copper Ions, Adam J. Drelich, Jessie Miller, Robert Donofrio, Jaroslaw Drelich

Michigan Tech Publications, Part 1

Using pottery clay, porous ceramic stones were molded and then decorated with copper sub-microparticles inside the pores. Copper added antimicrobial functionality to the clay-based ceramic and showed ability in disinfecting water. Populations of both Staphylococcus aureus and Klebsiella pneumoniae in contaminated water were reduced by >99.9% in 3 h when exposed to an antimicrobial stone. This antimicrobial performance is attributed to a slow release of copper into water at both room and elevated temperatures. Copper is leached by water to produce ion concentrations in water at a level of 0.05–0.20 ppm after 24 to 72 h immersion tests. This concentration …

Study On Physical, Optical And Luminescence Of Er3+ In K2o-Cao-B2o3 Glasses For Photonic Application, N Wantana, S Insiripong, Y Ruangthaweep, J Kaewkhao

Journal of Metals, Materials and Minerals

In this work, potassium calcium borate glasses doped with of Er3+ ions (KCaBEr) have been prepared by a melt quenching technique. The glass physical, optical and luminescence properties have been investigated as a function of Er2O3 concentration. Density was measured by Archimedes' principle and brought to calculate the molar volume. The optical absorption spectra were measured in the ultraviolet, visible light and near-infrared regions. The emission and excitation spectra represents the strong emission from glass sample. All results indicate the potential to use KCaBEr glass in the photonic applications such as laser and optical amplification.

Investigating Rheological, Morphological And Mechanical Properties Of Pbs/Pbat Blends, A Boonprasertpoh, D Pentrakoon, J Junkasem

Journal of Metals, Materials and Minerals

Morphological, rheological and mechanical properties of various biodegradable poly(butylene succinate) (PBS)/poly(butylene adipate-co-terephthalate) (PBAT) blends via conventional melt blending technique are studied. The morphology, rheology, and tensile properties of the PBS/PBAT blends were observed by scanning electron microscope (SEM), rotational rheometer, and universal testing machine, respectively. The SEM micrographs of the PBS/PBAT blends reveal an occurrence of phase separation indicating by a presence of spherical particles/cavities for a range of 10 to 30 wt% (i.e. PBS90-PBS70), and 70 to 90 wt% (i.e. PBS30-PBS10) PBT content and co-continuous structure for a range of 40 to 60 wt% (i.e. PBS60PBS40) PBAT content. The …

Mechanical And Thermal Properties Of Eucalyptus Fiber Composites From Blend Between Biodegradable Poly(Butylene Succinate) And Recycled Pet, N Hongsriphan, P Dangmanee, M Mankrut, W Jantaraka

Journal of Metals, Materials and Minerals

The goal of this study was to enhance rigidity and to reduce cost of the PBS-based composites by blending with recycled poly(ethylene terephthalate) (r-PET) and Eucalyptus fibers. Prior compounding, Eucalyptus fibers were treated with alkali and γ-methacryloxypropyl trimethoxysilane (MPS) solution for compatibility improvement. PBS and r-PET were melt blended in a twin-screw extruder with the weight ratio of 95/5, 90/10, and 80/20 wt%, and compounded with MPS treated Eucalyptus fibers using fiber loading of 3, 5, and 7 wt% of composites. Samples were characterized by tensile test, notched Izod impact test, SEM, NMR, and DSC. It was found that r-PET …

Strengthening Of The Astm-356 Alloy With Silicon Carbide Particles, Jaime Hinojosa-Torres, Diego Sánchez-García, Andrés Herrera-Vázquez, Jose Luis Velázquez-Ortega

Journal of Metals, Materials and Minerals

Extensive research has been done in recent years in composites of metallic matrix in order to get better melting practices, mechanical properties and structure. In this work, steel metal mould was previously preheated to three different temperatures. The ASTM-356 alloy was melted and heated to 993 K. For the purpose of reinforcing, silicon carbide particles (mesh: 325, 400) were introduced into the melted alloy then stirred. For each obtained solid its solidification time was recorded. Cylindrical specimens were tested in a tension test machine in order to obtain the ultimate tensile strength (UTS) and fracture toughness (KIc) values. Hardness measurements …

Antireflective Surface Of Nanostructures Fabricated By Cf4 Plasma Etching, W Somrang, S Denchitcharoen, P Eiamchai, M Horprathum, C Chananonnawathorn

Journal of Metals, Materials and Minerals

In this research, the nanostructures surface were fabricated by the CF4 plasma etching process on the SiO2-based substrates for antireflection applications. The nickel films were firstly deposited on the substrates by the sputtering system. The prepared Ni layers were then annealed at 500°C for 1 minute in order to promote dewetting process to be used as metal masks. During the etching process, CF4 etching condition was performed for 15-60 min to create the SiO2 nanopillars. After the etching process, the samples were immersed in nitric acid for 5 min to remove the nickel masks. The SiO2 nanopillars without Ni were …

Computationally Connecting Organic Photovoltaic Performance To Atomistic Arrangements And Bulk Morphology, Matthew L. Jones, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

Rationally designing roll-to-roll printed organic photovoltaics requires a fundamental understanding of active layer morphologies optimized for charge separation and transport, and which ingredients can be used to self-assemble those morphologies. In this review article we discuss advances in three areas of computational modeling that provide insight into active layer morphology and the charge transport properties that result. We explain the computational bottlenecks prohibiting atomistically-detailed simulations of device-scale active layers and the coarse-graining and hardware acceleration strategies for overcoming them. We review coarse-grained simulations of organic photovoltaic active layers and show that high throughput simulations of experimentally-relevant length scales are now …

