Materials Science and Engineering Commons^™

Synthesis, Characterization, And Electronic Properties Of Novel 2d Materials : Transition Metal Dichalcogenides And Phosphorene., George Anderson

Electronic Theses and Dissertations

Scaling electronic devices has become paramount. The current work builds upon scaling efforts by developing novel synthesis methods and next generation sensing devices based on 2D materials. A new combination method utilizing thermal evaporation and chemical vapor deposition was developed and analyzed to show the possibilities of Transition Metal Dichalcogenide monolayers and heterostructures. The materials produced from the above process showed high degrees of compositional control in both spatial dimensions and chemical structure. Characterization shows controlled fabrication of heterostructures, which may pave the way for future band gap engineering possibilities. In addition, Phosphorene based field effect transistors, photodetectors, and gas …

Molecule Assisted Hydrothermal Synthesis Of Zinc Oxide Nanomaterials With Possible Applicatios In Solar Energy, Austin Major Shearin

Graduate Theses/Dissertations

A molecule assisted hydrothermal synthesis of zinc oxide nanomaterials with L-lysine has been performed to understand the interaction between the biomolecule and the zinc oxide structures during synthesis. The molecule alters the growth kinetics during the formation of the nanomaterials in the hydrothermal reaction. This alters the size and shape of the materials as seen in the scanning electron microscope. X-ray diffraction results confirm the hexagonal Wurtzite structure that zinc oxide forms and indicates no other phases in the nanomaterial. The lattice parameters are not altered, but the atomic percentage of zinc to oxygen within the structure changes as analyzed …

High-Pressure Properties Of Several Narrow Bandgap Semiconductors From First-Principles Calculations, Andrew Michael Alvarado

UNLV Theses, Dissertations, Professional Papers, and Capstones

The electronic, thermodynamic, and structural properties of three semiconducting materials, ZnO, InN, and PbS, at high pressure are investigated utilizing first-principles calculations based on density function theory. The first two systems, ZnO and InN, crystalize as hexagonal structures at ambient conditions and transition to a cubic structure at higher pressures. The last system, PbS, is cubic at ambient conditions, but transitions to an orthorhombic structure at higher pressure. At ambient conditions, these materials are well known semiconductors with vast amount of research and a variety of wide ranging applications in electrical devices. However, there is a lack of understanding of …

Effect Of Thermal Treatment On High Temperature Deformation Of Alloy Ep-~823, Martin Milburn Lewis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this research topic is to determine mechanical properties of Alloy EP-823 and to provide a mechanistic understanding of its sensitivity to both thermal treatment and performance temperature. EP-823 is a leading target material for accelerator-driven waste transmutation applications. Overall, the tensile test results of Alloy EP-823 indicated a general trend of decreasing mechanical performance with an increase in tempering time. An increase in tempering time had a statistically significant inverse relationship with ultimate tensile strength (UTS) and yield strength (YS). An increase in tempering time did not have a significant effect on elongation and reduction in area. …

Impedance Spectroscopy Studies Of Yttria Stabilized Zirconia Under Extreme Conditions, Quinlan Blaine Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttria Stabilized Zirconia (YSZ) is of interest for many industries. Varying amounts of Yttria (Y2O3) can be doped into Zirconia (ZrO2) to create materials with specific characteristics. For instance, 3mol% YSZ (3YSZ) is known to be a super hard material and is used as a coating on drill tips and as an abrasive. Eight mol% YSZ (8YSZ) is commonly used as a solid electrolyte in Solid Oxide Fuel Cells because of its good ionic conducting abilities and stability at high temperatures. In this thesis project, a novel experimental setup was created and used to study the ionic conductivity of (3 …

Mechanical And Electrical Characterization Of Hybrid Carbon Nanotube Sheet-Graphene Nanocomposites For Sensing Applications, Jiukun Li

Doctoral Dissertations and Master's Theses

The unique mechanical and electrical properties of carbon nanotubes and graphitic structures have drawn extensive attention from researchers over the past two decades. The electro-mechanical behavior of these structures and their composites, in which electrical resistance changes when mechanical deformation is applied facilitates their use in sensing applications.

In this work, carbon nanotube sheet- epoxy nanocomposites with the matrix modified with various contents of coarse and fine graphene nanoplatelets are fabricated. The addition of a secondary filler results in improvements of both electrical and mechanical properties. In addition, with the inclusion of the second filler, change in resistivity with mechanical …

Phase-Field Models For Simulating Physical Vapor Deposition And Microstructure Evolution Of Thin Films, James Stewart Jr.

Graduate Theses and Dissertations

The focus of this research is to develop, implement, and utilize phase-field models to study microstructure evolution in thin films during physical vapor deposition (PVD). There are four main goals to this dissertation. First, a phase-field model is developed to simulate PVD of a single-phase polycrystalline material by coupling previous modeling efforts on deposition of single-phase materials and grain evolution in polycrystalline materials. Second, a phase-field model is developed to simulate PVD of a polymorphic material by coupling previous modeling efforts on PVD of a single-phase material, evolution in multiphase materials, and phase nucleation. Third, a novel free energy functional …

Thermal Property Measurement Of Thin Fibers By Complementary Methods, Troy Robert Munro

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Thin fibers are prevalent in many engineering materials. Measuring how well heat transfers in such small fibers can be difficult to determine, and previous methods have led to erroneous results. This dissertation details three proposed methods to improve the measurement of the thermal conductivity, thermal diffusivity, and volumetric heat capacity of thin fibers. Of particular interest is natural and synthetic spider silks because previously published values of the natural silk thermal conductivity was similar to copper, an excellent thermal conductor.

The three methods developed are the improved transient electrothermal technique (which was redeveloped to include radiation and convection heat losses …

Synthesis Of Structurally Ordered Platinum-Iron Catalysts With Enhanced Oxygen Reduction Reaction Activity, Ye-Zheng Cai, Ming-Chuan Luo, Fang-Hui Wang, Zhao-Nan Sun, Hong Zhu

Journal of Electrochemistry

To improve oxygen reduction reaction catalytic activity of the precious metals platinum for fuel cell, the precursors of carbon-supported structurally disordered platinum-iron alloy (D-Pt₃Fe/C and D-PtFe/C) catalysts with different compositions were synthesized via a modified polyol reduction method. Then, by optimizing the annealing conditions in the inert gas, we turned the structurally disordered platinum-iron alloy to the structurally ordered platinum-iron alloy (O-Pt₃Fe/C and O-PtFe/C) catalysts. The structural characterizations of the as-prepared catalysts were performed by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), and X-ray photoelectron spectroscopy (XPS). The results …

Special Issue: Electrocatalyst And Electrocatalysis In Fuel Cells Preface, Zi-Dong Wei

Journal of Electrochemistry

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Recent Progress In Non-Precious Metal Oxygen Reduction Reaction Catalysts With An Encapsulation Structure, Mei-Ling Xiao, Jian-Bing Zhu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing

Journal of Electrochemistry

Platinum-based materials, the state-of-the-art catalysts for fuel cells, suffer from prohibitive costs, limited resources and insufficient durability. Accordingly, tremendous efforts were made in searching for efficient, durable and inexpensive alternatives to precious-metal electrocatalysts for the oxygen reduction reaction (ORR). Transition-metals (Fe, Co)/nitrogen co-doped hybrids, heteroatom (N, P, S, F, et al) doped carbons and composites with transition-metals encapsulated in graphitic layers are reported as the most efficient non-precious metal ORR catalysts. Among the various non-precious metal ORR catalysts, transition-metals encased in graphitic layer catalysts are a novel type of catalysts for ORR with high activity and durability, and thus, the …

Mini-Review: Possible Applications Of Scanning Electrochemical Microscopy (Secm) In Characterizations Of Oxygen Reduction Reaction And Oxygen Evolution Reaction, Xing-Xing Chen

Journal of Electrochemistry

Scanning electrochemical microscopy (SECM) has been proved to be a unique technique for combinatorial screening of localized phenomena for different electrocatalysts potentially used in new energy conversion and storage systems. This mini-review provides a brief summary of different SECM working modes, such as direct mode, feedback mode, generation-collection mode, redox competition mode and noise mode, which are especially applied for characterizing the oxygen reactions. Particularly, a series of important development in SECM screening of electrocatalysts for oxygen reduction reaction and oxygen evolution reaction from the author and W. Schuhmann’s group in Germany has been highlighted and overviewed. Finally, some prospects …