Synthesis,Structure And Properties Of Ruthenium Polypyridyl Metalloligand Based Metal-Organic Frameworks, Mamatha Polapally

Masters Theses & Specialist Projects

Metal-organic frameworks (MOFs) have been extensively studied because of their amazing applications in gas storage, purification, photocatalysis, chemical sensing, and imaging techniques. Ruthenium polypyridyl complexes have been broadly considered as photosensitizers for the conversion of solar energy and photoelectronic materials. With this aspect, we have synthesized three new ruthenium polypyridyl based MOFs ([Ru(H2bpc)Cu(bpc)(Hbpc)2(H2O)]·5H2O (1), [Ru(H2bpc)(Fe(bpc)(Hbpc)2(H2O)2]·6H2O (2) and [Ru(H2bpc)Ni(bpc)(Hbpc)2(H2O)2]·6H2O (3)) from ruthenium(III) chloride, bpc (2,2’- bipyridine-4,4’-dicarboxylic acid) ligand, and 3d M(II) metal ions (M(II)= Cu(II), Fe(II), Ni(II)). These MOFs were synthesized under hydro or solvothermal conditions by using water, ethanol or methanol as solvents. The crystal structures of the new compounds …

Eu3+ Doped Borosilicate Glass For Solid-State Luminescence Material, S Rakpanich, N Wantana, Y Ruangthaweep, J Kaewkhao

Journal of Metals, Materials and Minerals

The Eu3+ doped potassium borosilicate (KBSi:Eu3+) glasses were prepared by the melt quenching technique. The physical, optical and luminescence properties of glasses were investigated. Glass density and molar volume increase with increasing of Eu2O3 concentration. Glasses absorbed photons in the visible light and near infrared region. Since 394 nm excitation, glasses emitted the strong light with 613 nm in milliseconds of lifetime. CIE 1931 chromaticity diagram exhibits that emission from KBSi:Eu3+ glass is reddish-orange light. In summary, this KBSiEu glass performs the interesting property for using in the photonic devices such as solid-state laser and LEDs.

Elastic Properties Of Superconductors And Materials With Weakly Correlated Spins, Christian Binek

Christian Binek Publications

It is shown that in the ergodic regime, the temperature dependence of Young’s modulus is solely determined by the magnetic properties of a material. For the large class of materials with paramagnetic or diamagnetic response, simple functional forms of the temperature derivative of Young’s modulus are derived and compared with experimental data and empirical results. Superconducting materials in the Meissner phase are ideal diamagnets. As such, they display remarkable elastic properties. Constant diamagnetic susceptibility gives rise to a temperature independent elastic modulus for ceramic and single crystalline superconductors alike. The thermodynamic approach established in this report, paves the way to …

Solvent Based 3d Printing Of Biopolymer/Bioactive Glass Composite And Hydrogel For Tissue Engineering Applications, Krishna Kolan, Yong Liu, Jakeb Baldridge, Caroline Murphy, Julie A. Semon, D. E. Day, Ming-Chuan Leu

Biological Sciences Faculty Research & Creative Works

Three-dimensional (3D) bioprinting is an emerging technology in which scaffolding materials and cell-laden hydrogels may be deposited in a pre-determined fashion to create 3D porous constructs. A major challenge in 3D bioprinting is the slow degradation of melt deposited biopolymer. In this paper, we describe a new method for printing poly-caprolactone (PCL)/bioactive borate glass composite as a scaffolding material and Pluronic F127 hydrogel as a cell suspension medium. Bioactive borate glass was added to a mixture of PCL and organic solvent to make an extrudable paste using one syringe while hydrogel was extruded and deposited in between the PCL/borate glass …

Anion Exchange Membrane Capacitive Deionization Cells, Ayokunle Omosebi, Xin Gao, Nicolas Holubowitch, Zhiao Li, James Landon, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The electrochemical response of capacitive deionization (CDI) employing a single anion exchange membrane (AEM-CDI) is contrasted to conventional two-membrane CDI (MCDI) formed with complementary anion and cation exchange membranes. Pristine activated carbon cloth electrodes that possess native positive surface charge in solution were used as both anode (positive electrode) and cathode (negative electrode) in these cells. In a separate set of tests to investigate the impact of surface charge modification on deionization responses, the single and dual membrane cells were formed with asymmetric electrodes (AEM-aCDI and aMCDI) consisting of nitric acid oxidized electrodes that possess negative surface charge as the …

Homogenization Of Plastic Deformation In Heterogeneous Lamella Structures, Rui Yuan, Irene J. Beyerlein, Caizhi Zhou

Materials Science and Engineering Faculty Research & Creative Works

It has been shown that unlike its constituent nanocrystalline (NC) phase, a heterogeneous lamella (HL) composite comprising NC and coarse-grain layers exhibits greatly improved ductility. To understand the origin of this enhancement, we present a 3D discrete dislocation, crystal plasticity finite element model to study the development of strains across this microstructure. Here we show that the HL structure homogenizes the plastic strains in the NC layer, weakening the effect of strain concentrations. These findings can provide valuable insight into the effects of material length scales on material instabilities, which is needed to design heterogeneous structures with superior properties.