Syntheses Of Carbon Paper Supported High-Index Faceted Pt Nanoparticles And Their Performance In Direct Formic Acid Fuel Cells, Long Huang, Mei Zhan, Yu-Cheng Wang, Yan-Fen Lin, Shuo Liu, Ting Yuan, Hui Yang, Shi-Gang Sun

Journal of Electrochemistry

Direct formic acid fuel fuels (DFAFCs) are promising energy source for portable electronic devices. Palladium (Pd) is more active than platinum (Pt) for the formic acid electrooxidation. However, the stability of Pd is much poorer than that of Pt. Unfortunately, the ultra-low natural abundance of the Pt makes it extremely expensive and limits its application as a fuel cell catalyst. Boosting both the activity and stability of Pt nanoparticles to enhance their efficiency is urgent. As previous works illustrated, nanoparticles enclosed with high-index facets usually bare a higher activity toward fuel cell related reactions than those nanoparticles with low-index facet. …

Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Shang Li, Fen Zhou, Lei Chen, Mu Pan

Journal of Electrochemistry

It is an urgent need to reduce the Pt loading in electrode for practical fuel cell applications worldwide. Herein, we theoretically investigate the oxygen distribution, generated current, and minimum Pt loading of Pt/C electrode for practical applications based on kinetic model of oxygen reduction reaction. The results indicate that with increasing electrode effective thickness to 40 mm, serious concentration polarization is expected for Pt/C electrode. To generate a power density of 1.4 W⋅cm^-2 (2.1A⋅cm^-2@0.67 V) for fuel cell, the cathode catalyst layer thickness in PEMFC should be as thin as 3 mm. The minimum Pt loading will …

Multi-Scaled Carbon Supported Platinum As A Stable Electrocatalyst For Oxygen Reduction Reaction, Yu-Ping Li, Lu-Hua Jiang, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

The stability of carbon supports is essential for electrocatalysts of fuel cells. Herein, the mesoporous carbon with the high graphitic degree (highly graphitic mesoporous carbon, HGMC) was synthesized by using resorcinol as the carbon precursor, SiO₂ as the templates and urea as the reducing agent. The as-prepared HGMC was characterized by XRD, Raman spectroscopy, TEM, N2 adsorption. The stability of HGMC was evaluated by mimicking the start-up/shut-down conditions of fuel cells in a three-electrode system referring to the NREL standard. The obtained HGMC is of moderate surface area (187.4 m²•g^-1) and is chemically stable under …

Recycling Mf Solid Waste Into Mesoporous Nitrogen-Doped Carbon With Iron Carbide Complex In Graphitic Layers As An Efficient Catalyst For Oxygen Reduction Reaction, Can-Yun Zhao, Lin Huang, Yong You, Ying-Fang Yao, Xiao-Gang Su, Hong Wan, Jian-Guo Liu, Cong-Ping Wu

Journal of Electrochemistry

Nitrogen-doped carbon materials with iron ions are known as catalytic growth agents for the oxygen reduction reaction (ORR) in fuel cells, but the design and synthesis of high-performance and low-cost catalysts still remain a significant challenge. Herein, we present a cost-effective approach to dispose of MF solid waste as the precursor for the synthesis of MCFes catalyst with the favorable structure features such as the high specific surface area, abundant active sites and suitable pore structure. The results showed that the MCFe-10/10/2 had specific surface area as high as 780.7 m²•g^-1 and high efficient catalytic activity comparable …

Recent Progresses In Molybdenum-Based Electrocatalysts For The Hydrogen Evolution Reaction, Ze-Xing Wu, Jie Wang, Jun-Po Guo, Jing Zhu, De-Li Wang

Journal of Electrochemistry

Electrochemical catalytic production of hydrogen has been considered as a promising and sustainable strategy for clean and renewable energy technologies. Molybdenum-based non noble metal catalysts for the hydrogen evolution reaction have attracted extensive attention due to its effective catalytic performance. In this review, the recent progresses in molybdenum-carbide, phosphide, nitride and sulfide electrocatalysts are presented. In addition, the strategies to improve the catalytic performance are analyzed and the prospects for the future development trends are expected.

Nitrogen, Fluorine Co-Doped Silk-Derived Carbon For Electrochemical Oxygen Reduction With High Performance In Alkaline Solution, Fang-Fang Liu, Hong-Liang Peng, Shi-Jun Liao

Journal of Electrochemistry

A high-performance, doped carbon-based catalyst was synthesized by pyrolyzing hydrothermally treated silkworm cocoon. The effects of preparation conditions and fluorine promotion on various catalysts’ performance were investigated. The catalyst prepared under optimal conditions and doped with nitrogen and fluorine possessed the high specific surface area of more than 1000 m^2⋅g^-1 and contained 3.5 and 7.3% (by mass, the same below) N and F, respectively. The activity of the catalyst toward oxygen reduction reaction in an alkaline medium was comparable to that of commercial Pt/C, showing both superior tolerance to methanol poisoning and better durability. Doping with fluorine …

Rambling Between "Zhong Yong" And "Catalysis", Zi-Dong Wei

Journal of Electrochemistry

“Zhong Yong” represents a traditional Chinese wisdom, which was first proposed by Confucius and continuously richened by his followers. “Zhong Yong” pursues the balances among all kinds of contradictions, and insists that neither “too much” nor “not enough” is good. For a successful catalyst, on which the adsorption of reactants must be not so strong and not so weak either. On this point of view, there are the same pursuits for “Zhong Yong” and catalysis. In this paper, the author starts his story with a conversation between Confucius and his student, followed by 3 interesting stories happening in the ancient …

Preparation And Performance Of 3d Graphene Type Porous Carbon Employing Nano Fe(Oh)3 As Template For Oxygen Reduction Catalyst, Chong-Yun Sun, Zhong-Fang Li, Xue-Wei Lu, Xi-Zhan Zhong, Yu-Rong Liu

Journal of Electrochemistry

The 3D graphene type porous carbon was prepared using coal tar pitch as carbon source and nano Fe(OH)₃ as template. Optimal conditions for the catalytic oxygen reduction performance were determined as: the mass ratio of coal tar, nano Fe(OH)₃ and KOH is 6:8:4; the pyrolysis temperature is 800 ^oC. SEM images show that the products have uniformly porous structure. TEM images demonstrate that the products are porous with foam shapes. HRTEM images further indicate that the products have formed several-layers 3D graphene structure, which are also supported by XRD and Raman data, and the pore size mainly …

Application Of Web Published Virtual Instruments In Delivering Engineering Instructions And Performing Experimental Research, Shahnam Navaee

GS4 Student Scholars Symposium

In this presentation the special utility of the LabVIEW Virtual Instruments published as HTML files is documented and discussed. The Virtual Instruments (LabVIEW programs) created using the software's web publishing tool can be used to complement the effectiveness of the classroom instructions and extend the reach of engineering researchers in more effectively conducting laboratory and field experimentation. The Virtual Instruments (VIs) created as web documents can be placed on a web-server and made available to users at remote locations. These files can enhance the collaborations and interactions among individuals at these stations. For example, the created VIs for a course …

Emotion Recognition Using Fuzzy Clustering Analysis, Tejal Udhan

GS4 Student Scholars Symposium

This research project investigates using fuzzy clustering algorithms for emotion recognition. Emotion recognition has gained significant attention in recent years in applications such as artificial intelligence, human-computer interaction, speech and voice recognition. The ability of a computer or machine to understand human emotion and respond to users in a more human way can lead to significant advances in conversational speech recognition systems, improved quality of life in persons with speech disorders, such as Parkinson’s disease and even in voice response systems, such as Google Voice or Apple’s Siri. Experimental results in this area can inform discovery and innovation of machine …

Particle Boards Created From Modified Lignin, Robbie Kazen

GS4 Student Scholars Symposium

My name is Robert Kazen, a student directed under Dr. Rafael Quirino currently working on the Lignin Modification project. The research project involves the isolation of lignin from black liquor, a byproduct produced by the paper pulping industry. Isolated chemically the lignin was then modified using two methods, (1) acrylation acid and (2) transesterification with tung oil modifications. The black liquor obtained was sent by the Arizona Chemical and Herty Advanced Materials Development Center. Currently the tung oil modification gives the most valuable product physically and its products will be mainly used for particle board creation and testing. The tung …

Warning Systems Evaluation For Overhead Clearance Detection, Clayton Rogers

GS4 Student Scholars Symposium

The accurate detection of road vehicle heights is a need that arises in departments of transportation across the nation. Usually, this dimension is required to solve various transportation issues. In particular, numerous bridges in the state of Georgia have been affected by repetitive crashes of tall vehicles against their structural elements. As an example, a recent inspection report of the Houlihan Bridge over the Savannah River documents damages resulting from numerous hits by overheight vehicles. This case emphasizes the urgency of finding preventive measures. To address this issue, a number of solutions are investigated. The known methods of vehicle height …

Autonomous Methods In The Application Of Simple Swarm Capabilities, Joseph Watt Iii

GS4 Student Scholars Symposium

Swarm technology is a relatively new aspect to the drone industry. It involves multiple drones being able to communicate with each other and relay this back to the user. From this standpoint one operator can control all of them at once while only giving directions to one or more. This involves the use of different autonomous algorithms, similar to autopilot where programs fly the plane, that relay to one another on what adjustments to make or where to go. This idea is very useful in search and rescue operations where it might be too dangerous to insert a human. Also …

Measuring Frequency Availability For Cognitive Radio Networks By Means Of Adaptive Threshold, Isaac Cushman

GS4 Student Scholars Symposium

Radio Frequency spectrums designated by the FCC broadcast almost all mediums of communication, in both licensed and unlicensed bands, within the United States. As technology rapidly grows however, the availability of open frequencies will quickly decrease. Our goal is to design and experimentally test a system that allows for secondary users to access frequency bands that are not currently being optimally used by the primary users and also determine the effects of mobility on the ability for a sensor to accurately find frequencies by determining an appropriate power level for communication. We set up experimental scenarios in order to test …

Fabrication Of Nano-Scale Metal Organic Framework (Mof) Loaded Nanofibrous Membrane For Enhanced Gas Adsorption Performance, Wahiduz Zaman

GS4 Student Scholars Symposium

Nitrogen storage capacity was investigated on a highly efficient adsorbent nanoparticle called Metal Organic Framework (MOF). A copper-based MOF called MOF-199 has been synthesized from subsequent reaction of Copper nitrate (10 wt.%), Trimesic Acid (8 wt.%) and Triethylamine (0.3 wt.%). TEA served as a deprotonating agent to form small particles. The reactants were mixed in a solution of Dimethylformamide (DMF), Ethanol and Deionized water (1:1:1) and vigorously sonicated for an hour at room temperature. This yielded single blue octahedral MOF crystals which were later washed with mother solution and extracted via centrifuge. The MOFªs were later activated for gas adsorption …

Creation And Implementation Of An Underwater-Capable Vr Headset Through The Use Of Additive Manufacturing, Matthew D. Meyers, Nathan Sonnenfeld

Human Factors and Applied Psychology Student Conference

No abstract provided.

A Numerical Approach To Investigate The Influence Of Deformable Blockages On Blood Flow In An Elastic Vessel, Tai-Hsien Wu

Research and Creative Activities Poster Day

In this work, we presented a new numerical approach to study the deformation of blockages and fluid properties in an elastic blood vessel. In computational hemodynamics, only few of the current numerical models considered the elasticity of vessels, and those models were difficult to extend to other topics like the deformation of blockages in elastic blood vessels. In addition, the approach that we employed is especially effective on visualization. A validation for the present method is carried out by comparing the simulation results with a theoretical prediction of the deformation of the pulmonary blood vessel in a steady flow. Subsequently, …

Optimizing Chemical & Rheological Properties Of Rejuvenated Bitumen, Dominic Nguyen, Hamzeh Haghshenas Fatmehsari, Santosh Kommidi, Yong-Rak Kim

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Bitumen has long been a material used in the construction of roadways, yet new pavement only consists of low fractions of recycled materials due to poor compatibility of aged bitumen and new materials. Thus, rejuvenators, chemical additives, have been used in an attempt to re-balance the chemical composition and restore the physical properties of aged bitumen back to its virgin state. A fundamental understanding of how one particular rejuvenator, soybean oil, revitalizes bitumen was investigated using a multi-scale approach.

Fourier-transform infrared spectroscopy (FTIR) was used to determine the changes in chemical properties of pure and rejuvenated virgin and aged samples. …